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    Eta phase materials, methods of producing the same, and use thereof as catalysts for alcohol synthesis, hydrocarbon synthesis, hydrocarbon hydrogenation and hydrocarbon conversion reactions
    6.
    发明授权
    Eta phase materials, methods of producing the same, and use thereof as catalysts for alcohol synthesis, hydrocarbon synthesis, hydrocarbon hydrogenation and hydrocarbon conversion reactions 失效
    伊塔相材料，其制备方法及其作为醇合成，烃合成，烃氢化和烃转化反应的催化剂的用途

    公开(公告)号：US5138111A

    公开(公告)日：1992-08-11

    申请号：US760316

    申请日：1991-09-16

    申请人： Edwin L. Kugler ,  Larry E. McCandlish ,  Allan J. Jacobson ,  Russell R. Chianelli

    发明人： Edwin L. Kugler ,  Larry E. McCandlish ,  Allan J. Jacobson ,  Russell R. Chianelli

    IPC分类号： B01J27/22 ,  B01J27/24 ,  C01B21/06 ,  C01B21/082 ,  C01B31/30 ,  C07C1/04 ,  C07C5/02 ,  C07C5/03 ,  C07C5/10 ,  C07C5/22 ,  C07C5/32 ,  C07C5/367 ,  C07C29/156

    CPC分类号： C01B31/301 ,  B01J27/22 ,  B01J27/24 ,  C01B21/0602 ,  C01B21/0828 ,  C01B31/30 ,  C07C1/0435 ,  C07C29/156 ,  C07C5/02 ,  C07C5/03 ,  C07C5/10 ,  C07C5/2213 ,  C07C5/322 ,  C07C5/367 ,  C01P2002/50 ,  C01P2006/12 ,  C07C2527/22 ,  C07C2527/24 ,  Y02P20/52

    摘要： An eta phase composition in powder form, prepared in the absence of sulfur or sulfur bearing compounds, having a surface area greater than about 2m.sup.2 /g and consisting of X.sub.6 Y.sub.6 Z.sub.a wherein X is at least one element selected from the group consiting of Mo and W, Y is at least one element selected from the group consisting of Fe, Co. Ni, Mo and W, Z is at least one element selected from the group consisting of C, N and combinations thereof such that when Z is N, a is greater than or equal to 1 but less than or equal to 2 and when Z is C, a is greater than 1 but less than or equal to 2 except when Z is C and Y is Fe, then a is greater than or equal to 1 but less than or equal to 2. The eta phase may be a carbide, nitride or carbonitride. A method for producing the eta-phase composition includes providing a precursor compound including at least two eta-phase forming metals, and a ligand containing carbon, nitrogen or combinations thereof. The precursor compound is thermally decomposed in a nonoxidizing atmosphere, free of sulfur or sulfur bearing compounds, and reacts with carbon or nitrogen derived from the decomposition of the ligand with the metals to form the eta-phase. The eta phase forming metals are at lest two of the metals tungsten, molybdenum, nickel, cobalt and iron. These eta-phase composition may be used for producing or converting hydrocarbons or alcohols. This includes hydrogenation of CO (to produce at least one hydrocarbon or at least one alcohol and hydrogenation of unsaturated hydrocarbons, aromatic hydrocarbons and olefinic hydrocarbons), isomerization and dehydrogenation.

    摘要翻译： 表面积大于约2m2 / g，由X6Y6Za组成的粉末形式的等离子体组成，其中X是选自Mo和W中的至少一种元素， Y是选自Fe，Co，Ni，Mo和W中的至少一种元素，Z是选自C，N及其组合中的至少一种元素，使得当Z是N时，a更大 1以上且2以下，当Z为C时，a大于1但小于等于2，除非Z为C且Y为Fe，那么a大于或等于1但a 小于或等于2.等离子体相可以是碳化物，氮化物或碳氮化物。 制备等离子体组合物的方法包括提供包含至少两个形成η相的金属的前体化合物和含有碳，氮或其组合的配体。 前体化合物在不含硫或硫的化合物的非氧化气氛中热分解，并与衍生自配体与金属分解的碳或氮反应形成η相。 等离子体相形成金属中至少有两种金属是钨，钼，镍，钴和铁。 这些η相组合物可用于生产或转化烃或醇。 这包括CO的氢化（产生至少一种烃或至少一种醇和不饱和烃，芳族烃和烯烃的氢化），异构化和脱氢。

    Addition of hydrogen and C2 to C4 hydrocarbons to the feed gas in the catalytic conversion of methane to higher molecular weight hydrocarbons
    7.
    发明授权
    Addition of hydrogen and C2 to C4 hydrocarbons to the feed gas in the catalytic conversion of methane to higher molecular weight hydrocarbons 失效
    在将甲烷催化转化成较高分子量烃时，向原料气中加入氢气和C2至C4烃

    公开(公告)号：US4814534A

    公开(公告)日：1989-03-21

    申请号：US794343

    申请日：1985-10-31

    申请人： Louis Devries ,  P. R. Ryason

    发明人： Louis Devries ,  P. R. Ryason

    IPC分类号： C07C2/00

    CPC分类号： C07C2/00 ,  C07C2521/02 ,  C07C2521/06 ,  C07C2521/10 ,  C07C2523/02 ,  C07C2523/04 ,  C07C2523/10 ,  C07C2523/12 ,  C07C2527/22 ,  C07C2527/24 ,  Y10S585/943

    摘要： Disclosed is a continuous catalytic process for the production of higher molecular weight hydrocarbons from methane in which a methane-containing gas is contacted in a reaction zone with a higher molecular weight hydrocarbon synthesis catalyst under C.sub.2 +hydrocarbon synthesis conditions, the improvement comprising adding a C.sub.2 to C.sub.4 hydrocarbon and hydrogen to said gas thereby forming a reaction gas wherein said C.sub.2 to C.sub.4 hydrocarbon comprises 0.1 to 10 volume percent of said reaction gas and said hydrogen comprises 1 to 25 volume percent of said reaction gas, said synthesis conditions including a temperature greater than 1000.degree. C. and a gas hourly space velocity of greater than 3200 hr.sup.31 1.

    摘要翻译： 公开了一种用于从甲烷生产较高分子量烃的连续催化方法，其中在C2 +烃合成条件下，含甲烷气体在反应区与更高分子量的烃合成催化剂接触，其改进包括加入C2 将C 4烃和氢气转化成所述气体，从而形成反应气体，其中所述C2至C4烃包含0.1至10体积％的所述反应气体，所述氢气包含1至25体积％的所述反应气体，所述合成条件包括较高的温度 超过1000℃，气时空速大于3200hr31 1。