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1.发明授权
公开(公告)号：US5773482A
公开(公告)日：1998-06-30
申请号：US809959
申请日：1997-05-22
申请人： Takayoshi Ueno , Takashi Hashida , Masaaki Suzuki , Fumihiro Inagaki , Nobuo Sonoda , Hideo Nakamoto , Tomohisa Tenra , Tsukasa Takushima , Yoshio Kishimoto
发明人： Takayoshi Ueno , Takashi Hashida , Masaaki Suzuki , Fumihiro Inagaki , Nobuo Sonoda , Hideo Nakamoto , Tomohisa Tenra , Tsukasa Takushima , Yoshio Kishimoto
CPC分类号： C08J9/0061 , C08G18/003 , C08G18/088 , C08G18/58 , C08G2101/00 , C08G2101/0025 , C08J2205/052 , C08J2375/04 , C08J2463/00
摘要： There are disclosed a thermal insulating foamed material, which is superior in thermal insulating property and does not cause deterioration of the thermal insulating property with a time lapse, and a method for producing the same. According to a method for producing a thermal insulating foamed material, a foamed polyurethane resin composition having closed cells, in which at least carbon dioxide is filled, is formed by blowing a raw material mixture containing epoxides comprising at least two members of an epoxide compound having high reactivity with carbon dioxide and an epoxide compound having low reactivity with carbon dioxide, a carbon dioxide fixation catalyst, polyisocyanate, a reactive blowing agent which evolves carbon dioxide by reacting with said polyisocyanate, and a polyol composition. Then, the carbon dioxide in the closed cells is allowed to react with the epoxides in the presence of the carbon dioxide fixation catalyst, thereby to fix carbon dioxide as carbonate compounds.
摘要翻译： PCT No.PCT / JP96 / 02386 Sec。 371日期：1997年5月22日 102（e）日期1997年5月22日PCT提交1996年8月26日PCT公布。 出版物WO97 / 09361 日期1997年3月13日公开了绝热发泡材料，其隔热性优异，并且不会随时间推移导致绝热性的劣化及其制造方法。 根据绝热发泡材料的制造方法，通过吹入含有环氧化物的原料混合物形成至少填充了二氧化碳的封闭气泡的发泡聚氨酯树脂组合物，所述环氧化物包含至少两种具有 与二氧化碳的高反应性和与二氧化碳反应性低的环氧化合物，二氧化碳固定催化剂，多异氰酸酯，通过与所述多异氰酸酯反应释放二氧化碳的反应性发泡剂和多元醇组合物。 然后，在二氧化碳固定催化剂的存在下，闭孔中的二氧化碳与环氧化物反应，从而将二氧化碳固定为碳酸盐化合物。
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公开(公告)号：US5721285A
公开(公告)日：1998-02-24
申请号：US592068
申请日：1996-01-26
申请人： Hideo Nakamoto , Tomohisa Tenra , Tsukasa Takushima , Takayoshi Ueno , Masaaki Suzuki , Fumihiro Inagaki , Takashi Hashida , Yoshio Kishimoto
发明人： Hideo Nakamoto , Tomohisa Tenra , Tsukasa Takushima , Takayoshi Ueno , Masaaki Suzuki , Fumihiro Inagaki , Takashi Hashida , Yoshio Kishimoto
CPC分类号： C08J9/0066 , C08J9/14 , C08J2375/04
摘要： The present invention provides a thermal insulating foamed material with excellent thermal insulating properties and a method of manufacturing the same. The method comprises the steps of: concurrently mixing and blowing a polyurethane material to produce a foamed polyurethane resin composition with a multiplicity of closed cells, the polyurethane material including a reactive blowing agent, a volatile compound having a boiling point of not higher than 150.degree. C. and a molecular weight of not less than 70, an epoxy compound, and a carbon dioxide fixation catalyst, wherein the closed cells are filled with the volatile compound and carbon dioxide produced by a reaction of the reactive blowing agent with a polyisocyanate; and allowing the carbon dioxide to chemically react with epoxy groups of the epoxy compound in the presence of the carbon dioxide fixation catalyst to form a solid or liquid cyclic carbonate. The method gives a foamed material with the closed cells substantially filled with vapor of the volatile compound at a partial pressure of at least 5 mmHg at 25.degree. C.
摘要翻译： 本发明提供一种隔热性优异的绝热发泡体及其制造方法。 该方法包括以下步骤：同时混合和吹塑聚氨酯材料以制备具有多个闭孔的发泡聚氨酯树脂组合物，所述聚氨酯材料包括反应性发泡剂，沸点不高于150℃的挥发性化合物 C，分子量不小于70，环氧化合物和二氧化碳固定催化剂，其中闭孔充满挥发性化合物和通过反应性发泡剂与多异氰酸酯的反应产生的二氧化碳; 并且在二氧化碳固定催化剂的存在下使二氧化碳与环氧化合物的环氧基发生化学反应以形成固体或液体环状碳酸酯。 该方法产生泡沫材料，其中闭孔在25℃下在至少5mmHg的分压下基本上充满挥发性化合物的蒸气。
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3.发明授权
公开(公告)号：US5877226A
公开(公告)日：1999-03-02
申请号：US67519
申请日：1998-04-28
CPC分类号： C08J9/009 , C08G18/088 , C08G18/482 , C08J9/0066 , C08G2101/0025 , C08G2101/005 , C08J2205/052 , C08J2375/04
摘要： A thermal insulating foamed material is a polyurethane foam having closed cells, and produced by mixing, agitating and foaming a polyol, a polyisocyanate, a foam stabilizer, a catalyst, a blowing agent and a carbon dioxide adsorbent. The carbon dioxide adsorbent is produced by mixing and granulating powders of at least one member of alkali metal hydroxides and alkaline-earth metal hydroxides and organic or inorganic powders having a water absorbing property and soaked with water in advance, and formed by a resin film, such as a methacrylic acid ester, which is permeable to carbon dioxide but hardly permeable to water.
摘要翻译： 绝热泡沫材料是具有闭孔的聚氨酯泡沫体，通过混合，搅拌和发泡多元醇，多异氰酸酯，泡沫稳定剂，催化剂，发泡剂和二氧化碳吸附剂而制备。 二氧化碳吸附剂通过预先将碱金属氢氧化物和碱土金属氢氧化物中的至少一种成分和吸水性的有机或无机粉末混合并造粒，并通过树脂膜形成， 例如甲基丙烯酸酯，其可渗透二氧化碳但几乎不渗透水。
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4.发明授权Thermal insulation foamed material having carbon dioxide absorbents and method for manufacturing same 失效具有二氧化碳吸收剂的绝热泡沫材料及其制造方法
公开(公告)号：US5792801A
公开(公告)日：1998-08-11
申请号：US599451
申请日：1996-01-22
CPC分类号： C08J9/009 , C08G18/088 , C08G18/482 , C08J9/0066 , C08G2101/0025 , C08G2101/005 , C08J2205/052 , C08J2375/04
摘要： A thermal insulating foamed material is a polyurethane foam having closed cells, and produced by mixing, agitating and foaming a polyol, a polyisocyanate, a foam stabilizer, a catalyst, a blowing agent and a carbon dioxide adsorbent. The carbon dioxide adsorbent is produced by mixing and granulating powders of at least one member of alkali metal hydroxides and alkaline-earth metal hydroxides and organic or inorganic powders having a water absorbing property and soaked with water in advance, and formed by a resin film, such as a methacrylic acid ester, which is permeable to carbon dioxide but hardly permeable to water.
摘要翻译： 绝热泡沫材料是具有闭孔的聚氨酯泡沫体，通过混合，搅拌和发泡多元醇，多异氰酸酯，泡沫稳定剂，催化剂，发泡剂和二氧化碳吸附剂而制备。 二氧化碳吸附剂通过预先将碱金属氢氧化物和碱土金属氢氧化物中的至少一种成分和吸水性的有机或无机粉末混合并造粒，并通过树脂膜形成， 例如甲基丙烯酸酯，其可渗透二氧化碳但几乎不渗透水。
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公开(公告)号：US06355700B1
公开(公告)日：2002-03-12
申请号：US09301960
申请日：1999-04-29
IPC分类号： C08G1804
CPC分类号： C08G18/8083 , C08G18/288 , C08G18/3878 , C08G2101/00 , C08G2101/0025 , C08G2101/005 , F16L59/02 , F25D23/061 , F25D23/064 , F25D2201/126
摘要： An insulated structure is formed by injection of a foamed thermal-insulating material created by foaming into a space between a plastic board and metal plate with a disposition of copper pipes. A non-halogenated organophosphorus compound having a molecular weight over 150 as an additive with an OH group as a functional group is mixed with the raw materials of the foamed thermal-insulating material including polyol, a foam stabilizer, a catalyst, a foaming agent having at least one component of hydrocarbon, and an organic polyisocyanates. By adding a non-halogenated organophosphorus compound, which has a molecular weight over 150 as an additive with an OH group as a functional group, the burning rate of the foamed thermal-insulating material becomes the same as that of the foamed thermal-insulating material which uses CFC11 as a foaming agent. Also, the possibilities of phosphor corrosion by free ionization to copper pipes, which are disposed inside of the insulated structure, are eliminated and phosphorus transfer to the plastic board and worries of food contamination are also eliminated.
摘要翻译： 通过以铜管的布置将由发泡产生的泡沫绝热材料注入到塑料板和金属板之间的空间中而形成绝缘结构。 将分子量超过150的非卤化有机磷化合物作为具有OH基作为官能团的添加剂与包含多元醇，泡沫稳定剂，催化剂，发泡剂的发泡绝热材料的原料混合，所述发泡绝热材料具有 烃的至少一种组分和有机多异氰酸酯。 通过添加分子量超过150的非卤化有机磷化合物作为具有OH基作为官能团的添加剂，发泡绝热材料的燃烧速率与发泡绝热材料的燃烧速率相同 其使用CFC11作为发泡剂。 此外，消除了设置在绝缘结构内部的通过自由离子化到铜管的荧光体腐蚀的可能性，并且消除了向塑料板的磷转移和食品污染的担忧。
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公开(公告)号：US5983647A
公开(公告)日：1999-11-16
申请号：US682677
申请日：1996-07-24
IPC分类号： C08G18/06 , C08G18/08 , C08G18/28 , C08G18/32 , C08G18/38 , C08G18/50 , C08G18/80 , C08J9/14 , F16L59/02 , F25D23/06 , F25D23/08 , F17C11/00 , A47B96/04 , F25D11/00
CPC分类号： C08G18/288 , C08G18/3878 , C08G18/8083 , F16L59/02 , F25D23/061 , F25D23/064 , C08G2101/00 , C08G2101/0025 , C08G2101/005 , F25D2201/126
摘要： An insulated structure is formed by injection of a foamed thermal-insulating material created by foaming into a space between a plastic board and metal plate with a disposition of copper pipes. A non-halogenated organophosphorus compound having a molecular weight over 150 as an additive with an OH group as a functional group is mixed with the raw materials of the foamed thermal-insulating material including polyol, a foam stabilizer, a catalyst, a foaming agent having at least one component of hydrocarbon, and an organic polyisocyanates. By adding a non-halogenated organophosphorus compound, which has a molecular weight over 150 as an additive with an OH group as a functional group, the burning rate of the foamed thermal-insulating material becomes the same as that of the foamed thermal-insulating material which uses CFC11 as a foaming agent. Also, the possibilities of phosphor corrosion by free ionization to copper pipes, which are disposed inside of the insulated structure, are eliminated and phosphorus transfer to the plastic board and worries of food contamination are also eliminated.
摘要翻译： PCT No.PCT / JP94 / 01984 Sec。 371日期：1996年7月24日 102（e）日期1996年7月24日PCT 1994年11月24日PCT PCT。 公开号WO96 / 16098 日期：1996年5月30日绝缘结构是通过将塑料板和金属板之间的空间注入由发泡形成的发泡绝热材料与铜管的配置而形成的。 将分子量超过150的非卤化有机磷化合物作为具有OH基作为官能团的添加剂与包含多元醇，泡沫稳定剂，催化剂，发泡剂的发泡绝热材料的原料混合，所述发泡绝热材料具有 烃的至少一种组分和有机多异氰酸酯。 通过添加分子量超过150的非卤化有机磷化合物作为具有OH基作为官能团的添加剂，发泡绝热材料的燃烧速率与发泡绝热材料的燃烧速率相同 其使用CFC11作为发泡剂。 此外，消除了设置在绝缘结构内部的通过自由电离到铜管的荧光体腐蚀的可能性，并且消除了向塑料板的磷转移和食品污染的担忧。
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公开(公告)号：US08790477B2
公开(公告)日：2014-07-29
申请号：US12851180
申请日：2010-08-05
申请人： Tomohisa Tenra , Takao Fujimoto
发明人： Tomohisa Tenra , Takao Fujimoto
IPC分类号： F16L59/065
CPC分类号： G06F1/203 , E04B1/803 , F16L59/065 , H01L2924/0002 , Y02A30/242 , Y02B80/12 , Y10T156/103 , Y10T428/231 , H01L2924/00
摘要： A vacuum heat insulator small in limitation in shape of applicable objects, and wide in application is presented. A vacuum heat insulator is formed of a plurality of core members of thickness of 5 mm or less made of glass fiber shaped nearly in a regular octagonal shape, being coated with a gas barrier enveloping member and evacuated in side. The core members are shaped in octagon, and disposed in lattice layout at specified intervals so as to form folding lines in four directions of vertical, lateral and oblique 45-degree directions, parallel to each side. In order that the plurality of core members may be located in independent spaces individually, the entire surface of the enveloping member around the core members is formed as heat seal parts, and it is foldable in four directions and is flexible. By cutting the heat seal parts along the core members so as to leave about 3 mm in the periphery, a vacuum heat insulator of any desired shape and wide effective heat insulating area can be obtained. The core members may be formed in desired shape, and complicated shapes and through-holes can be formed, so that vacuum heat insulators applicable in a very wide scope of purposes can be presented.
摘要翻译： 介绍了适用对象形状限制小，应用广泛的真空绝热体。 真空绝热体由厚度5mm以下的多个核心部件形成，玻璃纤维的形状几乎为正八边形，涂覆有阻气性包封部件并抽出。 芯部件成形为八边形，并且以规定的间隔以格子布置设置，以在垂直，横向和倾斜的45度方向的四个方向上形成平行于每一侧的折叠线。 为了使多个芯体可以单独设置在独立的空间中，包围构件周围的芯部件的整个表面形成为热密封部分，并且其可以在四个方向上折叠并且是柔性的。 通过沿芯部切割热封部分以在周边留下约3mm，可以获得任何所需形状和宽的有效绝热面积的真空绝热体。 芯构件可以形成为期望的形状，并且可以形成复杂的形状和通孔，从而可以呈现适用于非常宽的目的的真空绝热体。
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公开(公告)号：US07762634B2
公开(公告)日：2010-07-27
申请号：US11569390
申请日：2005-06-02
IPC分类号： A47B96/00
CPC分类号： F16L59/065 , B32B3/04 , B32B7/12 , B32B15/08 , B32B15/20 , B32B27/00 , B32B27/08 , B32B27/12 , B32B27/306 , B32B27/32 , B32B27/34 , B32B27/36 , B32B27/40 , B32B2255/10 , B32B2255/20 , B32B2255/205 , B32B2262/101 , B32B2307/304 , B32B2307/31 , B32B2307/558 , B32B2307/7242 , B32B2509/10 , F16L59/029 , Y10T428/31522 , Y10T428/31529
摘要： A vacuum heat insulation material has a covering material which is a lamination body including a sealant layer, a metal foil layer, a first plastic film layer, and a second plastic film layer which are laminated in this order from inside to outside via adhesive layers. When a foreign body is pierced into the vacuum heat insulation material, the propagation of breakage caused by the piercing is blocked somewhere inside the lamination body, thereby preventing the formation of through-pinholes. This results in the provision of a high-quality vacuum heat insulation material with excellent long-term insulation performance by using a covering material excellent in gas barrier properties and pinhole resistance to the piercing of minute foreign bodies.
摘要翻译： 真空绝热材料具有覆盖材料，该覆盖材料是包括密封剂层，金属箔层，第一塑料膜层和第二塑料膜层的层叠体，其通过粘合剂层从内向外依次层叠。 当异物穿入真空隔热材料时，由穿孔引起的断裂的传播在层压体内的某处被阻挡，从而防止形成穿孔。 这样，通过使用阻气性和针孔耐冲击性优异的覆盖材料，能够提供具有优异的长期绝缘性能的高品质的真空隔热材料。
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9.发明申请公开(公告)号：US20060234006A1
公开(公告)日：2006-10-19
申请号：US10595081
申请日：2005-02-02
申请人： Tomohisa Tenra
发明人： Tomohisa Tenra
IPC分类号： B32B3/02
CPC分类号： B32B27/12 , B32B3/04 , B32B5/02 , B32B17/02 , B32B2250/03 , B32B2250/40 , B32B2262/101 , B32B2264/105 , B32B2307/304 , B32B2307/7242 , B32B2307/726 , B32B2419/00 , B32B2509/10 , F25D23/062 , F25D2201/14 , F25D2400/04 , Y10T428/231
摘要： A vacuum heat insulator has a core formed of a glass fiber laminated body where glass fibers are laminated in the thickness direction, and an enveloping member that covers the core and has gas barrier property. The inside of the enveloping member is evacuated and the enveloping member is sealed. The core is pressurized and molded and the glass fibers are drawn by heat deformation of the glass fibers at a temperature at which the glass fibers start to slightly deform due to own weight of the glass fibers or a temperature at which the glass fibers become deformable due to a vertical load in pressing and the sectional shapes of the glass fibers do not significantly vary. Additionally, the shape of the core is kept by entanglement of parts of the glass fibers instead of binding of the glass fibers.
摘要翻译： 真空绝热体具有由厚度方向层压有玻璃纤维的玻璃纤维层叠体形成的芯部和覆盖芯部并具有阻气性的包络部件。 包封部件的内部被抽真空并且包封部件被密封。 核心被加压和模制，并且玻璃纤维在玻璃纤维由于玻璃纤维的自身重量开始轻微变形的温度或玻璃纤维可变形的温度下由于玻璃纤维的热变形而被拉伸， 达到按压的垂直载荷，并且玻璃纤维的截面形状没有显着变化。 此外，芯的形状通过玻璃纤维的部分的缠结来保持，而不是玻璃纤维的结合。
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10.发明申请公开(公告)号：US20090029095A1
公开(公告)日：2009-01-29
申请号：US11919866
申请日：2006-05-19
申请人： Tomohisa Tenra , Masamichi Hashida
发明人： Tomohisa Tenra , Masamichi Hashida
CPC分类号： B32B17/02 , F16L59/065 , F25D2201/14 , Y10T428/239
摘要： Vacuum insulator includes core member and jacket which covers core member. Jacket is decompressed its interior and core member includes a glass-fiber laminated unit. The glass fiber is formed of reinforced glass-fiber which is low brittle and its fiber strength is reinforced. This structure allows improving the heat insulating performance as well as lowering the material cost of vacuum insulator.
摘要翻译： 真空绝缘体包括芯部件和覆盖芯部件的护套。 夹套减压其内部，芯部件包括玻璃纤维层压单元。 玻璃纤维由脆弱的强化玻璃纤维形成，纤维强度增强。 这种结构允许提高隔热性能以及降低真空绝缘子的材料成本。
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