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    Sulfo group-containing basic azo compounds having a central 1,3,5-triazine ring and two terminal 1-hydroxynaphthyl-2 groups and 1:1 and 1:2 metal complexes therof
    1.
    发明授权
    Sulfo group-containing basic azo compounds having a central 1,3,5-triazine ring and two terminal 1-hydroxynaphthyl-2 groups and 1:1 and 1:2 metal complexes therof 失效
    含有磺基的碱性偶氮化合物，具有中心的1,3,5-三嗪环和两个末端的1-羟基萘基-2和1：1和1：2的金属络合物

    公开(公告)号：US4742160A

    公开(公告)日：1988-05-03

    申请号：US834976

    申请日：1986-02-28

    申请人： Jacky Dore ,  Reinhard Pedrazzi

    发明人： Jacky Dore ,  Reinhard Pedrazzi

    IPC分类号： C09B35/039 ,  C09B43/16 ,  C09B44/02 ,  C09B44/06 ,  C09B45/24 ,  C09B62/095 ,  D06P1/02 ,  D06P1/41 ,  D06P3/32 ,  D21H19/10 ,  D21H21/28 ,  C09B35/18 ,  C09B44/08 ,  C09B45/26

    CPC分类号： D06P3/3226 ,  C09B43/16 ,  C09B44/02 ,  C09B62/095 ,  D06P1/02 ,  D21H21/28

    摘要： Metal-free compounds of the formula ##STR1## and 1:1 and 1:2 metal complexes thereof, and salts of the metal-free compounds and 1:1 and 1:2 metal complexes, whereR is hydrogen, --SO.sub.3 H or --NR.sub.5 R.sub.6 ;R.sub.a is hydrogen or --NR.sub.5 R.sub.6 ;R.sub.1 is hydrogen, halogen, --OH, C.sub.1-4 alkyl, C.sub.1-4 alkoxy or --SO.sub.3 H;R.sub.3 is hydrogen or C.sub.1-4 alkyl;R.sub.4 is halogen, --OH, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, phenyl, --NH.sub.2, an aliphatic, cycloaliphatic or aromatic amino group, a heterocyclic amino group containing 1 to 3 hereto atoms or a hydrazino group,R.sub.5 is hydrogen or C.sub.1-4 alkyl; andR.sub.6 is an organic radical, are useful as cationic dyes for dyeing and printing fibers, threads and textile materials comprising, for example, a natural or regenerated cellulosic material such as cotton, a modified synthetic polyamide or polyester, and a homo- or co-polymer of acrylonitrile or 1,1-dicyanoethylene, bast fibers such as hemp and particularly paper and leather.

    摘要翻译： 具有式 + TR＆lt; IMAGE＆gt;和1：1和1：2金属络合物的金属化合物和无金属化合物和1：1和1：2金属络合物的盐，其中 R为氢，-SO 3 H或-NR 5 R 6; Ra是氢或-NR5R6; R 1是氢，卤素，-OH，C 1-4烷基，C 1-4烷氧基或-SO 3 H; R3是氢或C1-4烷基; R 4是卤素，-OH，C 1-4烷基，C 1-4烷氧基，苯基，-NH 2，脂族，脂环族或芳族氨基，含有1至3个原子的杂环氨基或肼基，R5是氢或C1- 4个烷基; 并且R6是有机基团，可用作染色和印刷纤维，丝线和纺织材料的阳离子染料，其包括例如天然或再生纤维素材料如棉，改性合成聚酰胺或聚酯，以及均聚物或共聚物 丙烯腈或1,1-二氰基乙烯的聚合物，诸如大麻，特别是纸和皮革的韧皮纤维。

    Disazo and polyazo compounds containing at least two cationic groups in metal-free or 1:1 or 1:2 metal complex form
    2.
    发明授权
    Disazo and polyazo compounds containing at least two cationic groups in metal-free or 1:1 or 1:2 metal complex form 失效
    含有无金属或1：1或1：2金属络合物形式的至少两个阳离子基团的双偶氮和多偶氮化合物

    公开(公告)号：US4670546A

    公开(公告)日：1987-06-02

    申请号：US625716

    申请日：1984-06-28

    申请人： Jacky Dore ,  Reinhard Pedrazzi

    发明人： Jacky Dore ,  Reinhard Pedrazzi

    IPC分类号： C09B44/02 ,  C09B44/08 ,  D06P1/41 ,  D06P3/60

    CPC分类号： C09B44/02

    摘要： Compounds of the formula ##STR1## in metal-free, 1:1 or 1:2 metal complex form, or in acid addition salt form, where the symbols are defined in the specification, useful as dyes for, for example, regenerated cellulose, cotton, synthetic polyamides and polyesters modified to contain acid groups and polymers and copolymers of acrylonitrile and 1,1-dicyanoethylene.

    摘要翻译： 不含金属的1：1或1：2金属络合物形式的式（I）＆lt; IMAGE＆gt;的化合物或其酸符号在本说明书中定义，可用作染料， 例如，再生纤维素，棉花，合成聚酰胺和被改性成含有酸基团的聚酯以及丙烯腈和1,1-二氰基乙烯的聚合物和共聚物。

    Metal-free monoazo and disazo compounds having a 1-hydroxy-5,6-, 7- or 8- substituted 1,3,5-triazinylamino-3- or 4 sulfonic acid coupling component radical and 1:1 copper complexes
    3.
    发明授权
    Metal-free monoazo and disazo compounds having a 1-hydroxy-5,6-, 7- or 8- substituted 1,3,5-triazinylamino-3- or 4 sulfonic acid coupling component radical and 1:1 copper complexes 失效
    具有1-羟基-5,6-，7-或8-取代的1,3,5-三嗪基氨基-3-或4-磺酸偶联组分基团和1：1铜络合物的无金属单偶氮和双偶氮化合物

    公开(公告)号：US4764175A

    公开(公告)日：1988-08-16

    申请号：US897445

    申请日：1986-08-15

    申请人： Jacky Dore ,  Reinhard Pedrazzi

    发明人： Jacky Dore ,  Reinhard Pedrazzi

    IPC分类号： C09B29/16 ,  C09B29/30 ,  C09B31/072 ,  C09B31/08 ,  C09B43/16 ,  C09B44/08 ,  C09B45/16 ,  C09B45/18 ,  C09B45/28 ,  D06P1/41 ,  D06P1/06 ,  D06P3/32

    CPC分类号： C09B44/08 ,  C09B43/16 ,  D06P1/41 ,  Y10S8/918 ,  Y10S8/919

    摘要： Metal-free compounds of the formula, ##STR1## and 1:1 copper complexes of metallizable metal-free compounds of said formula and internal and external salts of metal-free compounds of said formula and of 1:1 copper complexes of metallizable metal-free compounds of said formula, whereineach Q is independently linear or branched C.sub.2-6 alkylene; linear or branched C.sub.2-6 alkylene interrupted by --O--, --S-- or --NR.sub.4 --; linear or branched C.sub.3-6 alkylene monosubstituted or disubstituted by hydroxy or --*NHCO--CH.sub.2 --, wherein the * denotes the atom attached to the --NR.sub.4 -- radical,each R.sub.1 is independently hydrogen, halo, nitro, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, (C.sub.1-4 alkyl)carbonylamino, --SO.sub.2 NR.sub.3 R.sub.4, --CONR.sub.4 --C.sub.6 H.sub.5 or benzamido,R.sub.2 is hydrogen, hydroxy, halo, nitro, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, (C.sub.1-4 alkyl)carbonylamino or --NHCONR.sub.3 R.sub.4,X is --NR.sub.5 R.sub.6 or --N.sup..sym. R.sub.7 R.sub.8 R.sub.9 An.sup..crclbar., wherein R.sub.5 -R.sub.9 and An.sup..crclbar. are as defined in the specification, andn is 0 or 1whereineach R.sub.3 is independently hydrogen, C.sub.1-4 alkyl or C.sub.1-4 alkyl monosubstituted by hydroxy, halo, cyano or C.sub.1-4 alkoxy, andeach R.sub.4 is independently hydrogen or C.sub.1-4 alkyl, are useful, as such and in the form of solid and liquid aqueous dye preparations as direct dyes for dyeing or printing hydroxy-group or nitrogen-containing organic substrates, such as textiles consisting of or containing cellulose, leather and especially paper; they are also suitable for dyeing glass and products thereof and in inks.

    摘要翻译： 所述式的金属化合物，所述式的金属化无金属化合物和所述式的金属化合物的内部和外部盐与1：1铜的金属化合物， + TR＆lt; IMAGE＆gt;和1： 所述式的可镀金属的无金属化合物的络合物，其中每个Q独立地为直链或支链的C 2-6亚烷基; 由-O - ， - S-或-NR4-间隔的直链或支链C 2-6亚烷基; 被羟基或 - * NHCO-CH2-单取代或二取代的直链或支链C 3-6亚烷基，其中*表示与-NR 4 - 基团连接的原子，每个R 1独立地为氢，卤素，硝基，C 1-4烷基，C 1-4烷氧基 ，（C 1-4烷基）羰基氨基，-SO 2 NR 3 R 4，-CONR 4 -C 6 H 5或苯甲酰氨基，R 2是氢，羟基，卤素，硝基，C 1-4烷基，C 1-4烷氧基，（C 1-4烷基）羰基氨基或-NHCONR 3 R 4，X是-NR 5 R 6 或-N（+）R 7 R 8 R 9 An（ - ），其中R 5 -R 9和An（ - ）如说明书中所定义，并且n为0或1，其中每个R 3独立地为氢，C 1-4烷基或被单个取代的C 1-4烷基 羟基，卤素，氰基或C 1-4烷氧基，并且每个R 4独立地是氢或C 1-4烷基，可以这样使用，并且是固体和液体水性染料制剂的形式，作为用于染色或印刷羟基或氮 - 包含有机基材，如由纤维素，皮革和特别是纸组成的纤维素或纺织品; 它们也适用于对玻璃及其产品和油墨进行染色。

    "> Substituted 2,4-di[4'-(disulfonaphth-2
    6.
    发明授权
    Substituted 2,4-di[4'-(disulfonaphth-2"-ylazo)phenylamino]-6-amino-1,3,5-triazines 失效
    取代的2,4-二[4' - （二磺基萘-2“ - 基偶氮）苯基氨基] -6-氨基-1,3,5-三嗪

    公开(公告)号：US5006128A

    公开(公告)日：1991-04-09

    申请号：US399665

    申请日：1989-08-25

    申请人： Reinhard Pedrazzi

    发明人： Reinhard Pedrazzi

    IPC分类号： C09B33/02 ,  C09B33/16 ,  C09B35/039 ,  C09B43/16 ,  C09B67/36 ,  C09D11/037 ,  D06P1/39

    CPC分类号： C09D11/037 ,  C09B35/039 ,  C09B43/16 ,  C09B67/0079 ,  D06P1/39 ,  Y10S8/917 ,  Y10S8/918 ,  Y10S8/919 ,  Y10S8/924

    摘要： Compounds of the formula ##STR1## and salts thereof, whereinR.sub.1 is hydrogen or methyl,R.sub.2 is hydrogen, methyl or acetamido,R.sub.3 is hydrogen, methyl or methoxy,R.sub.4 is hydrogen, C.sub.1-4 alkyl or hydroxy(C.sub.2-4 alkyl),R.sub.5 is hydroxy(C.sub.2-4 alkyl) or hydroxy(C.sub.2-4 alkoxy)C.sub.2-4 alkyl, or--NR.sub.4 R.sub.5 is a 5- or 6-membered ring containing 1 to 3 hetero atoms which ring is unsubstituted or substituted by 1 to 3 substituents selected from C.sub.1-4 alkyl and C.sub.2-4 alkyl monosubstituted by hydroxy or amino, andthe two naphthyl-2 groups are identically substituted, with the proviso that when R.sub.3 is methoxy, R.sub.1 and R.sub.2 are different, solid and aqueous liquid dye compositions and printing inks comprising such compounds and salts and the use of such compounds and salts for dyeing and printing substrates, especially hydroxy group- and nitrogen-containing organic substrates.

    摘要翻译： 其中R 1是氢或甲基，R 2是氢，甲基或乙酰氨基，R 3是氢，甲基或甲氧基，R 4是氢，C 1-4烷基或C 1 -C 4烷基， 羟基（C 2-4烷基），R 5是羟基（C 2-4烷基）或羟基（C 2-4烷氧基）C 2-4烷基，或-NR 4 R 5是含有1至3个杂原子的5或6元环，该环是未取代或取代的 1〜3个选自C 1-4烷基的取代基和被羟基或氨基单取代的C2-4烷基，两个萘基-2基团相同取代，条件是当R3为甲氧基时，R1和R2不同，固体和水性液体 染料组合物和包含这些化合物和盐的印刷油墨，以及这些化合物和盐的用途，用于染色和印刷底物，特别是含羟基和含氮有机基材。

    Oxazine compounds substituted by one or more basic groups and preparation thereof
    7.
    发明授权
    Oxazine compounds substituted by one or more basic groups and preparation thereof 失效
    被一个或多个碱性基团取代的恶嗪化合物及其制备

    公开(公告)号：US4876342A

    公开(公告)日：1989-10-24

    申请号：US199211

    申请日：1988-05-26

    申请人： Reinhard Pedrazzi

    发明人： Reinhard Pedrazzi

    IPC分类号： C07D498/22 ,  C07C19/00 ,  C09B19/00 ,  C09B19/02 ,  C09B21/00 ,  D06P3/32 ,  D06P3/60 ,  D21H21/28

    CPC分类号： C09B19/02

    摘要： Oxazine compounds containing basic groups correspond to the formula ##STR1## wherein the symbols are as defined in the Specification. These compounds are suitable for dyeing or printing organic substrates containing hydroxy groups or nitrogen in accordance with known methods. Preferred substrates are textile materials which consist of or contain natural or regenerated cellulose, e.g. cotton, but also bast fibres or leather. Most preferred substrates are paper or paper products. Furthermore, these compounds can be used to prepare all kinds of inks, such as ball-pen inks or printing inks.Similarly, a mixture of one or more of the above compounds together with one or more copper phthalocyanine dyes containing basic and/or cationic groups can be used as dyeing or printing agent.

    摘要翻译： 含有碱性基团的恶嗪化合物对应于式“IMAGE”，其中符号如本说明书中所定义。 这些化合物适合于根据已知方法染色或印刷含羟基或氮的有机底物。 优选的基材是由天然或再生纤维素组成或包含天然或再生纤维素的纺织材料。 棉，但也是韧皮纤维或皮革。 最优选的基材是纸或纸制品。 此外，这些化合物可用于制备各种油墨，例如圆珠笔墨水或印刷油墨。 类似地，可以使用一种或多种上述化合物与一种或多种含碱性和/或阳离子基团的铜酞菁染料的混合物作为染色或印刷剂。

    Sulfo group containing triphendioxazines having at least one 1,3,5-triazine ring
    10.
    发明授权
    Sulfo group containing triphendioxazines having at least one 1,3,5-triazine ring 失效
    含有至少一个1,3,5-三唑环的三氟乙烯的SULFO集团

    公开(公告)号：US5122605A

    公开(公告)日：1992-06-16

    申请号：US484582

    申请日：1990-02-23

    申请人： Reinhard Pedrazzi

    发明人： Reinhard Pedrazzi

    IPC分类号： C09B19/02 ,  C09B56/00 ,  C09B62/04 ,  C09B62/08 ,  C09B69/10 ,  D06P1/38

    CPC分类号： C09B19/02 ,  C09B56/00 ,  C09B62/043 ,  C09B62/046 ,  C09B62/082 ,  C09B69/109

    摘要： Sulpho group-containing dioxazine compounds corresponding to the formula ##STR1## in which the symbols are as defined in the specification, and salts thereof as well as dyeing preparations thereof are useful for dyeing or printing hydroxy group- or nitrogen-containing organic substrates, optionally combined with a special after-treatment of the dyed or printed textiles thus obtained to improve their wet fastness properties. Most preferred substrates are textile material containing or consisting of cellulose and paper.

    摘要翻译： 对应于其中符号如说明书中所定义的式 + TR 的含磺基的二嗪类化合物及其盐及其染色制剂可用于染色或印刷羟基或氮 - 任选地与由此获得的染色或印花纺织品的特殊后处理组合以改善其耐湿牢度性质。 最优选的基材是含有纤维素和纸的纤维素材料。