POLYCARBONATE-POLYORGANOSILOXANE COPOLYMER

    公开(公告)号:US20230116659A1

    公开(公告)日:2023-04-13

    申请号:US17789165

    申请日:2020-12-25

    Abstract: A polycarbonate-polyorganosiloxane copolymer comprises a polycarbonate block (A-1) formed of a repeating unit with a specific structure and a polyorganosiloxane block (A-2) containing a repeating unit with a specific structure. A difference between the haze value (haze A) after retention for 3 minutes and the haze value (haze B) after retention for 20 minutes, of the polycarbonate-polyorganosiloxane copolymer or a resin composition thereof at 300° C. or 340° C., Δhaze, is less than 0.4.

    POLYCARBONATE RESIN COMPOSITION
    5.
    发明申请

    公开(公告)号:US20180355178A1

    公开(公告)日:2018-12-13

    申请号:US16064055

    申请日:2016-12-13

    Abstract: Provided is a polycarbonate-based resin composition containing: a polycarbonate-polyorganosiloxane copolymer (A-1) which contains a specific repeating unit and in which a polyorganosiloxane block has an average chain length of 20 or more and less than 60; a polycarbonate-polyorganosiloxane copolymer (A-2) which contains a specific repeating unit and in which a polyorganosiloxane block has an average chain length of 60 or more and less than 500; and a polycarbonate-based resin (A-3) except the polycarbonate-polyorganosiloxane copolymer (A-1) and the polycarbonate-polyorganosiloxane copolymer (A-2), wherein the ratio of the polycarbonate-based resin (A-3) to the total weight of the polycarbonate-polyorganosiloxane copolymer (A-1), the polycarbonate-polyorganosiloxane copolymer (A-2), and the polycarbonate-based resin (A-3) is 10 mass % or more.

    POLYCARBONATE-POLYORGANOSILOXANE COPOLYMER AND METHOD FOR PRODUCING SAME
    10.
    发明申请
    POLYCARBONATE-POLYORGANOSILOXANE COPOLYMER AND METHOD FOR PRODUCING SAME 有权
    聚碳酸酯 - 聚硅氧烷共聚物及其制造方法

    公开(公告)号:US20160017102A1

    公开(公告)日:2016-01-21

    申请号:US14771619

    申请日:2014-09-22

    Inventor: Aki YAMADA

    CPC classification number: C08G81/00 C08G64/186 C08G77/04 C08G77/448

    Abstract: Provided is a polycarbonate-polyorganosiloxane copolymer, including a specific polycarbonate block unit (A) and a specific polyorganosiloxane block unit (B), in which in a differential molecular weight distribution curve obtained from measurement of the polyorganosiloxane block unit (B) by gel permeation chromatography using the polystyrene calibration curve, the curve having an axis of abscissa indicating a logarithmic value log(M) of a molecular weight M and an axis of ordinate indicating dw/d log(M) obtained by differentiating a concentration fraction w with respect to the logarithmic value log(M) of the molecular weight, (1) a dw/d log(M) value becomes maximum in a range of 3.4≦log(M)≦4.0, and (2) in the differential molecular weight distribution curve, a ratio of a value obtained by integrating the dw/d log(M) value over a range of 4.0≦Log(M)≦4.5 to a value obtained by integrating the dw/d log(M) value over the entire range of the log(M) is 6% or more and 40% or less.

    Abstract translation: 提供了聚碳酸酯 - 聚有机硅氧烷共聚物,其包括特定的聚碳酸酯嵌段单元(A)和特定的聚有机硅氧烷嵌段单元(B),其中通过凝胶渗透法测定聚有机硅氧烷嵌段单元(B)得到的微分分子量分布曲线 使用聚苯乙烯校准曲线的色谱法,具有表示分子量M的对数值log(M)和表示dw / d log(M)的纵坐标轴的横坐标轴的曲线表示通过将浓度分数w相对于 分子量的对数值log(M),(1)dw / d log(M)值在3.4≦̸ log(M)≦̸ 4.0和(2)的范围内变为最大,差示分子量 分布曲线,通过将dw / d log(M)值在4.0≦̸ Log(M)≦̸ 4.5的范围内积分得到的值的比率与通过将dw / d log(M)值相乘得到的值 对数(M)的整个范围为6%以上且40%以上 ss。

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