公开(公告)号：US5256679A

公开(公告)日：1993-10-26

申请号：US745245

申请日：1991-08-14

申请人： Isao Minamida ,  Yasuyuki Kando ,  Hitoshi Ishizuka ,  Tetsuo Okauchi ,  Hideki Uneme

发明人： Isao Minamida ,  Yasuyuki Kando ,  Hitoshi Ishizuka ,  Tetsuo Okauchi ,  Hideki Uneme

IPC分类号： A01N51/00 ,  A01N43/40 ,  A01N43/78 ,  A01N43/84 ,  A01N47/44 ,  C07C255/58 ,  C07C277/08 ,  C07C279/34 ,  C07C335/40 ,  C07D205/10 ,  C07D207/40 ,  C07D207/404 ,  C07D207/44 ,  C07D207/448 ,  C07D209/48 ,  C07D211/88 ,  C07D213/16 ,  C07D213/36 ,  C07D213/61 ,  C07D213/69 ,  C07D213/75 ,  C07D241/12 ,  C07D277/12 ,  C07D277/20 ,  C07D277/28 ,  C07D277/32 ,  C07D277/34 ,  C07D277/38 ,  C07D277/48 ,  C07D417/12 ,  C07D213/26 ,  C07D277/30

CPC分类号： C07D207/404 ,  A01N51/00 ,  C07C255/58 ,  C07C335/40 ,  C07D205/10 ,  C07D207/448 ,  C07D209/48 ,  C07D211/88 ,  C07D213/61 ,  C07D213/69 ,  C07D241/12 ,  C07D277/32 ,  C07D277/34 ,  C07D417/12

摘要： Novel substituted nitroguanidine derivatives and salts thereof having the following formula: ##STR1## wherein R.sup.1 is a substituted or unsubstituted heterocyclic group; R.sup.2 is a group attached through a sulfur atom, a group attached through a phosphorus atom, cyano, --CO--OR.sup.6 wherein R.sup.6 is a substituted or unsubstituted hydrocarbon group or a substituted or unsubstituted heterocyclic group, or --CO--NR.sup.7 R.sup.8 wherein R.sup.7 and R.sup.8, which are the same or different, are each independently hydrogen, a substituted or unsubstituted hydrocarbon group or a substituted or unsubstituted heterocyclic group, or R.sup.7 and R.sup.8, taken together with the nitrogen atom to which they are attached are a cyclic amino group; R.sup.3 is hydrogen, a substituted or unsubstituted hydrocarbon group (except for one substituted with an oxo group at the binding site), a group attached through a sulfur atom, a group attached through a phosphorus atom, cyano, --CO--R.sup.9 wherein R.sup.9 is hydrogen, a substituted or unsubstituted hydrocarbon group or a substituted or unsubstituted heterocyclic group, --CO--OR.sup.10 wherein R.sup.10 is a substituted or unsubstituted hydrocarbon group or a substituted or unsubstituted heterocyclic group, or --CO--NR.sup.11 R.sup.12 wherein R.sup.11 and R.sup.12, which are the same or different, are each independently hydrogen, a substituted or unsubstituted hydrocarbon group or a substituted or unsubstituted heterocyclic group, or R.sup.11 and R.sup.12, taken together with the nitrogen atom to which they are attached are a cyclic amino group; and R.sup.4 is hydrogen or a lower alkyl group; which have unexpectedly potent pesticidal activity and very low toxicity.

公开(公告)号：US5084459A

公开(公告)日：1992-01-28

申请号：US426177

申请日：1989-10-25

申请人： Hideki Uneme ,  Isao Minamida ,  Tetsuo Okauchi ,  Noriko Higuchi

发明人： Hideki Uneme ,  Isao Minamida ,  Tetsuo Okauchi ,  Noriko Higuchi

IPC分类号： A01N43/00 ,  A01N43/54 ,  A01N43/78 ,  C07D239/06 ,  C07D401/04 ,  C07D401/06 ,  C07D401/12 ,  C07D401/14 ,  C07D403/02 ,  C07D405/02 ,  C07D409/02 ,  C07D411/02 ,  C07D413/02 ,  C07D417/02 ,  C07D417/06 ,  C07D417/12

CPC分类号： C07D239/06 ,  A01N43/54 ,  A01N43/78 ,  C07D401/04 ,  C07D401/06 ,  C07D401/12 ,  C07D401/14 ,  C07D417/06 ,  C07D417/12

摘要： There is provided a pest control composition containing a compound represented by the formula, ##STR1## wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are the same or different and independently mean a hydrogen atom, a hydrocarbon group which may be substituted or a heterocyclic group which may be substituted and X means an electron attracting group or a salt thereof.The compounds are of minimal toxicity to man, domestic animals and fish and selectively display remarkable control effect on pests.

公开(公告)号：US5633375A

公开(公告)日：1997-05-27

申请号：US481136

申请日：1995-06-07

申请人： Hideki Uneme ,  Koichi Iwanaga ,  Noriko Higuchi ,  Isao Minamida ,  Tetsuo Okauchi

发明人： Hideki Uneme ,  Koichi Iwanaga ,  Noriko Higuchi ,  Isao Minamida ,  Tetsuo Okauchi

IPC分类号： A01N47/44 ,  A01N51/00 ,  C07C279/36 ,  C07D213/40 ,  C07D213/61 ,  C07D213/75 ,  C07D239/26 ,  C07D241/12 ,  C07D277/28 ,  C07D277/32 ,  C07D277/34 ,  A01N43/40 ,  C07D213/24

CPC分类号： C07D213/40 ,  A01N47/44 ,  A01N51/00 ,  C07C279/36 ,  C07D213/61 ,  C07D213/75 ,  C07D239/26 ,  C07D241/12 ,  C07D277/28 ,  C07D277/32 ,  C07D277/34

摘要： An insecticidal composition containing a guanidine derivative of the formula: ##STR1## wherein R.sup.1 is an optionally substituted homocyclic or heterocyclic group, n is 0 or 1, R.sup.2 is a hydrogen atom or an optionally substituted hydrocarbon group, R.sup.3 is a primary, secondary or tertiary amino group, X is an electron attractive group such as nitro or trifluoroacetyl group, provided that when n is 0, R.sup.1 is an optionally substituted heterocyclic group or a salt thereof.

摘要翻译： 一种杀虫组合物，其含有下式的胍衍生物：其中R 1为任选取代的杂环或杂环基团，n为0或1，R 2为氢原子或任选取代的烃基，R 3为伯 仲或叔氨基，X是硝基或三氟乙酰基等吸电子基团，条件是当n为0时，R 1为任意取代的杂环基或其盐。

公开(公告)号：US5489603A

公开(公告)日：1996-02-06

申请号：US91744

申请日：1993-07-15

申请人： Hideki Uneme ,  Koichi Iwanaga ,  Noriko Higuchi ,  Isao Minamida ,  Tetsuo Okauchi

发明人： Hideki Uneme ,  Koichi Iwanaga ,  Noriko Higuchi ,  Isao Minamida ,  Tetsuo Okauchi

IPC分类号： A01N47/44 ,  A01N51/00 ,  C07C279/36 ,  C07D213/40 ,  C07D213/61 ,  C07D213/75 ,  C07D239/26 ,  C07D241/12 ,  C07D277/28 ,  C07D277/32 ,  C07D277/34 ,  A01N43/40 ,  C07D213/24

CPC分类号： C07D213/40 ,  A01N47/44 ,  A01N51/00 ,  C07C279/36 ,  C07D213/61 ,  C07D213/75 ,  C07D239/26 ,  C07D241/12 ,  C07D277/28 ,  C07D277/32 ,  C07D277/34

摘要： An insecticidal composition containing a guanidine derivative of the formula: ##STR1## wherein R.sup.1 is an optionally substituted homocyclic or heterocyclic group, n is 0 or 1, R.sup.2 is a hydrogen atom or an optionally substituted hydrocarbon group, R.sup.3 is a primary, secondary or tertiary amino group, X is an electron attractive group such as nitro or trifluoroacetyl group, provided that when n is 0, R.sup.1 is an optionally substituted heterocyclic group or a salt thereof.

摘要翻译： 一种杀虫组合物，其含有下式的胍衍生物：其中R 1为任选取代的杂环或杂环基团，n为0或1，R 2为氢原子或任选取代的烃基，R 3为伯 仲或叔氨基，X是硝基或三氟乙酰基等吸电子基团，条件是当n为0时，R 1为任意取代的杂环基或其盐。

公开(公告)号：US5438065A

公开(公告)日：1995-08-01

申请号：US507776

申请日：1990-04-12

申请人： Hideki Uneme ,  Isao Minamida ,  Tetsuo Okauchi

发明人： Hideki Uneme ,  Isao Minamida ,  Tetsuo Okauchi

IPC分类号： C07D277/20 ,  A01N43/40 ,  A01N43/78 ,  C07D213/36 ,  C07D213/61 ,  C07D213/64 ,  C07D213/643 ,  C07D213/74 ,  C07D277/32 ,  C07D521/00 ,  A61K31/44 ,  C07D213/38

CPC分类号： C07D213/643 ,  A01N43/40 ,  A01N43/78 ,  C07D213/61 ,  C07D213/74 ,  C07D277/32

摘要： Diaminoethylene derivatives of the formula: ##STR1## wherein R.sup.1 is a heterocyclic group which may be substituted, R.sup.2, R.sup.3 and R.sup.4 are a hydrogen atom or a hydrocarbon group which may be substituted or R.sup.3 and R.sup.4 are combined to form a cyclic amino group together with the adjacent nitrogen atom; R.sup.5 is hydrogen atom or a hydrocarbon group or heterocyclic group which may be substituted; X is an electron attractive group; Y is a hydroxyl or substituted hydroxyl group, amino or substituted amino group or mercapto or substituted mercapto group; n is 0 or 1; or their salts, which are useful as insecticides.

摘要翻译： 具有下式的二氨基亚乙基衍生物：其中R 1是可被取代的杂环基，R 2，R 3和R 4是氢原子或可被取代的烃基，或者R 3和R 4结合形成环状 氨基与相邻的氮原子一起; R5是氢原子或可被取代的烃基或杂环基; X是吸电子基团; Y是羟基或取代的羟基，氨基或取代的氨基或巯基或取代的巯基; n为0或1; 或其盐，其可用作杀虫剂。

公开(公告)号：US5034404A

公开(公告)日：1991-07-23

申请号：US456863

申请日：1989-12-27

申请人： Hideki Uneme ,  Koichi Iwanaga ,  Noriko Higuchi ,  Isao Minamida ,  Tetsuo Okauchi

发明人： Hideki Uneme ,  Koichi Iwanaga ,  Noriko Higuchi ,  Isao Minamida ,  Tetsuo Okauchi

IPC分类号： A01N47/44 ,  A01N51/00 ,  C07C279/36 ,  C07D213/40 ,  C07D213/61 ,  C07D213/75 ,  C07D239/26 ,  C07D241/12 ,  C07D277/28 ,  C07D277/32 ,  C07D277/34

CPC分类号： C07D213/40 ,  A01N47/44 ,  A01N51/00 ,  C07C279/36 ,  C07D213/61 ,  C07D213/75 ,  C07D239/26 ,  C07D241/12 ,  C07D277/28 ,  C07D277/32 ,  C07D277/34

摘要： An insecticidal composition containing a guanidine derivative of the formula: ##STR1## wherein R.sup.1 is an optionally substituted homocyclic or heterocyclic group, n is 0 or 1, R.sup.2 is a hydrogen atom or an optionally substituted hydrocarbon group, R.sup.3 is a primary, secondary or tertiary amino group, X is an electron attractive group such as nitro or trifluoroacetyl group, provided that when n is 0, R.sup.1 is an optionally substituted heterocyclic group or a salt thereof.

公开(公告)号：US5696256A

公开(公告)日：1997-12-09

申请号：US439790

申请日：1995-05-12

申请人： Yasuyuki Kando ,  Hideki Uneme ,  Isao Minamida

发明人： Yasuyuki Kando ,  Hideki Uneme ,  Isao Minamida

IPC分类号： A01N51/00 ,  C07C255/58 ,  C07C335/40 ,  C07D205/10 ,  C07D207/40 ,  C07D207/404 ,  C07D207/44 ,  C07D207/448 ,  C07D209/48 ,  C07D211/88 ,  C07D213/61 ,  C07D213/69 ,  C07D241/12 ,  C07D277/28 ,  C07D277/32 ,  C07D277/34 ,  C07D211/44 ,  C07D205/04 ,  C07D207/12 ,  C07D223/10

CPC分类号： C07D207/404 ,  A01N51/00 ,  C07C255/58 ,  C07C335/40 ,  C07D205/10 ,  C07D207/448 ,  C07D209/48 ,  C07D211/88 ,  C07D213/61 ,  C07D213/69 ,  C07D241/12 ,  C07D277/32 ,  C07D277/34

摘要： ##STR1## wherein R is a substituted or unsubstituted hydrocarbon residue or acyl group; X is an electron withdrawing group; Y
1 and Y
2 , which are the same or different, are each independently oxygen or sulfur; and A is a substituted or unsubstituted, divalent hydrocarbon residue have potent reactivity, this being useful in preparing guanidine derivatives.

摘要翻译： 其中R是取代或未取代的烃残基或酰基; X是吸电子基团; Y1和Y2相同或不同，各自独立地为氧或硫; 并且A是取代或未取代的二价烃残基具有有效的反应性，这可用于制备胍衍生物。

公开(公告)号：US6160126A

公开(公告)日：2000-12-12

申请号：US682247

申请日：1991-04-09

申请人： Yasuyuki Kando ,  Hideki Uneme ,  Isao Minamida

发明人： Yasuyuki Kando ,  Hideki Uneme ,  Isao Minamida

IPC分类号： A01N51/00 ,  C07C255/58 ,  C07C335/40 ,  C07D205/10 ,  C07D207/40 ,  C07D207/404 ,  C07D207/44 ,  C07D207/448 ,  C07D209/48 ,  C07D211/88 ,  C07D213/61 ,  C07D213/69 ,  C07D241/12 ,  C07D277/28 ,  C07D277/32 ,  C07D277/34 ,  C07D205/09 ,  C07D207/12 ,  C07D211/36

CPC分类号： C07D207/404 ,  A01N51/00 ,  C07C255/58 ,  C07C335/40 ,  C07D205/10 ,  C07D207/448 ,  C07D209/48 ,  C07D211/88 ,  C07D213/61 ,  C07D213/69 ,  C07D241/12 ,  C07D277/32 ,  C07D277/34

摘要： Novel Intermediates ##STR1## wherein R is a substituted or unsubstituted hydrocarbon residue or acyl group; X is an electron withdrawing group; Y.sup.1 and Y.sup.2, which are the same or different, are each independently oxygen or sulfur; and A is a substituted or unsubstituted, divalent hydrocarbon residue have potent reactivity, this being useful in preparing guanidine derivatives.

摘要翻译： 新型中间体，其中R是取代或未取代的烃残基或酰基; X是吸电子基团; Y1和Y2相同或不同，各自独立地为氧或硫; 并且A是取代或未取代的二价烃残基具有有效的反应性，这可用于制备胍衍生物。

公开(公告)号：US5180833A

公开(公告)日：1993-01-19

申请号：US666128

申请日：1991-03-07

申请人： Hideki Uneme ,  Noriko Higuchi ,  Isao Minamida

发明人： Hideki Uneme ,  Noriko Higuchi ,  Isao Minamida

IPC分类号： A01N47/46 ,  A01N51/00 ,  C07D277/20 ,  C07D277/32

CPC分类号： C07D277/32 ,  A01N51/00

摘要： Novel processes for preparing 2-chlorothiazoles, useful as an intermediate for insecticides, from allyl isothiocyanate derivatives having the formula [II]: ##STR1## wherein X represents a leaving group, are simple and convenient reaction procedures under mild conditions without need of a large excess of a chlorinating agent. Further, processes for preparing 5-(aminomethyl)-2-chlorothiazole or salts thereof from the compound [II] achieve higher yields by simple, convenient and inexpensive procedures.

公开(公告)号：US6166215A

公开(公告)日：2000-12-26

申请号：US391463

申请日：1999-09-08

申请人： Hideki Uneme ,  Hitoshi Ishizuka

发明人： Hideki Uneme ,  Hitoshi Ishizuka

IPC分类号： C07D209/48 ,  C07D213/61 ,  C07D277/28 ,  C07D277/32 ,  C07D277/04

CPC分类号： C07D209/48 ,  C07D213/61 ,  C07D277/32

摘要： A process for producing the compound [I] or a salt thereof having excellent pesticidal activity as shown in the following schema. ##STR1##

摘要翻译： 具有如下模式所示的具有优良杀虫活性的化合物[I]或其盐的方法。