摘要:
The present invention aims to provide lithium composite compound particles which can exhibit good cycle characteristics and an excellent high-temperature storage property when used as a positive electrode active substance of a secondary battery, and a secondary battery using the lithium composite compound particles. The present invention relates to lithium composite compound particles having a composition represented by the compositional formula: Li1+xNi1−y−z−aCoyMnzMaO2, in which the lithium composite compound particles have an ionic strength ratio A (LiO−/NiO2−) of not more than 0.5 and an ionic strength ratio B (Li3CO3+/Ni+) of not more than 20 as measured on a surface of the respective lithium composite compound particles using a time-of-flight secondary ion mass spectrometer.
摘要翻译:本发明的目的在于提供当用作二次电池的正极活性物质和使用该锂复合化合物颗粒的二次电池时,可以表现出良好的循环特性和优异的高温保存性的锂复合化合物颗粒。 本发明涉及具有由Li1 + xNi1-yz-aCoyMnzMaO2组成表示的组成的锂复合化合物颗粒,其中锂复合化合物颗粒的离子强度比A(LiO- / NiO 2))不大于 0.5,离子强度比B(Li 3 CO 3 + / Ni +)为不超过20,在各锂复合化合物颗粒的表面上使用飞行时间二次离子质谱仪测定。
摘要:
The present invention aims to provide lithium composite compound particles which can exhibit good cycle characteristics and an excellent high-temperature storage property when used as a positive electrode active substance of a secondary battery, and a secondary battery using the lithium composite compound particles. The present invention relates to lithium composite compound particles having a composition represented by the compositional formula: Li1+xNi1−y−z−aCoyMnzMaO2, in which the lithium composite compound particles have an ionic strength ratio A (LiO−/NiO2−) of not more than 0.5 and an ionic strength ratio B (Li3CO3+/Ni+) of not more than 20 as measured on a surface of the respective lithium composite compound particles using a time-of-flight secondary ion mass spectrometer.
摘要翻译:本发明的目的在于提供当用作二次电池的正极活性物质和使用该锂复合化合物颗粒的二次电池时,可以表现出良好的循环特性和优异的高温保存性的锂复合化合物颗粒。 本发明涉及具有由Li1 + xNi1-y-z-aCoyMnzMaO2组成表示的组成的锂复合化合物颗粒,其中锂复合化合物颗粒的离子强度比A(LiO- / NiO 2)不是 大于0.5,离子强度比B(Li 3 CO 3 + / Ni +)不超过20,这在使用飞行时间二次离子质谱仪的各种锂复合化合物颗粒的表面上测量。
摘要:
The present invention relates to Li—Ni-based composite oxide particles comprising Mn, and Co and/or Al, wherein Co and Al are uniformly dispersed within the particles, and Mn is present with a gradient of its concentration in a radial direction of the respective particles such that a concentration of Mn on a surface of the respective particles is higher than that at a central portion thereof. The Li—Ni-based composite oxide particles can be produced by allowing an oxide and a hydroxide comprising Mn to mechanically adhere to Li—Ni-based oxide comprising Co and/or Al; and then heat-treating the obtained material at a temperature of not lower than 400° C. and not higher than 1,000° C. The Li—Ni-based composite oxide particles of the present invention are improved in thermal stability and alkalinity.
摘要:
The present invention relates to Li—Ni-based composite oxide particles comprising Mn, and Co and/or Al, wherein Co and Al are uniformly dispersed within the particles, and Mn is present with a gradient of its concentration in a radial direction of the respective particles such that a concentration of Mn on a surface of the respective particles is higher than that at a central portion thereof. The Li—Ni-based composite oxide particles can be produced by allowing an oxide and a hydroxide comprising Mn to mechanically adhere to Li—Ni-based oxide comprising Co and/or Al; and then heat-treating the obtained material at a temperature of not lower than 400° C. and not higher than 1,000° C. The Li—Ni-based composite oxide particles of the present invention are improved in thermal stability and alkalinity.
摘要:
The present invention relates to positive electrode active substance particles comprising a compound having at least a crystal system belonging to a space group of R−3m and a crystal system belonging to a space group of C2/m, and boron, wherein the compound is a composite oxide comprising at least Li, Mn, and Co and/or Ni; a relative intensity ratio [(a)/(b)] of a maximum diffraction peak intensity (a) observed at 2θ=20.8±1° in a powder X-ray diffraction pattern of the positive electrode active substance as measured using a Cu-Ka ray to a maximum diffraction peak intensity (b) observed at 2θ=18.6±1° in the powder X-ray diffraction pattern, is 0.02 to 0.5; a content of Mn in the positive electrode active substance particles is controlled such that a molar ratio of Mn/(Ni+Co+Mn) therein is not less than 0.55; and the positive electrode active substance particles comprise the boron in an amount of 0.001 to 3% by weight. The positive electrode active substance particles of the present invention are produced by calcining a mixture comprising precursor particles comprising Mn, and Ni and/or Co, a lithium compound and a boron compound at a temperature of 500 to 1500° C. The positive electrode active substance particles of the present invention can provide a secondary battery which can be improved in charge/discharge capacity and cycle characteristics.
摘要:
Positive electrode active substance particles including a compound having at least a crystal system belonging to a space group of R−3m and a crystal system belonging to a space group of C2/m, and boron. The compound is a composite oxide comprising at least Li, Mn, and Co and/or Ni; a relative intensity ratio [(a)/(b)] of a maximum diffraction peak intensity (a) observed at 2θ=20.8±1° in a powder X-ray diffraction pattern of the positive electrode active substance as measured using a Cu-Ku ray to a maximum diffraction peak intensity (b) observed at 2θ=18.6±1° in the powder X-ray diffraction pattern, is 0.02 to 0.5; a content of Mn in the positive electrode active substance particles such that a molar ratio of Mn/(Ni+Co+Mn) is not less than 0.55; and the positive electrode active substance particles include boron in an amount of 0.001 to 3% by weight.
摘要:
The present invention relates to positive electrode active substance particles comprising a compound having a spinel type structure comprising at least Li, Ni and Mn, and having an Li content which is controlled such that a molar ratio of Li(Ni+Mn) therein is 0.3 to 0.65, an Ni content of 5 to 25% by weight, an Na content of 0.05 to 1.9% by weight and an S content of 0.0005 to 0.16% by weight, a sum of the Na content and the S content being 0.09 to 1.9005% by weight. The positive electrode active substance particles according to the present invention can be suitably used as positive electrode active substance particles for non-aqueous electrolyte secondary batteries which can exhibit a high discharge voltage and an excellent discharge capacity.
摘要:
A processing apparatus for processing elements, which are contained in a message received via a network, by an application is provided. The apparatus includes a selection unit configured to select, in accordance with the number of elements contained in the received message, whether conversion of an element to a form by the application is carried out in response to or prior to a request from the application, a storage unit configured to store an element, which is converted to a form by the application, in response to a request from the application, a read-out unit configured to read an element, which has been requested by the application, out of the storage unit, and a conversion unit configured to convert an element to a form by the application in response to and prior to a request from the application in accordance with the selection.
摘要:
Provided is a new system for content use and settlement. A user requests a mobile telephone charge management server (3000) to perform proxy settlement for goods purchased using mobile telephones 1 (4100), 2 (4200) and 3 (4300). The mobile telephone charge management server (3000) makes an inquiry to a registration server (3100) as to whether or not proxy settlement is possible. When proxy settlement is not possible, the mobile telephone performs settlement using electronic money that has been deposited therein.
摘要:
The present invention provides mobile terminals with various types of services such as electronic commerce service, music delivery service, and position information service. User applications required for the electronic commerce service, music delivery service, and position information service are respectively configured as service objects each having a server facility, and further a local gateway is provided, whereby various types of services can be used through a browser.