-
1.发明授权Resin composition for optical member and optical member obtained from the same 有权用于光学部件的树脂组合物和由其获得的光学部件公开(公告)号：US08389671B2
公开(公告)日：2013-03-05
申请号：US12529918
申请日：2008-03-11
CPC分类号： C08F12/30 , C08F212/08 , C08F212/14 , C08F212/36 , C08F216/1466 , C08F220/38 , C08F2222/1013 , C08G75/08 , G02B1/04 , C08L81/00
摘要： The present invention can provide a composition for optical members, which contains (a) a compound having one or more of any group selected from the group consisting of an acryloyl group, a methacryloyl group, an allyl group and a vinyl group and one or more β-epithiopropyl groups in a molecule. In a preferable embodiment of the present invention, the composition for optical members further contains at least one compound selected from (b) a compound having one or more β-epithiopropyl groups in a molecule while having no polymerizable unsaturated bond group, (c) an inorganic compound having a sulfur atom and/or a selenium atom, (d) a compound having one or more thiol groups in a molecule, (e) a compound having one or more amino groups in a molecule while having no heterocyclic ring, and (f) a compound having one or more of at least one group selected from the group consisting of a vinyl group, an acryloyl group, a methacryloyl group and an allyl group in a molecule.
摘要翻译： 本发明可以提供一种光学部件用组合物，其含有（a）具有选自丙烯酰基，甲基丙烯酰基，烯丙基和乙烯基中的一个或多个的一种或多种的化合物和一种或多种 一个分子中的β-二硫丙基。 在本发明的优选实施方案中，用于光学部件的组合物还含有至少一种选自（b）分子中具有一个或多个β-伯硫丙基的化合物中的化合物，同时不具有可聚合的不饱和键基，（c） 具有硫原子和/或硒原子的无机化合物，（d）分子中具有一个或多个硫醇基的化合物，（e）分子中具有一个或多个氨基但不具有杂环的化合物，以及 （f）在分子中具有一个或多个选自乙烯基，丙烯酰基，甲基丙烯酰基和烯丙基中的至少一个基团的化合物。
-
公开(公告)号：US07169845B2
公开(公告)日：2007-01-30
申请号：US10297383
申请日：2002-04-04
申请人： Masaki Tamura , Takahiro Matsui , Masanori Shimuta , Yuichi Yoshimura , Motoharu Takeuchi , Hiroshi Horikoshi , Hiroyuki Okada
发明人： Masaki Tamura , Takahiro Matsui , Masanori Shimuta , Yuichi Yoshimura , Motoharu Takeuchi , Hiroshi Horikoshi , Hiroyuki Okada
CPC分类号： C08G75/08 , C07D331/02
摘要： In the present invention, an episulfide compound having, in one molecule, at least one epithio structure represented by the following Formula 2: wherein R5 is C1–C10 hydrocarbylene or single bond, R6, R7 and R8 are each independently C1–C10 hydrocarbyl or hydrogen, Y is O, S, Se or Te, p is an integer from 1 to 5 and q is an integer from 0 to 5, is polymerized in the presence of a halide of a 13–16 group element of the long periodic table and/or a polymerization regulator represented by the following Formula 1: wherein R1, R2 and R3 are each C1–C10 hydocarbyl or hydrogen, R4 is C1–C10 hydrocarbylene or single bond, X is F, Cl, Br, I, As, SH, OH, C1–C10 alkoxyl, C1–C10 alkylthio, or C1–C10 mercaptoalkythio, and m is an integer from 1 to 5, to produce a cured resin suitable as an optical material. By using the polymerization regulator, the polymerization rate of the episulfide compound can be suitably regulated to obtain a cured resin with less defect. By using the halide, the increase in the viscosity of the starting composition during the storage or the casting operation can be prevented.
摘要翻译： 在本发明中，在一个分子中具有由下式2表示的至少一个环硫结构的环硫化合物：其中R 5是C 1 -C 10亚烃基或单键，R 6 R 7和R 8各自独立地为C 1 -C 10烃基或氢，Y为O，S，Se或Te，p为1的整数 至5和q为0至5的整数，在长周期表的13-16族元素的卤化物和/或由下式1表示的聚合调节剂的存在下聚合：其中R“ 1，R 2和R 3各自为C 1 -C 10氢碳基或氢，R 4为C 1 -C 10亚烃基或单 键，X为F，Cl，Br，I，As，SH，OH，C 1 -C 10烷氧基，C 1 -C 10烷硫基或C 1 -C 10巯基偶氮，m为1〜5的整数， 作为光学材料。 通过使用聚合调节剂，可以适当调节环硫化合物的聚合速度，得到缺陷少的固化树脂。 通过使用卤化物，可以防止在储存或铸造操作期间起始组合物的粘度的增加。
-
公开(公告)号：US06534589B1
公开(公告)日：2003-03-18
申请号：US09450762
申请日：1999-11-30
IPC分类号： C08L8100
摘要： A process for producing a resin having a large refractive index which comprises curing an episulfide compound having one or more epithio structures represented by formula (1) in one molecule by polymerization in the presence of a polymerization catalyst and 0.001 to 3.0 parts by weight of a phenol derivative per 100 parts by weight of the episulfide compound. (R1 represents a hydrocarbon group having 1 to 10 carbon atoms, R2, R3 and R4 each represents hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms, Y represents S, O, Se or Te and m and n each represents 0 or 1).
摘要翻译： 一种具有大折射率的树脂的制造方法，其特征在于，在聚合催化剂的存在下，通过在聚合催化剂的存在下进行聚合，在一分子中固化具有式（1）所示的一个以上的环硫结构的环硫化合物，以及0.001〜3.0重量份的 苯酚衍生物相对于环硫化合物100重量份（R1表示碳原子数1〜10的烃基，R2，R3和R4各自表示氢原子或碳原子数1〜10的烃基，Y表示S，O ，Se或Te，m和n各自表示0或1）。
-
4.发明申请RESIN COMPOSITION FOR OPTICAL MEMBER AND OPTICAL MEMBER OBTAINED FROM THE SAME 有权用于光学部件和从其获得的光学部件的树脂组合物公开(公告)号：US20100130661A1
公开(公告)日：2010-05-27
申请号：US12529918
申请日：2008-03-11
IPC分类号： C08K3/30
CPC分类号： C08F12/30 , C08F212/08 , C08F212/14 , C08F212/36 , C08F216/1466 , C08F220/38 , C08F2222/1013 , C08G75/08 , G02B1/04 , C08L81/00
摘要： The present invention can provide a composition for optical members, which contains (a) a compound having one or more of any group selected from the group consisting of an acryloyl group, a methacryloyl group, an allyl group and a vinyl group and one or more β-epithiopropyl groups in a molecule. In a preferable embodiment of the present invention, the composition for optical members further contains at least one compound selected from (b) a compound having one or more β-epithiopropyl groups in a molecule while having no polymerizable unsaturated bond group, (c) an inorganic compound having a sulfur atom and/or a selenium atom, (d) a compound having one or more thiol groups in a molecule, (e) a compound having one or more amino groups in a molecule while having no heterocyclic ring, and (f) a compound having one or more of at least one group selected from the group consisting of a vinyl group, an acryloyl group, a methacryloyl group and an allyl group in a molecule.
摘要翻译： 本发明可以提供一种光学部件用组合物，其含有（a）具有选自丙烯酰基，甲基丙烯酰基，烯丙基和乙烯基中的一个或多个的一种或多种的化合物和一种或多种 一个分子中的β-二硫丙基。 在本发明的优选实施方案中，用于光学部件的组合物还含有至少一种选自（b）分子中具有一个或多个β-伯硫丙基的化合物中的化合物，同时不具有可聚合的不饱和键基，（c） 具有硫原子和/或硒原子的无机化合物，（d）分子中具有一个或多个硫醇基的化合物，（e）分子中具有一个或多个氨基但不具有杂环的化合物，以及 （f）在分子中具有一个或多个选自乙烯基，丙烯酰基，甲基丙烯酰基和烯丙基中的至少一个基团的化合物。
-
公开(公告)号：US07446163B2
公开(公告)日：2008-11-04
申请号：US11189859
申请日：2005-07-27
申请人： Masaki Tamura , Takahiro Matsui , Masanori Shimuta , Yuichi Yoshimura , Motoharu Takeuchi , Hiroshi Horikoshi , Hiroyuki Okada
发明人： Masaki Tamura , Takahiro Matsui , Masanori Shimuta , Yuichi Yoshimura , Motoharu Takeuchi , Hiroshi Horikoshi , Hiroyuki Okada
IPC分类号： C08G75/08
CPC分类号： C08G75/08 , C07D331/02
摘要： In the present invention, an episulfide compound having, in one molecule, at least one epithio structure represented by the following Formula 2: wherein R5 is C1-C10 hydrocarbylene or single bond, R6, R7 and R8 are each independently C1-C10 hydrocarbyl or hydrogen, Y is O, S, Se or Te, p is an integer from 1 to 5 and q is an integer from 0 to 5, is polymerized in the presence of a halide of a 13-16 group element of the long periodic table and/or a polymerization regulator represented by the following Formula 1: wherein R1, R2 and R3 are each C1-C10 hydrocarbyl or hydrogen, R4 is C1-C10 hydrocarbylene or single bond, X is F, Cl, Br, I, As, SH, OH, C1-C10 alkoxyl, C1-C10 alkylthio, or C1-C10 mercaptoalkylthio, and m is an integer from 1 to 5, to produce a cured resin suitable as an optical material. By using the polymerization regulator, the polymerization rate of the episulfide compound can be suitably regulated to obtain a cured resin with less defect. By using the halide, the increase in the viscosity of the starting composition during the storage or the casting operation can be prevented.
摘要翻译： 在本发明中，在一个分子中具有由下式2表示的至少一个环硫结构的环硫化合物：其中R 5是C 1 -C 10亚烃基或单键，R 6 R 7和R 8各自独立地为C 1 -C 10烃基或氢，Y为O，S，Se或Te，p为1的整数 至5和q为0至5的整数，在长周期表的13-16族元素的卤化物和/或由下式1表示的聚合调节剂的存在下聚合：其中R“ R 1，R 2和R 3各自为C 1 -C 10烃基或氢，R 4为C 1 -C 10亚烃基或单 键，X为F，Cl，Br，I，As，SH，OH，C1-C10烷氧基，C1-C10烷硫基或C1-C10巯基烷硫基，m为1〜5的整数， 作为光学材料。 通过使用聚合调节剂，可以适当调节环硫化合物的聚合速度，得到缺陷少的固化树脂。 通过使用卤化物，可以防止在储存或铸造操作期间起始组合物的粘度的增加。
-
6.发明授权公开(公告)号：US08575293B2
公开(公告)日：2013-11-05
申请号：US12310474
申请日：2007-09-11
CPC分类号： C08G18/3876 , C08G18/7635 , C08G18/7642 , C08G18/765 , G02B1/041 , C08L75/04
摘要： According to the present invention, a resin compound for optical material, comprising (a) an episulfide compound represented by a specific structural formula, (b) a xylylenedithiol compound and (c) a xylylenediisocyanate compound can be provided. In a preferable embodiment of the present invention, a resin compound for optical material having superb optical properties, a high density and a high thermal resistance can be provided. Also according to the present invention, an optical material obtained by curing the above-described resin compound can be provided.
摘要翻译： 根据本发明，可以提供一种光学材料用树脂组合物，其包含（a）由具体结构式表示的环硫化合物，（b）亚二硫醚硫醇化合物和（c）亚二甲苯基二异氰酸酯化合物。 在本发明的优选实施方案中，可以提供具有极好的光学特性，高密度和高耐热性的光学材料用树脂组合物。 另外，根据本发明，可以提供通过固化上述树脂化合物而获得的光学材料。
-
公开(公告)号：US07309794B1
公开(公告)日：2007-12-18
申请号：US10415906
申请日：2000-11-07
申请人： Akikazu Amagai , Yuichi Yoshimura , Motoharu Takeuchi , Atsuki Niimi , Hiroshi Horikoshi , Masanori Shimuta , Nobuyuki Uemura
发明人： Akikazu Amagai , Yuichi Yoshimura , Motoharu Takeuchi , Atsuki Niimi , Hiroshi Horikoshi , Masanori Shimuta , Nobuyuki Uemura
IPC分类号： C07D331/02
CPC分类号： C07D331/02
摘要： Episulfide compounds useful as starting materials of optical materials are stably stored for a long period of time at a temperature ranging from their solidifying points to 20° C., preventing the production or precipitation of polymers and the yellowing.
摘要翻译： 可用作光学材料原料的二硫化合物在其凝固点至20℃的温度下长时间稳定地储存，防止聚合物的产生或沉淀和变黄。
-
公开(公告)号：US20050261467A1
公开(公告)日：2005-11-24
申请号：US11189859
申请日：2005-07-27
申请人： Masaki Tamura , Takahiro Matsui , Masanori Shimuta , Yuichi Yoshimura , Motoharu Takeuchi , Hiroshi Horikoshi , Hiroyuki Okada
发明人： Masaki Tamura , Takahiro Matsui , Masanori Shimuta , Yuichi Yoshimura , Motoharu Takeuchi , Hiroshi Horikoshi , Hiroyuki Okada
IPC分类号： C07D331/02 , C08G75/08 , C08G75/00
CPC分类号： C08G75/08 , C07D331/02
摘要： In the present invention, an episulfide compound having, in one molecule, at least one epithio structure represented by the following Formula 2: wherein R5 is C1-C10 hydrocarbylene or single bond, R6, R7 and R8 are each independently C1-C10 hydrocarbyl or hydrogen, Y is O, S, Se or Te, p is an integer from 1 to 5 and q is an integer from 0 to 5, is polymerized in the presence of a halide of a 13-16 group element of the long periodic table and/or a polymerization regulator represented by the following Formula 1: wherein R1, R2 and R3 are each C1-C10 hydrocarbyl or hydrogen, R4 is C1-C10 hydrocarbylene or single bond, X is F, Cl, Br, I, As, SH, OH, C1-C10 alkoxyl, C1-C10 alkylthio, or C1-C10 mercaptoalkylthio, and m is an integer from 1 to 5, to produce a cured resin suitable as an optical material. By using the polymerization regulator, the polymerization rate of the episulfide compound can be suitably regulated to obtain a cured resin with less defect. By using the halide, the increase in the viscosity of the starting composition during the storage or the casting operation can be prevented.
摘要翻译： 在本发明中，在一个分子中具有由下式2表示的至少一个环硫结构的环硫化合物：其中R 5是C 1 -C 10亚烃基或单键，R 6 R 7和R 8各自独立地为C 1 -C 10烃基或氢，Y为O，S，Se或Te，p为1的整数 至5和q为0至5的整数，在长周期表的13-16族元素的卤化物和/或由下式1表示的聚合调节剂的存在下聚合：其中R“ R 1，R 2和R 3各自为C 1 -C 10烃基或氢，R 4为C 1 -C 10亚烃基或单 键，X为F，Cl，Br，I，As，SH，OH，C1-C10烷氧基，C1-C10烷硫基或C1-C10巯基烷硫基，m为1〜5的整数， 作为光学材料。 通过使用聚合调节剂，可以适当调节环硫化合物的聚合速度，得到缺陷少的固化树脂。 通过使用卤化物，可以防止在储存或铸造操作期间起始组合物的粘度的增加。
-
9.发明授权Process for tinting a resin having a large refractivity index and optical material tinted by the process 有权用于着色具有大的折射率的树脂和通过该方法着色的光学材料的方法公开(公告)号：US06197226B1
公开(公告)日：2001-03-06
申请号：US09221939
申请日：1998-12-28
IPC分类号： B29D1100
CPC分类号： D06P5/22 , C08G75/08 , D06P1/0004 , D06P1/623 , D06P1/625 , D06P1/65118 , D06P1/65131 , D06P1/67316 , G02B1/04 , C08L81/02
摘要： A process for tinting a resin and a tinted optical material produced by the process. The process comprising dipping a resin into a liquid containing at least one compound selected from the group consisting of polar inorganic compounds and polar organic compounds and subsequently tinting the resin, wherein the resin is obtained by curing by polymerization of a sulfur-containing compound alone or a composition comprising the sulfur-containing compound, the sulfur-containing compound having in the molecule thereof one or more structures represented by the following formula hydrocarbon group having 1 to 10 carbon atoms, R2, R3 and R4 each represents a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms, Y represents S or O and n represents 0 or 1.
摘要翻译： 用于着色树脂和通过该方法生产的着色光学材料的方法。 该方法包括将树脂浸入含有至少一种选自极性无机化合物和极性有机化合物的化合物的液体中，随后使树脂着色，其中树脂通过单独的含硫化合物的聚合固化而获得，或 包含含硫化合物的组合物，在分子中含有下式的碳原子数1〜10的碳原子数为1〜10的结构的含硫化合物，R2，R3，R4各自表示氢原子或烃基 具有1至10个碳原子，Y表示S或O，n表示0或1。
-
10.发明申请公开(公告)号：US20100004421A1
公开(公告)日：2010-01-07
申请号：US12310474
申请日：2007-09-11
IPC分类号： C08G18/77
CPC分类号： C08G18/3876 , C08G18/7635 , C08G18/7642 , C08G18/765 , G02B1/041 , C08L75/04
摘要： According to the present invention, a resin compound for optical material, comprising (a) an episulfide compound represented by a specific structural formula, (b) a xylylenedithiol compound and (c) a xylylenediisocyanate compound can be provided. In a preferable embodiment of the present invention, a resin compound for optical material having superb optical properties, a high density and a high thermal resistance can be provided. Also according to the present invention, an optical material obtained by curing the above-described resin compound can be provided.
摘要翻译： 根据本发明，可以提供一种光学材料用树脂组合物，其包含（a）由具体结构式表示的环硫化合物，（b）亚二硫醚硫醇化合物和（c）亚二甲苯基二异氰酸酯化合物。 在本发明的优选实施方案中，可以提供具有极好的光学特性，高密度和高耐热性的光学材料用树脂组合物。 另外，根据本发明，可以提供通过固化上述树脂化合物而获得的光学材料。
-
-
-
-
-
-
-
-
-
搜索结果
50 条记录 (耗时 0.017 秒)
