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公开(公告)号：US07589151B2
公开(公告)日：2009-09-15
申请号：US10591455
申请日：2005-03-04
申请人： Hideo Aoki , Masakazu Ito , Takashi Miura , Masahiro Osuka
发明人： Hideo Aoki , Masakazu Ito , Takashi Miura , Masahiro Osuka
CPC分类号： C08L33/12 , C08F6/22 , C08L51/04 , C08L67/04 , C08L2666/02
摘要： A thermoplastic resin composition comprising a polylactic acid polymer (A), an acrylic polymer (B) containing units of methyl methacrylate monomer, and a graft copolymer (C) obtained by graft-polymerizing a vinyl monomer onto a rubbery polymer, wherein the refractive index, Rc, of the graft copolymer (C) and the total refractive index, Rab, of the polylactic acid polymer (A) and the acrylic polymer (B) satisfy the following formula (1) −0.004≦Rc−Rab≦+0.008 (1).
摘要翻译： 一种包含聚乳酸聚合物（A），含有甲基丙烯酸甲酯单体单元的丙烯酸类聚合物（B）和通过将乙烯基单体接枝聚合到橡胶状聚合物上而获得的接枝共聚物（C）的热塑性树脂组合物，其中折射率 接枝共聚物（C）的Rc和聚乳酸聚合物（A）和丙烯酸类聚合物（B）的总折射率Rab满足下式（1）<β在线配方说明=“ 在线公式“end =”lead“？> - 0.004 <= Rc-Rab <= + 0.008（1）。<？in-line-formula description =”In-line Formulas“end =”tail“？>
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公开(公告)号：US20070276090A1
公开(公告)日：2007-11-29
申请号：US10591455
申请日：2005-03-04
申请人： Hideo Aoki , Masakazu Ito , Takashi Miura , Masahiro Osuka
发明人： Hideo Aoki , Masakazu Ito , Takashi Miura , Masahiro Osuka
CPC分类号： C08L33/12 , C08F6/22 , C08L51/04 , C08L67/04 , C08L2666/02
摘要： A thermoplastic resin composition comprising a polylactic acid polymer (A), an acrylic polymer (B) containing units of methyl methacrylate monomer, and a graft copolymer (C) obtained by graft-polymerizing a vinyl monomer onto a rubbery polymer, wherein the refractive index, Rc, of the graft copolymer (C) and the total refractive index, Rab, of the polylactic acid polymer (A) and the acrylic polymer (B) satisfy the following formula (1). −0.004≦−Rc−Rab≦+0.008 (1)
摘要翻译： 一种包含聚乳酸聚合物（A），含有甲基丙烯酸甲酯单体单元的丙烯酸类聚合物（B）和通过将乙烯基单体接枝聚合到橡胶状聚合物上而获得的接枝共聚物（C）的热塑性树脂组合物，其中折射率 接枝共聚物（C）的Rc和聚乳酸聚合物（A）和丙烯酸类聚合物（B）的总折射率Rab满足下式（1）。 <？in-line-formula description =“In-line Formulas”end =“lead”？> - 0.004 <= - Rc-Rab <= + 0.008（1）<？in-line-formula description =“In-line 公式“end =”tail“？>
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公开(公告)号：US20060217496A1
公开(公告)日：2006-09-28
申请号：US10548444
申请日：2004-03-09
申请人： Takashi Miura , Keiji Nakamura , Mari Sekita , Masahiro Osuka
发明人： Takashi Miura , Keiji Nakamura , Mari Sekita , Masahiro Osuka
CPC分类号： C08L69/00 , C08L51/04 , C08L2666/24
摘要： The present invention provides a thermoplastic resin composition capable of demonstrating impact strength, and high resistance to hydrolysis and heat discoloration without impairing the essential properties of the thermoplastic resin. The present invention provides a thermoplastic resin composition containing: 70 to 99% by mass of thermoplastic resin (A) containing a polycarbonate resin as an essential component; and 1 to 30% by mass of graft copolymer (B) which is a graft copolymer obtained by emulsion graft polymerization of a monomer or monomer mixture containing at least alkyl methacrylate in the presence of a latex containing a butadiene rubber polymer, wherein the amount of the butadiene rubber polymer included is in the range of 55 to 90% by mass, and the graft copolymer (B) is obtained by using 0.05 to 10 parts by mass of sodium alkylphenylether disulfonate with respect to 100 parts by mass of the graft copolymer (B).
摘要翻译： 本发明提供能够显示冲击强度，耐水解性和耐热变色性而不损害热塑性树脂的基本性能的热塑性树脂组合物。 本发明提供一种热塑性树脂组合物，其含有70〜99质量％的含有聚碳酸酯树脂作为必要成分的热塑性树脂（A） 和1〜30质量％的接枝共聚物（B），其是通过在含有丁二烯橡胶聚合物的胶乳存在下，至少含有甲基丙烯酸烷基酯的单体或单体混合物的乳液接枝聚合得到的接枝共聚物，其中， 所含的丁二烯橡胶聚合物的含量为55〜90质量％，相对于100质量份的接枝共聚物，使用0.05〜10质量份的烷基苯基醚二磺酸钠，得到接枝共聚物（B） B）。
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公开(公告)号：US20050014003A1
公开(公告)日：2005-01-20
申请号：US10617664
申请日：2003-07-14
申请人： Seiji Takei , Masahiro Osuka , Hideo Aoki , Mari Sekita , Masaaki Mouri
发明人： Seiji Takei , Masahiro Osuka , Hideo Aoki , Mari Sekita , Masaaki Mouri
CPC分类号： C08F14/26 , C08L23/04 , Y10T428/25 , Y10T428/254 , Y10T428/2998 , C08F2/16 , C08L2666/06
摘要： The present invention provides a thermoplastic resin composition comprising a thermoplastic resin (A), an acrylic polymer (B), a polytetrafluoroethylene-containing powder mixture (C) and a filler (D), the amount of the acrylic polymer (B) being from 0.1 to 400 parts by weight, the amount of the filler (D) being from 1 to 2000 parts by weight, based on 100 parts by weight of the thermoplastic resin (A), and the amount of a polytetrafluoroethylene component in the polytetrafluoroethylene-containing powder mixture (C) is from 0.01 to 400 parts by weight based on 100 parts by weight of the thermoplastic resin (A).
摘要翻译： 本发明提供一种包含热塑性树脂（A），丙烯酸类聚合物（B），含聚四氟乙烯的粉末混合物（C）和填料（D）的热塑性树脂组合物，丙烯酸类聚合物（B）的量来自 相对于热塑性树脂（A）100重量份，含有聚四氟乙烯的聚四氟乙烯成分的含量为0.1〜400重量份，填料（D）的含量为1〜2000重量份 粉末混合物（C）相对于热塑性树脂（A）100重量份为0.01〜400重量份。
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公开(公告)号：US07029750B2
公开(公告)日：2006-04-18
申请号：US10617664
申请日：2003-07-14
申请人： Seiji Takei , Masahiro Osuka , Hideo Aoki , Mari Sekita , Masaaki Mouri
发明人： Seiji Takei , Masahiro Osuka , Hideo Aoki , Mari Sekita , Masaaki Mouri
CPC分类号： C08F14/26 , C08L23/04 , Y10T428/25 , Y10T428/254 , Y10T428/2998 , C08F2/16 , C08L2666/06
摘要： The present invention provides a thermoplastic resin composition comprising a thermoplastic resin (A), an acrylic polymer (B), a polytetrafluoroethylene-containing powder mixture (C) and a filler (D), the amount of the acrylic polymer (B) being from 0.1 to 400 parts by weight, the amount of the filler (D) being from 1 to 2000 parts by weight, based on 100 parts by weight of the thermoplastic resin (A), and the amount of a polytetrafluoroethylene component in the polytetrafluoroethylene-containing powder mixture (C) is from 0.01 to 400 parts by weight based on 100 parts by weight of the thermoplastic resin (A).
摘要翻译： 本发明提供一种包含热塑性树脂（A），丙烯酸类聚合物（B），含聚四氟乙烯的粉末混合物（C）和填料（D）的热塑性树脂组合物，丙烯酸类聚合物（B）的量来自 相对于热塑性树脂（A）100重量份，含有聚四氟乙烯的聚四氟乙烯成分的含量为0.1〜400重量份，填料（D）的含量为1〜2000重量份 粉末混合物（C）相对于热塑性树脂（A）100重量份为0.01〜400重量份。
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公开(公告)号：US07671129B2
公开(公告)日：2010-03-02
申请号：US10548444
申请日：2004-03-09
申请人： Takashi Miura , Keiji Nakamura , Mari Sekita , Masahiro Osuka
发明人： Takashi Miura , Keiji Nakamura , Mari Sekita , Masahiro Osuka
IPC分类号： C08L69/00
CPC分类号： C08L69/00 , C08L51/04 , C08L2666/24
摘要： The present invention provides a thermoplastic resin composition capable of demonstrating impact strength, and high resistance to hydrolysis and heat discoloration without impairing the essential properties of the thermoplastic resin. The present invention provides a thermoplastic resin composition containing: 70 to 99% by mass of thermoplastic resin (A) containing a polycarbonate resin as an essential component; and 1 to 30% by mass of graft copolymer (B) which is a graft copolymer obtained by emulsion graft polymerization of a monomer or monomer mixture containing at least alkyl methacrylate in the presence of a latex containing a butadiene rubber polymer, wherein the amount of the butadiene rubber polymer included is in the range of 55 to 90% by mass, and the graft copolymer (B) is obtained by using 0.05 to 10 parts by mass of sodium alkylphenylether disulfonate with respect to 100 parts by mass of the graft copolymer (B).
摘要翻译： 本发明提供能够显示冲击强度，耐水解性和耐热变色性而不损害热塑性树脂的基本性能的热塑性树脂组合物。 本发明提供一种热塑性树脂组合物，其含有70〜99质量％的含有聚碳酸酯树脂作为必要成分的热塑性树脂（A） 和1〜30质量％的接枝共聚物（B），其是通过在含有丁二烯橡胶聚合物的胶乳存在下，至少含有甲基丙烯酸烷基酯的单体或单体混合物的乳液接枝聚合得到的接枝共聚物，其中， 所含的丁二烯橡胶聚合物的含量为55〜90质量％，相对于100质量份的接枝共聚物，使用0.05〜10质量份的烷基苯基醚二磺酸钠，得到接枝共聚物（B） B）。
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7.发明申请Modifier for resin and resin composition using the same and formed article 审中-公开用于树脂和树脂组合物的改性剂使用该树脂和成型制品公开(公告)号：US20070191542A1
公开(公告)日：2007-08-16
申请号：US10589501
申请日：2005-02-15
申请人： Tsuneki Wakita , Keiji Nakamura , Hideaki Makino , Masahiro Osuka , Yohei Miwa , Yasutaka Doi
发明人： Tsuneki Wakita , Keiji Nakamura , Hideaki Makino , Masahiro Osuka , Yohei Miwa , Yasutaka Doi
IPC分类号： C08L51/00
CPC分类号： C08L63/00 , C08F265/04 , C08F279/02 , C08F283/12 , C08L33/04 , C08L51/003 , C08L51/04 , C08L51/085 , H01L23/293 , H01L2924/0002 , C08L2666/24 , C08L2666/02 , H01L2924/00
摘要： A modifier for resin has an average particle size of 20 μm or more, wherein particles having an average particle size of 10 μm or less account for less than 30% by mass of the modifier, and particles having an average particle size of 10 μm or less account for 30% by mass or more of the modifier after irradiating the modifier with ultrasonic wave of 40 W for 5 minutes. Also a resin composition comprises 1 to 40% by mass of the modifier for resin and 99 to 60% by mass (the total amount of both components is 100% by mass) of a thermoplastic resin or a curable resin, and a molded article is produced by molding the same.
摘要翻译： 树脂改性剂的平均粒径为20μm以上，平均粒径为10μm以下的粒子比改性剂的质量小于30质量％，平均粒径为10μm以下的粒子或 在40W的超声波照射改性剂5分钟后，少于30质量％以上的改性剂。 此外，树脂组合物包含1〜40质量％的树脂用改性剂和99〜60质量％（两种成分的总量为100质量％）的热塑性树脂或固化性树脂，成型品为 通过成型制成。
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8.发明申请Impact modifier, process for producing the same, and thermoplastic resin composition 有权抗冲改性剂，其制造方法和热塑性树脂组合物公开(公告)号：US20050239949A1
公开(公告)日：2005-10-27
申请号：US10504334
申请日：2003-02-26
申请人： Keiji Nakamura , Kimihiko Hattori , Masahiro Osuka
发明人： Keiji Nakamura , Kimihiko Hattori , Masahiro Osuka
CPC分类号： C08L55/02 , C08F265/04 , C08L51/00 , C08L51/003 , C08L51/04 , C08L67/02 , C08L69/00 , C08L2666/24 , C08L2666/02 , C08L2666/14
摘要： There is disclosed an impact modifier which comprises a graft copolymer comprising a rubber polymer (A) obtained from a mixture of one or more kinds of (meth)acrylic monomers as major ingredients, having a glass transfer temperature of 0° C. or lower, and forming particles having each of 80 wt % or more of them has a particle diameter within the range of 400 to 1,000 nm as determined from a particle diameter distribution on a weight basis, and branches (B) grafted thereto obtained from one or more kinds of vinyl monomers; a process for producing thereof; and a thermoplastic resin composition containing the impact modifier.
摘要翻译： 公开了一种抗冲改性剂，其包含接枝共聚物，该接枝共聚物包含由玻璃转移温度为0℃以下的作为主要成分的一种或多种（甲基）丙烯酸单体的混合物获得的橡胶聚合物（A） 并且由80重量％以上的成型粒子的粒径分布在重量的基础上为400〜1000nm的范围，从一种或多种获得的分支（B） 的乙烯基单体; 其制造方法; 和含有抗冲改性剂的热塑性树脂组合物。
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公开(公告)号：US5847050A
公开(公告)日：1998-12-08
申请号：US793449
申请日：1997-03-03
IPC分类号： C08C1/065 , C08C1/14 , C08F279/02 , C08F285/00 , C08L25/06 , C08L27/06 , C08L51/04
CPC分类号： C08L51/04 , C08C1/065 , C08C1/14 , C08F279/02 , C08F285/00 , C08L25/06 , C08L27/06
摘要： A method for particles agglomeration and enlargement of a diene type polymer rubber latex, which comprises subjecting a diene type polymer rubber latex produced by emulsion polymerization, to particles agglomeration and enlargement to obtain a particles-enlarged diene type polymer rubber latex (A), wherein the particles enlargement is allowed to take place by agglomeration based mainly on Brownian coagulation; a graft copolymer (B) of a particles-enlarged diene type polymer rubber latex (A) obtained by the above method; and a thermoplastic resin composition comprising said graft copolymer (B).
摘要翻译： PCT No.PCT / JP96 / 01854 Sec。 371日期1997年3月3日 102（e）1997年3月3日PCT PCT 1997年7月4日PCT公布。 出版物WO97 / 02295 日期1997年1月23日一种二聚型聚合物橡胶胶乳的颗粒聚集和扩大的方法，其包括将通过乳液聚合制备的二烯类聚合物橡胶胶乳进行颗粒附聚和扩大以获得增大二甲基聚合物橡胶胶乳 （A），其中通过主要基于布朗凝固的聚集使颗粒增大发生; 通过上述方法获得的增大二聚型聚合物橡胶胶乳（A）的接枝共聚物（B）; 和包含所述接枝共聚物（B）的热塑性树脂组合物。
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公开(公告)号：US5349017A
公开(公告)日：1994-09-20
申请号：US984238
申请日：1992-12-01
申请人： Koji Matsumoto , Masaru Morimoto , Masahiro Osuka , Naomi Uno
发明人： Koji Matsumoto , Masaru Morimoto , Masahiro Osuka , Naomi Uno
IPC分类号： C08F285/00 , C08L27/06 , C08L51/00 , C08L51/04 , G01T1/18 , C08L9/04 , C08F265/04
CPC分类号： C08L27/06 , C08L51/003 , C08L51/00
摘要： A polyvinyl chloride resin composition comprising (i) 100 parts by weight of a polyvinyl chloride resin and (ii) 2 to 40 parts by weight of a multi-stage copolymer obtained by polymerizing resin component formable monomers in the range of from more than 30 parts by weight to 50 parts by weight in three stages onto 50-70 parts by weight of a butadiene elastomer having a glass transition temperature ranging from -40.degree. C. to 5.degree. C. obtained by a copolymerization of a monomer mixture of 70 to 90% by weight of butadiene, 10 to 30 percent by weight of an aromatic vinyl monomer and a polyfunctional monomer added in an amount corresponding to 3 to 10 parts by weight per 100 parts by weight of the total amount of the butadiene and aromatic vinyl monomer.
摘要翻译： 一种聚氯乙烯树脂组合物，其包含（i）100重量份的聚氯乙烯树脂和（ii）2至40重量份的多阶段共聚物，其通过将树脂组分可形成单体聚合在30多个 的50〜70重量份的三元共聚物，50-70重量份的玻璃化转变温度为-40℃〜5℃的丁二烯弹性体，通过共聚合70〜90的单体混合物 丁二烯的重量百分比，10〜30重量％的芳族乙烯基单体和多官能单体，其相对于丁二烯和芳族乙烯基单体的总量为100重量份，相当于3〜10重量份。
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