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公开(公告)号：US10041192B1
公开(公告)日：2018-08-07
申请号：US15744841
申请日：2016-10-25
发明人： Huirong Zhao , Xiaobing Fan , Chaoming Yang , Lijun Wang
摘要： The present invention discloses an ultra-low shrinkage polyester industrial yarn and its preparation method. The ultra-low shrinkage polyester industrial yarn is prepared by subjecting a polyester to dissolution, washing and solid state polycondensation followed by spinning. The ultra-low shrinkage polyester industrial yarn has a dry heat shrinkage rate of 1.8±0.25% under test conditions of 177° C.×10 min×0.05 cN/dtex. The polycondensation catalyst consists of magnesium ethylene glycol and antimony ethylene glycol, has a small thermal degradation coefficient. The present invention reduces oligomers during polymerization, reduces thermal degradation during processing, and as a result the invention greatly reduces impurities and nucleating agent in the polyester, leading to an increase in the probability of homogeneous nucleation based on the reduction of heterogeneous nucleation. The dissolution and washing of polyester further decreases oligomer content, facilitating the growth of the grain size and the optimization of crystal perfection in the ultra-low shrinkage polyester industrial yarn.
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公开(公告)号：US11788212B2
公开(公告)日：2023-10-17
申请号：US17042129
申请日：2019-10-29
发明人： Lili Wang , Zangzang Niu , Chaoming Yang
CPC分类号： D01F6/92 , B01J23/18 , C08K3/22 , D01F11/08 , D10B2331/04
摘要： A type of semi-dull polyester drawn yarns and preparing method thereof are disclosed. The preparing method is to melt spinning a modified polyester with FDY technique, wherein the modified polyester is the product of the esterification and the successive polycondensation reactions of evenly mixed terephthalic acid, ethylene glycol, main chain silicated diol, fluorinated dicarboxylic acid, matting agent and doped Bi2O3, in which the main chain silicated diol could be dimethylsiloxane diol, dimethyldiphenyldisiloxane glycol or tetramethyldisiloxane diol, and in which the fluorinated dicarboxylic acids could be 2,2-difluoro-1,3-malonic acid, 2,2-difluoro-1,4-succinic acid, 2,2-difluoro-1,5-glutaric acid or 2,2,3,3-tetrafluoro-1,4-succinic acid. The obtained fiber has a dye uptake of 87.5-91.8% when dyed at 120° C., and has an intrinsic viscosity drop of 18-26% when stored at 25° C. and R.H. 65% for 60 months. This invention features a method with ease of application and a product with good dyeing and degradation performance.
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公开(公告)号：US12077883B2
公开(公告)日：2024-09-03
申请号：US18269968
申请日：2021-08-25
发明人： Shanshui Wang , Fangming Tang , Lili Wang , Yiwei Shao , Yanli Zhao , Xiaoyu Wang , Chaoming Yang
IPC分类号： D01F6/84 , C08G63/183 , C08G63/685 , C08G63/80 , C08G63/86 , C08G63/91 , D01D5/08 , D01F11/08
CPC分类号： D01F6/84 , C08G63/183 , C08G63/6856 , C08G63/80 , C08G63/866 , C08G63/916 , D01D5/08 , D01F11/08 , D10B2331/04 , D10B2401/063
摘要： A high-strength thermal-stability polyester industrial yarn is prepared by spinning, winding and coordination treatment of a modified polyester after a solid-state polycondensation; wherein the method of coordination treatment comprises: soaking the wound fiber in an aqueous solution of a coordination agent, and the concentration of the aqueous solution of the coordination agent is 0.1-0.2 mol/L; wherein the condition of coordination treatment is 48-72 hours at 80-100° C., and the concentration of the aqueous solution of the coordination agent is 0.1-0.2 mol/L; wherein the polyester segments of the prepared high-strength thermal-stability polyester industrial yarn comprises a terephthalic acid segment, an ethylene glycol segment and a 2,6-pyridinedicarboxylic acid segment, and 2,6-pyridinedicarboxylic acid segments of different polyester segments are coordinated by Fe3+, the molar ratio of the terephthalic acid segment to the 2,6-pyridinedicarboxylic acid segment is 1:(0.03-0.05).
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公开(公告)号：US10590564B2
公开(公告)日：2020-03-17
申请号：US16322950
申请日：2017-06-26
发明人： Hongwei Fan , Guanfan Jin , Ming Chen , Lixin Yin , Fangming Tang , Chaoming Yang
IPC分类号： C08G63/183 , D01D5/247 , D01D5/253 , D01D5/08 , C08G63/91 , D01D4/02 , D01F6/84 , D02G1/18 , D06P3/54 , D01D5/16 , D01F1/10 , D01F6/92
摘要： A different shrinkage composite yarn and preparation method. The modified polyester is spun with a porous spinneret to produce a different shrinkage composite yarn, and the spinneret holes on the porous spinneret are arranged in an elliptical arrangement. The different shrinkage composite yarn is obtained by winding modified polyester POY yarn and FDY yarn, network recombining, and coiling them. The preparation method of modified polyester is as follows: terephthalic acid reacts with ethylene glycol to produce ethylene terephthalate. The modified polyester is obtained by the reaction of terephthalic acid with branched diol. The fiber of the invention has good properties and the deviation rate of fiber density. The CV value of breaking strength is ≤4.0%, the CV value of elongation at break is ≤8.0%, the CV value of coefficient of variation of coiling shrinkage is ≤8.0%.
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