Process for polymerization of olefins
    5.
    发明授权
    Process for polymerization of olefins 失效
    烯烃聚合方法

    公开(公告)号:US4565798A

    公开(公告)日:1986-01-21

    申请号:US672780

    申请日:1984-11-19

    CPC分类号: C08F10/00

    摘要: A process for polymerizing olefins in the presence of a catalyst composed of:(A) a catalyst component obtained by contacting with one another,(a) a magnesium alkoxide,(b) a silicon compound having a hydrogen-silicon bond,(c) an electron donor compound, and(d) a titanium compound(B) an organic compound of a metal of Groups I and III of the Periodic Table, and(C) an organo silicon compound represented by the formula R.sub.q.sup.9 SiX.sub.g.sup.2 (OR.sup.10).sub.k wherein R.sup.9 and R.sup.10 are the same or different hydrocarbon groups, X.sub.2 is a halogen atom, 0.ltoreq.q

    摘要翻译: 一种在催化剂存在下聚合烯烃的方法,该催化剂由以下组成:(A)通过彼此接触获得的催化剂组分,(a)烷醇镁,(b)具有氢 - 硅键的硅化合物,(c) 电子给体化合物和(d)钛化合物(B)元素周期表第I族和第III族金属的有机化合物和(C)由式Rq9SiXg2(OR10)k表示的有机硅化合物,其中R9 R 10为相同或不同的烃基,X2为卤素原子,0

    Titanium trichloride catalyst and process for the production thereof
    6.
    发明授权
    Titanium trichloride catalyst and process for the production thereof 失效
    三氯化钛催化剂及其生产方法

    公开(公告)号:US4321346A

    公开(公告)日:1982-03-23

    申请号:US111171

    申请日:1979-07-20

    CPC分类号: C08F10/00

    摘要: A titanium trichloride catalytic complex is produced by reducing titanium tetrachloride with an organo-metal compound and then treating the resulting reduced solids product with a chlorinated saturated hydrocarbon having two carbon atoms in the presence of a complexing agent. The resulting titanium trichloride complex composition, when employed as a co-catalyst with an organo-metal compound for Ziegler-type catalysts in polymerization of .alpha.-olefins, results in uniform polymer grains with unexpectedly high polymerization activity and high stereoregular polymer yielding ratios.

    摘要翻译: 通过用有机金属化合物还原四氯化钛然后在络合剂存在下用具有两个碳原子的氯化饱和烃处理所得的还原固体产物来制备三氯化钛催化络合物。 所得到的三氯化钛复合物组合物当用作α-烯烃聚合中的齐格勒型催化剂的有机金属化合物的助催化剂时,导致均匀的聚合物颗粒具有意想不到的高聚合活性和高立体规则聚合物产率。

    Process for the production of a catalyst component for use in the
polymerization of alpha olefins
    7.
    发明授权
    Process for the production of a catalyst component for use in the polymerization of alpha olefins 失效
    用于生产用于α-烯烃聚合的催化剂组分的方法

    公开(公告)号:US4062804A

    公开(公告)日:1977-12-13

    申请号:US703562

    申请日:1976-07-08

    CPC分类号: C08F10/00 Y02P20/52

    摘要: The invention relates to a method for preparing a catalyst composition for polymerization of propylene, having high activity and producing polypropylene of high stereoregularity in narrow particle size distribution, which comprises:1. reducing TiCl.sub.4 by a mixture of diethylaluminum chloride (DEAC) and ethylaluminum dichloride (EADC), thereby forming a reduced solid (TiCl.sub.3),2. removing the aluminum compound from the reduced solid;3. treating the said reduced solid with a mixture or complex of TiCl.sub.4 and diisoamylether (IAE), and4. separating the solid catalyst from the solution.Preferably step 2 is performed by washing with a complexing agent for the aluminum compound.

    摘要翻译: 本发明涉及一种制备聚合丙烯的催化剂组合物的方法,该催化剂组合物具有高活性并产生窄的粒度分布具有高立构规整性的聚丙烯,其包括:

    Process for polymerization of olefins

    公开(公告)号:US4716206A

    公开(公告)日:1987-12-29

    申请号:US927551

    申请日:1986-11-05

    CPC分类号: C08F10/00

    摘要: A process for homopolymerizing an olefin or copolymerizing an olefin with another olefin in the presence of a catalyst composed of(a) a solid catalyst component containing magnesium atoms, titanium atoms, halogen atoms, and an electron donor compound,(b) an organoaluminum compound represented by the formula R.sup.1 R.sup.2 R.sup.3 Al (wherein R.sup.1, R.sup.2, and R.sup.3, which may be the same or different, each denote a C.sub.1-20 alkyl, alkenyl, cycloalkyl, aryl, aralkyl, or alkoxy group, or a hydrogen atom;(c) an organoaluminum compound represented by the formula R.sup.4.sub.3-n AlX.sub.n (wherein R.sup.4 denotes a C.sub.1-20 alkyl, alkenyl, cycloalkyl, aryl, aralkyl, or alkoxy group; X denotes a halogen atom; and n.gtoreq.1),(d) an electron donor compound containing a nitrogen atom, sulfur atom, oxygen atom, or phosphorus atom, and(e) an aromatic ester compound.

    Process for producing ethylene polymers
    10.
    发明授权
    Process for producing ethylene polymers 失效
    生产乙烯聚合物的方法

    公开(公告)号:US4485187A

    公开(公告)日:1984-11-27

    申请号:US418499

    申请日:1982-09-15

    CPC分类号: C08F10/00

    摘要: A catalyst for polymerizing ethylene and .alpha.-olefins and process for producing ethylene polymers which comprises homopolymerizing ethylene or copolymerizing ethylene and other olefins in the presence of a catalyst comprising a catalyst component and an organoaluminum compound, said catalyst component being obtained by mechanically copulverizing (A) a magnesium halide and (B) magnesium hydrocarbyloxide at a molar ratio of B/A=0.5 to 1.5 and subsequently bringing the resulting pulverized product into contact with a tetravalent titanium halide in the presence of a hydrocarbon and/or halogenated hydrocarbon.

    摘要翻译: 一种用于聚合乙烯和α-烯烃的催化剂以及用于生产乙烯聚合物的方法,该方法包括在包含催化剂组分和有机铝化合物的催化剂的存在下均聚乙烯或共聚乙烯和其它烯烃,所述催化剂组分通过机械共混(A )卤化镁和(B)摩尔比为B / A = 0.5至1.5的镁氢氧化镁,随后在烃和/或卤代烃存在下将所得粉碎产物与四价卤化钛接触。