公开(公告)号：US06559272B1

公开(公告)日：2003-05-06

申请号：US10057386

申请日：2002-01-24

申请人： Jae-Young Jeon ,  Yoon-Hee Hong ,  Sung-Gi Kim

发明人： Jae-Young Jeon ,  Yoon-Hee Hong ,  Sung-Gi Kim

IPC分类号： C08G6378

CPC分类号： C08G63/85 ,  C08G63/181 ,  C08K5/49

摘要： Disclosed is a method for preparing polyester resins copolymerized with glycol for modification such as 1,4-cyclohexanedimethanol, in which the content of said glycol ingredient for modification ranges from 20 to 80 mol % of the total glycol content. Dicarboxylic acid such as terephthalic acid is esterified with ethylene glycol and said glycol for modification. The esterification product is subjected to polycondensation in the presence of a titanium dioxide/silicon dioxide coprecipitate catalyst, said catalyst being in the form of 4% or less strength by weight suspension in glycol. The copolyester prepared as above shows excellent transparency and color properties in addition to being produced at high efficiency.

摘要翻译： 公开了一种用于制备与乙二醇共聚的聚酯树脂的方法，例如1,4-环己烷二甲醇，其中所述改性二醇成分的含量为总二醇含量的20至80摩尔％。 二羧酸如对苯二甲酸用乙二醇酯化，所述二醇用于改性。 酯化产物在二氧化钛/二氧化硅共沉淀催化剂存在下进行缩聚，所述催化剂为乙二醇悬浮液中4重量％以下的重量。 如上制备的共聚聚酯除了高效生产之外还显示出优异的透明性和着色性。

公开(公告)号：US09546248B2

公开(公告)日：2017-01-17

申请号：US13697282

申请日：2011-05-06

申请人： Kyu-Tae Park ,  Sung-Gi Kim ,  Jae-Bong Lim ,  Il-Hoon Cha ,  Se-Ho Lee

发明人： Kyu-Tae Park ,  Sung-Gi Kim ,  Jae-Bong Lim ,  Il-Hoon Cha ,  Se-Ho Lee

IPC分类号： C08G75/00 ,  C08G75/14 ,  C08G75/02 ,  C08L81/02

CPC分类号： C08G75/14 ,  C08G75/0204 ,  C08L81/02 ,  Y10T428/249921

摘要： The present invention relates to polyarylene sulfide, in which a ratio of a peak area of a polymer chain of a second polyarylene sulfide having a lower molecular weight than the maximum peak molecular weight to a peak area of a polymer chain of a first polyarylene sulfide having a higher molecular weight than the maximum peak molecular weight is 1.3 or less in the molecular weight distribution of the polyarylene sulfide, as measured by gel permeation chromatography using polystyrene as a standard, and a preparation method thereof. This polyarylene sulfide exhibits excellent processability and generates no burrs (flashes) or the like, and can satisfactorily mold a product requiring high molding precision.

摘要翻译： 本发明涉及聚芳硫醚，其中具有比最大峰分子量低的分子量的第二聚芳硫醚的聚合物链的峰面积与具有第一聚亚芳基硫醚的聚合物链的峰面积的比率 通过使用聚苯乙烯作为标准物的凝胶渗透色谱法测定，聚亚芳基硫醚的分子量分布中的分子量比最大峰分子量高的分子量为1.3以下，及其制备方法。 该聚亚芳基硫醚显示出优异的加工性，不产生毛刺（闪光）等，能够令人满意地成型需要高成型精度的产品。

公开(公告)号：US08859720B2

公开(公告)日：2014-10-14

申请号：US13141822

申请日：2009-12-22

申请人： Yong-Jun Shin ,  Jae-Bong Lim ,  Joon-Sang Cho ,  Il-Hoon Cha ,  Sung-Gi Kim

发明人： Yong-Jun Shin ,  Jae-Bong Lim ,  Joon-Sang Cho ,  Il-Hoon Cha ,  Sung-Gi Kim

IPC分类号： C08G75/14 ,  C08G75/02 ,  C08G75/16

CPC分类号： C08G75/0209 ,  C08G75/0268

摘要： The present invention relates to a method for preparing polyarylene sulfide, in which the polyarylene sulfide is prepared by a polymerization reaction of reactants including a diiodo aromatic compound and a sulfur compound, the method including: further adding 0.01 to 10.0 wt. % of diphenyl disulfide with respect to the weight of the polyarylene sulfide to the reactants to form the polyarylene sulfide having a melting point of 265 to 320° C.The diphenyl disulfide included in the reactants according to the present invention costs far less than other conventional polymerization inhibitors to dramatically lower the production cost, and the polyarylene sulfide prepared using the diphenyl disulfide exhibits low iodine content and very excellence in thermal stability.

摘要翻译： 本发明涉及一种聚芳硫醚的制备方法，其中聚芳硫醚通过包括二碘芳族化合物和硫化合物的反应物的聚合反应制备，所述方法包括：进一步加入0.01至10.0wt。 相对于聚芳硫醚相对于反应物的重量的二苯基二硫化物的％为二苯醚，以形成熔点为265至320℃的聚芳硫醚。根据本发明的反应物中包含的二苯基二硫醚的成本远低于其它常规 聚合抑制剂大大降低生产成本，并且使用二苯基二硫化物制备的聚芳硫醚表现出低碘含量和非常优异的热稳定性。

公开(公告)号：US09249263B2

公开(公告)日：2016-02-02

申请号：US13582874

申请日：2011-02-28

申请人： Sung-Gi Kim ,  Il-Hoon Cha

发明人： Sung-Gi Kim ,  Il-Hoon Cha

IPC分类号： C08G75/16 ,  C08G75/02 ,  C08G75/14 ,  C08J5/18

CPC分类号： C08G75/16 ,  C08G75/02 ,  C08G75/14 ,  C08J5/18 ,  C08J2381/04

摘要： Embodiments of the present invention relate to recyclable polyarylene sulfide that may exhibit and maintain excellent mechanical properties, particularly does not exhibit decrease in melt viscosity when it is molten, and thus, exhibit little deterioration of mechanical properties, and a method for preparing the same. The polyarylene sulfide has initial melt viscosity measured at 300° C. of 300 to 6000 poise, and melt viscosity after heat treated and molten at 300° C., equal to or greater than the initial melt viscosity.

摘要翻译： 本发明的实施方式涉及可显示和保持优异的机械性能的可回收聚芳撑硫醚，特别是熔融时熔体粘度不会降低，因此几乎不显示出机械性能的劣化及其制备方法。 聚亚芳基硫醚在300℃下测定的初始熔融粘度为300〜6000泊，热处理后的熔融粘度在300℃下熔融，等于或大于初始熔融粘度。

公开(公告)号：US08759478B2

公开(公告)日：2014-06-24

申请号：US13576229

申请日：2011-01-31

申请人： Yong-Jun Shin ,  Il-Hoon Cha ,  Jae-Bong Lim ,  Sung-Gi Kim

发明人： Yong-Jun Shin ,  Il-Hoon Cha ,  Jae-Bong Lim ,  Sung-Gi Kim

IPC分类号： C08G75/00

CPC分类号： C08G75/14 ,  C08G75/0263

摘要： A method for preparing polyarylene sulfide having reduced iodine content and excellent thermal stability is described. The method includes reacting a composition comprising diiodide aromatic compounds, sulfur compounds, and a polymerization terminator. The preparation method may effectively reduce iodine content of polyarylene sulfide to prevent corrosion of post processing equipment, improve properties of polyarylene sulfide such as thermal stability, and the like, and thus, it may be usefully applied in the industrial field relating to preparation of polyarylene sulfide.

摘要翻译： 描述了制备具有降低的碘含量和优异的热稳定性的聚芳硫醚的方法。 该方法包括使包含二碘化物芳族化合物，硫化合物和聚合终止剂的组合物反应。 制备方法可有效降低聚芳硫醚的碘含量，防止后处理设备的腐蚀，改善聚芳硫醚的热稳定性等，从而可用于有关制备聚亚芳基的工业领域 硫化物。

公开(公告)号：US20120322971A1

公开(公告)日：2012-12-20

申请号：US13582874

申请日：2011-02-28

申请人： Sung-Gi Kim ,  Il-Hoon Cha

发明人： Sung-Gi Kim ,  Il-Hoon Cha

IPC分类号： C08G75/14

CPC分类号： C08G75/16 ,  C08G75/02 ,  C08G75/14 ,  C08J5/18 ,  C08J2381/04

摘要： This disclosure relates to recyclable polyarylene sulfide that may exhibit and maintain excellent mechanical properties, particularly does not exhibit decrease in melt viscosity when it is molten, and thus, exhibit little deterioration of mechanical properties, and a method for preparing the same.The polyarylene sulfide has initial melt viscosity measured at 300□ of 300 to 6000 poise, and melt viscosity after heat treated and molten at 300□, equal to or greater than the initial melt viscosity

摘要翻译： 本公开涉及可显示和保持优异的机械性能的可回收聚芳硫醚，特别是当其熔融时熔体粘度不显示降低，因此几乎不显示出机械性能的劣化及其制备方法。 聚亚芳基硫醚的初始熔融粘度在300□为300〜6000泊，熔融粘度为300□以上，熔融粘度等于或大于初始熔融粘度

公开(公告)号：US20120302726A1

公开(公告)日：2012-11-29

申请号：US13576229

申请日：2011-01-31

申请人： Yong-Jun Shin ,  II-Hoon Cha ,  Jae-Bong Lim ,  Sung-Gi Kim

发明人： Yong-Jun Shin ,  II-Hoon Cha ,  Jae-Bong Lim ,  Sung-Gi Kim

IPC分类号： C08G75/16

CPC分类号： C08G75/14 ,  C08G75/0263

摘要： This disclosure relates to a method for preparing polyarylene sulfide having reduced iodine content while having excellent thermal stability, specifically to a method comprising polymerization reacting a composition comprising diiodide aromatic compounds, sulfur compounds, and a polymerization terminator. The preparation method may effectively reduce iodine content of polyarylene sulfide to prevent corrosion of post processing equipment, improve properties of polyarylene sulfide such as thermal stability, and the like, and thus, it may be usefully applied in the industrial field relating to preparation of polyarylene sulfide.

摘要翻译： 本公开内容涉及一种具有降低碘含量同时具有优异的热稳定性的聚芳硫醚的制备方法，具体涉及使包含二碘化物芳族化合物，硫化合物和聚合终止剂的组合物聚合反应的方法。 制备方法可以有效降低聚芳硫醚的碘含量，防止后处理设备的腐蚀，改善聚芳硫醚的热稳定性等，从而可用于与聚亚芳基的制备有关的工业领域 硫化物。

公开(公告)号：US20110257363A1

公开(公告)日：2011-10-20

申请号：US13141822

申请日：2009-12-22

申请人： Yong-Jun Shin ,  Jae-Bong Lim ,  Joon-Sang Cho ,  Il-Hoon Cha ,  Sung-Gi Kim

发明人： Yong-Jun Shin ,  Jae-Bong Lim ,  Joon-Sang Cho ,  Il-Hoon Cha ,  Sung-Gi Kim

IPC分类号： C08G75/04

CPC分类号： C08G75/0209 ,  C08G75/0268

摘要： The present invention relates to a method for preparing polyarylene sulfide, in which the polyarylene sulfide is prepared by a polymerization reaction of reactants including a diiodo aromatic compound and a sulfur compound, the method including: further adding 0.01 to 10.0 wt. % of diphenyl disulfide with respect to the weight of the polyarylene sulfide to the reactants to form the polyarylene sulfide having a melting point of 265 to 320° C.The diphenyl disulfide included in the reactants according to the present invention costs far less than other conventional polymerization inhibitors to dramatically lower the production cost, and the polyarylene sulfide prepared using the diphenyl disulfide exhibits low iodine content and very excellence in thermal stability.

摘要翻译： 本发明涉及一种聚芳硫醚的制备方法，其中聚芳硫醚通过包括二碘芳族化合物和硫化合物的反应物的聚合反应制备，所述方法包括：进一步加入0.01至10.0wt。 相对于聚芳硫醚相对于反应物的重量的二苯基二硫化物的％为二苯醚，以形成熔点为265至320℃的聚芳硫醚。根据本发明的反应物中包含的二苯基二硫醚的成本远低于其它常规 聚合抑制剂大大降低生产成本，并且使用二苯基二硫化物制备的聚芳硫醚表现出低碘含量和非常优异的热稳定性。

公开(公告)号：USD544528S1

公开(公告)日：2007-06-12

申请号：US29220666

申请日：2005-01-04

申请人： Sung-Gi Kim

设计人： Sung-Gi Kim

公开(公告)号：US5659866A

公开(公告)日：1997-08-19

申请号：US522154

申请日：1995-08-31

申请人： Sung-Gi Kim

发明人： Sung-Gi Kim

IPC分类号： G03G15/20

CPC分类号： G03G15/2053

摘要： A heat fixing roller in an electrophotographic recording system provides a high degree of radiating efficiency and reduces the amount of time it takes for the heat fixing roller to achieve a temperature necessary to perform a printing operation. The heat fixing roller has a heat lamp installed along a center axis within an interior portion of the heat fixing roller. A plurality of hollowed-out heat conduits extend outwardly in a radial manner from the heat lamp to provide a path through which heat generated by the heat lamp can radiate to rapidly increase the temperature of an outer surface of the heat fixing roller.

摘要翻译： 电子照相记录系统中的热定影辊提供高度的辐射效率并减少热定影辊达到执行打印操作所需的温度所花费的时间。 热定影辊具有沿着中心轴安装在热定影辊的内部内的加热灯。 多个中空的热导管从加热灯以径向方式向外延伸，以提供通过加热灯产生的热量可以辐射的路径，以快速增加热定影辊的外表面的温度。