公开(公告)号：US08187747B2

公开(公告)日：2012-05-29

申请号：US11727389

申请日：2007-03-26

申请人： Isao Abe ,  Satoshi Matsumoto ,  Shuji Tsutsumi ,  Takashi Takeuchi

发明人： Isao Abe ,  Satoshi Matsumoto ,  Shuji Tsutsumi ,  Takashi Takeuchi

IPC分类号： H01M4/00

CPC分类号： H01M4/525 ,  C01G51/42 ,  C01G53/00 ,  C01G53/42 ,  C01P2002/52 ,  C01P2002/54 ,  C01P2002/88 ,  C01P2006/12 ,  C01P2006/40

摘要： The present invention provides a positive electrode active material for a non-aqueous electrolyte-based secondary battery, composed of a lithium/nickel composite oxide with high capacity, low cost and excellent heat stability, an industrially suitable production method therefor, and a high safety non-aqueous electrolyte-based secondary battery. A lithium/nickel composite oxide is produced by the following steps (a) to (c): (a) Nickel hydroxide or nickel oxyhydroxide having a specified component is prepared at a temperature of 600 to 1100° C., under air atmosphere. (b) Fired powders are prepared after mixing said nickel oxide and a lithium compound, and then by firing at a maximal temperature range of 650 to 850° C., under oxygen atmosphere. (c) Obtained fired powders are washed with water within a time satisfying the following equation (2) and then filtered and dried. A≦B/40   (2) wherein, A represents washing time represented by unit of minute; and B represents slurry concentration represented by unit of g/L).

摘要翻译： 本发明提供一种非水电解质型二次电池用正极活性物质，由具有高容量，低成本，优异的热稳定性的锂/镍复合氧化物构成，其工业上合适的制造方法，高安全性 非水电解质二次电池。 通过以下步骤（a）至（c）制备锂/镍复合氧化物：（a）在空气气氛下，在600〜1100℃的温度下制备具有规定成分的氢氧化镍或氢氧化正镍。 （b）在氧化镍和锂化合物混合之后，然后在氧气氛下在最高温度范围650〜850℃下进行烧成，制备烧成粉末。 （c）获得的发泡粉末在满足下述式（2）的时间内用水洗涤，然后过滤并干燥。 A＆nlE; B / 40（2）其中，A表示以分钟为单位表示的洗涤时间; B表示以g / L为单位表示的浆料浓度）。

公开(公告)号：US07981546B2

公开(公告)日：2011-07-19

申请号：US11794579

申请日：2006-04-17

申请人： Takashi Takeuchi ,  Akihiro Taniguchi ,  Shuji Tsutsumi ,  Kensuke Nakura ,  Hiroshi Matsuno ,  Hideo Sasaoka ,  Satoshi Matsumoto

发明人： Takashi Takeuchi ,  Akihiro Taniguchi ,  Shuji Tsutsumi ,  Kensuke Nakura ,  Hiroshi Matsuno ,  Hideo Sasaoka ,  Satoshi Matsumoto

IPC分类号： H01M4/48

CPC分类号： H01M4/525 ,  C01G53/42 ,  C01P2002/52 ,  C01P2004/51 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2006/11 ,  C01P2006/12 ,  C01P2006/40 ,  H01B1/122 ,  H01M4/131 ,  H01M4/485 ,  H01M4/505 ,  H01M10/052 ,  H01M2004/021

摘要： A lithium-containing composite oxide represented by the formula 1: LixNi1-y-z-v-wCoyAlzM1vM2wO2 is used as a positive electrode active material for a non-aqueous electrolyte secondary battery. The element M1 is at least one selected from the group consisting of Mn, Ti, Y, Nb, Mo, and W. The element M2 includes at least two selected from the group consisting of Mg, Ca, Sr, and Ba, and the element M2 includes at least Mg and Ca. The formula 1 satisfies 0.97≦x≦1.1, 0.05≦y≦0.35, 0.005≦z≦0.1, 0.0001≦v≦0.05, and 0.0001≦w≦0.05. The primary particles have a mean particle size of 0.1 μm or more and 3 μm or less, and the secondary particles have a mean particle size of 8 μm or more and 20 μm or less.

摘要翻译： 作为非水电解质二次电池用正极活性物质，使用由式1表示的含锂复合氧化物：LixNi1-y-z-v-wCoyAlzM1vM2wO2。 元素M1是选自Mn，Ti，Y，Nb，Mo和W中的至少一种元素。元素M2包括选自Mg，Ca，Sr和Ba中的至少两种元素，并且 元素M2至少包括Mg和Ca。 式1满足0.97＆nlE; x＆nlE; 1.1,0.05＆nlE; y＆nlE; 0.35,0.005＆nlE; z＆nlE; 0.1,0.0001和nlE; v＆nlE; 0.05和0.0001≤n≤E≤0.05。 一次粒子的平均粒径为0.1μm以上且3μm以下，二次粒子的平均粒径为8μm以上且20μm以下。

公开(公告)号：US20090035659A1

公开(公告)日：2009-02-05

申请号：US11794579

申请日：2006-04-17

申请人： Takashi Takeuchi ,  Akihiro Taniguchi ,  Shuji Tsutsumi ,  Kensuke Nakura ,  Hiroshi Matsuno ,  Hideo Sasaoka ,  Satoshi Matsumoto

发明人： Takashi Takeuchi ,  Akihiro Taniguchi ,  Shuji Tsutsumi ,  Kensuke Nakura ,  Hiroshi Matsuno ,  Hideo Sasaoka ,  Satoshi Matsumoto

IPC分类号： H01M4/48 ,  H01M4/02 ,  H01M10/00 ,  H01B1/02 ,  C01G53/00 ,  H01M4/04

CPC分类号： H01M4/525 ,  C01G53/42 ,  C01P2002/52 ,  C01P2004/51 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2006/11 ,  C01P2006/12 ,  C01P2006/40 ,  H01B1/122 ,  H01M4/131 ,  H01M4/485 ,  H01M4/505 ,  H01M10/052 ,  H01M2004/021

摘要： A lithium-containing composite oxide represented by the formula 1: LixNi1-y-z-v-wCoyAlzM1vM2wO2 is used as a positive electrode active material for a non-aqueous electrolyte secondary battery. The element M1 is at least one selected from the group consisting of Mn, Ti, Y, Nb, Mo, and W. The element M2 includes at least two selected from the group consisting of Mg, Ca, Sr, and Ba, and the element M2 includes at least Mg and Ca. The formula 1 satisfies 0.97≦x≦1.1, 0.05≦y≦0.35, 0.005≦z≦0.1, 0.0001≦v≦0.05, and 0.0001≦w≦0.05. The primary particles have a mean particle size of 0.1 μm or more and 3 μm or less, and the secondary particles have a mean particle size of 8 μm or more and 20 μm or less.

摘要翻译： 作为非水电解质二次电池用正极活性物质，使用由式1表示的含锂复合氧化物：LixNi1-y-z-v-wCoyAlzM1vM2wO2。 元素M1是选自Mn，Ti，Y，Nb，Mo和W中的至少一种元素。元素M2包括选自Mg，Ca，Sr和Ba中的至少两种元素，并且 元素M2至少包括Mg和Ca。 式1满足0.97 <= x <= 1.1,0.05 <= y <=0.35,0.005≤z≤0.1,0.0001≤v≤0.05,0.0001≤w≤0.05。 初级粒子的平均粒径为0.1μm以上3μm以下，二次粒子的平均粒径为8μm以上且20μm以下。

公开(公告)号：US07776474B2

公开(公告)日：2010-08-17

申请号：US11262927

申请日：2005-11-01

申请人： Akihiro Taniguchi ,  Kohei Suzuki ,  Shuji Tsutsumi ,  Mitsuhiro Takeno ,  Kozo Watanabe ,  Takashi Takeuchi ,  Takaya Saito

发明人： Akihiro Taniguchi ,  Kohei Suzuki ,  Shuji Tsutsumi ,  Mitsuhiro Takeno ,  Kozo Watanabe ,  Takashi Takeuchi ,  Takaya Saito

IPC分类号： H01M4/02 ,  H01M4/58 ,  H01M4/62 ,  H01M4/00

CPC分类号： H01M4/525 ,  H01M4/131 ,  H01M4/505 ,  H01M4/621

摘要： Disclosed is a non-aqueous electrolyte secondary battery having an electrode group in which a positive electrode and a negative electrode are spirally wound with a separator interposed therebetween. The positive electrode contains a positive electrode active material and a binder. The positive electrode active material contains a mixture of two different particulate substances having different average particle sizes. The two different particulate substances are lithium composite metal oxides containing nickel as an essential element. The binder includes fluorocarbon resin and rubber particles. The fluorocarbon resin contains at least a vinylidene fluoride unit. The amount of the rubber particles per 100 parts by weight of the fluorocarbon resin is 1 to 25 parts by weight.

摘要翻译： 公开了一种具有电极组的非水电解质二次电池，其中正电极和负电极螺旋地缠绕有隔膜。 正极含有正极活性物质和粘合剂。 正极活性物质含有具有不同平均粒径的两种不同颗粒物质的混合物。 两种不同的颗粒物质是含有镍作为必需元素的锂复合金属氧化物。 粘合剂包括氟碳树脂和橡胶颗粒。 氟碳树脂含有至少一个偏氟乙烯单元。 每100重量份氟碳树脂中的橡胶颗粒的量为1至25重量份。

公开(公告)号：US20090087740A1

公开(公告)日：2009-04-02

申请号：US11994923

申请日：2006-07-06

申请人： Masaki Deguchi ,  Hiroshi Matsuno ,  Shuji Tsutsumi ,  Takashi Takeuchi ,  Masamichi Onuki ,  Shinichi Kinoshita

发明人： Masaki Deguchi ,  Hiroshi Matsuno ,  Shuji Tsutsumi ,  Takashi Takeuchi ,  Masamichi Onuki ,  Shinichi Kinoshita

IPC分类号： H01M10/40 ,  H01M4/66 ,  H01M4/58

CPC分类号： H01M4/525 ,  H01M4/1391 ,  H01M4/38 ,  H01M10/0525 ,  H01M10/0566 ,  H01M10/0567 ,  H01M2004/021

摘要： The invention intends to provide a high-capacity type non-aqueous electrolyte secondary battery that includes a nickel-containing lithium composite oxide as a positive electrode active material and exhibits good charge/discharge cycle characteristics even under a high temperature environment.The invention is a non-aqueous electrolyte secondary battery including: a positive electrode including a nickel-containing lithium composite oxide as a positive electrode active material; a negative electrode capable of absorbing and desorbing lithium; a separator interposed between the positive electrode and the negative electrode; and a non-aqueous electrolyte including a non-aqueous solvent and a solute dissolved in the non-aqueous solvent. In the nickel-containing lithium composite compound after a discharge to a predetermined cut-off voltage of discharge, the molar ratio r of lithium to the other metal elements than lithium is 0.85 or more and 0.92 or less. The non-aqueous electrolyte includes a fluorine-containing sulfonate compound.

摘要翻译： 本发明提供一种高容量型非水电解质二次电池，其包含含镍锂复合氧化物作为正极活性物质，即使在高温环境下也表现出良好的充放电循环特性。 本发明是一种非水电解质二次电池，其包括：正极，其包含含镍的锂复合氧化物作为正极活性物质; 能够吸收和解吸锂的负极; 夹在正极和负极之间的隔膜; 以及包含非水溶剂和溶解在非水溶剂中的溶质的非水电解质。 在放电至规定的放电截止电压后的含镍锂复合化合物中，与锂相比，锂与其它金属元素的摩尔比r为0.85以上且0.92以下。 非水电解质包含含氟磺酸盐化合物。

公开(公告)号：US20060115730A1

公开(公告)日：2006-06-01

申请号：US11262927

申请日：2005-11-01

申请人： Akihiro Taniguchi ,  Kohei Suzuki ,  Shuji Tsutsumi ,  Mitsuhiro Takeno ,  Kozo Watanabe ,  Takashi Takeuchi ,  Takaya Saito

发明人： Akihiro Taniguchi ,  Kohei Suzuki ,  Shuji Tsutsumi ,  Mitsuhiro Takeno ,  Kozo Watanabe ,  Takashi Takeuchi ,  Takaya Saito

IPC分类号： H01M4/62 ,  H01M4/52

CPC分类号： H01M4/525 ,  H01M4/131 ,  H01M4/505 ,  H01M4/621

摘要： Disclosed is a non-aqueous electrolyte secondary battery having an electrode group in which a positive electrode and a negative electrode are spirally wound with a separator interposed therebetween. The positive electrode contains a positive electrode active material and a binder. The positive electrode active material contains a mixture of two different particulate substances having different average particle sizes. The two different particulate substances are lithium composite metal oxides containing nickel as an essential element. The binder includes fluorocarbon resin and rubber particles. The fluorocarbon resin contains at least a vinylidene fluoride unit. The amount of the rubber particles per 100 parts by weight of the fluorocarbon resin is 1 to 25 parts by weight.

摘要翻译： 公开了一种具有电极组的非水电解质二次电池，其中正电极和负电极螺旋地缠绕有隔膜。 正极含有正极活性物质和粘合剂。 正极活性物质含有具有不同平均粒径的两种不同颗粒物质的混合物。 两种不同的颗粒物质是含有镍作为必需元素的锂复合金属氧化物。 粘合剂包括氟碳树脂和橡胶颗粒。 氟碳树脂含有至少一个偏二氟乙烯单元。 每100重量份氟碳树脂中的橡胶颗粒的量为1至25重量份。

公开(公告)号：US09136566B2

公开(公告)日：2015-09-15

申请号：US13391134

申请日：2011-07-27

申请人： Kenji Takeda ,  Koichi Yokoura ,  Takashi Takeuchi

发明人： Kenji Takeda ,  Koichi Yokoura ,  Takashi Takeuchi

IPC分类号： H01M10/42 ,  H01M10/48 ,  G01R31/36 ,  G01R19/00 ,  H01M10/04 ,  H02J7/00

CPC分类号： H01M10/482 ,  G01R19/00 ,  G01R31/36 ,  H01M10/0445 ,  H01M10/4207 ,  H01M10/4221 ,  H01M10/425 ,  H01M2010/4271 ,  H01M2010/4278 ,  H02J7/0021 ,  H02J7/0024

摘要： A battery pack (21A) according to embodiments of the present invention comprises a plurality of battery modules (11A-11D) connected to each other in either one or both of a series connection mode and a parallel connection mode. An identifying information setting section (25) sets identifying information on each of the plurality of battery elements (11A-11D). A connection mode managing section (47) manages the connection mode between the plurality of battery elements (11A-11D) by using the identifying information set by the identifying information setting section (25). The identifying information on each of the plurality of battery elements (11A-11D) is made up of a combination of first identifying information on the potential of the one of the plurality of battery elements (11A-11D) and second identifying information on the battery pack (21A) serving as a superordinate battery element to which the one of the plurality of battery elements (11A-11D) belongs.

摘要翻译： 根据本发明的实施例的电池组（21A）包括在串联和并联模式中的一个或两个中彼此连接的多个电池模块（11A-11D）。 识别信息设定部（25）在多个电池元件（11A-11D）中设置识别信息。 连接模式管理部分（47）通过使用由识别信息设置部分（25）设置的识别信息来管理多个电池元件（11A-11D）之间的连接模式。 多个电池元件（11A-11D）中的每一个的识别信息由关于多个电池元件（11A-11D）中的一个的电位的第一识别信息和关于电池的第二识别信息的组合构成 作为上述多个电池元件（11A-11D）中的一个所属的上位电池元件的电池组（21A）。