摘要:
Polyimide matrix microparticles or microcapsules having a thermally stable polyimide wall or matrix and functional polymer additives as core materials. The polyimide matrix microparticles or microcapsules can be processed into high-melting polymers by melt compounding.
摘要:
Functionalized particles having fully formed shells and cores comprising a polyurethane or polyurea matrix obtained by interfacial addition polymerisation of (i) at least one polyisocyanate derivative selected from the group of partially blocked polyisocyanates and polyisocyanates partially modified with fiber reactive groups and (ii) at least one polyamine or polyhydric alcohol, said functionalized particles being capable to chemically or physically bind to a substrate.
摘要:
The invention relates to encapsulated rubber additives in the form of microcapsules having a polymer capsule wall and a core which comprises at least one rubber additive. The invention likewise relates to a method for the production of microcapsules of this type. The microcapsules according to the invention are used during vulcanisation of natural and synthetic rubbers.
摘要:
Functionalized particles having fully formed shells and cores comprising a polyurethane or polyurea matrix obtained by interfacial addition polymerisation of (i) at least one polyisocyanate derivative selected from the group of partially blocked polyisocyanates and polyisocyanates partially modified with fiber reactive groups and (ii) at least one polyamine or polyhydric alcohol, said functionalized particles being capable to chemically or physically bind to a substrate.
摘要:
In a method for producing a homopolyester or copolyester obtainable from at least one cyclic monomer, the at least one cyclic monomer is polymerized in the presence of an initiator. The initiator is selected from organo-tin compounds, tin carboxylates, and tin alkoxides of the oxidation state II or IV that may contain optionally hydroxy groups. At the latest at a point in time when a desired degree of polymerization is reached, a phosphinic acid and/or a phosphinic derivative of the formula (R1)(R2)P(═O)X is added, wherein R1 and R2 each are independently of one another hydrogen, alkyl, aryl, or hetero aryl, and X is —OR3 or —NR1R2, wherein R3 is hydrogen, alkyl, aryl, MI or ½MII and MI is an alkali metal ion and MII is an alkaline earth metal ion and wherein the substituents R1 and R2 have the meaning indicated above.
摘要翻译:在由至少一种环状单体得到的均聚酯或共聚聚酯的制造方法中,至少一种环状单体在引发剂的存在下聚合。 引发剂选自可含有任选羟基的氧化态II或IV的有机锡化合物,羧酸锡和烷氧化锡。 最近在达到所需聚合度的时间点,式(R 1)2的次膦酸和/或次膦酸衍生物(R 1 H 2) )P(-O)X,其中R 1和R 2各自彼此独立地为氢,烷基,芳基或杂芳基,X为 - OR 3或-NR 1 R 2,其中R 3是氢,烷基,芳基,M I SUP>或1/2M II和M I L是碱金属离子,M II是碱土金属离子,其中, 取代基R 1和R 2 2具有上述含义。
摘要:
The invention relates to a method for producing polyesters with a reduced content of free acetaldehyde from terephthalic acid and ethylene glycol via a catalyzed polycondensation in the melt and also the use of this method. The method is based thereby on the usage of highly active polycondensation catalysts, on the deactivation of these catalysts by the addition of phosphorous-containing inhibitors and the addition of acetaldehyde-bonding substances. The entire polycondensation is thereby implemented at temperatures beneath 280° C.
摘要:
A method of stabilization of a melt viscosity of aliphatic- and/or aromatic homo- and/or co-polyesters containing catalysts and/or initiators, involves adding a masking agent which is tropon, .alpha.-tropolon, thujaplicin, pupurogallin or mixtures thereof to a melt resulting during synthesis of polyesters or during regeneration of polyesters.
摘要:
The invention relates to aminoplastics, which are created by reacting comnds that contain amide groups with glutaric dialdehyde, and to a process for their preparation and to their use. The aminoplastic according to the invention is free of formaldehyde and can be hardened without difficulty by acidic catalysis or thermal processes. The aminoplastic is prepared by polycondensation of compounds that contain amide groups with glutaric dialdehyde in aqueous solution.
摘要:
The invention relates to encapsulated rubber additives in the form of microcapsules having a polymer capsule wall and a core which comprises at least one rubber additive. The invention likewise relates to a method for the production of microcapsules of this type. The microcapsules according to the invention are used during vulcanization of natural and synthetic rubbers.
摘要:
Method for the production of L,L-, D,D-, D,L- and meso-dilactides, comprising the polycondensation and/or polytransesterification of an L-, D- or D,L-lactic acid or of esters thereof to polyesters of higher molecular weights of the L-, D- and D,L-lactic acid (polylactic acids) and cyclizing depolymerization of the polylactic acids to dilactides, wherein the polyesters of higher molecular weights of the L-, D- and D,L-lactic acids are produced in the presence of hydrolysis-stable metal compounds as catalyst.