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公开(公告)号：US09586887B2
公开(公告)日：2017-03-07
申请号：US14889978
申请日：2014-04-18
IPC分类号： C07C67/36 , C07C67/475 , C07C67/38 , B01J31/18
CPC分类号： C07C67/475 , B01J31/1815 , B01J2231/49 , B01J2231/70 , B01J2531/824 , C07C67/38 , C07C2603/94 , C07C69/757
摘要： A method for producing an ester compound including reacting a compound having at least one cyclic structure of a norbornene ring and a norbornadiene ring with an alcohol and carbon monoxide by using a palladium catalyst and an oxidizing agent, to thereby introduce ester groups to carbon atoms forming a double bond in the cyclic structure and obtain the ester compound, wherein the palladium catalyst comprises a palladium complex having a bipyridyl as a ligand.
摘要翻译： 一种酯化合物的制备方法，包括使用钯催化剂和氧化剂使具有降冰片烯环的至少一个环状结构和降冰片二烯环的化合物与醇和一氧化碳反应，从而将酯基引入形成碳原子 环状结构中的双键并获得酯化合物，其中钯催化剂包含具有联吡啶作为配体的钯络合物。
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2.发明授权Polyimide and alicyclic tetracarboxylic dianhydride used for producing the same 有权用于制备它的聚酰亚胺和脂环族四羧酸二酐公开(公告)号：US09399703B2
公开(公告)日：2016-07-26
申请号：US14424314
申请日：2013-08-29
发明人： Shinichi Komatsu , Rieko Fujishiro , Miki Fujiwara , Daisuke Watanabe , Akira Shibashi , Takaya Matsumoto
IPC分类号： C07D407/08 , C08G73/10 , C07D493/10
CPC分类号： C08G73/1067 , C07C2603/93 , C07D493/10 , C08G73/10 , C08G73/1007 , C08G73/1075 , C08G73/1078
摘要： A polyimide containing at least one of repeating units represented by the following general formulae (1) and (2): wherein the formulae (1) and (2), R1, R2, and R3 each independently represents a hydrogen atom or the like, R4 represents an aryl group having 6 to 40 carbon atoms, and n represents an integer of 0 to 12, wherein a total amount of the repeating units represented by the general formulae (1) and (2) is 90% by mole or more relative to all repeating units.
摘要翻译： 含有下列通式（1）和（2）表示的重复单元中的至少一种的聚酰亚胺：式（1）和（2）中，R 1，R 2和R 3各自独立地表示氢原子等， R4表示碳原子数为6〜40的芳基，n表示0〜12的整数，由通式（1）和（2）表示的重复单元的总量相对于90摩尔％ 到所有重复单位。
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3.发明申请POLYIMIDE AND ALICYCLIC TETRACARBOXYLIC DIANHYDRIDE USED FOR PRODUCING THE SAME 有权用于生产它的聚酰胺和二氧化硅四羧酸二乙酸公开(公告)号：US20150218317A1
公开(公告)日：2015-08-06
申请号：US14424314
申请日：2013-08-29
发明人： Shinichi Komatsu , Rieko Fujishiro , Miki Fujiwara , Daisuke Watanabe , Akira Shibashi , Takaya Matsumoto
IPC分类号： C08G73/10
CPC分类号： C08G73/1067 , C07C2603/93 , C07D493/10 , C08G73/10 , C08G73/1007 , C08G73/1075 , C08G73/1078
摘要： A polyimide containing at least one of repeating units represented by the following general formulae (1) and (2): wherein the formulae (1) and (2), R1, R2, and R3 each independently represents a hydrogen atom or the like, R4 represents an aryl group having 6 to 40 carbon atoms, and n represents an integer of 0 to 12, wherein a total amount of the repeating units represented by the general formulae (1) and (2) is 90% by mole or more relative to all repeating units.
摘要翻译： 含有下列通式（1）和（2）表示的重复单元中的至少一种的聚酰亚胺：式（1）和（2）中，R 1，R 2和R 3各自独立地表示氢原子等， R4表示碳原子数为6〜40的芳基，n表示0〜12的整数，由通式（1）和（2）表示的重复单元的总量相对于90摩尔％ 到所有重复单位。
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4.发明授权Method for producing ester compound and palladium catalyst used in the method 有权该方法中使用的酯化合物和钯催化剂的制备方法公开(公告)号：US09403158B2
公开(公告)日：2016-08-02
申请号：US14431849
申请日：2013-09-24
CPC分类号： B01J31/2239 , B01J2231/32 , B01J2231/321 , B01J2531/0219 , B01J2531/824 , C07C67/38 , C07C2602/42 , C07C2603/94 , C07C69/753 , C07C69/757
摘要： A method for producing an ester compound includes reacting a compound having at least one cyclic structure of a norbornene ring and a norbornadiene ring with an alcohol and carbon monoxide by using a palladium catalyst and an oxidizing agent, to thereby introduce ester groups to carbon atoms forming a double bond in the cyclic structure and obtaining the ester compound, wherein the palladium catalyst includes a palladium acetate having a nitrite ligand in an amount of 10% by mole or more in terms of metal, and the palladium acetate having a nitrite ligand is represented by the general formula (1): Pd3(CH3COO)5(NO2).
摘要翻译： 酯化合物的制造方法包括使用钯催化剂和氧化剂使具有降冰片烯环的至少一个环状结构的降冰片二烯环的化合物与醇和一氧化碳反应，从而将酯基引入形成的碳原子 环状结构中的双键并获得酯化合物，其中钯催化剂包括具有亚硝酸盐配体的乙酸钯，其量为金属换算为10摩尔％以上，并且具有亚硝酸盐配体的乙酸钯被表示 由通式（1）表示：Pd 3（CH 3 COO）5（NO 2）。
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5.发明申请TRANSPARENT FILM, TRANSPARENT ELECTRO-CONDUCTIVE LAMINATE, AND TOUCH PANEL, SOLAR CELL, AND DISPLAY DEVICE USING THE SAME 有权透明膜，透明导电层压板和触控面板，太阳能电池和使用其的显示装置公开(公告)号：US20140224318A1
公开(公告)日：2014-08-14
申请号：US14237635
申请日：2012-08-03
IPC分类号： H01L31/0224 , C08G73/10
CPC分类号： H01L31/022466 , C08G73/10 , C08G73/1042 , C08G73/105 , C08G73/1078 , C08G73/14 , C08L79/08 , H01L31/022475 , H01L31/0392 , Y02E10/50 , Y10T428/31721
摘要： A transparent electro-conductive laminate comprising: a substrate film made of a polyimide; and a thin film made of an electro-conductive material and stacked on the substrate film, wherein the polyimide is a polyimide containing at least one repeating unit represented by the following general formula (1): [in the formula (1), R1, R2, and R3 each independently represent one selected from the group consisting of a hydrogen atom, alkyl groups having 1 to 10 carbon atoms, and a fluorine atom, R4 represents an aryl group having 6 to 40 carbon atoms, and n represents an integer of 0 to 12], having a glass transition temperature of 350° C. to 450° C., and having a linear expansion coefficient of 30 ppm/° C. or less, the linear expansion coefficient being determined by measuring change in length under a nitrogen atmosphere and under a condition of a rate of temperature rise of 5° C./minute in a temperature range from 50° C. to 200° C.
摘要翻译： 1.一种透明导电性层叠体，其特征在于，包括：由聚酰亚胺构成的基材膜; 和由导电材料制成并层叠在基材膜上的薄膜，其中聚酰亚胺是含有至少一个由以下通式（1）表示的重复单元的聚酰亚胺：[在式（1）中，R 1， R 2和R 3各自独立地表示选自氢原子，碳原子数1〜10的烷基和氟原子的基团，R 4表示碳原子数为6〜40的芳基，n表示 0〜12]，玻璃化转变温度为350℃〜450℃，线膨胀系数为30ppm /℃以下，线膨胀系数通过测定a 在50°C至200°C的温度范围内，温度升高5℃/分钟的条件下进行。
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