Method for preparing a polymeric composition
    2.
    发明授权
    Method for preparing a polymeric composition 失效
    制备聚合物组合物的方法

    公开(公告)号:US4783501A

    公开(公告)日:1988-11-08

    申请号:US898496

    申请日:1986-08-21

    IPC分类号: C08F2/44 C08F292/00 C08K3/02

    CPC分类号: C08F292/00

    摘要: A method for preparing a polymeric composition in which an inorganic compound is firmly consolidated in an organic polymer, which comprises polymerizing at least one radical polymerizable vinyl monomer in an aqueous medium polymerization system comprising an inorganic compound dispersed in the presence of an organic acid monomer or organic acid salt monomer, by using a radical polymerization initiator.

    摘要翻译: 一种制备聚合物组合物的方法,其中无机化合物牢固地固结在有机聚合物中,其包括在包含在有机酸单体存在下分散的无机化合物的水性介质聚合体系中聚合至少一种可自由基聚合的乙烯基单体,或 有机酸盐单体,通过使用自由基聚合引发剂。

    Method for preparing a polymeric composition
    3.
    发明授权
    Method for preparing a polymeric composition 失效
    制备聚合物组合物的方法

    公开(公告)号:US4910251A

    公开(公告)日:1990-03-20

    申请号:US246737

    申请日:1988-09-20

    IPC分类号: C08F2/44 C08F292/00

    CPC分类号: C08F292/00

    摘要: A method for preparing a polymeric composition in which an inorganic compound is firmly consolidated in an organic polymer, which comprises polymerizing at least one radical polymerizable vinyl monomer in an aqueous medium polymerization system comprising an inorganic compound dispersed in the presence of an organic acid monomer or organic acid salt monomer, by using a radical polymerization initiator.

    Photopolymerizable dental composition
    4.
    发明授权
    Photopolymerizable dental composition 失效
    光聚合牙科组合物

    公开(公告)号:US4977197A

    公开(公告)日:1990-12-11

    申请号:US192931

    申请日:1988-05-12

    IPC分类号: A61K6/08 A61K6/083 A61K6/09

    CPC分类号: A61K6/083 A61K6/09

    摘要: A photopolymerizable dental composition, which comprises:(A) an organic composite filler obtained by polymerizing at least one carboxylic acid monomer of the formula: ##STR1## wherein R.sub.1 is a hydrogen atom, a C.sub.1 -C.sub.15 alkyl group, a --COOY group, a halogen atom, or a phenyl group or a derivative thereof; R.sub.2 is a hydrogen atom, a C.sub.1 -C.sub.15 alkyl group, a --COOZ group, a halogen atom, or a phenyl group or a derivative thereof; R.sub.3 is a hydrogen atom, a C.sub.1 -C.sub.15 alkyl group, a halogen atom, or a phenyl group or a derivative thereof; and each of X, Y and Z is a hydrogen atom, NH.sub.4 or an alkali metal atom; or the formula: ##STR2## wherein each of R.sub.4 and R.sub.5 is a hydrogen atom, a C.sub.1 -C.sub.15 alkyl group, a halogen atom, or a phenyl group or a derivative thereof; and at least one radical polymerizable vinyl monomer in a polymerization system in which an inorganic compound is dispersed;(B) a monomer mixture comprising 2,2-bis[4-(methacryloxyethoxy)phenyl]propane, at least one hexa-functional urethane (meth)acrylate of the formula: ##STR3## wherein n is an integer of from 1 to 10, and each of R.sub.1 and R.sub.2 which may be the same or different is a hydrogen atom or a methyl group, and a diluting ethylenic vinyl monomer; and(C) a photopolymerization initiator comprising an .alpha.-diketone compound and a reducing agent, wherein the reducing agent is a diaminobenzophenone compound of the formula: ##STR4## wherein each of R.sub.1 to R.sub.4 which may be the same or different is a hydrogen atom or a C.sub.1 -C.sub.5 alkyl group, provided that at least one of them is the alkyl group.

    摘要翻译: 一种可光聚合的牙科用组合物,其包含:(A)通过聚合至少一种下式的羧酸单体获得的有机复合填料:其中R 1是氢原子,C 1 -C 15烷基,-COOY基, 卤素原子或苯基或其衍生物; R2是氢原子,C1-C15烷基,-COOZ基,卤原子或苯基或其衍生物; R3是氢原子,C1-C15烷基,卤原子或苯基或其衍生物; X,Y和Z各自为氢原子,NH 4或碱金属原子; 或下式:其中R 4和R 5各自为氢原子,C 1 -C 15烷基,卤原子或苯基或其衍生物; 和在其中分散无机化合物的聚合体系中的至少一种可自由基聚合的乙烯基单体; (B)包含2,2-双[4-(甲基丙烯酰氧基乙氧基)苯基]丙烷,至少一种下式的六官能氨基甲酸酯(甲基)丙烯酸酯的单体混合物:其中n为1至10的整数 R 1和R 2可以相同或不同,为氢原子或甲基,稀释乙烯基乙烯基单体; 和(C)包含α-二酮化合物和还原剂的光聚合引发剂,其中还原剂是下式的二氨基二苯甲酮化合物:其中可以相同或不同的R 1至R 4各自为氢原子 或C 1 -C 5烷基,条件是它们中的至少一个是烷基。 n

    Photopolymerizable dental composition
    5.
    发明授权
    Photopolymerizable dental composition 失效
    光聚合牙科组合物

    公开(公告)号:US4933376A

    公开(公告)日:1990-06-12

    申请号:US184803

    申请日:1988-04-22

    IPC分类号: A61K6/083 A61K6/09

    CPC分类号: A61K6/083 A61K6/087 A61K6/09

    摘要: A photopolymerizable dental composition, which comprises:(A) an organic composite filler obtained by polymerizing a sulfonic acid or sulfonate monomer of the formula: ##STR1## wherein R.sub.1 is a hydrogen atom, a C.sub.1 -C.sub.20 alkyl group, a phenyl group or a derivative thereof, or a halogen atom; ##STR2## wherein each of R.sub.2 and R.sub.3 is a hydrogen atom or a C.sub.1 -C.sub.15 alkyl group, R.sub.4 is a C.sub.1 -C.sub.15 alkylene group, m is an integer of from 1 to 20 and n is an integer of from 0 to 20; and Y is a hydrogen atom, NH.sub.4 or an alkali metal atom, and at least one radical polymerizable vinyl monomer in a polymerization system in which an inorganic compound is dispersed;(B) a monomer mixture comprising 2,2-bis[4-(methacryloxyethoxy)phenyl]propane, at least one hexa-functional urethane (meth)acrylate of the formula: ##STR3## wherein X is ##STR4## wherein n is an integer of from 1 to 10, and each of R.sub.1 and R.sub.2 which may be the same or different is a hydrogen atom or a methyl group, and a diluting ethylenic vinyl monomer; and(C) a photopolymerization initiator comprising an .alpha.-diketone compound and a reducing agent, wherein the reducing agent is at least one member selected from the group consisting of diaminobenzophenone compounds of the formula: ##STR5## wherein each of R.sub.1 to R.sub.4 which may be the same or different is a hydrogen atom or a C.sub.1 -C.sub.5 alkyl group, provided that at least one of them is the alkyl group, and C.sub.5 -C.sub.10 alkyl esters of 4-(N,N-dimethylamino)benzoic acid.

    Dental adhesive composition
    8.
    发明授权

    公开(公告)号:US4968725A

    公开(公告)日:1990-11-06

    申请号:US221549

    申请日:1988-07-20

    IPC分类号: A61K6/00 A61K6/09

    CPC分类号: A61K6/0023

    摘要: Disclosed are dental adhesive compositions consisting essentially of(a) at least one urethane prepolymer containing one or more isocyanate groups, or a blend of the urethane prepolymer and an inert diluent;(b) at least one radical-polymerizable unsaturated monomer;(c) a photopolymerization initiator;and, if desired,(d) a polymerizable phosphoric ester compound having a specific structure.These dental adhesive compositions can be used to bond a restorative material to dentin without requiring any troublesome pretreatment with an etching agent such as phosphoric acid, and can exhibit bonding power sufficient for practical purposes.

    Dental composition and process for producing dental polymeric shaped
articles
    9.
    发明授权
    Dental composition and process for producing dental polymeric shaped articles 失效
    用于生产牙科聚合物制品的牙科组合物和方法

    公开(公告)号:US5296513A

    公开(公告)日:1994-03-22

    申请号:US915880

    申请日:1992-07-20

    IPC分类号: A61K6/083 A61K6/08 C08F20/10

    CPC分类号: A61K6/083

    摘要: Disclosed is a process for producing dental polymeric shaped articles resistant to the adhesion of plaque which comprises the steps of shaping and curing a dental composition containing a monomer having at least one (meth)acryloyloxy group, and bringing the cured product into contact with a halogen or a halogen compound. Also disclosed is a dental composition comprising a monomer having at least one (meth)acryloyloxy group and a polymerization initiator, which is characterized by having added thereto at least one of a halogen and a halogen compound. When cured, this dental composition produces dental polymeric shaped articles resistant to the adhesion of plaque.

    摘要翻译: 本发明公开了一种抗粘附斑块的牙科用聚合物制品的制造方法,该方法包括以下步骤:使包含具有至少一个(甲基)丙烯酰氧基的单体的牙科用组合物成形和固化,并使固化产物与卤素接触 或卤素化合物。 还公开了包含具有至少一个(甲基)丙烯酰氧基的单体和聚合引发剂的牙科用组合物,其特征在于向其中加入至少一种卤素和卤素化合物。 当固化时,该牙科组合物产生耐牙菌斑粘附的牙科聚合物形状制品。