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公开(公告)号:US20250076761A1
公开(公告)日:2025-03-06
申请号:US18951794
申请日:2024-11-19
Applicant: JSR CORPORATION
Inventor: Ryuichi NEMOTO , Masayuki MIYAKE , Hajime INAMI , Tsuyoshi FURUKAWA , Noboru OTSUKA , Kensuke MIYAO
Abstract: A radiation-sensitive resin composition includes: a first onium salt compound represented by formula (1); a second onium salt compound represented by formula (2); a resin including a structural unit having an acid-dissociable group; and a solvent. R1 is a substituted or unsubstituted monovalent hydrocarbon group or the like; R2 and R3 are each independently a hydrogen atom or a monovalent hydrocarbon group; one of Rf11 and Rf12 is a fluorine atom, and the other is a fluorine atom or a monovalent fluorinated hydrocarbon group; and Z1+ represents a monovalent radiation-sensitive onium cation. R4 is a monovalent organic group including a cyclic structure; Rf21 and Rf22 each independently represent a fluorine atom or a monovalent fluorinated hydrocarbon group; and Z2+ represents a monovalent radiation-sensitive onium cation.
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公开(公告)号:US20250085629A1
公开(公告)日:2025-03-13
申请号:US18953228
申请日:2024-11-20
Applicant: JSR CORPORATION
Inventor: Ryuichi NEMOTO , Masayuki MIYAKE , Hajime INAMI , Tsuyoshi FURUKAWA , Noboru OTSUKA , Kensuke MIYAO
Abstract: A radiation-sensitive resin composition includes: an onium salt compound represented by formula (1), a resin including a structural unit having an acid-dissociable group, and an alcohol-based solvent having a boiling point of 90° C. or higher. R1 is a substituted or unsubstituted monovalent hydrocarbon group or a group including a divalent hetero atom-containing group between two adjacent carbon atoms of the hydrocarbon group; R2 and R3 are each independently a hydrogen atom or a monovalent hydrocarbon group, one of Rf11 and Rf12 is a fluorine atom, and the other is a fluorine atom or a monovalent fluorinated hydrocarbon group, m1 is an integer of 1 to 3; m2 is an integer of 0 to 8; and Z1+ represents a monovalent radiation-sensitive onium cation.
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公开(公告)号:US20250076762A1
公开(公告)日:2025-03-06
申请号:US18951861
申请日:2024-11-19
Applicant: JSR CORPORATION
Inventor: Ryuichi NEMOTO , Masayuki MIYAKE , Hajime INAMI , Tsuyoshi FURUKAWA , Noboru OTSUKA , Kensuke MIYAO
Abstract: A radiation-sensitive resin composition includes: a first onium salt compound represented by formula (1); a second onium salt compound represented by formula (2); a resin including an acid-dissociable group; and a solvent. R1 is a substituted or unsubstituted monovalent hydrocarbon group or the like; R2 and R3 are each independently a hydrogen atom, a fluorine atom, or the like; and Z+ represents a monovalent radiation-sensitive onium cation. R4 is a monovalent organic group; one of Rf21 and Rf22 is a fluorine atom, and the other is a fluorine atom or a monovalent fluorinated hydrocarbon group; Ar is a monovalent organic group including an aromatic ring; R5, R6, R7, and R8 each independently represent a hydrogen atom, a hydroxy group, a halogen atom, or a monovalent organic group; and X is a single bond or a divalent hetero atom-containing group.
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公开(公告)号:US20250076760A1
公开(公告)日:2025-03-06
申请号:US18952057
申请日:2024-11-19
Applicant: JSR CORPORATION
Inventor: Ryuichi NEMOTO , Masayuki MIYAKE , Hajime INAMI , Tsuyoshi FURUKAWA , Noboru OTSUKA , Kensuke MIYAO
IPC: G03F7/004 , C08F220/18 , C08F220/28 , C08F220/36 , G03F7/00 , G03F7/038 , G03F7/039
Abstract: A radiation-sensitive resin composition includes: a first onium salt compound represented by formula (1); a second onium salt compound represented by formula (2); a resin including a structural unit having an acid-dissociable group; and a solvent. R1 is a substituted or unsubstituted monovalent hydrocarbon group or a group including a divalent hetero atom-containing group between two adjacent carbon atoms of the hydrocarbon group; R2 and R3 are each independently a hydrogen atom, a fluorine atom, or the like; and one of Rf11 and Rf12 is a fluorine atom, and the other is a hydrogen atom, a fluorine atom, or a monovalent fluorinated hydrocarbon group. R4 is a monovalent organic group in which neither a fluorine atom nor a fluorinated hydrocarbon group is bonded to an atom adjacent to the sulfur atom.
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