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公开(公告)号：US20070292925A1
公开(公告)日：2007-12-20
申请号：US11667688
申请日：2005-10-31
CPC分类号： C12P7/26 , C12P41/003
摘要： According to the present invention, there is provided a method for preparing an optically active compound, characterized in that said method comprises permitting a mixture of optical isomers relative to the carbon atom in the β-position in relation to the carbon atom bound to an esterified hydroxy group of an enol ester to hydrolyse either one optical isomer preferentially in the presence of an enzyme and allowing the carbonyl compound resulting from such hydrolysis to enrich the proportion of its isomer having either one configuration in the β-position in relation to the carbonyl group or allowing the enol ester left non-hydrolyzed to enrich the proportion of its isomer having either one configuration on the carbon atom in the β-position in relation to the carbon atom to which the esterified hydroxyl group bonds.
摘要翻译： 根据本发明，提供了一种制备光学活性化合物的方法，其特征在于所述方法包括允许相对于与酯化的结合的碳原子相对于β-位置的碳原子的光学异构体的混合物 使烯醇酯的羟基在酶的存在下优先水解一种旋光异构体，并使得由这种水解产生的羰基化合物能够富集其相对于羰基在β-位上具有一个结构的异构体的比例 或使烯醇酯未水解以富集其相对于酯化羟基键合的碳原子在β-位上的碳原子上具有一种构型的异构体的比例。
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2.发明授权Optically active 3-methylcyclopentadecanone and method for producing intermediate thereof 有权光学活性3-甲基环十五烷酮及其中间体的制备方法公开(公告)号：US07728177B2
公开(公告)日：2010-06-01
申请号：US11920600
申请日：2006-05-17
申请人： Shigeru Tanaka , Kenya Ishida , Hiroyuki Matsuda
发明人： Shigeru Tanaka , Kenya Ishida , Hiroyuki Matsuda
IPC分类号： C07C45/00
CPC分类号： C07B53/00 , C07B2200/07 , C07C45/513 , C07C45/54 , C07C67/00 , C07C2601/18 , C07F9/657154 , C07C49/385 , C07C69/013 , C07C69/24
摘要： Disclosed is a method for producing an optically active 3-methylcyclopentadecan-1-one which is characterized in that 2-cyclopentadecen-1-one is subjected to a 1,4-conjugate addition reaction of a methyl group by using a methylated organic metal in the presence of a copper catalyst, an enol anion scavenger and a specific optically active phosphoramidite for obtaining an optically active 3-methyl-1-cyclopentadecene derivative, and then the thus-obtained 3-methyl-1-cyclopentadecene derivative is subjected to a solvolysis.
摘要翻译： 公开了一种光学活性3-甲基环戊烷-1-酮的制备方法，其特征在于2-环戊烯-1-酮通过使用甲基化有机金属在甲基化有机金属中进行1,4-偶合物加成反应 存在铜催化剂，烯醇阴离子清除剂和用于获得光学活性的3-甲基-1-环戊烯衍生物的特定光学活性亚磷酰胺，然后由此得到的3-甲基-1-环戊烯衍生物进行溶剂分解 。
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3.发明申请Optically Active 3-Methylcyclopentadecanone And Method For Producing Intermediate Thereof 有权光学活性3-甲基环十五烷酮及其制备方法公开(公告)号：US20090124826A1
公开(公告)日：2009-05-14
申请号：US11920600
申请日：2006-05-17
申请人： Shigeru Tanaka , Kenya Ishida , Hiroyuki Matsuda
发明人： Shigeru Tanaka , Kenya Ishida , Hiroyuki Matsuda
IPC分类号： C07C45/51 , C07C67/00 , C07F9/6571
CPC分类号： C07B53/00 , C07B2200/07 , C07C45/513 , C07C45/54 , C07C67/00 , C07C2601/18 , C07F9/657154 , C07C49/385 , C07C69/013 , C07C69/24
摘要： Disclosed is a method for producing an optically active 3-methylcyclopentadecan-1-one which is characterized in that 2-cyclopentadecen-1-one is subjected to a 1,4-conjugate addition reaction of a methyl group by using a methylated organic metal in the presence of a copper catalyst, an enol anion scavenger and a specific optically active phosphoramidite for obtaining an optically active 3-methyl-1-cyclopentadecene derivative, and then the thus-obtained 3-methyl-1-cyclopentadecene derivative is subjected to a solvolysis.
摘要翻译： 公开了一种光学活性3-甲基环戊烷-1-酮的制备方法，其特征在于2-环戊烯-1-酮通过使用甲基化有机金属在甲基化有机金属中进行1,4-偶合物加成反应 存在铜催化剂，烯醇阴离子清除剂和用于获得光学活性的3-甲基-1-环戊烯衍生物的特定光学活性亚磷酰胺，然后由此得到的3-甲基-1-环戊烯衍生物进行溶剂分解 。
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公开(公告)号：US07846701B2
公开(公告)日：2010-12-07
申请号：US11667688
申请日：2005-10-31
IPC分类号： C12P7/26
CPC分类号： C12P7/26 , C12P41/003
摘要： According to the present invention, there is provided a method for preparing an optically active compound, characterized in that said method comprises permitting a mixture of optical isomers relative to the carbon atom in the β-position in relation to the carbon atom bound to an esterified hydroxy group of an enol ester to hydrolyse either one optical isomer preferentially in the presence of an enzyme and allowing the carbonyl compound resulting from such hydrolysis to enrich the proportion of its isomer having either one configuration in the β-position in relation to the carbonyl group or allowing the enol ester left non-hydrolyzed to enrich the proportion of its isomer having either one configuration on the carbon atom in the β-position in relation to the carbon atom to which the esterified hydroxyl group bonds.
摘要翻译： 根据本发明，提供了一种制备光学活性化合物的方法，其特征在于所述方法包括允许相对于与一个碳原子结合的碳原子相对于碳原子的光学异构体的混合物 烯醇酯的酯化羟基在酶的存在下优先水解任一种旋光异构体，并使得由这种水解产生的羰基化合物能够富集其相对于化合物中的任何一种构型的其异构体的比例 使烯醇酯残留未水解以富集其相对于与酯化羟基键合的碳原子相关的碳原子上具有一个构型的异构体的比例。
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公开(公告)号：US20070287870A1
公开(公告)日：2007-12-13
申请号：US11667476
申请日：2004-11-11
申请人： Hiroyuki Matsuda , Shigeru Tanaka
发明人： Hiroyuki Matsuda , Shigeru Tanaka
IPC分类号： C07C45/00
CPC分类号： C07C45/513 , C07B2200/07 , C07C45/511 , C07C45/54 , C07C49/385 , C07C67/08 , C07C68/06 , C07C69/013 , C07C69/96 , C07C2601/18 , C07C69/24 , C07C69/145
摘要： A process for producing muscone by methyl addition to the 1,4-conjugation of 2-cyclopentadecenone. By the process, muscone is produced in high yield not under reaction condition including an extremely low temperature and a low concentration but under practical condition. The process comprises subjecting 2-cyclopentadecenone to a 1,4-conjugation addition reaction with an organometallic methylation reagent in the presence of a copper or nickel catalyst and an enol anion scavenger to obtain a 3-methyl-1-cyclopentadecene derivative represented by General Formula (II) and then solvolyzing the enol moiety of the 3-methyl-1-cyclopentadecene derivative to obtain muscone.
摘要翻译： 通过甲基添加到2-环戊烯酮的1,4-缀合物来生产肌肉的方法。 通过该方法，在非常低的温度和低浓度但在实际条件下的反应条件下，以高产率生产肌肉。 该方法包括在铜或镍催化剂和烯醇阴离子清除剂存在下，使有机金属甲基化试剂与2-环戊烯酮进行1,4-缀合加成反应，得到通式（1）表示的3-甲基-1-环戊烯衍生物 （II），然后溶剂化3-甲基-1-环十五碳烯衍生物的烯醇部分以获得肌肉酮。
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公开(公告)号：US07479574B2
公开(公告)日：2009-01-20
申请号：US11667476
申请日：2004-11-11
申请人： Hiroyuki Matsuda , Shigeru Tanaka
发明人： Hiroyuki Matsuda , Shigeru Tanaka
IPC分类号： C07C45/00
CPC分类号： C07C45/513 , C07B2200/07 , C07C45/511 , C07C45/54 , C07C49/385 , C07C67/08 , C07C68/06 , C07C69/013 , C07C69/96 , C07C2601/18 , C07C69/24 , C07C69/145
摘要： A process for producing muscone by methyl addition to the 1,4-conjugation of 2-cyclopentadecenone. By the process, muscone is produced in high yield not under reaction condition including an extremely low temperature and a low concentration but under practical condition. The process comprises subjecting 2-cyclopentadecenone to a 1,4-conjugation addition reaction with an organometallic methylation reagent in the presence of a copper or nickel catalyst and an enol anion scavenger to obtain a 3-methyl-1-cyclopentadecene derivative represented by General Formula (II) and then solvolyzing the enol moiety of the 3-methyl-1-cyclopentadecene derivative to obtain muscone.
摘要翻译： 通过甲基添加到2-环戊烯酮的1,4-缀合物来生产肌肉的方法。 通过该方法，在非常低的温度和低浓度但在实际条件下的反应条件下，以高产率生产肌肉。 该方法包括在铜或镍催化剂和烯醇阴离子清除剂存在下，使有机金属甲基化试剂与2-环戊烯酮进行1,4-缀合加成反应，得到通式（1）表示的3-甲基-1-环戊烯衍生物 （II），然后溶剂化3-甲基-1-环十五碳烯衍生物的烯醇部分以获得肌肉酮。
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公开(公告)号：US20150224579A1
公开(公告)日：2015-08-13
申请号：US13882723
申请日：2012-12-08
申请人： Hiroyuki Matsuda , Gorou Arahi , Hidenori Ando
发明人： Hiroyuki Matsuda , Gorou Arahi , Hidenori Ando
CPC分类号： B23B5/36 , B23B1/00 , B29C33/303 , B29L2011/0016 , C03B11/06 , C03B11/082 , C03B2215/06 , C03B2215/414 , Y10T82/10
摘要： A metal mold manufacturing method is provided, which is capable of forming a metal mold having a plurality of transfer surfaces with positions of optical axes being different by a lathe at high accuracy. An n-th (n is an integer of 1 to 4) side surface SDn of a material 1 of the metal mold abuts against an X-axis directional reference plane 2b of a jig 2, an (n+1)th side surface (but n=1 when n is 4) of a material 1′ of the metal mold abuts against a Y-axis directional reference plane 2c of the jig 2, and the material 1 of the metal mold is thus fixed to the jig 2. Subsequently, the n-th transfer surface is formed by cutting the material 1′ of the metal mold while rotating the jig 2 and the material 1 of the metal mold together by a lathe. Thereafter, the steps are repeated in a way that raises n by one.
摘要翻译： 提供了一种金属模具制造方法，其能够以高精度形成具有多个转轴表面的金属模具，其中光轴的位置由车床不同。 金属模的材料1的第n（n为1〜4的整数）侧面SDn与夹具2的X轴方向基准面2b抵接，第（n + 1）侧面 但n = 1时，n = 1，金属模的材料1'与夹具2的Y轴方向基准面2c抵接，金属模的材料1固定在夹具2上。随后 通过在车床上将金属模具2和金属模具的材料1一起旋转的同时，通过切割金属模具的材料1'来形成第n个转印面。 此后，以将n提高1的方式重复这些步骤。
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公开(公告)号：US20140055860A1
公开(公告)日：2014-02-27
申请号：US13988483
申请日：2012-10-09
申请人： Tomoyuki Morimoto , Takashi Sannokyou , Hiroshi Nagoya , Hiroumi Tanigawa , Hiroyuki Matsuda , Toshiyuki Imai , Sadaharu Honda , Takahiro Mizukane , Kojiro Takatori , Shuhei Ashida
发明人： Tomoyuki Morimoto , Takashi Sannokyou , Hiroshi Nagoya , Hiroumi Tanigawa , Hiroyuki Matsuda , Toshiyuki Imai , Sadaharu Honda , Takahiro Mizukane , Kojiro Takatori , Shuhei Ashida
CPC分类号： G02B13/0015 , B29D11/00298 , B29D11/00403 , G02B3/0031 , G02B3/0062 , G02B7/02 , G02B7/021 , G02B13/003 , G02B13/0085 , Y10T29/49998 , Y10T156/1052
摘要： To provide a lens unit producing method capable for positioning a lens array with high precision over a long period of time, a lens array, and a lens unit. When the first flat surfaces LA1f come in contact with the respective tapered surfaces HLD1, the glass lens array LA1 cannot rotate more than that for the holder HLD. Meanwhile, since the tapered surfaces HLD1 are regulated by the respective opposite first flat surface LA1f, the glass lens array LA1 cannot move more than that relatively to the holder HLD. That is, by holding the glass lens array LA1 with the holder HLD, the glass lens array LA1 can be positioned with high precision for the holder HLD.
摘要翻译： 为了提供能够长时间高精度地定位透镜阵列的透镜单元制造方法，透镜阵列和透镜单元。 当第一平面LA1f与各个锥面HLD1接触时，玻璃透镜阵列LA1不能比保持器HLD旋转更多。 同时，由于锥形表面HLD1被相应的相对的第一平坦表面LA1f调节，所以玻璃透镜阵列LA1不能相对于保持器HLD移动。 也就是说，通过用保持器HLD保持玻璃透镜阵列LA1，玻璃透镜阵列LA1可以高精度地定位于保持器HLD。
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公开(公告)号：US08040783B2
公开(公告)日：2011-10-18
申请号：US12606705
申请日：2009-10-27
申请人： Takeshi Endo , Hiroshi Hatano , Tetsuya Noda , Kazutaka Noguchi , Hiroyuki Matsuda , Shigeru Yamasaki
发明人： Takeshi Endo , Hiroshi Hatano , Tetsuya Noda , Kazutaka Noguchi , Hiroyuki Matsuda , Shigeru Yamasaki
IPC分类号： G11B7/00
CPC分类号： G11B7/083 , G11B7/0065 , G11B7/082 , G11B7/1362
摘要： An optical information recording and reproducing apparatus relating to the invention employs a two-beam interference method. In the optical information recording and reproducing apparatus, a moving device moves an information recording medium between a recording and reproducing position and a retracting position, and a mirror moves together with the information recording medium. When the information recording medium moves to the recording and reproducing position, the mirror moves to a position which is displaced from the at least one of the reference beam and the information beam. When the information recording medium moves to the retracting position, the mirror moves to a position where the mirror can reflect the at least one of the reference beam and the information beam toward a detector for detecting a deviation of the at least one of the reference beam and the information beam.
摘要翻译： 本发明的光信息记录再现装置采用双光束干涉法。 在光学信息记录和再现装置中，移动装置在记录和再现位置与缩回位置之间移动信息记录介质，并且反射镜与信息记录介质一起移动。 当信息记录介质移动到记录和再现位置时，反射镜移动到从参考光束和信息光束中的至少一个偏移的位置。 当信息记录介质移动到缩回位置时，反射镜移动到反射镜可以将参考光束和信息光束中的至少一个反射到检测器的位置，用于检测参考光束中的至少一个的偏差 和信息光束。
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公开(公告)号：US07522989B2
公开(公告)日：2009-04-21
申请号：US11368684
申请日：2006-03-07
申请人： Hiroyuki Matsuda
发明人： Hiroyuki Matsuda
IPC分类号： G08G1/00
CPC分类号： G08G1/0104
摘要： The present invention provides a carriage system which, to choose one of a plurality of running routes, can appropriately determine the congestion statuses of the running routes to choose one of them along which a carriage can reach its destination earliest. In a carriage system 10, each carriage 1 is provided with running status reporting means 1b for reporting a running status based on a running speed to a zone controller 3. The zone controller 3 is provided with congestion information generating means 3b for generating congestion information by putting together reports from the running status reporting means 1b of the carriages 1.
摘要翻译： 本发明提供一种滑架系统，用于选择多个运行路线中的一个运行路线，可以适当地确定运行路线的拥挤状态，以选择运输路线最早到达目的地的其中一个。 在托架系统10中，每个托架1设置有运行状态报告装置1b，用于基于运行速度向区域控制器3报告运行状态。区域控制器3设置有拥挤信息生成装置3b，用于通过 将来自车厢1的运行状态报告单元1b的报告放在一起。
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