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公开(公告)号：US07776439B2
公开(公告)日：2010-08-17
申请号：US11994642
申请日：2006-07-05
Applicant: In-Sik Han , Jae-Young Lee , Jae-Young Kim , Tae-Hak Park , So-Yeon Kwon
Inventor： In-Sik Han , Jae-Young Lee , Jae-Young Kim , Tae-Hak Park , So-Yeon Kwon
IPC: D02G3/00
CPC classification number: D01F6/605 , B01F7/00766 , B01F2215/0454 , C08G69/32 , Y10T428/2913 , Y10T428/2969
Abstract: Disclosed are wholly aromatic polyamide filament and a method of manufacturing the same, characterized in that, in the process of preparing the wholly aromatic polyamide polymer, the aromatic diamine, aromatic diacid chloride and polymerization solvent put into the reactor 20 are agitated by an agitation device which is installed in the reactor 20 and consists of: (i) a rotor 3 driven by a motor 2 and having a plurality of pins 3a; and (ii) a stator 4 having a plurality of pins 4a, wherein spin speed of the rotor 3 is controlled to 10 to 100 times of both of feeding rates for the aromatic diacid chloride and the aromatic diamine in the polymerization solvent into the reactor and, at the same time, contact frequency between the pins 3a and the pins 4a is regulated within a range of 100 to 1,000 Hz. The present invention is effective to progress uniform and homogeneous polymerization over all of area of a polymerization reactor 20, thereby reducing deviation in degree of polymerization, since polymeric monomers are miscible and react together very well in the reactor 20. Accordingly, the wholly aromatic polyamide filament produced exhibits narrow PDI and lowered paracrystalline parameter gII leading to reduction of defects of a crystal itself, so as to considerably improve strength and modulus thereof.
Abstract translation: 公开了全芳香族聚酰胺长丝及其制造方法，其特征在于，在制备全芳香族聚酰胺聚合物的方法中，通过搅拌装置搅拌加入到反应器20中的芳族二胺，芳族二酰氯和聚合溶剂 其安装在反应器20中并且包括：（i）由电动机2驱动并具有多个销3a的转子3; 和（ii）具有多个销4a的定子4，其中转子3的旋转速度被控制在聚合溶剂中的芳族二酰氯和芳族二胺的进料速率的两倍到反应器中的10至100倍， 同时，引脚3a和引脚4a之间的接触频率调节在100至1000Hz的范围内。 本发明有效地在聚合反应器20的所有区域上均匀均匀聚合，从而降低聚合度的偏差，因为聚合物单体是可混溶的，并且在反应器20中非常好地反应。因此，全芳族聚酰胺 所生产的长丝表现出窄的PDI和降低的结晶参数gII，导致晶体本身缺陷的减少，从而显着提高其强度和模量。
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公开(公告)号：US20060049539A1
公开(公告)日：2006-03-09
申请号：US10529543
申请日：2003-10-17
Applicant: Yoeng-Baeg Choi , Young-Hwan Lee , In-Sik Han
Inventor： Yoeng-Baeg Choi , Young-Hwan Lee , In-Sik Han
IPC: D01F6/00
CPC classification number: D01D5/247 , D01F1/10 , D01F6/06 , D01F6/60 , D01F6/62 , Y10T428/2935 , Y10T428/2975
Abstract: The present invention discloses microcellular fibers, in which microcells are formed with a density of more than 107 cells/cm3 with a supercritical fluid introduced into fiber forming polymers and have a rate of volume expansion of 1.2 to 50, a ratio of microcell length to microcell diameter of more than 2 and a monofilament diameter of more than 5 μm. The microcellular fibers provide high and uniform cell densities and are good in the rate of volume expansion and the ratio of cell length to cell diameter, thus they are very excellent in lightweight feeling and touch. The microcellular fibers are made by a method for making microcellular fibers, wherein a supercritical fluid is introduced into an extruder upon melting and mixing fiber forming polymers in the extruder, to thus prepare a single-phase solution of molten polymer and gas, then the single-phase solution of molten polymer and gas is extruded (spun) through spinneret of spinning pack by subjecting the single-phase solution to a rapid pressure drop, to thus make microcellular extrusion materials, the microcellular extrusion materials are rapidly cooled by a cooling medium, and then they are wound at a winding speed of 10 to 6,000 m/min so that a spinning draft can be 2 to 300.
Abstract translation: 本发明公开了一种微孔纤维，其中将微孔形成的密度大于10 7个/ cm 3，超临界流体被引入成纤聚合物中，并具有 体积膨胀率为1.2〜50，微细胞长度与微细胞直径之比大于2，单丝直径大于5um。 微细胞纤维提供高且均匀的细胞密度，并且体积膨胀速率和细胞长度与细胞直径的比例是良好的，因此它们在轻量级感和触感方面非常优异。 微孔纤维通过制造微孔纤维的方法制造，其中在挤出机中熔融和混合纤维形成聚合物时将超临界流体引入挤出机中，从而制备熔融聚合物和气体的单相溶液，然后将单一 熔融聚合物和气体的相溶液通过使单相溶液快速压降，通过纺丝组件的喷丝头挤出（纺丝），从而制成微孔挤出材料，微孔挤出材料通过冷却介质快速冷却， 然后以10〜6000m / min的卷绕速度卷绕，使得纺丝牵伸力可以为2〜300。
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公开(公告)号：US08105521B2
公开(公告)日：2012-01-31
申请号：US11994643
申请日：2006-07-05
Applicant: In-Sik Han , Jae-Young Lee , Seung-Hwan Lee , Chang-Bae Lee , So-Yeon Kwon
Inventor： In-Sik Han , Jae-Young Lee , Seung-Hwan Lee , Chang-Bae Lee , So-Yeon Kwon
IPC: D01D5/18
CPC classification number: D01F6/605 , Y10T428/2913 , Y10T428/2969
Abstract: Disclosed are wholly aromatic polyamide filament and a method of manufacturing the same, characterized in that, in a process of preparing wholly aromatic polyamide polymer, a multiple tubular feed pipe for polymeric monomer and polymerization solvent with specific construction of adjacent inner paths 11a and outer paths 11b which are alternately arranged one another is used to feed either aromatic diacid chloride A or aromatic diamine dissolved in the polymerization solvent B into a polymerization reactor 20 through corresponding one among the inner and outer paths 11a and 11b. The present invention is effective to progress uniform and homogeneous polymerization over all of area of a polymerization reactor 20 leading to reduction of deviation in degree of polymerization, since polymeric monomers are miscible and react together very well immediately after putting the monomers into the reactor 20. Accordingly, the wholly aromatic polyamide filament produced exhibits narrow PDI and increased ACS, so as to considerably improve strength and modulus thereof.
Abstract translation: 公开了全芳族聚酰胺长丝及其制造方法，其特征在于，在制备全芳族聚酰胺聚合物的方法中，用于聚合单体的多管式进料管和具有相邻内部通道11a和外部通道的特定结构的聚合溶剂 11b彼此交替排列，用于将溶解在聚合溶剂B中的芳香族二酰氯A或芳香族二胺通过内部通路11a和内部通路11b中的相应一个进入聚合反应器20。 本发明有效地在聚合反应器20的所有区域上进行均匀均匀的聚合，导致聚合度偏差的降低，因为聚合单体是可混溶的，并且在将单体放入反应器20后立即非常好地反应。 因此，所生产的全芳族聚酰胺长丝表现出窄的PDI和增加的ACS，从而显着提高其强度和模量。
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公开(公告)号：US20080227947A1
公开(公告)日：2008-09-18
申请号：US11994642
申请日：2006-07-05
Applicant: In-Sik Han , Jae-Young Lee , Jae-Young Kim , Tae-Hak Park , So-Yeon Kwon
Inventor： In-Sik Han , Jae-Young Lee , Jae-Young Kim , Tae-Hak Park , So-Yeon Kwon
CPC classification number: D01F6/605 , B01F7/00766 , B01F2215/0454 , C08G69/32 , Y10T428/2913 , Y10T428/2969
Abstract: Disclosed are wholly aromatic polyamide filament and a method of manufacturing the same, characterized in that, in the process of preparing the wholly aromatic polyamide polymer, the aromatic diamine, aromatic diacid chlrodie and polymerization solvent put into the reactor 20 are agitated by an agitation device which is installed in the reactor 20 and consists of: (i) a rotor 3 driven by a motor 2 and having a plurality of pins 3a; and (ii) a stator 4 having a plurality of pins 4a, wherein spin speed of the rotor 3 is controlled to 10 to 100 times of both of feeding rates for the aromatic diacid chloride and the aromatic diamine in the polymerization solvent into the reactor and, at the same time, contact frequency between the pins 3a and the pins 4a is regulated within a range of 100 to 1,000 Hz. The present invention is effective to progress uniform and homogeneous polymerization over all of area of a polymerization reactor 20, thereby reducing deviation in degree of polymerization, since polymeric monomers are miscible and react together very well in the reactor 20. Accordingly, the wholly aromatic polyamide filament produced exhibits narrow PDI and lowered paracrystalline parameter gII leading to reduction of defects of a crystal itself, so as to considerably improve strength and modulus thereof.
Abstract translation: 公开了全芳族聚酰胺长丝及其制造方法，其特征在于，在制备全芳香族聚酰胺聚合物的方法中，通过搅拌装置搅拌放入反应器20中的芳族二胺，芳族二酸氯乙烯和聚合溶剂 其安装在反应器20中并且包括：（i）由电动机2驱动并具有多个销3a的转子3; 和（ii）具有多个销4a的定子4，其中转子3的旋转速度被控制在聚合溶剂中的芳族二酰氯和芳族二胺的进料速率的两倍至反应器的10到100倍 并且同时，引脚3a和引脚4a之间的接触频率被调节在100至1000Hz的范围内。 本发明有效地在聚合反应器20的所有区域上进行均匀均匀的聚合，由此降低聚合度的偏差，因为聚合物单体是可混溶的并且在反应器20中非常好地反应。因此，全芳族聚酰胺 产生的长丝表现出窄的PDI和降低的结晶参数g II II导致晶体本身缺陷的减少，从而显着提高其强度和模量。
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公开(公告)号：US07097905B2
公开(公告)日：2006-08-29
申请号：US10529543
申请日：2003-10-17
Applicant: Yoeng-Baeg Choi , Young-Hwan Lee , In-Sik Han
Inventor： Yoeng-Baeg Choi , Young-Hwan Lee , In-Sik Han
IPC: D01F6/00
CPC classification number: D01D5/247 , D01F1/10 , D01F6/06 , D01F6/60 , D01F6/62 , Y10T428/2935 , Y10T428/2975
Abstract: The present invention discloses microcellular fibers, in which microcells are formed with a density of more than 107 cells/cm3 with a supercritical fluid introduced into fiber forming polymers and have a rate of volume expansion of 1.2 to 50, ratio of microcell length to microcell diameter of more than 2 and a monofilament diameter of more than 5 μm. The microcellular fibers provide high and uniform cell densities and are good in the rate of volume expansion and the ratio of cell length to cell diameter, thus they are very excellent in lightweight feeling and touch. The microcellular fibers are made by a method for making microcellular fibers, wherein a supercritical fluid is introduced into an extruder upon melting and mixing fiber forming polymers in the extruder, to thus prepare a single-phase solution of molten polymer and gas, then the single-phase solution of molten polymer and gas is extruded (spun) through spinneret of spinning pack by subjecting the single-phase solution to a rapid pressure drop, to thus make microcellular extrusion materials, the microcellular extrusion materials are rapidly cooled by a cooling medium, and then they are wound at a winding speed of 10 to 6,000 m/min so that a spinning draft can be 2 to 300.
Abstract translation: 本发明公开了一种微孔纤维，其中将微孔形成的密度大于10 7个/ cm 3，超临界流体被引入成纤聚合物中，并具有 体积膨胀率为1.2〜50，微细胞长度与微细胞直径的比例大于2，单丝直径大于5um。 微细胞纤维提供高且均匀的细胞密度，并且体积膨胀速率和细胞长度与细胞直径的比例是良好的，因此它们在轻量级感和触感方面非常优异。 微孔纤维通过制造微孔纤维的方法制造，其中在挤出机中熔融和混合纤维形成聚合物时将超临界流体引入挤出机中，从而制备熔融聚合物和气体的单相溶液，然后将单一 熔融聚合物和气体的相溶液通过使单相溶液快速压降，通过纺丝组件的喷丝头挤出（纺丝），从而制成微孔挤出材料，微孔挤出材料通过冷却介质快速冷却， 然后以10〜6000m / min的卷绕速度卷绕，使得纺丝牵伸力可以为2〜300。
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Patent Agency Ranking
公开(公告)号：US08084571B2
公开(公告)日：2011-12-27
申请号：US12470122
申请日：2009-05-21
Applicant: In-Sik Han , Jae-Young Lee , Seung-Hwan Lee , Chang-Bae Lee , So-Yeon Kwon
Inventor： In-Sik Han , Jae-Young Lee , Seung-Hwan Lee , Chang-Bae Lee , So-Yeon Kwon
IPC: C08G69/26
CPC classification number: D01F6/605 , Y10T428/2913 , Y10T428/2969
Abstract: Disclosed are wholly aromatic polyamide filament and a method of manufacturing the same, characterized in that, in a process of preparing wholly aromatic polyamide polymer, a multiple tubular feed pipe for polymeric monomer and polymerization solvent with specific construction of adjacent inner paths 11a and outer paths 11b which are alternately arranged one another is used to feed either aromatic diacid chloride A or aromatic diamine dissolved in the polymerization solvent B into a polymerization reactor 20 through corresponding one among the inner and outer paths 11a and 11b. The present invention is effective to progress uniform and homogeneous polymerization over all of area of a polymerization reactor 20 leading to reduction of deviation in degree of polymerization, since polymeric monomers are miscible and react together very well immediately after putting the monomers into the reactor 20. Accordingly, the wholly aromatic polyamide filament produced exhibits narrow PDI and increased ACS, so as to considerably improve strength and modulus thereof.
Abstract translation: 公开了全芳族聚酰胺长丝及其制造方法，其特征在于，在制备全芳族聚酰胺聚合物的方法中，用于聚合单体的多管式进料管和具有相邻内部通道11a和外部通道的特定结构的聚合溶剂 11b彼此交替排列，用于将溶解在聚合溶剂B中的芳香族二酰氯A或芳香族二胺通过内部通路11a和内部通路11b中的相应一个进入聚合反应器20。 本发明有效地在聚合反应器20的所有区域上进行均匀均匀的聚合，导致聚合度偏差的降低，因为聚合单体是可混溶的，并且在将单体放入反应器20后立即非常好地反应。 因此，所生产的全芳族聚酰胺长丝表现出窄的PDI和增加的ACS，从而显着提高其强度和模量。
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公开(公告)号：US20100237532A1
公开(公告)日：2010-09-23
申请号：US12792304
申请日：2010-06-02
Applicant: In-Sik Han , Jae-Young Lee , Jae-Young Kim , Tae-Hak Park , So-Yeon Kwon
Inventor： In-Sik Han , Jae-Young Lee , Jae-Young Kim , Tae-Hak Park , So-Yeon Kwon
IPC: B29C47/08
CPC classification number: D01F6/605 , B01F7/00766 , B01F2215/0454 , C08G69/32 , Y10T428/2913 , Y10T428/2969
Abstract: Disclosed are wholly aromatic polyamide filament and a method of manufacturing the same, characterized in that, in the process of preparing the wholly aromatic polyamide polymer, the aromatic diamine, aromatic diacid chloride and polymerization solvent put into the reactor 20 are agitated by an agitation device which is installed in the reactor 20 and consists of: (i) a rotor 3 driven by a motor 2 and having a plurality of pins 3a; and (ii) a stator 4 having a plurality of pins 4a, wherein spin speed of the rotor 3 is controlled to 10 to 100 times of both of feeding rates for the aromatic diacid chloride and the aromatic diamine in the polymerization solvent into the reactor and, at the same time, contact frequency between the pins 3a and the pins 4a is regulated within a range of 100 to 1,000 Hz. The present invention is effective to progress uniform and homogeneous polymerization over all of area of a polymerization reactor 20, thereby reducing deviation in degree of polymerization, since polymeric monomers are miscible and react together very well in the reactor 20. Accordingly, the wholly aromatic polyamide filament produced exhibits narrow PDI and lowered paracrystalline parameter gII leading to reduction of defects of a crystal itself, so as to considerably improve strength and modulus thereof.
Abstract translation: 公开了全芳香族聚酰胺长丝及其制造方法，其特征在于，在制备全芳香族聚酰胺聚合物的方法中，通过搅拌装置搅拌加入到反应器20中的芳族二胺，芳族二酰氯和聚合溶剂 其安装在反应器20中并且包括：（i）由电动机2驱动并具有多个销3a的转子3; 和（ii）具有多个销4a的定子4，其中转子3的旋转速度被控制在聚合溶剂中的芳族二酰氯和芳族二胺的进料速率的两倍到反应器中的10至100倍， 同时，引脚3a和引脚4a之间的接触频率调节在100至1000Hz的范围内。 本发明有效地在聚合反应器20的所有区域上进行均匀均匀的聚合，由此降低聚合度的偏差，因为聚合物单体是可混溶的并且在反应器20中非常好地反应。因此，全芳族聚酰胺 所生产的长丝表现出窄的PDI和降低的结晶参数gII，导致晶体本身缺陷的减少，从而显着提高其强度和模量。
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公开(公告)号：US20090253890A1
公开(公告)日：2009-10-08
申请号：US12470122
申请日：2009-05-21
Applicant: In-Sik Han , Jae-Young Lee , Seung-Hwan Lee , Chang-Bae Lee , So-Yeon Kwon
Inventor： In-Sik Han , Jae-Young Lee , Seung-Hwan Lee , Chang-Bae Lee , So-Yeon Kwon
IPC: C08G69/26
CPC classification number: D01F6/605 , Y10T428/2913 , Y10T428/2969
Abstract: Disclosed are wholly aromatic polyamide filament and a method of manufacturing the same, characterized in that, in a process of preparing wholly aromatic polyamide polymer, a multiple tubular feed pipe for polymeric monomer and polymerization solvent with specific construction of adjacent inner paths 11a and outer paths 11b which are alternately arranged one another is used to feed either aromatic diacid chloride A or aromatic diamine dissolved in the polymerization solvent B into a polymerization reactor 20 through corresponding one among the inner and outer paths 11a and 11b. The present invention is effective to progress uniform and homogeneous polymerization over all of area of a polymerization reactor 20 leading to reduction of deviation in degree of polymerization, since polymeric monomers are miscible and react together very well immediately after putting the monomers into the reactor 20. Accordingly, the wholly aromatic polyamide filament produced exhibits narrow PDI and increased ACS, so as to considerably improve strength and modulus thereof.
Abstract translation: 公开了全芳族聚酰胺长丝及其制造方法，其特征在于，在制备全芳族聚酰胺聚合物的方法中，用于聚合单体的多管式进料管和具有相邻内部通道11a和外部通道的特定结构的聚合溶剂 11b彼此交替排列，用于将溶解在聚合溶剂B中的芳香族二酰氯A或芳香族二胺通过内部通路11a和内部通路11b中的相应一个进入聚合反应器20。 本发明有效地在聚合反应器20的所有区域上进行均匀均匀的聚合，导致聚合度偏差的降低，因为聚合单体是可混溶的，并且在将单体放入反应器20后立即非常好地反应。 因此，所生产的全芳族聚酰胺长丝表现出窄的PDI和增加的ACS，从而显着提高其强度和模量。
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公开(公告)号：US20140360346A1
公开(公告)日：2014-12-11
申请号：US14357312
申请日：2011-12-27
Applicant: In-Sik Han
Inventor： In-Sik Han
CPC classification number: F41H1/02 , D03D1/0052 , D03D15/00 , D06M15/256 , D06M15/277 , D06M15/295 , D06M15/564 , D06M15/576 , D06M2101/36 , D10B2331/021 , F41H5/0478 , Y10T442/2148 , Y10T442/2164 , Y10T442/2189
Abstract: The present invention discloses a bulletproof fabric and a body armor manufactured using the same. The bulletproof fabric includes an aramid fabric 10 including wholly aromatic polyamide multifilaments as warps and wefts, a primary water-repellent coating layer 20 formed on the aramid fabric 10, and a secondary water-repellent coating layer 30 formed on the primary water-repellent coating layer 20. The body armor of the present invention has a laminate structure of stacking up 10 to 50 sheets of the above bulletproof fabrics, preferably, further includes an aramid composite pad 40 inserted in a pocket provided at a part of the body armor. According to the present invention, water-repellent properties are excellent to noticeably improve bulletproof performance in a wet state, and specifically, when the body armor has the aramid composite pad 40 inserted therein, rear deformation of the body armor after the bulletproof performance test is considerably reduced.
Abstract translation: 本发明公开了一种使用其制造的防弹织物和身体护甲。 防弹织物包括芳族聚酰胺织物10，其包括作为经纱和纬纱的全芳族聚酰胺复丝，形成在芳族聚酰胺织物10上的主要防水涂层20和形成在主要防水涂层上的第二防水涂层30 本发明的身体护甲具有堆叠10〜50张上述防弹织物的叠层结构，优选地还包括插入设置在身体装甲的一部分的口袋中的芳族聚酰胺复合垫40。 根据本发明，在湿润状态下，防水性能显着提高，具体来说，当装甲中插入有芳族聚酰胺复合垫40时，防弹性能试验后的身体护甲的后变形为 大大减少
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公开(公告)号：US08419990B2
公开(公告)日：2013-04-16
申请号：US12792304
申请日：2010-06-02
Applicant: In-Sik Han , Jae-Young Lee , Jae-Young Kim , Tae-Hak Park , So-Yeon Kwon
Inventor： In-Sik Han , Jae-Young Lee , Jae-Young Kim , Tae-Hak Park , So-Yeon Kwon
CPC classification number: D01F6/605 , B01F7/00766 , B01F2215/0454 , C08G69/32 , Y10T428/2913 , Y10T428/2969
Abstract: Disclosed are wholly aromatic polyamide filament and a method of manufacturing the same, characterized in that, in the process of preparing the wholly aromatic polyamide polymer, the aromatic diamine, aromatic diacid chloride and polymerization solvent put into the reactor 20 are agitated by an agitation device which is installed in the reactor 20 and consists of: (i) a rotor 3 driven by a motor 2 and having a plurality of pins 3a; and (ii) a stator 4 having a plurality of pins 4a, wherein spin speed of the rotor 3 is controlled to 10 to 100 times of both of feeding rates for the aromatic diacid chloride and the aromatic diamine in the polymerization solvent into the reactor and, at the same time, contact frequency between the pins 3a and the pins 4a is regulated within a range of 100 to 1,000 Hz. The present invention is effective to progress uniform and homogeneous polymerization over all of area of a polymerization reactor 20, thereby reducing deviation in degree of polymerization, since polymeric monomers are miscible and react together very well in the reactor 20. Accordingly, the wholly aromatic polyamide filament produced exhibits narrow PDI and lowered paracrystalline parameter gII leading to reduction of defects of a crystal itself, so as to considerably improve strength and modulus thereof.
Abstract translation: 公开了全芳香族聚酰胺长丝及其制造方法，其特征在于，在制备全芳香族聚酰胺聚合物的方法中，通过搅拌装置搅拌加入到反应器20中的芳族二胺，芳族二酰氯和聚合溶剂 其安装在反应器20中并且包括：（i）由电动机2驱动并具有多个销3a的转子3; 和（ii）具有多个销4a的定子4，其中转子3的旋转速度被控制在聚合溶剂中的芳族二酰氯和芳族二胺的进料速率的两倍到反应器中的10至100倍， 同时，引脚3a和引脚4a之间的接触频率调节在100至1000Hz的范围内。 本发明有效地在聚合反应器20的所有区域上进行均匀均匀的聚合，由此降低聚合度的偏差，因为聚合物单体是可混溶的并且在反应器20中非常好地反应。因此，全芳族聚酰胺 所生产的长丝表现出窄的PDI和降低的结晶参数gII，导致晶体本身缺陷的减少，从而显着提高其强度和模量。
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