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公开(公告)号：US08263687B2
公开(公告)日：2012-09-11
申请号：US11722501
申请日：2005-12-21
IPC分类号： C08L63/00 , C08L61/10 , C08L61/12 , C08K5/09 , C08G59/56 , C08G59/62 , B05D1/00 , B05D3/02 , B32B27/26 , B32B27/38
CPC分类号： C08G59/182 , A61B8/06 , A61B8/481 , C08G59/56 , C08G59/621 , F16L58/1009
摘要： A curable composition comprising a) an epoxy resin containing on average more than one epoxy group per molecule, and b) as curing agent a hybrid hardener, whereby said hardener is a blend of b1) an aminic compound selected from aliphatic, cycloaliphatic, araliphatic amines, imidazoline group-containing amidoamines based on mono- or polybasic acids, adducts of said amines or amidoamines made from glycidyl compounds, adducts of said amines or amidoamines with cyclic carbonates, whereby said aminic compound contains, on average per molecule, at least two reactive hydrogen atoms bound to nitrogen atoms, and b2) a polyphenol novolac, and wherein the polyphenol novolac is used in an amount of from 30% to 45% by weight, based on the total weight of hardener blend comprising b1) and b2), useful for rapid setting and protective coatings and adhesives in application fields like civil engineering, marine, architectural and maintenance.
摘要翻译： 一种可固化组合物，其包含a）每分子平均含有多于一个环氧基的环氧树脂，以及b）作为固化剂的混合硬化剂，其中所述固化剂是b1）选自脂族，脂环族，芳脂族胺的胺化合物 基于单酸或多元酸的含咪唑啉基的酰氨基胺，所述胺的加合物或由缩水甘油基化合物制成的酰氨基胺，所述胺或酰氨基胺与环状碳酸酯的加合物，其中所述胺化合物平均每分子含有至少两个反应性 氢原子与氮原子键合，和b2）多酚酚醛清漆，其中多酚酚醛清漆的用量为30重量％至45重量％，基于包含b1）和b2）的固化剂共混物的总重量，有用 用于在土木工程，海洋，建筑和维护等应用领域快速固化和保护涂料和粘合剂。
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公开(公告)号：US20100210758A1
公开(公告)日：2010-08-19
申请号：US11722501
申请日：2005-12-21
IPC分类号： C08L63/04 , C09D163/04 , C09J1/00 , C09J163/04
CPC分类号： C08G59/182 , A61B8/06 , A61B8/481 , C08G59/56 , C08G59/621 , F16L58/1009
摘要： A curable composition comprising a) an epoxy resin containing on average more than one epoxy group per molecule, and b) as curing agent a hybrid hardener, whereby said hardener is a blend of b1) an aminic compound selected from aliphatic, cycloaliphatic, araliphatic amines, imidazoline group-containing amidoamines based on mono- or polybasic acids, adducts of said amines or amidoamines made from glycidyl compounds, adducts of said amines or amidoamines with cyclic carbonates, whereby said aminic compound contains, on average per molecule, at least two reactive hydrogen atoms bound to nitrogen atoms, and b2) a polyphenol novolac, and wherein the polyphenol novolac is used in an amount of from 30% to 45% by weight, based on the total weight of hardener blend comprising b1) and b2), useful for rapid setting and protective coatings and adhesives in application fields like civil engineering, marine, architectural and maintenance.
摘要翻译： 一种可固化组合物，其包含a）每分子平均含有多于一个环氧基的环氧树脂，以及b）作为固化剂的混合硬化剂，其中所述固化剂是b1）选自脂族，脂环族，芳脂族胺的胺化合物 基于单酸或多元酸的含咪唑啉基的酰氨基胺，所述胺的加合物或由缩水甘油基化合物制成的酰氨基胺，所述胺或酰氨基胺与环状碳酸酯的加合物，其中所述胺化合物平均每分子含有至少两个反应性 氢原子与氮原子键合，和b2）多酚酚醛清漆，其中多酚酚醛清漆的用量为30重量％至45重量％，基于包含b1）和b2）的固化剂共混物的总重量，有用 用于在土木工程，海洋，建筑和维护等应用领域快速固化和保护涂料和粘合剂。
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公开(公告)号：US20090264593A1
公开(公告)日：2009-10-22
申请号：US11630500
申请日：2005-06-20
申请人： Jorg Volle , Michael Vogel
发明人： Jorg Volle , Michael Vogel
CPC分类号： C08G59/188
摘要： Curing agent for epoxy resins, consisting of A) 1%-99% by weight of an adduct obtainable by reacting a1) a polyethylene polyamine having up to six nitrogens in the molecule with a2) a monoglycidyl ether, the adduct of a1) and a2) preferably being isolated by removal of the excess polyethylene polyamine, and B) 99%-1% by weight of an adduct obtainable by reacting b1) a diamine or polyamine with b2) styrene, and also curable compositions further comprising an epoxide compound, and the use of these curable compositions for producing mouldings and sheetlike structures, and also for applications in the adhesives and sealants sector and for epoxy-resin mortars.
摘要翻译： 环氧树脂固化剂由A）1重量％-99重量％的加合物制得，可通过使a1）分子中具有多达六个氮的聚乙烯多胺与a2）单缩水甘油醚，a1）和a2的加合物 ）优选通过除去过量的聚乙烯多胺而分离，以及B）99％-1％（重量）的加合物，其可通过使b1）二胺或多胺与b2）苯乙烯以及还包含环氧化合物的可固化组合物和 这些可固化组合物用于生产模制品和片状结构的用途，以及用于粘合剂和密封剂领域以及用于环氧树脂砂浆的应用。
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公开(公告)号：US20050176899A1
公开(公告)日：2005-08-11
申请号：US10512594
申请日：2003-04-16
申请人： Jorg Volle
发明人： Jorg Volle
IPC分类号： C07C217/14 , C08G59/18 , C08G59/50 , C08G59/62 , C09D163/00 , C09J11/06 , C09J163/00 , C09K3/10 , C08G59/14
CPC分类号： C08G59/623 , C08G59/184
摘要： Mannich bases as curing agents for epoxy resins, characterized in that to prepare the Mannich base an isolated amine adduct is used obtainable by reacting a) an amine containing at least three active amine hydrogens with b) an epoxide compound containing on average one or more than one epoxide group in the molecule, optionally using a solvent, there being an excess of a) relative to reactive groups of components a) and b), and subsequently the adduct formed is isolated from free amines. Curable epoxy resin compositions comprising these Mannich bases are suitable owing to good obtainable surface properties in particular for coating, adhesively bonding and enhancing metallic and mineral substrates, as adhesive and sealant, and for producing mouldings and sheetlike structures.
摘要翻译： 曼尼希碱作为环氧树脂的固化剂，其特征在于为了制备曼尼希碱，分离的胺加合物可通过使a）含有至少三个活性胺氢的胺与b）通常包含一个或多个 分子中的一个环氧基团，任选地使用溶剂，相对于组分a）和b）的反应性基团过量a），随后形成的加合物与游离胺分离。 包含这些曼尼希碱的可固化环氧树脂组合物是合适的，因为具有良好的表面性能，特别是用于涂覆，粘合和增强金属和矿物基材，粘合剂和密封剂，以及用于生产模制品和片状结构。
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公开(公告)号：US20050010024A1
公开(公告)日：2005-01-13
申请号：US10491552
申请日：2002-09-20
申请人： Jorg Volle , Wolfgang Scherzer
发明人： Jorg Volle , Wolfgang Scherzer
CPC分类号： C08G59/184 , F16L11/16
摘要： Method of producing pipes and pipe auxiliary pieces for pipeline systems in composite material, especially for service water and drinking water, produced by the filament winding process with binders based on epoxy resins containing on average more than one epoxide group in the molecule and on curing agents for the epoxy resins, with the use of customary auxiliaries and additives, characterized in that as binder a curable composition comprising a) a liquid epoxy resin having epoxide values of from 0.40 to 0.65 and b) an adduct of a triethylenetetraminoimidazoline with a glycidyl ether having more than one epoxide group per molecule is used.
摘要翻译： 生产用于复合材料管道系统的管道和管道辅助件的制造方法，特别是用于服务用水和饮用水的管道和管道辅助件，其通过使用基于分子中平均含有多于一个环氧基团的环氧树脂的粘合剂和固化剂 对于环氧树脂，使用常规助剂和添加剂，其特征在于作为粘合剂，可固化组合物，其包含a）环氧化物值为0.40至0.65的液体环氧树脂，和b）三亚乙基四胺咪唑啉与缩水甘油醚的加合物具有 每分子使用多于一个环氧基团。
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公开(公告)号：US20070043153A1
公开(公告)日：2007-02-22
申请号：US10564068
申请日：2004-07-08
申请人： Alfred Kruse , Christa Broll , Jorg Volle
发明人： Alfred Kruse , Christa Broll , Jorg Volle
IPC分类号： C08K5/06
CPC分类号： C08K5/06 , C08L27/06 , C08L77/08 , C08L2666/20
摘要： The invention relates to adhesion promoters for plastisols based on polyaminoamides, characterized in that the adhesion promoter comprises not only a polyaminoamide but also at least 10% by weight, and at most 60% by weight, based on the total amount of adhesion promoter, of ethyldiglycol (ethyl Carbitol), and to a process for the production of coatings and adhesive bonds for materials, and also to plastisols in which these adhesion promoters are used concomitantly.
摘要翻译： 本发明涉及基于聚氨基酰胺的增塑溶胶的粘合促进剂，其特征在于粘合促进剂不仅包含聚氨基酰胺，而且包括至少10重量％，最多60重量％，基于粘合促进剂的总量， 乙基二甘醇（乙基卡必醇），以及用于生产用于材料的涂料和粘合剂粘合剂的方法，以及其中同时使用这些粘合促进剂的增塑溶胶。
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公开(公告)号：US20080293870A1
公开(公告)日：2008-11-27
申请号：US11630498
申请日：2005-06-20
CPC分类号： C08G59/184 , C08G59/54 , C08L63/00 , C08L2666/20
摘要： Curing agent for epoxy resins, consisting of A) 1%-99% by weight of an adduct obtainable by reacting a1) a poly-ethylene polyamine having up to six nitrogens in the molecule with a2) a monoglycidyl ether, the adduct of a1) and a2) preferably being isolated by removal of the excess polyethylene polyamine, and B) 99%-1% by weight of an adduct obtainable by reacting b1) a diamine or polyamine with b2) acrylonitrile and/or C) 99%-1% by weight of a polyaminoamide, and also curable compositions further comprising an epoxide compound, and the use of these curable compositions for producing mouldings and sheetlike structures, and also for applications in the adhesives and sealants sector and for epoxy-resin mortars.
摘要翻译： 环氧树脂固化剂由A）1重量％-99重量％的加合物，a1）聚分子中具有最多6个氮原子的聚亚乙基多胺与a）单缩水甘油醚，a1）的加合物， 和a2）优选通过除去过量的聚乙烯多胺来分离，以及B）99％-1％（重量）的加合物，其可通过使b1）二胺或多胺与b2）丙烯腈和/或C）99％-1％ 重量的聚氨基酰胺，以及还包含环氧化合物的可固化组合物，以及这些可固化组合物用于生产模制品和片状结构的用途，以及用于粘合剂和密封剂领域以及环氧树脂砂浆中的应用。
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公开(公告)号：US20070292620A1
公开(公告)日：2007-12-20
申请号：US11631900
申请日：2005-07-08
申请人： Jorg Volle , Michael Vogel
发明人： Jorg Volle , Michael Vogel
CPC分类号： C08G59/50 , C08G18/6685 , C08G59/1444 , C08L63/00 , C08L71/02 , C08L75/00 , C08L2666/22
摘要： Special amine compositions comprising a) 30-70% by weight of a polyetherdiamine of the general formula (I) in which n is from 10 to 70, b) 3-30% by weight of a monoamine of the general formula R1—NH2, in which R1 is the straight-chain or branched, saturated or preferably unsaturated radical of a hydrocarbon having 5 to 22 carbon atoms or of a monofunctional polyetheramine having a molecular weight of up to 400 g/mol and c) 3-30% by weight of a di- or triamine and d) 5-40% by weight of an alkylphenol of the general formula (II) in which R2 is the straight-chain, branched or cyclic, saturated or unsaturated radical of a hydrocarbon having 5 to 14 carbon atoms, and curable epoxy resin compositions comprising these special amine compositions, the use of which results in thermosets which have a low degree of crosslinking, are resilient even at low temperatures and are resistant to chemical compositions, and the production of shaped articles and coatings using these curable compositions.
摘要翻译： 特殊胺组合物，其包含a）30-70重量％的通式（I）的聚醚二胺，其中n为10至70，b）3-30重量％的通式R 1的单胺， 其中R 1是具有5至22个碳原子的烃的直链或支链，饱和或优选不饱和基团，或 的分子量高达400g / mol的单官能聚醚胺和c）3-30重量％的二 - 或三胺和d）5-40重量％的通式（II）的烷基酚在 其中R 2是具有5至14个碳原子的烃的直链，支链或环状饱和或不饱和基团，以及包含这些特殊胺组合物的可固化环氧树脂组合物，使用哪些结果 在具有低交联度的热固性材料中，即使在低温下也具有弹性并且耐化学组成，以及成型制品和共混物的生产 使用这些可固化组合物。
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