摘要:
The present invention relates to methods for making the compounds of formula I which is a dehydrohalogenative coupling of hydrochlorosilanes of formula II with organic halides of formula III in the presence of a Lewis base catalyst. R3CH2SiR1Cl2 (I) HSiR1Cl2 (II) R2CH2X (III) In formulas I and II, R1 represents a hydrogen, chloro, or methyl; in formula III, X represents a chloro or bromo; in formula III, R2 can be selected from the group consisting of a C1-17 alkyl, a C1-10 fluorinated alkyl with partial or full fluorination, a C1-5 alkenyl groups, a silyl group containing alkyls, (CH2)nSiMe3-mClm wherein n is 0 to 2 and m is 0 to 3, aromatic groups, Ar(R′)1 wherein Ar is C6-14 aromatic hydrocarbon, R′ is a C1-4 alkyl, halogen, alkoxy, or vinyl, and q is 0 to 5, a haloalkyl group, (CH2)pX wherein p is 1 to 9 and X is a chloro or bromo; or an aromatic hydrocarbon, Ar CH2X wherein Ar is C6-14 aromatic hydrocarbon and X is a chloro or bromo. in formula I, R3 is the same as R2 in formula III and further, R3 can also be (CH2)pSiR1Cl2 or ArCH2SiR1Cl2 when R2 in formula III is (CH2)pX or ArCH2X, because of the coupling reaction of X with the compound of formula II.
摘要:
The present invention relates to a process for preparing organosilicon compounds by the silylation of conjugated dienes and more particularly, to the process for preparing organosilicon compounds expressed by the following Formulas 1a and 1b in high yield, comprising the steps of heating trichlorosilane in the presence of quaternary organophosphonium salt catalystto generate dichlorosilylene (:SiCl2); and silylating the result with linear or cyclic conjugated dienes, wherein R1, R2, R3, R4, R5 and R6 are independently a hydrogen atom, a C1-C6 alkyl, phenyl group, or two functional groups among R1, R2, R3, R4, R5 and R6 may be covalently bonded to each other to form a cyclic compound of C4-C8.
摘要:
The present invention relates to a process for preparing organochlorosilanes and more particularly, to the process for preparing organochlorosilanes of R4R3CHSiR1Cl2 (I) by a dehydrohalogenative coupling of hydrochlorosilanes of HSiR1Cl2 (II) with organic halides of R2R3 CHX (III) in the presence of quaternary phosphonium salt as a catalyst to provide better economical matter and yield compared with conventional methods, because only a catalytic amount of phosphonium chloride is required and the catalyst can be separated from the reaction mixture and recycled easily.
摘要:
Particular codebook entries used for a MIMO system of a lower dimension (i.e., having a relatively low number of antennas) can be used to generate a codebook for a MIMO system of a higher dimension (i.e., having a relatively high number of antennas). The entries in rank 1 of the codebook related to the MIMO system having four transmit antennas are used to newly construct entries for rank 1 through rank 8 of two base matrices for a MIMO base codebook related to eight transmit antennas.
摘要:
There is provided an air intake for a vacuum-conveyance waste collection system, to form a high-speed air flow by allowing air to enter a conveying line through which waste being put into a waste receiving device is conveyed to a central waste collection station.The air intake for the vacuum-conveyance waste collection system according to the present invention comprises: an air inflow pipe 1 including an upper air inflow opening 1a and a lower air inflow opening 1b to allow outside air to enter; a noise pipe 4 with an upper end inserted under the air inflow pipe 1 and a sound absorption material 4c attached to an inner wall of the noise pipe 4; and a housing 5 including an air suction valve 6 installed inside and a sound absorption material 5a attached to an inner wall of the housing 5, the housing connected to a lower end of the noise pipe 4, to guide the air entered through the air inflow pipe 1 to a waste conveying line 10, wherein un upper rain cap in a cone shape is installed at an upper position in the air inflow pipe, a mesh is installed at the upper end of the noise pipe, and a lower rain cap in a frustum shape including a central through-hole is installed between the upper rain cap and the mesh.
摘要:
Particular codebook entries used for a MIMO system of a lower dimension (i.e., having a relatively low number of antennas) can be used to generate a codebook for a MIMO system of a higher dimension (i.e., having a relatively high number of antennas). The entries in rank 1 of the codebook related to the MIMO system having four transmit antennas are used to newly construct entries for rank 1 through rank 8 of two base matrices for a MIMO base codebook related to eight transmit antennas.
摘要:
There is provided a waste discharge valve for a vacuum-conveyance waste collection system in which waste put in a waste receiving device is automatically conveyed to a central waste collection station through a conveying line.In the vacuum-conveyance waste collection system in which a housing includes an upper end on which a waste receiving opening is formed and a lower end which is connected to a conveying line connected to a central waste collection station, and a chute is installed in the housing, temporality stores waste and guides the waste to the conveying line, the waste discharge valve is installed at a lower end of the chute and comprises: an air cylinder; a first link plate connected to one end of a cylinder rod of the air cylinder; a damper arm for opening/closing the waste discharge valve by pivot; and a second link plate pivotally connected to the first link plate and the damper arm so that the opening/closing of the waste discharge valve is controlled, and wherein the chute includes an airline with an upper air inlet, a middle air outlet and a lower air outlet.