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公开(公告)号：US5237106A
公开(公告)日：1993-08-17
申请号：US825083
申请日：1992-01-24
IPC分类号： B01J31/24 , B01J23/46 , B01J23/90 , B01J31/26 , B01J31/40 , B01J38/52 , B01J38/62 , C07B61/00 , C07C27/22 , C07C45/34 , C07C45/49 , C07C45/50 , C07C45/73
CPC分类号： B01J31/24 , B01J31/2404 , B01J31/4046 , B01J38/62 , C07C45/50 , B01J2231/321 , B01J2531/822 , B01J31/0201 , B01J31/0235 , B01J31/04 , Y02P20/584
摘要： A process for improving the catalytic activity of a partially deactivated solubilized rhodium-tertiary organophosphine complex hydroformylation catalyst by treating it with propargyl alcohol and a carboxylic acid.
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公开(公告)号：US5288918A
公开(公告)日：1994-02-22
申请号：US953016
申请日：1992-09-29
申请人： John M. Maher , James E. Babin , Ernst Billig , David R. Bryant , Tak W. Leung
发明人： John M. Maher , James E. Babin , Ernst Billig , David R. Bryant , Tak W. Leung
IPC分类号： B01J31/22 , B01J31/18 , B01J31/28 , C07B61/00 , C07C45/50 , C07C47/02 , C07F9/6574 , C07F15/00
CPC分类号： C07F15/008 , B01J31/185 , C07C45/50 , C07F9/65746 , B01J2231/321 , B01J2531/0266 , B01J2531/822 , Y02P20/582
摘要： An improved rhodium-organophosphite complex catalyzed hydroformylation process, the improvement comprising carrying out said process in the presence of a catalytic activity enhancing additive said additive being selected from the class consisting of added water, a weakly acidic compound, or both added water and a weakly acidic compound.
摘要翻译： 改进的铑 - 有机亚磷酸酯络合物催化加氢甲酰化方法，其改进包括在催化活性增强添加剂存在下进行所述方法，所述添加剂选自加入的水，弱酸性化合物或加入的水和弱的 酸性化合物。
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公开(公告)号：US5183943A
公开(公告)日：1993-02-02
申请号：US670874
申请日：1991-03-18
IPC分类号： B01J31/24 , B01J31/40 , C07B61/00 , C07C27/22 , C07C45/49 , C07C45/50 , C07C45/80 , C07C47/02
CPC分类号： B01J31/0237 , B01J31/24 , B01J31/2404 , B01J31/4046 , B01J31/4053 , C07C45/50 , C07C45/80 , B01J2231/321 , B01J2531/822 , Y02P20/584
摘要： A process for improving the catalytic activity of a partially deactivated solubilized rhodium - tertiary organophosphine complex hydroformylation catalyst.
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公开(公告)号：US4935550A
公开(公告)日：1990-06-19
申请号：US231508
申请日：1988-08-12
申请人： David J. Miller , David R. Bryant
发明人： David J. Miller , David R. Bryant
CPC分类号： B01J31/24 , B01J31/2404 , B01J31/2409 , B01J31/2414 , B01J31/4046 , C07C45/50 , B01J2231/321 , B01J2531/80 , B01J2531/822 , B01J2531/96 , B01J31/0201 , Y02P20/584
摘要： A method for recovering a transition metal, e.g., rhodium, from a non-polar organic solution containing non-polar organic solvent-soluble and polar solvent-insoluble coordination complex of the transition metal and a non-polar organic solvent-soluble and polar solvent-insoluble ligand, e.g., an organophosphorus ligand, by contacting the non-polar organic solution with a polar solution of an ionic organophosphine ligand, the transition metal then can be transferred back into a non-polar solution for reuse. In one embodiment rhodium is rendered amenable for back-extraction by treating the polar solution with a suitable conditioning reagent.
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公开(公告)号：US4861918A
公开(公告)日：1989-08-29
申请号：US231510
申请日：1988-08-12
CPC分类号： B01J31/4046 , B01J31/24 , B01J31/2404 , C07C45/50 , B01J2231/321 , B01J2531/822 , B01J31/0201 , B01J31/0215 , B01J31/0231 , B01J31/0255 , B01J31/04 , Y02P20/582 , Y02P20/584
摘要： A process for improving the catalytic activity of a partially deactivated solubilized rhodium - tertiary organophosphine complex hydroformylation catalyst.
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公开(公告)号：US4740272A
公开(公告)日：1988-04-26
申请号：US32259
申请日：1987-03-31
申请人： Ernesto Vera-Castaneda , Diane A. Montevideo , David J. Miller , John E. Logsdon , David R. Bryant
发明人： Ernesto Vera-Castaneda , Diane A. Montevideo , David J. Miller , John E. Logsdon , David R. Bryant
CPC分类号： C07C51/56 , C07C67/54 , Y10S203/20
摘要： A method of producing substantially pure dialkyl maleate by separating monoalkyl maleate from dialkyl maleate in a short residence time distillation zone while minimizing reversion of the monoalkyl maleate to alkanol and maleic anhydride and without having to neutralize the monoalkyl maleate.
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公开(公告)号：US4929767A
公开(公告)日：1990-05-29
申请号：US254197
申请日：1988-10-06
CPC分类号： B01J31/24 , B01J31/2404 , B01J31/4046 , C07C45/50 , B01J2231/321 , B01J2531/822 , B01J31/0201 , B01J31/0215 , B01J31/0231 , B01J31/0255 , B01J31/04 , Y02P20/584
摘要： A process for treating an organic solution of a partially deactivated solubilized rhodium-tertiary organophosphine complex hydroformylation catalyst with an organic reagent in order to improve the extractability of rhodium therefrom into an aqueous solution containing an ionic organophosphine ligand.
摘要翻译： 用有机试剂处理部分失活的溶解的铑 - 叔有机膦配合物加氢甲酰化催化剂的有机溶液的方法，以便将铑从其中提取成含有离子型有机膦配体的水溶液。
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公开(公告)号：US4945185A
公开(公告)日：1990-07-31
申请号：US445927
申请日：1989-12-05
申请人： Anthony J. Papa , David R. Bryant
发明人： Anthony J. Papa , David R. Bryant
CPC分类号： B01J31/2404 , B01J31/20 , C07C45/50 , B01J2231/321 , B01J2531/822 , B01J31/2234 , B01J31/2295
摘要： A hydrocarbonylation process for producing an aldehyde or a mixture of a ketone and an aldehyde which comprises:(I) forming a reaction mixture comprising:(a) a catalytic amount of a complex catalyst consisting essentially of rhodium in complex combination with:(i) a triorganophosphine, and(ii) a carboxylic acid having a phenyl group substituted at the para position with a non-reactive electron-withdrawing group, said phenyl group being free of further substitution and said electron withdrawing group being substantially non-reactive in said process;(b) an alpha-olefin having 2 to 5 carbon atoms,(c) carbon monixide, and(d) hydrogenwith the proviso that the reaction mixture has mole ratio of said carbxoylic acid to rhodium of at least about 2; and(II) maintaining the reaction mixture at a temperature and pressure at which said (b), (c) and (d) react to form an aldehyde or a mixture of an aldehyde and a ketone.
摘要翻译： 用于产生醛或酮和醛的混合物的烃基化方法，其包括：（I）形成反应混合物，其包含：（a）催化量的基本上由铑组成的复合催化剂，其复合组合与：（i） 三有机膦，和（ii）具有在对位被非反应性吸电子基团取代的苯基的羧酸，所述苯基不再进一步取代，并且所述吸电子基团在所述方法中基本上不反应 ; （b）具有2至5个碳原子的α-烯烃，（c）一碳化碳和（d）氢，条件是反应混合物具有至少约2的所述羧甲基酸与铑的摩尔比; 和（II）将反应混合物保持在所述（b），（c）和（d）反应的温度和压力下，形成醛或醛和酮的混合物。
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公开(公告)号：US4599206A
公开(公告)日：1986-07-08
申请号：US685025
申请日：1984-12-28
IPC分类号： C07C47/02 , B01J27/18 , B01J31/18 , B01J31/20 , C07B61/00 , C07C45/00 , C07C45/50 , C07C67/00 , C07F9/06 , C07F9/547 , C07F9/6564 , C07F9/6574 , C07F9/6578 , C07F15/00 , C07F9/02
CPC分类号： C07F15/008 , B01J31/185 , C07C45/50 , C07F9/65744 , C07F9/6578 , B01J2231/321 , B01J2531/0266 , B01J2531/822 , Y02P20/582
摘要： Transition metal-diorganophosphite complex catalyzed carbonylation processes, especially hydroformylation, as well as transition metal-diorganophosphite ligand complex compositions, diorganophosphite ligands and transition metal-diorganophosphite catalysts.
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公开(公告)号：US4409149A
公开(公告)日：1983-10-11
申请号：US278897
申请日：1981-06-29
申请人： Ernst Billig , David R. Bryant
发明人： Ernst Billig , David R. Bryant
CPC分类号： C07F15/008
摘要： This invention relates to a novel process for the preparation of rhodium(I) carbonyltriorganophosphorus mono-.beta.-ketoenolate complexes which comprises reacting a halocarbonylbis(triorganophosphorus) rhodium(I) complex, a .beta.-ketoenolate source and an oxygen transfer agent. The complexes so produced are useful as precursors for catalysts in hydroformylation processes.
摘要翻译： 本发明涉及一种制备铑（I）羰基三有机磷单糖β-酮酯复合物的新方法，其包括使卤代羰基双（三有机磷）铑（I）络合物，β-酮多烯酸酯源和氧转移剂反应。 如此制备的络合物可用作加氢甲酰化方法中催化剂的前体。
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