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    Process for producing 1,2,4-triazolin-5-one derivatives, and intermediates therefor
    1.
    发明授权
    Process for producing 1,2,4-triazolin-5-one derivatives, and intermediates therefor 失效
    制备1,2,4-三唑啉-5-酮衍生物的方法及其中间体

    公开(公告)号：US4845232A

    公开(公告)日：1989-07-04

    申请号：US923935

    申请日：1986-10-24

    申请人： Hisanori Matsui ,  Keiji Sutoh ,  Moriharu Yamamoto ,  Kazuhiro Takagi ,  Kunihiro Yabutani ,  Kuniaki Taninaka ,  Mitsuru Kajioka

    发明人： Hisanori Matsui ,  Keiji Sutoh ,  Moriharu Yamamoto ,  Kazuhiro Takagi ,  Kunihiro Yabutani ,  Kuniaki Taninaka ,  Mitsuru Kajioka

    IPC分类号： C07D249/12

    CPC分类号： C07D249/12

    摘要： A process for producing 1,2,4-triazolin-5-one derivatives represented by the general formula (I) ##STR1## wherein R is a haloalkyl group of 1 to 5 carbon atoms and R.sup.1 is a hydrogen atom, an alkyl group of 1 to 6 carbon atoms, an alkyl group of 1 to 6 carbon atoms having halogen atom substituents, a cycloalkyl group of 3 to 6 carbon atoms, a cycloalkyl group of 3 to 6 carbon atoms having halogen atom substituents, a cyanoalkyl group of 2 to 4 carbon atoms, an alkenyl group of w to 6 carbon atoms, an alkynyl group of 2 to 6 carbon atoms, a lower alkoxyalkyl group of 2 to 6 carbon atoms, a lower alkylthioalkyl group of 2 to 8 carbon atoms, a lower alkylsufinylalkyl group of 2 to 6 carbon atoms, a lower alkylsufonylalkyl group of 2 to 6 carbon atoms, a lower alkoxyalkoxyalkyl group of 3 to 8 carbon atoms, a hydroxycarbonylalkyl group of 2 to 3 carbon atoms, a lower alkoxycarbonylalkyl group of 3 to 6 carbon atoms, a benzylgroup, a benzyl group having 1 to 2 substituents (selected from a halogen atom, a lower alkyl group of 1 to 3 carbon atoms, a lower alkoxy group of 1 to 3 carbon atoms, a nitro group, a lower alkoxycarbonyl group of 2 to 4 carbon atoms, a hydroxycarbonyl group and a phenoxy group), an alpha-methylbenzyl group or a phenethyl group.

    摘要翻译： 一种由通式（I）表示的1,2,4-三唑啉-5-酮衍生物的方法，其中R是1至5个碳原子的卤代烷基，R 1是氢原子， 具有1至6个碳原子的烷基，具有卤素原子取代基的1至6个碳原子的烷基，3至6个碳原子的环烷基，具有卤素原子取代基的3至6个碳原子的环烷基，氰基烷基 2至4个碳原子的链烯基，2至6个碳原子的炔基，2至6个碳原子的低级烷氧基烷基，2至8个碳原子的低级烷硫基烷基， 2至6个碳原子的低级烷基磺酰基烷基，2至6个碳原子的低级烷基磺酰基烷基，3至8个碳原子的低级烷氧基烷氧基烷基，2至3个碳原子的羟基羰基烷基，3至6个低级烷氧基羰基烷基 碳原子，苄基，具有1〜2个取代基的苄基（选自a 卤素原子，1〜3个碳原子的低级烷基，1〜3个碳原子的低级烷氧基，硝基，2〜4个碳原子的低级烷氧基羰基，羟基羰基和苯氧基）， α-甲基苄基或苯乙基。

    .DELTA..sup.2 -1,2,4-triazolin-5-one derivatives and herbicidal usage thereof
    3.
    发明授权
    .DELTA..sup.2 -1,2,4-triazolin-5-one derivatives and herbicidal usage thereof 失效
    DELTA 2-1,2,4-三唑啉-5-酮衍生物及其除草用途

    公开(公告)号：US4318731A

    公开(公告)日：1982-03-09

    申请号：US162558

    申请日：1980-06-24

    申请人： Mitsuru Kajioka ,  Hitoshi Kurono ,  Katsumasa Okawa ,  Tatsuo Harada

    发明人： Mitsuru Kajioka ,  Hitoshi Kurono ,  Katsumasa Okawa ,  Tatsuo Harada

    IPC分类号： A01N43/653 ,  C07D249/12 ,  A01N43/64

    CPC分类号： A01N43/653 ,  C07D249/12

    摘要： A novel .DELTA..sup.2 -1,2,4-triazolin-5-one derivative having a herbicidal activity, which is represented by the formula ##STR1## wherein, R.sup.1 is a C.sub.1 -C.sub.4 alkyl; R.sup.2 is a hydrogen atom, a C.sub.1 -C.sub.6 alkyl group, or a C.sub.2 -C.sub.4 alkenyl group; and X is a hydroxy group, a C.sub.1 -C.sub.4 alkyl group, a C.sub.1 -C.sub.6 alkyloxy group, an alkyloxyalkyloxy group of which two alkyls may be same as or different from each other and each alkyl is of C.sub.1 -C.sub.4, a C.sub.2 -C.sub.4 alkenyloxy, or an alkyloxycarbonylalkyloxy group of which two alkyls may be same as or different from each other and each alkyl is of C.sub.1 -C.sub.4.

    摘要翻译： 具有除草活性的新颖的具有除草活性的DELTA 2-1,2,4-三唑啉-5-酮衍生物，其由下式表示：其中R1是C1-C4烷基; R2是氢原子，C1-C6烷基或C2-C4烯基; X为羟基，C 1〜C 4烷基，C 1〜C 6烷氧基，2个烷基可以相同或不同的烷氧基烷氧基，各烷基为C1-C4，C2-C4 链烯氧基或烷氧基羰基烷氧基，其中两个烷基可以彼此相同或不同，并且每个烷基是C1-C4。

    .DELTA..sup.2 -1,2,4-triazolin-5-one derivatives, and uses thereof
    6.
    发明授权
    .DELTA..sup.2 -1,2,4-triazolin-5-one derivatives, and uses thereof 失效
    DELTA 2-1,2,4-三唑啉-5-酮衍生物及其用途

    公开(公告)号：US4909833A

    公开(公告)日：1990-03-20

    申请号：US106599

    申请日：1987-10-13

    申请人： Mitsuru Kajioka ,  Atsushi Tsushima ,  Yoichi Hachitani ,  Kenichi Ikeda

    发明人： Mitsuru Kajioka ,  Atsushi Tsushima ,  Yoichi Hachitani ,  Kenichi Ikeda

    IPC分类号： A01N43/653 ,  C07D249/12

    CPC分类号： C07D249/12 ,  A01N43/653

    摘要： A .DELTA..sup.2 -1,2,4-triazolin-5-one derivative represented by the following general formula (I), a process for manufacturing thereof, a herbicidal composition comprising it as an active ingredient, and a use of it as a herbicide: ##STR1## wherein R is a hydrogen atom, a univalent alkali metal atom, an unsubstituted quaternary ammonium salt, a substituted quaternary ammonium salt having at least one C.sub.1 -C.sub.4 alkyl group as a substituent, an unsubstituted-alkyl group having 1 to 6 carbon atoms, a C.sub.1 -C.sub.6 substituted-alkyl group having at least one halogen atom as a substituent, a cycloalkyl group having 3 to 6 carbon atoms, a C.sub.1 -C.sub.3 substituted-alkyl group having a cyano group as a substituent, an alkenyl group having 2 to 6 carbon atoms, an alkynyl group having to 2 to 6 carbon atoms, an alkoxyalkyl group having 2 to 6 carbon atoms, an alkylthioalkyl group having to 2 to 8 carbon atoms, an alkylsulfinylalkyl group having 2 to 6 carbon atoms, an alkylsulfonylalkyl group having 2 to 6 carbon atoms, an alkoxyalkoxyalkyl group having 3 to 8 carbon atoms, a hydroxycarbonylalkyl group having 2 to 3 carbon atoms, an alkoxycarbonylalkyl group having 3 to 6 carbon atoms, an unsubstituted-benzyl group, a substituted-benzyl group having at least one substituent selected from the group consisting of halogen atoms and alkyl groups having 1 to 3 carbon atoms, or a phenethyl group; R.sup.1 is a haloalkyl group having 2 to 5 carbon atoms; and X is a halogen atom.

    摘要翻译： 由以下通式（I）表示的DELTA 2-1,2,4-三唑啉-5-酮衍生物，其制备方法，包含其作为活性成分的除草组合物及其作为除草剂的用途 ：其中R是氢原子，一价碱金属原子，未取代的季铵盐，具有至少一个C1-C4烷基作为取代基的取代的季铵盐，未取代的烷基， 1至6个碳原子，具有至少一个卤素原子作为取代基的C1-C6取代的烷基，具有3至6个碳原子的环烷基，具有氰基作为取代基的C1-C3取代的 - 烷基， 碳原子数2〜6的烯基，碳原子数2〜6的炔基，碳原子数2〜6的烷氧基烷基，碳原子数2〜8的烷硫基烷基，碳原子数2〜6的烷基亚磺酰基烷基 原子，具有2〜6个碳原子的烷基磺酰基烷基 ms，具有3至8个碳原子的烷氧基烷氧基烷基，具有2至3个碳原子的羟基羰基烷基，具有3至6个碳原子的烷氧基羰基烷基，未取代的苄基，具有至少一个取代基的取代苄基， 由卤素原子和碳原子数1〜3的烷基构成的基团，或苯乙基; R1是碳原子数2〜5的卤代烷基; X为卤素原子。