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    LONG-FIBER-REINFORCED RESIN COMPOSITION AND MOLDED ARTICLE THEREOF
    1.
    发明申请
    LONG-FIBER-REINFORCED RESIN COMPOSITION AND MOLDED ARTICLE THEREOF 有权
    长纤维增强树脂组合物及其成型品

    公开(公告)号：US20110040022A1

    公开(公告)日：2011-02-17

    申请号：US12922348

    申请日：2009-03-19

    申请人： Hirofumi Goda ,  Toru Iwashita

    发明人： Hirofumi Goda ,  Toru Iwashita

    IPC分类号： C08L33/00

    CPC分类号： C08L23/12 ,  C08K5/14 ,  C08K7/14 ,  C08L23/02 ,  C08L23/10 ,  C08L51/003 ,  C08L2203/12 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2205/03 ,  C08L2205/16 ,  C08L2666/02 ,  C08L2666/24 ,  C08L2666/06

    摘要： A long-fiber-reinforced resin composition including the following component (A) and the component (B), the content of the component (A) being 50 to 90 wt % and the content of the component (B) being 10 to 50 wt %; and the content of reinforcing fiber contained in the component (A) being 20 to 60 wt % relative to the total amount of the fiber-reinforced resin composition:[Component (A)] a long-fiber-reinforced thermoplastic resin pellet including a thermoplastic resin, a modified polyolefin-based resin modified with an unsaturated carboxylic acid or its derivative and reinforcing fiber and satisfying the following (A-1) to (A-4): (A-1): the melt index of the thermoplastic resin (resin temperature: 230° C., load: 21.18N) is 100 to 250 g/10 min; (A-2): the relaxation time λ of the thermoplastic resin at an angular frequency ω=1 (rad/sec) calculated from the storage modulus G′ and the loss modulus G″ measured by means of a cone-and-plate rheometer is 0.1 (sec) or less; (A-3) the content of the reinforcing fiber is 40 to 70 wt %; and (A-4) the content of the modified polyolefin-based resin is 1 to 5 wt %; [Component (B)] a polyolefin-based resin satisfying the following (B-1) and (B-2): (B-1) the melt index of the polyolefin-based resin (resin temperature: 230° C., load: 21.18N) is 20 to 70 g/10 min; and (B-2) the relaxation time λ of the polyolefin-based resin at an angular frequency ω=1 (rad/sec) calculated from the storage modulus G′ and the loss modulus G″ measured by means of a cone-and-plate rheometer is 0.23 (sec) or less.

    摘要翻译： 包含以下组分（A）和组分（B）的长纤维增强树脂组合物，组分（A）的含量为50至90重量％，组分（B）的含量为10至50重量％ ％; 组分（A）中所含的增强纤维的含量相对于纤维增强树脂组合物的总量为20〜60重量％：[组分（A）]包含热塑性塑料的长纤维增强热塑性树脂颗粒 树脂，不饱和羧酸或其衍生物改性的改性聚烯烃系树脂及增强纤维，满足以下（A-1）〜（A-4）：（A-1）：热塑性树脂的熔融指数 树脂温度：230℃，负荷21.18N）为100〜250g / 10分钟; （A-2）：以通过锥板流变仪测量的储能模量G'和损耗模量G“计算的角频率ω= 1（rad / sec）的热塑性树脂的弛豫时间λ 为0.1（秒）以下; （A-3）增强纤维的含量为40〜70重量％。 和（A-4）中，改性聚烯烃系树脂的含量为1〜5重量％ [组分（B）]满足以下（B-1）和（B-2）的聚烯烃类树脂（B-1）聚烯烃系树脂的熔融指数（树脂温度：230℃，负荷 ：21.18N）为20〜70g / 10min; 和（B-2）以从储能模量G'和损耗模量G“计算的角频率ω= 1（rad / sec）的聚烯烃类树脂的松弛时间λ， 板流变仪为0.23（秒）以下。

    Long-fiber-reinforced resin composition and molded article thereof
    2.
    发明授权
    Long-fiber-reinforced resin composition and molded article thereof 有权
    长纤维增强树脂组合物及其模塑制品

    公开(公告)号：US09359492B2

    公开(公告)日：2016-06-07

    申请号：US12922348

    申请日：2009-03-19

    申请人： Hirofumi Goda ,  Toru Iwashita

    发明人： Hirofumi Goda ,  Toru Iwashita

    IPC分类号： C08K3/40 ,  C08L33/00 ,  C08L23/02 ,  C08L23/10 ,  C08L23/12 ,  C08K7/14 ,  C08L51/00

    CPC分类号： C08L23/12 ,  C08K5/14 ,  C08K7/14 ,  C08L23/02 ,  C08L23/10 ,  C08L51/003 ,  C08L2203/12 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2205/03 ,  C08L2205/16 ,  C08L2666/02 ,  C08L2666/24 ,  C08L2666/06

    摘要： A long-fiber-reinforced resin composition including (A) a long-fiber-reinforced thermoplastic resin pellet including a thermoplastic resin, a modified polyolefin-based resin modified with an unsaturated carboxylic acid or its derivative and reinforcing fiber and satisfying (A-1) the melt index of the thermoplastic resin is 100-250 g/10 min, (A-2) the relaxation time λ of the thermoplastic resin is 0.1 (sec) or less, (A-3) the content of the reinforcing fiber is 40-70 wt %, and (A-4) the content of the modified polyolefin-based resin is 1-5 wt %; and (B) a polyolefin-based resin satisfying (B-1) the melt index of the polyolefin-based resin is 20-70 g/10 min, and (B-2) the relaxation time λ of the polyolefin-based resin is 0.23 (sec) or less; wherein the content of reinforcing fiber contained in (A) is 20-60 wt % relative to the total amount of the fiber-reinforced resin composition.

    摘要翻译： 一种长纤维增强树脂组合物，其包含（A）包含热塑性树脂的长纤维强化热塑性树脂颗粒，用不饱和羧酸或其衍生物改性的改性聚烯烃基树脂和增强纤维，并满足（A-1 ）热塑性树脂的熔融指数为100-250g / 10min，（A-2）热塑性树脂的松弛时间λ为0.1（sec）以下，（A-3）增强纤维的含量为 40-70重量％，（A-4）改性聚烯烃类树脂的含量为1-5重量％ 和（B）满足（B-1）聚烯烃类树脂的熔融指数为20-70g / 10min的聚烯烃系树脂，（B-2）聚烯烃系树脂的松弛时间λ为 0.23（秒）以下; 其中（A）中所含的增强纤维的含量相对于纤维增强树脂组合物的总量为20〜60重量％。

    FIBER-REINFORCED RESIN COMPOSITION AND MOLDED BODY THEREOF
    3.
    发明申请
    FIBER-REINFORCED RESIN COMPOSITION AND MOLDED BODY THEREOF 有权
    纤维增强树脂组合物及其成型体

    公开(公告)号：US20130059966A1

    公开(公告)日：2013-03-07

    申请号：US13604808

    申请日：2012-09-06

    申请人： Hirofumi Goda ,  Toru Iwashita ,  Keita Itakura

    发明人： Hirofumi Goda ,  Toru Iwashita ,  Keita Itakura

    IPC分类号： C08L23/12 ,  C08L23/30

    CPC分类号： C08L23/10 ,  C08J3/12 ,  C08J5/04 ,  C08J2323/00 ,  C08J2323/10 ,  C08K7/14 ,  C08L23/04 ,  C08L23/12 ,  C08L51/003 ,  C08L2205/02 ,  C08L2666/06 ,  C08L2666/02

    摘要： Long-fiber-reinforced thermoplastic resin particles and a blend thereof are provided, wherein the opening property of the reinforcing fibers during molding is good, and a molded body exhibiting an excellent appearance and having high mechanical strength is obtained. The particles (A) contain a thermoplastic resin (A1), produced by using a metallocene catalyst, a modified polyolefin resin (A2) modified with an unsaturated carboxylic acid or a derivative thereof, and reinforcing fibers (A3) and satisfying additional requirements described herein.

    摘要翻译： 提供了长纤维增强热塑性树脂颗粒及其共混物，其中，成型时的增强纤维的开口性良好，得到外观美观，机械强度高的成型体。 颗粒（A）含有通过使用金属茂催化剂，用不饱和羧酸或其衍生物改性的改性聚烯烃树脂（A2）和增强纤维（A3）制备并满足本文所述的附加要求的热塑性树脂（A1） 。

    Long-fiber-reinforced resin composition and molded article thereof
    4.
    发明授权
    Long-fiber-reinforced resin composition and molded article thereof 有权

    公开(公告)号：US08680194B2

    公开(公告)日：2014-03-25

    申请号：US12922348

    申请日：2009-03-19

    申请人： Hirofumi Goda ,  Toru Iwashita

    发明人： Hirofumi Goda ,  Toru Iwashita

    IPC分类号： C08K3/40 ,  C08L33/00

    摘要： A long-fiber-reinforced resin composition including (A) a long-fiber-reinforced thermoplastic resin pellet including a thermoplastic resin, a modified polyolefin-based resin modified with an unsaturated carboxylic acid or its derivative and reinforcing fiber and satisfying (A-1) the melt index of the thermoplastic resin is 100-250 g/10 min, (A-2) the relaxation time λ of the thermoplastic resin is 0.1 (sec) or less, (A-3) the content of the reinforcing fiber is 40-70 wt %, and (A-4) the content of the modified polyolefin-based resin is 1-5 wt %; and (B) a polyolefin-based resin satisfying (B-1) the melt index of the polyolefin-based resin is 20-70 g/10 min, and (B-2) the relaxation time λ of the polyolefin-based resin is 0.23 (sec) or less; wherein the content of reinforcing fiber contained in (A) is 20-60 wt % relative to the total amount of the fiber-reinforced resin composition.

    FIBER-REINFORCED RESIN COMPOSITION AND MOLDED BODY THEREOF
    5.
    发明申请
    FIBER-REINFORCED RESIN COMPOSITION AND MOLDED BODY THEREOF 审中-公开
    纤维增强树脂组合物及其成型体

    公开(公告)号：US20110178229A1

    公开(公告)日：2011-07-21

    申请号：US13121384

    申请日：2009-09-28

    申请人： Hirofumi Goda ,  Toru Iwashita ,  Keita Itakura

    发明人： Hirofumi Goda ,  Toru Iwashita ,  Keita Itakura

    IPC分类号： C08L33/00

    CPC分类号： C08L23/10 ,  C08J3/12 ,  C08J5/04 ,  C08J2323/00 ,  C08J2323/10 ,  C08K7/14 ,  C08L23/04 ,  C08L23/12 ,  C08L51/003 ,  C08L2205/02 ,  C08L2666/06 ,  C08L2666/02

    摘要： Long-fiber-reinforced thermoplastic resin particles and a blend thereof are provided, wherein the opening property of the reinforcing fibers during molding is good, and a molded body exhibiting an excellent appearance and having high mechanical strength is obtained. The particles (A) contains a thermoplastic resin (A1), produced by using a metallocene catalyst, a modified polyolefin resin (A2) modified with an unsaturated carboxylic acid or a derivative thereof, and reinforcing fibers (A3) and satisfy the following requirements (1) to (5); (1) the amount of modification of the unsaturated carboxylic acid or a derivative thereof is 0.01 to 2 percent by weight in 100 percent by weight of the total of (A1) and (A2); (2) (A1) and (A2) constitute 20 to 70 percent by weight in 100 percent by weight of the total of (A1), (A2), and (A3); (3) (A3) constitutes 30 to 80 percent by weight in 100 percent by weight of the total of (A1), (A2), and (A3); (4) when 25 g of (A) is encapsulated in a 20-L chamber and is stood at 65° C. for 1 hour, the amount of acetaldehyde dissipated from (A) is 3.0 μg/m3 or less; and (5) the melting point of the resin component in (A) is 150° C. or higher.

    摘要翻译： 提供了长纤维增强热塑性树脂颗粒及其共混物，其中，成型时的增强纤维的开口性良好，得到外观美观，机械强度高的成型体。 颗粒（A）含有通过使用金属茂催化剂，用不饱和羧酸或其衍生物改性的改性聚烯烃树脂（A2）和增强纤维（A3）制备的热塑性树脂（A1），并满足以下要求 1）至（5）; （1）不饱和羧酸或其衍生物的改性量为（A1）和（A2）总量的100重量％中的0.01〜2重量％。 （A1），（A2）和（A3）的总量的100重量％中，（2）（A1）和（A2）构成20〜70重量％ （A3）（A3）占（A1），（A2）和（A3）总重量的100重量％的30〜80重量％。 （4）当将25g（A）包封在20L室中并放置在65℃下1小时时，从（A）消散的乙醛的量为3.0μg/ m 3或更小; （5）（A）中的树脂成分的熔点为150℃以上。

    Fiber-reinforced resin composition and molded body thereof
    6.
    发明授权
    Fiber-reinforced resin composition and molded body thereof 有权
    纤维增强树脂组合物及其成型体

    公开(公告)号：US08420728B2

    公开(公告)日：2013-04-16

    申请号：US13604808

    申请日：2012-09-06

    申请人： Hirofumi Goda ,  Toru Iwashita ,  Keita Itakura

    发明人： Hirofumi Goda ,  Toru Iwashita ,  Keita Itakura

    IPC分类号： C08K3/40

    CPC分类号： C08L23/10 ,  C08J3/12 ,  C08J5/04 ,  C08J2323/00 ,  C08J2323/10 ,  C08K7/14 ,  C08L23/04 ,  C08L23/12 ,  C08L51/003 ,  C08L2205/02 ,  C08L2666/06 ,  C08L2666/02

    摘要： Long-fiber-reinforced thermoplastic resin particles and a blend thereof are provided, wherein the opening property of the reinforcing fibers during molding is good, and a molded body exhibiting an excellent appearance and having high mechanical strength is obtained. The particles (A) contain a thermoplastic resin (A1), produced by using a metallocene catalyst, a modified polyolefin resin (A2) modified with an unsaturated carboxylic acid or a derivative thereof, and reinforcing fibers (A3) and satisfying additional requirements described herein.

    摘要翻译： 提供了长纤维增强热塑性树脂颗粒及其共混物，其中，成型时的增强纤维的开口性良好，得到外观美观，机械强度高的成型体。 颗粒（A）含有通过使用金属茂催化剂，用不饱和羧酸或其衍生物改性的改性聚烯烃树脂（A2）和增强纤维（A3）制备并满足本文所述的附加要求的热塑性树脂（A1） 。

    CARBON FIBER BUNDLE AND METHOD FOR PRODUCING SAME
    10.
    发明申请
    CARBON FIBER BUNDLE AND METHOD FOR PRODUCING SAME 审中-公开
    碳纤维布及其制造方法

    公开(公告)号：US20120208019A1

    公开(公告)日：2012-08-16

    申请号：US13394634

    申请日：2010-09-08

    申请人： Naoki Sugiura ,  Toru Iwashita ,  Toshiyuki Ishii ,  Rikuo Onishi

    发明人： Naoki Sugiura ,  Toru Iwashita ,  Toshiyuki Ishii ,  Rikuo Onishi

    IPC分类号： D02G3/36 ,  B05D3/02

    CPC分类号： C08F8/32 ,  B29B15/12 ,  B29K2023/00 ,  D06M7/00 ,  D06M15/227 ,  D06M15/263 ,  D06M15/267 ,  D06M15/285 ,  D06M15/3562 ,  D06M2101/40 ,  Y10T428/2918 ,  C08F210/02

    摘要： The present invention relates to a carbon fiber bundle to which an amino group-containing modified polyolefin resin has applied, wherein the amount of applying amino group-containing modified polyolefin resin is 0.2 to 5.0% by mass. This carbon fiber bundle can be produced by applying 0.2 to 5.0% by mass of the amino group-containing modified polyolefin resin to the surface of the carbon fiber bundle. The present invention can exhibit excellent interface adhesion to a polyolefin resin, particularly to a polypropylene resin, and can provide a carbon fiber bundle useful for reinforcing the polyolefin resin and a method of producing the same.

    摘要翻译： 本发明涉及应用含氨基的改性聚烯烃树脂的碳纤维束，其中施加氨基的改性聚烯烃树脂的量为0.2〜5.0质量％。 该碳纤维束可以通过将0.2〜5.0质量％的含氨基的改性聚烯烃树脂施加到碳纤维束的表面来制造。 本发明可以表现出对聚烯烃树脂，特别是聚丙烯树脂的优异的界面粘附性，并且可以提供用于增强聚烯烃树脂的碳纤维束及其制造方法。