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公开(公告)号:US09328183B2
公开(公告)日:2016-05-03
申请号:US14382114
申请日:2013-03-07
申请人: Ineos Europe AG
CPC分类号: C08F6/005 , C07C7/00 , C08F2/01 , C08F2/06 , C08F6/001 , C08F10/00 , C08F210/16 , Y02P20/582 , C08L23/06 , C08F10/02 , C08F2/001 , C08F210/14 , C08F2500/05 , C08F2500/12
摘要: Polymerization process including polymerizing a monomer and a comonomer in a polymerization reaction, withdrawing an effluent stream containing solid polymer and a mixture of unreacted monomer and unreacted comonomer, and passing the effluent to a high pressure recovery system having (a) a high pressure separation step for separating vapor containing unreacted monomer and unreacted comonomer from the solids, and (b) a high pressure recycle system for recycling a portion of the vapor to the polymerization reaction, passing the solids from the high pressure recovery system to a low pressure recovery system having (a) a low pressure separation step for separating further unreacted monomer and unreacted comonomer from the solids, and (b) a low pressure recycle system for recycling at least a portion of the unreacted monomer and unreacted comonomer to the polymerization reaction. A portion of the vapor separated in step 2(a) is passed to the low pressure recovery system.
摘要翻译: 聚合方法包括在聚合反应中聚合单体和共聚单体,取出含有固体聚合物的流出物流和未反应的单体与未反应的共聚单体的混合物,并将流出物送至高压回收系统,该系统具有(a)高压分离步骤 用于从固体中分离含有未反应的单体和未反应的共聚单体的蒸气,和(b)用于将一部分蒸气再循环到聚合反应中的高压循环系统,将固体从高压回收系统传递到具有 (a)用于从固体中分离未反应单体和未反应的共聚单体的低压分离步骤,和(b)将至少一部分未反应单体和未反应的共聚单体再循环至聚合反应的低压循环系统。 在步骤2(a)中分离出的蒸气的一部分被传递到低压回收系统。
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公开(公告)号:US09139673B2
公开(公告)日:2015-09-22
申请号:US14382147
申请日:2013-03-07
申请人: Ineos Europe AG
CPC分类号: C08F6/005 , C07C7/00 , C08F2/01 , C08F2/06 , C08F6/001 , C08F10/00 , C08F210/16 , Y02P20/582 , C08L23/06 , C08F10/02 , C08F2/001 , C08F210/14 , C08F2500/05 , C08F2500/12
摘要: Process for the introduction of liquid feeds to a polymerization process, and in particular for the introduction of a fresh feed selected from fresh comonomer and fresh inert hydrocarbon to a polymerization reactor. The process includes passing the fresh feed and a process stream containing a first component selected from hydrogen, nitrogen and methane and a second component which is a monomer to a separator at a pressure of 0.4 MPa (4 bar) or less to produce a first stream containing the majority of the first component and a second stream containing the majority of the fresh feed and the majority of the second component, and passing the second stream to the polymerization reactor.
摘要翻译: 将液体进料引入聚合方法,特别是将选自新鲜共聚单体和新鲜惰性烃的新鲜原料引入聚合反应器的方法。 该方法包括使新鲜进料和含有选自氢,氮和甲烷的第一组分的工艺物流和作为单体的第二组分以0.4MPa(4bar)或更低的压力通入分离器,以产生第一流 含有大多数第一组分和含有大部分新鲜进料和大部分第二组分的第二料流,并将第二料流送入聚合反应器。
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公开(公告)号:US20150065665A1
公开(公告)日:2015-03-05
申请号:US14382114
申请日:2013-03-07
申请人: Ineos Europe AG
IPC分类号: C08F210/16
CPC分类号: C08F6/005 , C07C7/00 , C08F2/01 , C08F2/06 , C08F6/001 , C08F10/00 , C08F210/16 , Y02P20/582 , C08L23/06 , C08F10/02 , C08F2/001 , C08F210/14 , C08F2500/05 , C08F2500/12
摘要: The present invention relates to the treatment and recycle of effluent streams from a polymerisation process, and in particular provides a polymerisation process comprising the steps of: 1) Polymerising a monomer and a comonomer in a polymerisation reaction, 2) Withdrawing an effluent stream comprising solid polymer and a mixture comprising unreacted monomer and unreacted comonomer, and passing the effluent to a high pressure recovery system comprising a. a high pressure separation step for separating a vapour comprising unreacted monomer and unreacted comonomer from said solids, and b. a high pressure recycle system for recycling a portion of the vapour to the polymerisation reaction, 3) Passing the solids from the high pressure recovery system to a low pressure recovery system comprising a. a low pressure separation step for separating further unreacted monomer and unreacted comonomer from said solids, and b. a low pressure recycle system for recycling at least a portion of the unreacted monomer and unreacted comonomer to the polymerisation reaction, characterised in that a portion of the vapour separated in step 2(a) is passed to the low pressure recovery system.
摘要翻译: 本发明涉及从聚合方法处理和再循环流出物流,特别是提供聚合方法,其包括以下步骤:1)在聚合反应中聚合单体和共聚单体,2)将包含固体的流出物流 聚合物和包含未反应单体和未反应的共聚单体的混合物,并将流出物送至包含a的高压回收系统。 用于从所述固体中分离包含未反应单体和未反应的共聚单体的蒸气的高压分离步骤,以及b。 用于将一部分蒸气再循环到聚合反应的高压循环系统,3)将固体从高压回收系统传送到包括a的低压回收系统。 用于从所述固体中分离未反应单体和未反应的共聚单体的低压分离步骤,和b。 用于将至少一部分未反应的单体和未反应的共聚单体再循环到聚合反应中的低压循环系统,其特征在于将步骤2(a)中分离出的蒸汽的一部分通入低压回收系统。
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公开(公告)号:US20160053030A1
公开(公告)日:2016-02-25
申请号:US14929913
申请日:2015-11-02
申请人: INEOS EUROPE AG
IPC分类号: C08F10/00
CPC分类号: C08F6/005 , C07C7/00 , C08F2/01 , C08F2/06 , C08F6/001 , C08F10/00 , C08F210/16 , Y02P20/582 , C08L23/06 , C08F10/02 , C08F2/001 , C08F210/14 , C08F2500/05 , C08F2500/12
摘要: The present invention relates to a polymerisation process, in particular to the polymerisation of olefins in a reactor system comprising two reactors in series, and most particularly provides a process for the polymerisation of monomer in at least first and second reactors operated in series, which process comprises contacting a first stream comprising vapour derived from the effluent withdrawn from the second reactor with a feed stream to the second reactor, said feed stream comprising effluent derived from the first reactor.
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公开(公告)号:US09175120B2
公开(公告)日:2015-11-03
申请号:US14382185
申请日:2013-03-07
申请人: Ineos Europe AG
IPC分类号: C08F2/06 , C08F2/38 , C07C7/00 , C08F210/16 , C08F2/01 , C08F6/00 , C08F210/14
CPC分类号: C08F6/005 , C07C7/00 , C08F2/01 , C08F2/06 , C08F6/001 , C08F10/00 , C08F210/16 , Y02P20/582 , C08L23/06 , C08F10/02 , C08F2/001 , C08F210/14 , C08F2500/05 , C08F2500/12
摘要: Polymerization of olefins in a reactor system having two reactors in series, more particularly a process for the polymerization of monomer in at least first and second reactors operated in series. The process includes contacting a first stream containing vapor derived from the effluent withdrawn from the second reactor with a feed stream to the second reactor, the feed stream containing effluent derived from the first reactor.
摘要翻译: 具有串联的两个反应器的反应器系统中的烯烃的聚合,更具体地,涉及在串联操作的至少第一和第二反应器中单体聚合的方法。 该方法包括将含有来自第二反应器排出的流出物的蒸气的第一物流与第二反应器的进料流接触,所述进料流含有源自第一反应器的流出物。
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公开(公告)号:US09605092B2
公开(公告)日:2017-03-28
申请号:US14903372
申请日:2014-07-22
申请人: INEOS EUROPE AG
IPC分类号: C08F2/00 , C08F110/06 , C08F110/02 , C08F210/02 , C08F6/00
CPC分类号: C08F110/02 , C08F6/003 , C08F6/005 , C08F110/06 , C08F210/02 , Y02P20/582 , C08F2/001 , C08F2/14 , C08F2/01 , C08F210/14 , C08F2500/05 , C08F2500/07 , C08F210/16 , C08F2500/08 , C08L23/0815
摘要: Polymerization process, in particular for the polymerization of monomer selected from ethylene and propylene in a reaction system containing at least three reactors operated in series. The process includes (a) polymerizing monomer in a first reactor having a volume of at least 50 m3 to produce a first polymer, (b) passing the first polymer to a second reactor and polymerizing monomer in the second reactor to produce a second polymer containing the first polymer and polymer produced in the second reactor, and (c) passing the second polymer to a third reactor and polymerizing monomer in the third reactor to produce a third polymer containing the second polymer and polymer produced in the third reactor. The polymerizations are performed such that between 0.01 and 5 w % of the total mass of the third polymer is polymer produced in the second reactor.
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公开(公告)号:US09605091B2
公开(公告)日:2017-03-28
申请号:US15141017
申请日:2016-04-28
申请人: Ineos Europe AG
CPC分类号: C08F6/005 , C07C7/00 , C08F2/01 , C08F2/06 , C08F6/001 , C08F10/00 , C08F210/16 , Y02P20/582 , C08L23/06 , C08F10/02 , C08F2/001 , C08F210/14 , C08F2500/05 , C08F2500/12
摘要: Process for enhancing the separation of monomer components from light components other than monomer by providing a first stream containing monomer and light components other than monomer and passing the first stream to a first separator at a first pressure to separate a gaseous second stream containing at least some of the light components other than monomer and provide a liquid third stream containing monomer. A portion of the third stream and a fourth stream containing monomer and light components other than monomer is passed to a second separator at a second pressure which is lower than the first pressure to separate a gaseous fifth stream containing at least some of the light components other than monomer from the fourth stream and provide a liquid sixth stream containing monomer.
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公开(公告)号:US09567411B2
公开(公告)日:2017-02-14
申请号:US14929913
申请日:2015-11-02
申请人: INEOS EUROPE AG
IPC分类号: C08F6/24 , C08F6/00 , C08F2/01 , C08F2/14 , C08F210/16 , C08F2/06 , C07C7/00 , C08F10/00 , B01J19/18
CPC分类号: C08F6/005 , C07C7/00 , C08F2/01 , C08F2/06 , C08F6/001 , C08F10/00 , C08F210/16 , Y02P20/582 , C08L23/06 , C08F10/02 , C08F2/001 , C08F210/14 , C08F2500/05 , C08F2500/12
摘要: Process for polymerizing monomer in a reactor by withdrawing an effluent from the reactor which is a slurry of polymer solids in a liquid medium and contacting a first stream containing vapor derived from the effluent withdrawn from the reactor with a feed stream to the reactor. The first stream which has the majority of the vaporized components of the liquid medium in the effluent withdrawn from the reactor is brought into contact with the feedstream to the reactor at a pressure of 0.5 MPa or above and/or the first stream is separated from the polymer withdrawn from the reactor at a pressure of 0.5 MPa or above.
摘要翻译: 在反应器中聚合单体的方法是从反应器中排出流出物,反应器是聚合物固体在液体介质中的浆液,并将含有源自反应器的流出物的蒸气的第一流与进料流接触。 在从反应器排出的流出物中具有液体介质的大部分蒸发成分的第一流与0.5MPa或更高压力的进料流与反应器接触,和/或将第一流与 聚合物在0.5MPa或更高的压力下从反应器中取出。
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公开(公告)号:US09540467B2
公开(公告)日:2017-01-10
申请号:US14909505
申请日:2013-08-14
申请人: INEOS EUROPE AG
IPC分类号: C08F210/06 , C08F2/14 , C08F2/38 , C08F6/00 , C08F210/16 , C07C7/00
CPC分类号: C08F210/16 , C08F2/14 , C08F10/02 , C08F2/34 , C08F2/001 , C08F210/14 , C08F2500/05 , C08F2500/07 , C08F2500/12
摘要: Process for introducing a fresh feed of fresh comonomer and/or fresh inert hydrocarbon to a polymerization reactor which is part of a polymerization process having high and low pressure recovery systems, the high pressure recovery system being at a pressure of 0.5 MPa (5 bar) or above and the low pressure recovery system being at a pressure of less than 0.5 MPa (5 bar). The process includes passing the fresh feed and a process stream containing a first component of hydrogen, nitrogen and/or methane and a second component of a monomer to a separator which is part of the low pressure recovery system and is at a pressure of 0.4 MPa or less to produce a first stream containing a majority of the first component and a second stream containing the second component and a majority of the fresh feed, and passing the second stream to the polymerization reactor.
摘要翻译: 将新鲜共聚单体和/或新鲜惰性烃的新鲜进料引入作为具有高低压回收系统的聚合方法的一部分的聚合反应器的方法,高压回收系统处于0.5MPa(5巴)的压力下, 以上,低压回收系统的压力小于0.5MPa(5巴)。 该方法包括将新鲜进料和含有氢,氮和/或甲烷的第一组分和单体的第二组分的工艺流送入作为低压回收系统一部分的分离器,并且压力为0.4MPa 或更少以产生含有大部分第一组分的第一料流和含有第二组分和大部分新鲜进料的第二料流,并将第二料流送至聚合反应器。
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公开(公告)号:US20150025203A1
公开(公告)日:2015-01-22
申请号:US14382185
申请日:2013-03-07
申请人: Ineos Europe AG
IPC分类号: C08F210/16 , C07C7/00
CPC分类号: C08F6/005 , C07C7/00 , C08F2/01 , C08F2/06 , C08F6/001 , C08F10/00 , C08F210/16 , Y02P20/582 , C08L23/06 , C08F10/02 , C08F2/001 , C08F210/14 , C08F2500/05 , C08F2500/12
摘要: The present invention relates to a polymerisation process, in particular to the polymerisation of olefins in a reactor system comprising two reactors in series, and most particularly provides a process for the polymerisation of monomer in at least first and second reactors operated in series, which process comprises contacting a first stream comprising vapour derived from the effluent withdrawn from the second reactor with a feed stream to the second reactor, said feed stream comprising effluent derived from the first reactor.
摘要翻译: 本发明涉及一种聚合方法,特别是涉及在包含串联的两个反应器的反应器系统中烯烃的聚合,并且最具体地提供了在串联操作的至少第一和第二反应器中聚合单体的方法,该方法 包括将包含从第二反应器排出的流出物的蒸汽的第一物流与进料流接触到第二反应器,所述进料流包含来自第一反应器的流出物。
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