摘要:
A disadvantage upon heat treatment in an oxygen atmosphere of a dielectric film formed on a lower electrode of capacitance device of DRAM that oxygen permeating the lower electrode oxidizes a barrier layer to form an oxide layer of high resistance and low dielectric constant is prevented. An Ru silicide layer is formed on the surface of a plug in a through hole formed below a lower electrode for an information storage capacitance device C and an Ru silicon nitride layer is formed further on the surface of the Ru silicide layer. Upon high temperature heat treatment in an oxygen atmosphere conducted in the step of forming a dielectric film on the lower electrode, the Ru silicon nitride layer is oxidized sacrificially into an Ru silicon oxynitride to prevent progress of oxidation in the Ru silicide layer.
摘要:
A disadvantage upon heat treatment in an oxygen atmosphere of a dielectric film formed on a lower electrode of capacitance device of DRAM that oxygen permeating the lower electrode oxidizes a barrier layer to form an oxide layer of high resistance and low dielectric constant is prevented. An Ru silicide layer is formed on the surface of a plug in a through hole formed below a lower electrode for an information storage capacitance device C and an Ru silicon nitride layer is formed further on the surface of the Ru silicide layer. Upon high temperature heat treatment in an oxygen atmosphere conducted in the step of forming a dielectric film on the lower electrode, the Ru silicon nitride layer is oxidized sacrificially into an Ru silicon oxynitride to prevent progress of oxidation in the Ru silicide layer.
摘要:
Disclosed are a semiconductor integrated circuit device and a method of manufacturing the same capable of improving the characteristics of the semiconductor integrated circuit device by reducing a leakage current of a capacitor used in a DRAM memory cell. A data storage capacitor connected to a data transfer MISFET in a memory cell forming area via plugs is formed in the following manner. That is, a lower electrode composed of an Ru film is formed in a hole in a silicon oxide film, and then, a tantalum oxide film is deposited on the lower electrode. Thereafter, a first thermal treatment in an oxidizing atmosphere is performed to the film at a temperature sufficient to repair an oxygen defect and having no influence on the materials below the tantalum oxide film. Further, a second thermal treatment in an inactive atmosphere is performed at a temperature at which the tantalum oxide film is not completely crystallized (650null C.) and higher than that applied in the later process. Thereafter, an upper electrode composed of a laminated film of an Ru film and a W film is formed on the capacitor insulating film made from the tantalum oxide film.
摘要:
In a semiconductor integrated circuit device according to the present invention, a polycrystalline silicon film is formed along an inner wall of a trench in which a capacitor is to be formed, and the polycrystalline silicon film and a lower electrode is contacted to each other on the entire inner wall of the trench. Therefore, oxygen permeated into the lower electrode at the time of a thermal treatment of a tantalum oxide film is consumed at an interface between the polycrystalline silicon film and the lower electrode. Thus, the oxygen does not reach the surface of the plug, so that such a disadvantage can be prevented that the oxygen permeated through the lower electrode causes the oxidation on the surface of the silicon plug below the lower electrode to form a high-resistance oxide layer when a dielectric film formed on a lower electrode of a capacitor of a DRAM is subjected to a thermal treatment in an oxygen atmosphere.
摘要:
Disclosed are a semiconductor integrated circuit device and a method of manufacturing the same capable of improving the characteristics of the semiconductor integrated circuit device by reducing a leakage current of a capacitor used in a DRAM memory cell. A data storage capacitor connected to a data transfer MISFET in a memory cell forming area via plugs is formed in the following manner. That is, a lower electrode composed of an Ru film is formed in a hole in a silicon oxide film, and then, a tantalum oxide film is deposited on the lower electrode. Thereafter, a first thermal treatment in an oxidizing atmosphere is performed to the film at a temperature sufficient to repair an oxygen defect and having no influence on the materials below the tantalum oxide film. Further, a second thermal treatment in an inactive atmosphere is performed at a temperature at which the tantalum oxide film is not completely crystallized (650null C.) and higher than that applied in the later process. Thereafter, an upper electrode composed of a laminated film of an Ru film and a W film is formed on the capacitor insulating film made from the tantalum oxide film.
摘要:
In a semiconductor integrated circuit device according to the present invention, a polycrystalline silicon film is formed along an inner wall of a trench in which a capacitor is to be formed, and the polycrystalline silicon film and a lower electrode is contacted to each other on the entire inner wall of the trench. Therefore, oxygen permeated into the lower electrode at the time of a thermal treatment of a tantalum oxide film is consumed at an interface between the polycrystalline silicon film and the lower electrode. Thus, the oxygen does not reach the surface of the plug, so that such a disadvantage can be prevented that the oxygen permeated through the lower electrode causes the oxidation on the surface of the silicon plug below the lower electrode to form a high-resistance oxide layer when a dielectric film formed on a lower electrode of a capacitor of a DRAM is subjected to a thermal treatment in an oxygen atmosphere.