公开(公告)号：US5374419A

公开(公告)日：1994-12-20

申请号：US994069

申请日：1992-12-18

申请人： James J. Krutak ,  Max A. Weaver ,  Clarence A. Coates, Jr. ,  Samuel D. Hilbert ,  Terry A. Oldfield ,  William W. Parham ,  Wayne P. Pruett

发明人： James J. Krutak ,  Max A. Weaver ,  Clarence A. Coates, Jr. ,  Samuel D. Hilbert ,  Terry A. Oldfield ,  William W. Parham ,  Wayne P. Pruett

IPC分类号： A61K8/00 ,  A61K8/04 ,  A61K8/40 ,  A61K8/46 ,  A61K8/85 ,  A61Q17/04 ,  C07C69/734 ,  C07C69/736 ,  C07C255/23 ,  C07C255/32 ,  C07C255/34 ,  C07C255/37 ,  C07C255/41 ,  C07C255/53 ,  C07C271/26 ,  C07C317/46 ,  C07C321/28 ,  C07C323/12 ,  C07C323/19 ,  C07C323/32 ,  C07C323/62 ,  C08G63/16 ,  C08G63/20 ,  C08G63/44 ,  C08G63/676 ,  C08G63/685 ,  C08G63/688 ,  C08G85/00 ,  C08J5/18 ,  C08K5/00 ,  C08L67/00 ,  C08L67/02 ,  C09K3/00 ,  A61K7/42 ,  A61K7/44 ,  C07C255/00

CPC分类号： A61Q17/04 ,  A61K8/40 ,  A61K8/46 ,  A61K8/85 ,  C07C255/41 ,  C08G63/676 ,  C08G63/6858 ,  C08G63/6888 ,  C08G85/00 ,  Y10S514/938 ,  Y10T428/13 ,  Y10T428/1352

摘要： Disclosed are sunscreen compositions containing certain poly-methine compounds having the formula ##STR1## wherein each R.sup.1 is independently selected from cyano; carboxy; alkenyloxycarbonyl; an unsubstituted or substituted alkoxycarbonyl, cycloalkoxycarbonyl or aryloxycarbonyl radical; an unsubstituted or substituted, carbocyclic or heterocyclic aryl radical; an unsubstituted or substituted alkanoyl, cycloalkanoyl or aroyl radical; an unsubstituted or substituted carbamoyl radical; or an unsubstituted or substituted alkylsulfonyl, cycloalkylsulfonyl or arylsulfonyl radical; each R.sup.2 is independently selected from cyano or an unsubstituted or substituted alkoxycarbonyl, cycloalkoxycarbonyl or aryloxycarbonyl radical; each A is independently selected from an unsubstituted or substituted 1,2-phenylene or 1,2-naphthylene radical; each Z is independently selected from --O-- or --S--; and L is an organic linking group bonded by non-oxo carbon atoms to each Z atom. Also disclosed are sunscreen formulations and polymeric compositions containing at least one of the poly-methine compounds or the reactive residue thereof.

摘要翻译： 公开了含有具有式“IMAGE”的某些多次甲基化合物的防晒组合物，其中每个R 1独立地选自氰基; 羧基; 烯氧基羰基; 未取代或取代的烷氧基羰基，环烷氧基羰基或芳氧基羰基; 未取代或取代的碳环或杂环芳基; 未取代或取代的烷酰基，环烷酰基或芳酰基; 未取代或取代的氨基甲酰基; 或未取代或取代的烷基磺酰基，环烷基磺酰基或芳基磺酰基; 每个R 2独立地选自氰基或未取代或取代的烷氧基羰基，环烷氧基羰基或芳氧基羰基; 每个A独立地选自未取代或取代的1,2-亚苯基或1,2-亚萘基; 每个Z独立地选自-O-或-S-; L是通过非氧代碳原子键合到每个Z原子上的有机连接基团。 还公开了含有至少一种多次甲基化合物或其反应残余物的防晒制剂和聚合物组合物。

公开(公告)号：US5442086A

公开(公告)日：1995-08-15

申请号：US308863

申请日：1994-09-19

申请人： James J. Krutak ,  Max A. Weaver ,  Clarence A. Coates, Jr. ,  Samuel D. Hilbert ,  Terry A. Oldfield ,  William W. Parham ,  Wayne P. Pruett

发明人： James J. Krutak ,  Max A. Weaver ,  Clarence A. Coates, Jr. ,  Samuel D. Hilbert ,  Terry A. Oldfield ,  William W. Parham ,  Wayne P. Pruett

IPC分类号： A61K8/00 ,  A61K8/04 ,  A61K8/40 ,  A61K8/46 ,  A61K8/85 ,  A61Q17/04 ,  C07C69/734 ,  C07C69/736 ,  C07C255/23 ,  C07C255/32 ,  C07C255/34 ,  C07C255/37 ,  C07C255/41 ,  C07C255/53 ,  C07C271/26 ,  C07C317/46 ,  C07C321/28 ,  C07C323/12 ,  C07C323/19 ,  C07C323/32 ,  C07C323/62 ,  C08G63/16 ,  C08G63/20 ,  C08G63/44 ,  C08G63/676 ,  C08G63/685 ,  C08G63/688 ,  C08G85/00 ,  C08J5/18 ,  C08K5/00 ,  C08L67/00 ,  C08L67/02 ,  C09K3/00 ,  C07C255/00

CPC分类号： A61Q17/04 ,  A61K8/40 ,  A61K8/46 ,  A61K8/85 ,  C07C255/41 ,  C08G63/676 ,  C08G63/6858 ,  C08G63/6888 ,  C08G85/00 ,  Y10S514/938 ,  Y10T428/13 ,  Y10T428/1352

摘要： Disclosed are certain poly-methine compounds having the formula ##STR1## wherein each R.sup.1 is independently selected from cyano; carboxy; alkenyloxycarbonyl; an unsubstituted or substituted alkoxycarbonyl, cycloalkoxycarbonyl or aryloxycarbonyl radical; an unsubstituted or substituted, carbocyclic or heterocyclic aryl radical; an unsubstituted or substituted alkanoyl, cycloalkanoyl or aroyl radical; an unsubstituted or substituted carbamoyl radical; or an unsubstituted or substituted alkylsulfonyl, cycloalkylsulfonyl or arylsulfonyl radical; each R.sup.2 is independently selected from cyano or an unsubstituted or substituted alkoxycarbonyl, cycloalkoxycarbonyl or aryloxycarbonyl radical; each A is independently selected from an unsubstituted or substituted 1,2-phenylene or 1,2-naphthylene radical; each Z is independently selected from --0-- or --S--; and L is an organic linking group bonded by non-oxo carbon atoms to each Z atom. Also disclosed are sunscreen formulations and polymeric compositions containing at least one of the poly-methine compounds or the reactive residue thereof.

摘要翻译： 公开了具有式“IMAGE”的某些聚次甲基化合物，其中每个R 1独立地选自氰基; 羧基; 烯氧基羰基; 未取代或取代的烷氧基羰基，环烷氧基羰基或芳氧基羰基; 未取代或取代的碳环或杂环芳基; 未取代或取代的烷酰基，环烷酰基或芳酰基; 未取代或取代的氨基甲酰基; 或未取代或取代的烷基磺酰基，环烷基磺酰基或芳基磺酰基; 每个R 2独立地选自氰基或未取代或取代的烷氧基羰基，环烷氧基羰基或芳氧基羰基; 每个A独立地选自未取代或取代的1,2-亚苯基或1,2-亚萘基; 每个Z独立地选自-O-或-S-; L是通过非氧代碳原子键合到每个Z原子上的有机连接基团。 还公开了含有至少一种多次甲基化合物或其反应残余物的防晒制剂和聚合物组合物。

公开(公告)号：US5302740A

公开(公告)日：1994-04-12

申请号：US968917

申请日：1992-10-30

申请人： James J. Krutak ,  Max A. Weaver ,  Clarence A. Coates, Jr. ,  Samuel D. Hilbert ,  Terry A. Oldfield ,  William W. Parham ,  Wayne P. Pruett

发明人： James J. Krutak ,  Max A. Weaver ,  Clarence A. Coates, Jr. ,  Samuel D. Hilbert ,  Terry A. Oldfield ,  William W. Parham ,  Wayne P. Pruett

IPC分类号： A61K8/00 ,  A61K8/04 ,  A61K8/40 ,  A61K8/46 ,  A61K8/85 ,  A61Q17/04 ,  C07C69/734 ,  C07C69/736 ,  C07C255/23 ,  C07C255/32 ,  C07C255/34 ,  C07C255/37 ,  C07C255/41 ,  C07C255/53 ,  C07C271/26 ,  C07C317/46 ,  C07C321/28 ,  C07C323/12 ,  C07C323/19 ,  C07C323/32 ,  C07C323/62 ,  C08G63/16 ,  C08G63/20 ,  C08G63/44 ,  C08G63/676 ,  C08G63/685 ,  C08G63/688 ,  C08G85/00 ,  C08J5/18 ,  C08K5/00 ,  C08L67/00 ,  C08L67/02 ,  C09K3/00

CPC分类号： A61Q17/04 ,  A61K8/40 ,  A61K8/46 ,  A61K8/85 ,  C07C255/41 ,  C08G63/676 ,  C08G63/6858 ,  C08G63/6888 ,  C08G85/00 ,  Y10S514/938 ,  Y10T428/13 ,  Y10T428/1352

摘要： Disclosed are certain poly-methine compounds having the formula ##STR1## wherein each R.sup.1 is independently selected from cyano; carboxy; alkenyloxycarbonyl; an unsubstituted or substituted alkoxycarbonyl, cycloalkoxycarbonyl or aryloxycarbonyl radical; an unsubstituted or substituted, carbocyclic or heterocyclic aryl radical; an unsubstituted or substituted alkanoyl, cycloalkanoyl or aroyl radical; an unsubstituted or substituted carbamoyl radical; or an unsubstituted or substituted alkylsulfonyl, cycloalkylsulfonyl or arylsulfonyl radical; each R.sup.2 is independently selected from cyano or an unsubstituted or substituted alkoxycarbonyl, cycloalkoxycarbonyl or aryloxycarbonyl radical; each A is independently selected from an unsubstituted or substituted 1,2-phenylene or 1,2-naphthylene radical; each Z is independently selected from --O-- or --S--; and L is an organic linking group bonded by non-oxo carbon atoms to each Z atom. Also disclosed are sunscreen formulations and polymeric compositions containing at least one of the poly-methine compounds or the reactive residue thereof.

摘要翻译： 公开了具有式“IMAGE”的某些聚次甲基化合物，其中每个R 1独立地选自氰基; 羧基; 烯氧基羰基; 未取代或取代的烷氧基羰基，环烷氧基羰基或芳氧基羰基; 未取代或取代的碳环或杂环芳基; 未取代或取代的烷酰基，环烷酰基或芳酰基; 未取代或取代的氨基甲酰基; 或未取代或取代的烷基磺酰基，环烷基磺酰基或芳基磺酰基; 每个R 2独立地选自氰基或未取代或取代的烷氧基羰基，环烷氧基羰基或芳氧基羰基; 每个A独立地选自未取代或取代的1,2-亚苯基或1,2-亚萘基; 每个Z独立地选自-O-或-S-; L是通过非氧代碳原子键合到每个Z原子上的有机连接基团。 还公开了含有至少一种多次甲基化合物或其反应残余物的防晒制剂和聚合物组合物。

公开(公告)号：US5057594A

公开(公告)日：1991-10-15

申请号：US395386

申请日：1989-08-17

申请人： James J. Krutak ,  Max A. Weaver ,  Clarence A. Coates, Jr. ,  Samuel D. Hilbert ,  Terry A. Oldfield ,  William W. Parham ,  Wayne P. Pruett

发明人： James J. Krutak ,  Max A. Weaver ,  Clarence A. Coates, Jr. ,  Samuel D. Hilbert ,  Terry A. Oldfield ,  William W. Parham ,  Wayne P. Pruett

IPC分类号： A61K8/00 ,  A61K8/04 ,  A61K8/40 ,  A61K8/46 ,  A61K8/85 ,  A61Q17/04 ,  C07C69/734 ,  C07C69/736 ,  C07C255/23 ,  C07C255/32 ,  C07C255/34 ,  C07C255/37 ,  C07C255/41 ,  C07C255/53 ,  C07C271/26 ,  C07C317/46 ,  C07C321/28 ,  C07C323/12 ,  C07C323/19 ,  C07C323/32 ,  C07C323/62 ,  C08G63/16 ,  C08G63/20 ,  C08G63/44 ,  C08G63/676 ,  C08G63/685 ,  C08G63/688 ,  C08G85/00 ,  C08J5/18 ,  C08K5/00 ,  C08L67/00 ,  C08L67/02 ,  C09K3/00

CPC分类号： A61Q17/04 ,  A61K8/40 ,  A61K8/46 ,  A61K8/85 ,  C07C255/41 ,  C08G63/676 ,  C08G63/6858 ,  C08G63/6888 ,  C08G85/00 ,  Y10S514/938 ,  Y10T428/13 ,  Y10T428/1352

摘要： Disclosed are certain poly-methine compounds having the formula ##STR1## wherein each R.sup.1 is independently selected from cyano; carboxy; alkenyloxycarbonyl; an unsubstituted or substituted alkoxycarbonyl, cycloalkoxycarbonyl or aryloxycarbonyl radical; an unsubstituted or substituted, carbocyclic or heterocyclic aryl radical; an unsubstituted or substituted alkanoyl, cycloalkanoyl or aroyl radical; an unsubstituted or substituted carbamoyl radical; or an unsubstituted or substituted alkylsulfonyl, cycloalkylsulfonyl or arylsulfonyl radical; each R.sup.2 is independently selected from cyano or an unsubstituted or substituted alkoxycarbonyl, cycloalkoxycarbonyl or aryloxycarbonyl radical; each A is independently selected from an unsubstituted or substituted 1,2-phenylene or 1,2-naphthylene radical; each Z is independently selected from --O-- or --S--; and L is an organic linking group bonded by non-oxo carbon atoms to each Z atom. Also disclosed are sunscreen formulations and polymeric compositions containing at least one of the poly-methine compounds or the reactive residue thereof.

公开(公告)号：US5030708A

公开(公告)日：1991-07-09

申请号：US628974

申请日：1990-12-17

申请人： James J. Krutak ,  William W. Parham ,  Clarence A. Coates, Jr. ,  Terry A. Oldfield ,  Wayne P. Pruett ,  Samuel D. Hilbert ,  Max A. Weaver

发明人： James J. Krutak ,  William W. Parham ,  Clarence A. Coates, Jr. ,  Terry A. Oldfield ,  Wayne P. Pruett ,  Samuel D. Hilbert ,  Max A. Weaver

IPC分类号： C08G63/685 ,  C08G63/688 ,  C09B23/00 ,  C09B23/01 ,  C09B69/10

CPC分类号： C09B69/105 ,  C08G63/685 ,  C08G63/688 ,  C09B23/00 ,  C09B23/0091

摘要： Provided are novel methine colorants derived from acetaldehyde, 1,3-dihydro-7-methoxycarbonyl-1,1,3-trimethyl-2H-benz[e]indol-2-ylidine and polyester compositions and concentrates having these colorants copolymerized therein. Also provided are novel intermediates useful for making the colorants.

摘要翻译： 提供衍生自乙醛，1,3-二氢-7-甲氧基羰基-1,1,3-三甲基-2H-苯并[e]吲哚-2-基，和具有这些着色剂的聚酯组合物和浓缩物的新型次甲基着色剂。 还提供了可用于制备着色剂的新型中间体。

公开(公告)号：US4999418A

公开(公告)日：1991-03-12

申请号：US401270

申请日：1989-08-31

申请人： James J. Krutak ,  Max A. Weaver ,  Clarence A. Coates, Jr. ,  Samuel D. Hilbert ,  Wayne P. Pruett ,  William W. Parham

发明人： James J. Krutak ,  Max A. Weaver ,  Clarence A. Coates, Jr. ,  Samuel D. Hilbert ,  Wayne P. Pruett ,  William W. Parham

IPC分类号： C08G63/685 ,  C08K5/18 ,  C08L67/00 ,  C08L67/02 ,  C09B1/26 ,  C09B69/10 ,  D01F6/62

CPC分类号： C09B1/26 ,  C08G63/6856 ,  C09B69/101

摘要： Disclosed are colored polyester compositions comprising a polyester having reacted therewith or copolymerized therein at least one residue of an anthraquinone compound having the formula ##STR1## wherein AQ is the residue of a 9,10-anthraquinone radical; R.sup.1 and R.sup.2 are the same or different and are unsubstituted or substituted alkyl, cycloalkyl or aryl; X is a group reactive with at least one of the functional groups of the monomers from which the polyester is prepared; and n is 1 or 2. The described anthraquinone compounds possess improved thermal stability and thus are not decomposed at the high temperatures at which polyesters are prepared. Also disclosed are shaped articles, particularly containers, fabricated from the colored polyester compositions.

公开(公告)号：US5274072A

公开(公告)日：1993-12-28

申请号：US878273

申请日：1992-05-04

申请人： Max A. Weaver ,  James J. Krutak ,  Clarence A. Coates, Jr. ,  William W. Parham ,  Wayne P. Pruett ,  Samuel D. Hilbert

发明人： Max A. Weaver ,  James J. Krutak ,  Clarence A. Coates, Jr. ,  William W. Parham ,  Wayne P. Pruett ,  Samuel D. Hilbert

IPC分类号： C07D413/04 ,  C07D413/14 ,  C07D417/14 ,  C08G63/685 ,  C08G63/688 ,  C08L101/00 ,  C08G63/08 ,  C07D277/62 ,  C07D307/02

CPC分类号： C07D413/14 ,  C07D413/04 ,  C07D417/14 ,  C08G63/685 ,  C08G63/688 ,  C08L101/00

摘要： Provided are certain novel substituted 2(5H)furanone compounds which are useful as ultraviolet/visible light absorbing compounds. Also provided are polyester compositions having such compounds copolymerized therein and shaped or formed articles comprised of such polyester compositions.

摘要翻译： 提供可用作紫外/可见光吸收化合物的某些新的取代的2（5H）呋喃酮化合物。 还提供了具有共聚合的这种化合物的聚酯组合物和由这种聚酯组合物组成的成形或成型制品。

公开(公告)号：US5106942A

公开(公告)日：1992-04-21

申请号：US461961

申请日：1990-01-08

申请人： James J. Krutak ,  William W. Parham ,  Max A. Weaver ,  Clarence A. Coates, Jr. ,  Terry A. Oldfield

发明人： James J. Krutak ,  William W. Parham ,  Max A. Weaver ,  Clarence A. Coates, Jr. ,  Terry A. Oldfield

IPC分类号： C07D209/08 ,  C07D215/12 ,  C07D265/36 ,  C08G63/685 ,  C09B67/44 ,  C09B69/10

CPC分类号： C08G63/6858 ,  C09B69/105

摘要： Disclose are polyester color concentrates, especially amorphous and partially-crystalline, polyester color concentrates, comprising a polyester having copolymerized therein colored residues of at least one polyester-reactive, thermally-stable methine colorant compound. The color concentrates may be used to impart yellow shades and colors to various polymeric materials, shaped articles fabricated of and coatings formulated from such polymeric materials and, especially, personal, medical and home care products where non-extractability of the colorant material is essential. Also disclosed are colored semicrystalline powders derived from the color concentrates.

摘要翻译： 折叠是聚酯颜色浓缩物，特别是无定形和部分结晶的聚酯彩色浓缩物，其包含在其中共聚有至少一种聚酯反应性热稳定的次甲基着色剂化合物的着色残余物的聚酯。 颜色浓缩物可以用于赋予各种聚合物材料，由这些聚合材料制成的成型制品和由此类聚合材料配制的涂层，特别是着色剂材料的不可萃取性是必需的个人，医疗和家庭护理产品的黄色色调和颜色。 还公开了衍生自颜色浓缩物的着色半结晶粉末。

公开(公告)号：US5032670A

公开(公告)日：1991-07-16

申请号：US400423

申请日：1989-08-30

申请人： William W. Parham ,  James J. Krutak ,  Max A. Weaver ,  Clarence A. Coates, Jr. ,  Terry A. Oldfield

发明人： William W. Parham ,  James J. Krutak ,  Max A. Weaver ,  Clarence A. Coates, Jr. ,  Terry A. Oldfield

IPC分类号： C08G63/685 ,  C08G73/00 ,  C08J3/02 ,  C08J3/20 ,  C08J3/22 ,  C09B1/16 ,  C09B1/28 ,  C09B69/10

CPC分类号： A61K8/355 ,  A61K8/85 ,  C08G63/6856 ,  C08J3/226 ,  C09B1/285 ,  C09B69/101 ,  A61K2800/43 ,  A61K2800/57 ,  C08J2467/00

摘要： Disclosed are color concentrate compositions which comprise a polyester having copolymerized therein at least 0.5 weight percent of an anthraquinone colorant compound having the formula ##STR1## wherein AQ is a 1,5- or 1,8-anthraquinonylene radical; R.sup.1 and R.sup.2 are the same or different and are unsubstituted or substituted alkyl, cycloalkyl or aryl; and X is a group reactive with at least one of the functional groups of the monomers from which the polyester is prepared. Amorphous polyesters and partially-crystalline polyesters are preferred embodiments of the color concentrates. Also disclosed are colored semicrystalline powders which may be obtained from the amorphous and partially-crystalline color concentrates by a dissolution-crystallization-precipitation procedure.

公开(公告)号：US4749774A

公开(公告)日：1988-06-07

申请号：US78434

申请日：1987-07-27

申请人： Max A. Weaver ,  Clarence A. Coates, Jr. ,  Wayne P. Pruett ,  Samuel D. Hilbert

发明人： Max A. Weaver ,  Clarence A. Coates, Jr. ,  Wayne P. Pruett ,  Samuel D. Hilbert

IPC分类号： C08F299/04 ,  C08F283/01 ,  C08G63/44 ,  C08G63/46 ,  C08G63/52 ,  C08G63/68 ,  C08G63/685 ,  C08G64/04 ,  C08L67/02 ,  C08G63/76 ,  C08G69/44

CPC分类号： C07C255/00 ,  C08G63/52 ,  C08G63/6858 ,  C08G64/045

摘要： Composition useful for molding into articles which as food containers, beverage bottles, cured structural plastics and the like comprising molding grade linear or unsaturated polyester or polycarbonate having reacted therewith or copolymerized therein the residue of one or more poly-methine compounds having the formula: ##STR1## wherein each R.sup.1 is independently selected from cyano, carboxy, alkenyloxycarbonyl, or a substituted or unsubstituted alkoxycarbonyl, cycloalkoxoycarbonyl or aryloxycarbonyl radical;each R.sup.2 is independently selected from one of the groups specified for R.sup.1 or an unsubstituted or substituted aryl, carbamoyl, alkanoyl, cycloalkanoyl, aroyl, alkylsulfonyl, cycloalkylsulfonyl, arylsulfonyl or aromatic, heterocyclic radical;each R.sup.3 is independently selected from hydrogen or an unsubstituted or substituted alkyl, cycloalkyl or aryl radical;A.sup.1 and A.sup.2 are independently selected from 1,4-phenylene radicals; andL is an organic linking group bonded by non-oxo carbon atoms to the oxygen atoms adjacent to L; provided the poly-methine compound bears at least one substituent that is reactive with one of the monomers from which the condensation polymer is derived.The polymethine residues are present in the polymer as an integral part of the polymer chain and absorb ultraviolet radiation in the range of about 250 to about 390 nm. The residues are non-extractable from the polymer and stable at the conditions at which the polymers are manufactured and processed.