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公开(公告)号：US5721285A
公开(公告)日：1998-02-24
申请号：US592068
申请日：1996-01-26
申请人： Hideo Nakamoto , Tomohisa Tenra , Tsukasa Takushima , Takayoshi Ueno , Masaaki Suzuki , Fumihiro Inagaki , Takashi Hashida , Yoshio Kishimoto
发明人： Hideo Nakamoto , Tomohisa Tenra , Tsukasa Takushima , Takayoshi Ueno , Masaaki Suzuki , Fumihiro Inagaki , Takashi Hashida , Yoshio Kishimoto
CPC分类号： C08J9/0066 , C08J9/14 , C08J2375/04
摘要： The present invention provides a thermal insulating foamed material with excellent thermal insulating properties and a method of manufacturing the same. The method comprises the steps of: concurrently mixing and blowing a polyurethane material to produce a foamed polyurethane resin composition with a multiplicity of closed cells, the polyurethane material including a reactive blowing agent, a volatile compound having a boiling point of not higher than 150.degree. C. and a molecular weight of not less than 70, an epoxy compound, and a carbon dioxide fixation catalyst, wherein the closed cells are filled with the volatile compound and carbon dioxide produced by a reaction of the reactive blowing agent with a polyisocyanate; and allowing the carbon dioxide to chemically react with epoxy groups of the epoxy compound in the presence of the carbon dioxide fixation catalyst to form a solid or liquid cyclic carbonate. The method gives a foamed material with the closed cells substantially filled with vapor of the volatile compound at a partial pressure of at least 5 mmHg at 25.degree. C.
摘要翻译： 本发明提供一种隔热性优异的绝热发泡体及其制造方法。 该方法包括以下步骤：同时混合和吹塑聚氨酯材料以制备具有多个闭孔的发泡聚氨酯树脂组合物，所述聚氨酯材料包括反应性发泡剂，沸点不高于150℃的挥发性化合物 C，分子量不小于70，环氧化合物和二氧化碳固定催化剂，其中闭孔充满挥发性化合物和通过反应性发泡剂与多异氰酸酯的反应产生的二氧化碳; 并且在二氧化碳固定催化剂的存在下使二氧化碳与环氧化合物的环氧基发生化学反应以形成固体或液体环状碳酸酯。 该方法产生泡沫材料，其中闭孔在25℃下在至少5mmHg的分压下基本上充满挥发性化合物的蒸气。
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2.发明授权
公开(公告)号：US5773482A
公开(公告)日：1998-06-30
申请号：US809959
申请日：1997-05-22
申请人： Takayoshi Ueno , Takashi Hashida , Masaaki Suzuki , Fumihiro Inagaki , Nobuo Sonoda , Hideo Nakamoto , Tomohisa Tenra , Tsukasa Takushima , Yoshio Kishimoto
发明人： Takayoshi Ueno , Takashi Hashida , Masaaki Suzuki , Fumihiro Inagaki , Nobuo Sonoda , Hideo Nakamoto , Tomohisa Tenra , Tsukasa Takushima , Yoshio Kishimoto
CPC分类号： C08J9/0061 , C08G18/003 , C08G18/088 , C08G18/58 , C08G2101/00 , C08G2101/0025 , C08J2205/052 , C08J2375/04 , C08J2463/00
摘要： There are disclosed a thermal insulating foamed material, which is superior in thermal insulating property and does not cause deterioration of the thermal insulating property with a time lapse, and a method for producing the same. According to a method for producing a thermal insulating foamed material, a foamed polyurethane resin composition having closed cells, in which at least carbon dioxide is filled, is formed by blowing a raw material mixture containing epoxides comprising at least two members of an epoxide compound having high reactivity with carbon dioxide and an epoxide compound having low reactivity with carbon dioxide, a carbon dioxide fixation catalyst, polyisocyanate, a reactive blowing agent which evolves carbon dioxide by reacting with said polyisocyanate, and a polyol composition. Then, the carbon dioxide in the closed cells is allowed to react with the epoxides in the presence of the carbon dioxide fixation catalyst, thereby to fix carbon dioxide as carbonate compounds.
摘要翻译： PCT No.PCT / JP96 / 02386 Sec。 371日期：1997年5月22日 102（e）日期1997年5月22日PCT提交1996年8月26日PCT公布。 出版物WO97 / 09361 日期1997年3月13日公开了绝热发泡材料，其隔热性优异，并且不会随时间推移导致绝热性的劣化及其制造方法。 根据绝热发泡材料的制造方法，通过吹入含有环氧化物的原料混合物形成至少填充了二氧化碳的封闭气泡的发泡聚氨酯树脂组合物，所述环氧化物包含至少两种具有 与二氧化碳的高反应性和与二氧化碳反应性低的环氧化合物，二氧化碳固定催化剂，多异氰酸酯，通过与所述多异氰酸酯反应释放二氧化碳的反应性发泡剂和多元醇组合物。 然后，在二氧化碳固定催化剂的存在下，闭孔中的二氧化碳与环氧化物反应，从而将二氧化碳固定为碳酸盐化合物。
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3.发明授权
公开(公告)号：US5877226A
公开(公告)日：1999-03-02
申请号：US67519
申请日：1998-04-28
CPC分类号： C08J9/009 , C08G18/088 , C08G18/482 , C08J9/0066 , C08G2101/0025 , C08G2101/005 , C08J2205/052 , C08J2375/04
摘要： A thermal insulating foamed material is a polyurethane foam having closed cells, and produced by mixing, agitating and foaming a polyol, a polyisocyanate, a foam stabilizer, a catalyst, a blowing agent and a carbon dioxide adsorbent. The carbon dioxide adsorbent is produced by mixing and granulating powders of at least one member of alkali metal hydroxides and alkaline-earth metal hydroxides and organic or inorganic powders having a water absorbing property and soaked with water in advance, and formed by a resin film, such as a methacrylic acid ester, which is permeable to carbon dioxide but hardly permeable to water.
摘要翻译： 绝热泡沫材料是具有闭孔的聚氨酯泡沫体，通过混合，搅拌和发泡多元醇，多异氰酸酯，泡沫稳定剂，催化剂，发泡剂和二氧化碳吸附剂而制备。 二氧化碳吸附剂通过预先将碱金属氢氧化物和碱土金属氢氧化物中的至少一种成分和吸水性的有机或无机粉末混合并造粒，并通过树脂膜形成， 例如甲基丙烯酸酯，其可渗透二氧化碳但几乎不渗透水。
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4.发明授权Thermal insulation foamed material having carbon dioxide absorbents and method for manufacturing same 失效具有二氧化碳吸收剂的绝热泡沫材料及其制造方法
公开(公告)号：US5792801A
公开(公告)日：1998-08-11
申请号：US599451
申请日：1996-01-22
CPC分类号： C08J9/009 , C08G18/088 , C08G18/482 , C08J9/0066 , C08G2101/0025 , C08G2101/005 , C08J2205/052 , C08J2375/04
摘要： A thermal insulating foamed material is a polyurethane foam having closed cells, and produced by mixing, agitating and foaming a polyol, a polyisocyanate, a foam stabilizer, a catalyst, a blowing agent and a carbon dioxide adsorbent. The carbon dioxide adsorbent is produced by mixing and granulating powders of at least one member of alkali metal hydroxides and alkaline-earth metal hydroxides and organic or inorganic powders having a water absorbing property and soaked with water in advance, and formed by a resin film, such as a methacrylic acid ester, which is permeable to carbon dioxide but hardly permeable to water.
摘要翻译： 绝热泡沫材料是具有闭孔的聚氨酯泡沫体，通过混合，搅拌和发泡多元醇，多异氰酸酯，泡沫稳定剂，催化剂，发泡剂和二氧化碳吸附剂而制备。 二氧化碳吸附剂通过预先将碱金属氢氧化物和碱土金属氢氧化物中的至少一种成分和吸水性的有机或无机粉末混合并造粒，并通过树脂膜形成， 例如甲基丙烯酸酯，其可渗透二氧化碳但几乎不渗透水。
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公开(公告)号：US20130306655A1
公开(公告)日：2013-11-21
申请号：US13983504
申请日：2012-02-14
申请人： Tsukasa Takushima , Noriyuki Miyaji , Kazutaka Uekado , Shinya Kojima , Masahiro Koshiyama , Masamichi Hashida
发明人： Tsukasa Takushima , Noriyuki Miyaji , Kazutaka Uekado , Shinya Kojima , Masahiro Koshiyama , Masamichi Hashida
IPC分类号： B65D81/38
CPC分类号： B65D81/3816 , B01D53/0407 , B01D53/261 , B01D2251/404 , B01D2253/108 , B01D2253/25 , B01D2257/102 , B01D2257/80 , B65D81/3818 , B65D81/3834
摘要： A heat-insulating box (1) according to the present invention includes: an outer casing (2); an inner casing (3) accommodated in the outer casing, such that heat insulating space is formed between the inner casing and an inner surface of the outer casing; a plurality of vacuum insulation panels (10) arranged in the heat insulating space; and a foam insulating material (4) which fills space in the heat insulating space other than the plurality of vacuum insulation panels. Each of the plurality of vacuum insulation panels includes at least a core material and a moisture adsorbent, and the core material and the moisture adsorbent are decompression-sealed in space covered by an outer skin material. Among the plurality of vacuum insulation panels, at least a vacuum insulation panel having a largest area includes a gas adsorbing device in addition to the core material and the moisture adsorbent, the gas adsorbing device having nitrogen adsorbing capability and moisture adsorbing capability, and the core material, the moisture adsorbent, and the gas adsorbing device are decompression-sealed in the space covered by the outer skin material.
摘要翻译： 根据本发明的绝热箱（1）包括：外壳（2）; 容纳在所述外壳中的内壳体（3），使得在所述内壳体和所述外壳体的内表面之间形成绝热空间; 布置在绝热空间中的多个真空绝热板（10）; 以及填充绝热空间中除了多个真空绝热板之外的空间的泡沫绝缘材料（4）。 多个真空绝热板中的每一个至少包括芯材和水分吸附剂，并且将芯材和水分吸附剂减压密封在被外皮材料覆盖的空间中。 在多个真空绝热板中，至少具有最大面积的真空绝热板除了芯材和水分吸附剂之外还包括气体吸附装置，具有氮吸附能力和吸湿能力的气体吸附装置， 材料，水分吸附剂和气体吸附装置在被外皮材料覆盖的空间内减压密封。
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