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1.发明授权Molecular oxidation of aromatic hydrocarbons to the corresponding anhydrides using an improved catalyst 失效使用改进的催化剂将芳族烃分子氧化成相应的酸酐
公开(公告)号：US4582911A
公开(公告)日：1986-04-15
申请号：US626405
申请日：1984-06-29
IPC分类号： C07D307/89 , B01J23/00 , B01J23/20 , B01J23/22 , B01J37/02 , C07B61/00 , C07C51/265 , C07D493/04
CPC分类号： C07C51/265 , B01J23/20 , B01J23/22 , B01J37/024
摘要： In accordance with the process of this invention, an improved catalyst for molecular oxidation of an aromatic hydrocarbon to form the corresponding aromatic carboxylic anhydrides is prepared by the steps of forming a catalyst precursor by depositing on titanium dioxide solids in the anatase form a discontinuous monolayer amount of at least one source of tantalum oxide, calcining the thus-formed catalyst precursor under conditions sufficient to convert the tantalum oxide source into the oxide form, depositing upon the calcined catalyst precursor a catalytically effective amount of at least one vanadium compound which is convertible into vanadium oxide upon heating and calcining the vanadium-deposited solids under conditions sufficient to convert the vanadium compound into vanadium oxide.
摘要翻译： 根据本发明的方法，通过以下步骤制备用于芳族烃分子氧化以形成相应的芳族羧酸酐的改进的催化剂：通过以锐钛矿形式的二氧化钛固体沉积形成不连续的单层量形成催化剂前体 的至少一种氧化钽源，在足以将氧化钽源转化为氧化物形式的条件下煅烧如此形成的催化剂前体，在煅烧的催化剂前体上沉积催化有效量的至少一种钒化合物，其可转化为 氧化钒加热并在足以将钒化合物转化为氧化钒的条件下煅烧钒沉积固体。
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公开(公告)号：US4791092A
公开(公告)日：1988-12-13
申请号：US796707
申请日：1985-11-12
IPC分类号： B01J23/20 , B01J23/22 , B01J37/02 , C07C51/265 , B01J21/06
CPC分类号： C07C51/265 , B01J23/20 , B01J23/22 , B01J37/024
摘要： In accordance with the process of this invention, an improved catalyst for molecular oxidation of an aromatic hydrocarbon to form the corresponding aromatc carboxylic anhydrides is prepared by the steps of forming a catalyst precursor by depositing on titanium dioxide solids in the anatase form a discontinuous monolayer amount of at least one source of tantalum oxide, calcining the thus-formed catalyst precursor under conditions sufficient to convert the tantalum oxide source into the oxide form, depositing upon the calcined catalyst precursor a catalytically effective amount of at least one vanadium compound which is convertible into vanadium oxide upon heating and calcining the vanadium-deposited solids under conditions sufficient to convert the vanadium compound into vanadium oxide.
摘要翻译： 根据本发明的方法，通过以下步骤制备用于分子氧化芳族烃以形成相应的芳族羧酸酐的改进的催化剂：通过以锐钛矿形式的二氧化钛固体沉积形成不连续单层量形成催化剂前体 的至少一种氧化钽源，在足以将氧化钽源转化为氧化物形式的条件下煅烧如此形成的催化剂前体，在煅烧的催化剂前体上沉积催化有效量的至少一种钒化合物，其可转化为 氧化钒加热并在足以将钒化合物转化为氧化钒的条件下煅烧钒沉积固体。
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3.发明授权
公开(公告)号：US4814317A
公开(公告)日：1989-03-21
申请号：US102164
申请日：1987-09-29
申请人： Ramzi Y. Saleh , Israel E. Wachs
发明人： Ramzi Y. Saleh , Israel E. Wachs
IPC分类号： B01J23/22 , C07C51/215 , C07C51/25 , C07C51/265 , C07C51/31 , B01J21/06
CPC分类号： C07C51/313 , B01J23/22 , C07C51/215 , C07C51/25 , C07C51/252 , C07C51/265
摘要： In accordance with the process of this invention, an improved catalyst for molecular oxidation of an aromatic hydrocarbon to form the corresponding aromatic carboxylic anhydrides is prepared by the steps of forming a catalyst precursor by depositing on titanium dioxide solids in the anatase form a continuous monolayer amount of at least one source of zirconium dioxide, calcining the thus-formed catalyst precursor under conditions sufficient to convert the zirconium oxide source into the oxide form, depositing upon the calcined catalyst precursor a catalytically effective amount of at least one vanadium compound which is convertible into vanadium oxide upon heating and calcining the vanadium-deposited solids under conditions sufficient to convert the vanadium compound into vanadium oxide.
摘要翻译： 根据本发明的方法，通过以下步骤制备用于分子氧化芳族烃以形成相应的芳族羧酸酐的改进的催化剂：通过以锐钛矿形式的二氧化钛固体沉积形成连续单层量形成催化剂前体 的至少一种二氧化锆源，在足以将氧化锆源转化为氧化物形式的条件下煅烧由此形成的催化剂前体，在煅烧的催化剂前体上沉积催化有效量的至少一种钒化合物，其可转化为 氧化钒加热并在足以将钒化合物转化为氧化钒的条件下煅烧钒沉积固体。
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公开(公告)号：US4831164A
公开(公告)日：1989-05-16
申请号：US180061
申请日：1988-04-11
申请人： Ramzi Y. Saleh , Israel E. Wachs
发明人： Ramzi Y. Saleh , Israel E. Wachs
IPC分类号： B01J23/22 , C07C51/215 , C07C51/25 , C07C51/265 , C07C51/31
CPC分类号： C07C51/313 , B01J23/22 , C07C51/215 , C07C51/25 , C07C51/252 , C07C51/265
摘要： In accordance with the process of this invention, an improved catalyst for molecular oxidation of hydrocarbons to form the corresponding carboxylic anhydrides is prepared by the steps of forming a catalyst precursor by depositing on titanium dioxide catalyst solids in the anatase form a continuous monolayer amount of at least one source of titanium oxide, calcining the thus-formed catalyst percursor under conditions sufficient to convert the titanium oxide source into the oxide form, depositing upon the calcined catalyst precursor a continuous monolayer amount of at least one vanadium compound which is convertible into vanadium oxide upon heating and calcining the vanadium-deposited solids under conditions sufficient to convert the vanadium compound into vanadium oxide.
摘要翻译： 根据本发明的方法，通过以下步骤制备用于分子氧化烃形成相应的羧酸酐的改进的催化剂：通过在锐钛矿上沉积二氧化钛催化剂固体形成连续单层量的 至少一种氧化钛来源，在足以将氧化钛源转化为氧化物形式的条件下煅烧由此形成的催化剂过氧化物，在煅烧的催化剂前体上沉积连续的单层量的至少一种可转化为氧化钒的钒化合物 在足以将钒化合物转化为氧化钒的条件下加热和煅烧钒沉积固体。
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5.发明授权
公开(公告)号：US4835126A
公开(公告)日：1989-05-30
申请号：US860155
申请日：1986-05-06
申请人： Israel E. Wachs , Ramzi Y. Saleh
发明人： Israel E. Wachs , Ramzi Y. Saleh
IPC分类号： B01J23/22 , B01J27/057 , B01J27/198 , C07C51/265
CPC分类号： C07C51/265 , B01J23/002 , B01J23/22 , B01J27/057 , B01J27/198 , B01J2523/00
摘要： In accordance with the process of this invention, an improved catalyst for molecular oxidation of a hydrocarbon to form the corresponding carboxylic anhydrides is prepared by the steps of (a) forming a catalyst precursor by depositing on titanium dioxide solids in the anatase form at least a monolayer amount of at least one source of vanadium oxide, (b) calcining the thus-formed catalyst precursor under conditions sufficient to convert the vanadium oxide source into the oxide form, (c) depositing upon the calcined catalyst precursor a catalytically effective amount of at least one vanadium oxide source which is convertible into vanadium oxide upon heating and at least one metal oxide source selected from the group consisting of oxides of Sb, Ga, Ge, In, Tl, Pb, Se, Te, P and Bi, which is convertible into the corresponding metal oxide upon heating and which is reactive with V.sub.2 O.sub.5, and (d) calcining the vanadium and reactive metal containing catalyst solids under conditions sufficient to form the corresponding vanadium oxide and reactive metal oxides.
摘要翻译： 根据本发明的方法，通过以下步骤制备用于烃的分子氧化以形成相应的羧酸酐的改进的催化剂：（a）通过以锐钛矿形式沉积在二氧化钛固体上至少形成催化剂前体 单层量的至少一种氧化钒源，（b）在足以将钒氧化物源转化为氧化物形式的条件下煅烧由此形成的催化剂前体，（c）在煅烧的催化剂前体上沉积催化有效量的 至少一种氧化钒源，其在加热时可转化为氧化钒，以及选自Sb，Ga，Ge，In，Tl，Pb，Se，Te，P和Bi的氧化物中的至少一种金属氧化物源，其是 加热时可转化成相应的金属氧化物，并与V2O5反应，和（d）在足以满足以下条件的条件下煅烧含钒和活性金属的催化剂固体： 形成相应的氧化钒和活性金属氧化物。
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6.发明授权Iron carbide on titania surface modified with group VA oxides as Fischer-Tropsch catalysts 失效用作为费 - 托催化剂的VA族氧化物改性的二氧化钛表面上的碳化铁
公开(公告)号：US4608359A
公开(公告)日：1986-08-26
申请号：US759669
申请日：1985-07-29
CPC分类号： C07C1/044 , B01J27/22 , C07C1/0445 , C07C2521/06 , C07C2523/20 , C07C2523/22 , C07C2527/22
摘要： Catalysts comprising iron carbide on a surface modified titania support wherein said support comprises a surface modifying oxide of tantalum, niobium, vanadium and mixtures thereof supported on said titania wherein at least a portion of said surface modifying oxide is in a non-crystalline form. These catalysts are useful for Fischer-Tropsch hydrocarbon synthesis reactions. Preferably, at least about 25 wt. % of said surface modifying oxide will be in a non-crystalline form.
摘要翻译： 在表面改性的二氧化钛载体上包含碳化铁的催化剂，其中所述载体包括负载在所述二氧化钛上的钽，铌，钒及其混合物的表面改性氧化物，其中所述表面改性氧化物的至少一部分是非结晶形式。 这些催化剂可用于费托烃合成反应。 优选地，至少约25wt。 所述表面改性氧化物的％将为非晶态。
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公开(公告)号：US4931572A
公开(公告)日：1990-06-05
申请号：US353252
申请日：1989-05-17
申请人： Ramzi Y. Saleh , Israel E. Wachs
发明人： Ramzi Y. Saleh , Israel E. Wachs
IPC分类号： B01J23/04 , B01J23/22 , C07C51/265
CPC分类号： B01J23/22 , B01J23/04 , C07C51/265
摘要： In accordance with the process of this invention, an improved titanium dioxide rutile-based catalyst for molecular oxidation of a hydrocarbon to form the corresponding carboxylic anhydrides is prepared by the steps of (a) forming a catalyst precursor by depositing on titanium dioxide solids in the rutile form a discontinuous monolayer amount of at least one source of a Group IA metal oxide; (b) calcining the thus-formed catalyst precursor under conditions sufficient to convert the Group IA metal oxide source into the corresponding Group IA metal oxide; (c) depositing upon the calcined catalyst precursor a catalytically effective amount of at least one vanadium oxide source which is convertible into vanadium oxide upon heating; and (d) calcining the vanadium-deposited solids under conditions sufficient to convert the vanadium compound into vanadium oxide.
摘要翻译： 根据本发明的方法，通过以下步骤制备用于烃的分子氧化以形成相应的羧酸酐的改进的二氧化钛金红石型催化剂：（a）通过沉积在二氧化钛固体中形成催化剂前体 金红石形成不连续单层量的至少一种IA族金属氧化物源; （b）在足以将IA族金属氧化物源转化成相应的IA族金属氧化物的条件下煅烧如此形成的催化剂前体; （c）在煅烧的催化剂前体上沉积催化有效量的至少一种氧化钒源，其在加热时可转化成氧化钒; 和（d）在足以将钒化合物转化为氧化钒的条件下煅烧钒沉积固体。
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公开(公告)号：US4728744A
公开(公告)日：1988-03-01
申请号：US782966
申请日：1985-10-02
申请人： Ramzi Y. Saleh , Israel E. Wachs
发明人： Ramzi Y. Saleh , Israel E. Wachs
IPC分类号： B01J23/22 , C07B61/00 , C07C51/215 , C07C51/25 , C07C51/265 , C07C51/31 , C07D307/89
CPC分类号： C07C51/313 , B01J23/22 , C07C51/215 , C07C51/25 , C07C51/252 , C07C51/265
摘要： In accordance with the process of this invention, an improved catalyst for molecular oxidation of an aromatic hydrocarbon to form the corresponding aromatic carboxylic anhydrides is prepared by the steps of forming a catalyst precursor by depositing on titanium dioxide solids in the anatase form a continuous monolayer amount of at least one source of zirconium dioxide, calcining the thus-formed catalyst precursor under conditions sufficient to convert the zirconium oxide source into the oxide form, depositing upon the calcined catalyst precursor a catalytically effective amount of at least one vanadium compound which is convertible into vanadium oxide upon heating and calcining the vanadium-deposited solids under conditions sufficient to convert the vanadium compound into vanadium oxide.
摘要翻译： 根据本发明的方法，通过以下步骤制备用于分子氧化芳族烃以形成相应的芳族羧酸酐的改进的催化剂：通过以锐钛矿形式的二氧化钛固体沉积形成连续单层量形成催化剂前体 的至少一种二氧化锆源，在足以将氧化锆源转化为氧化物形式的条件下煅烧由此形成的催化剂前体，在煅烧的催化剂前体上沉积催化有效量的至少一种钒化合物，其可转化为 氧化钒加热并在足以将钒化合物转化为氧化钒的条件下煅烧钒沉积固体。
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公开(公告)号：US4582912A
公开(公告)日：1986-04-15
申请号：US655745
申请日：1984-10-01
申请人： Ramzi Y. Saleh , Israel E. Wachs
发明人： Ramzi Y. Saleh , Israel E. Wachs
IPC分类号： C07D307/89 , B01J23/20 , B01J23/22 , B01J37/02 , C07B61/00 , C07C51/265 , C07D493/04
CPC分类号： C07C51/265 , B01J23/20 , B01J23/22 , B01J37/024
摘要： In accordance with the process of this invention, an improved catalyst for molecular oxidation of a hydrocarbon to form the corresponding carboxylic anhydrides is prepared by the steps of (a) forming a catalyst precursor by depositing on titanium dioxide solids in the anatase form at least a monolayer amount of at least one source of vanadium oxide, (b) calcining the thus-formed catalyst precursor under conditions sufficient to convert the vanadium oxide source into the oxide form, (c) depositing upon the calcined catalyst precursor a catalytically effective amount of at least one vanadium oxide source which is convertible into vanadium oxide upon heating and at least one metal oxide source selected from the group consisting of oxides of Sb, Ga, Ge, In, Tl, Pb, Se, Te, P and Bi, which is convertible into the corresponding metal oxide upon heating and which is reactive with V.sub.2 O.sub.5, and (d) calcining the vanadium and reactive metal containing catalyst solids under conditions sufficient to form the corresponding vanadium oxide and reactive metal oxides.
摘要翻译： 根据本发明的方法，通过以下步骤制备用于烃的分子氧化以形成相应的羧酸酐的改进的催化剂：（a）通过以锐钛矿形式沉积在二氧化钛固体上至少形成催化剂前体 单层量的至少一种氧化钒源，（b）在足以将钒氧化物源转化为氧化物形式的条件下煅烧由此形成的催化剂前体，（c）在煅烧的催化剂前体上沉积催化有效量的 至少一种氧化钒源，其在加热时可转化为氧化钒，以及选自Sb，Ga，Ge，In，Tl，Pb，Se，Te，P和Bi的氧化物中的至少一种金属氧化物源，其是 加热时可转化成相应的金属氧化物，并与V2O5反应，和（d）在足以满足以下条件的条件下煅烧含钒和活性金属的催化剂固体： 形成相应的氧化钒和活性金属氧化物。
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10.发明授权Iron carbide on titania surface modified with group VA oxides as Fisher-Tropsch catalysts 失效用作为费 - 托催化剂的VA族氧化物改性的二氧化钛表面上的碳化铁
公开(公告)号：US4559365A
公开(公告)日：1985-12-17
申请号：US626068
申请日：1984-06-29
CPC分类号： C07C1/044 , B01J27/22 , C07C1/0445 , C07C2521/06 , C07C2523/20 , C07C2523/22 , C07C2527/22
摘要： Catalysts comprising iron carbide on a surface modified titania support wherein said support comprises a surface modifying oxide of tantalum, niobium, vanadium and mixtures thereof supported on said titania wherein at least a portion of said surface modifying oxide is in a non-crystalline form. These catalysts are useful for Fischer-Tropsch hydrocarbon synthesis reactions. Preferably, at least about 25 wt. % of said surface modifying oxide will be in a non-crystalline form.
摘要翻译： 在表面改性的二氧化钛载体上包含碳化铁的催化剂，其中所述载体包括负载在所述二氧化钛上的钽，铌，钒及其混合物的表面改性氧化物，其中所述表面改性氧化物的至少一部分是非晶态的。 这些催化剂可用于费托烃合成反应。 优选地，至少约25wt。 所述表面改性氧化物的％将为非晶态。
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