公开(公告)号：US5182350A

公开(公告)日：1993-01-26

申请号：US605679

申请日：1990-10-30

申请人： James V. Fusco ,  Hsien-Chang Wang ,  Kenneth W. Powers

发明人： James V. Fusco ,  Hsien-Chang Wang ,  Kenneth W. Powers

IPC分类号： C08F210/12

CPC分类号： C08F210/12

摘要： Ozone resistant vulcanizable copolymers of isoolefins with non-conjugated dienes of the general formula: ##STR1## where R.sub.1 is ##STR2## and R.sub.2 is alkyl of 1 to 6 carbon atoms and vulcanizates thereof. The copolymers are prepared by polymerization in the presence of Lewis acids.

摘要翻译： 异烯烃与具有以下通式的非共轭二烯的耐臭氧可硫化共聚物：其中R 1是R 1和R 2是1至6个碳原子的烷基和其硫化产物。 共聚物通过在路易斯酸存在下聚合制备。

公开(公告)号：US5182333A

公开(公告)日：1993-01-26

申请号：US791764

申请日：1991-11-12

申请人： Kenneth W. Powers ,  Hsien-Chang Wang ,  Debra C. Handy ,  James V. Fusco

发明人： Kenneth W. Powers ,  Hsien-Chang Wang ,  Debra C. Handy ,  James V. Fusco

IPC分类号： C08F10/10 ,  C08L23/22 ,  C08L23/28

CPC分类号： C08L23/22 ,  C08F10/10 ,  C08L23/283 ,  Y10S525/918

摘要： A substantially gel free C.sub.4 to C.sub.7 isoolefin homopolymer rubber, butyl copolymer rubber, halogenated butyl rubber (e.g., chlorinated or brominated), or mixtures thereof, comprising a molecular weight distribution such that the ratio of the moments of said molecular weight distribution, Mz/Mw, is equal to or exceeds 2.0, and that portion of said molecular weight distribution which is equal to and greater than 4 times the peak molecular weight, Mp, comprises greater than 8 percent of the total polymer species, and Mp is greater than about 250,000 and wherein said polymer species of molecular weight less than Mp are substantially branch free. Various means are disclosed for effecting the molecular weight distribution including blending of homopolymers and/or copolymers of appropriate molecular weight and molecular weight distribution and direct polymerization using a functional reagent to introduce branching. The rubber compositions are particularly useful in applications in which butyl or halogenated butyl rubber is used and where it is desired to obtain high green strength in combination with an increased rate of stress relaxation. Such polymers are particularly well suited for use in tire innerliner compositions.

摘要翻译： 基本上不含凝胶的C4至C7异烯烃均聚物橡胶，丁基共聚物橡胶，卤化丁基橡胶（例如，氯化或溴化）或其混合物，其包含分子量分布，使得所述分子量分布的时间比Mz / Mw等于或超过2.0，等于和大于峰分子量Mp的4倍的分子量分布的那部分包含大于总聚合物种类的8％，并且M p大于约 250,000，并且其中分子量小于Mp的所述聚合物种类基本上无分支。 公开了用于实现分子量分布的各种方法，包括使用适当的分子量和分子量分布的均聚物和/或共聚物的共混，并使用官能试剂引入支化的直接聚合。 橡胶组合物在使用丁基或卤代丁基橡胶的应用中特别有用，并且其中期望获得高的绿色强度并且结合增加的应力松弛速率。 这种聚合物特别适用于轮胎内衬组合物。

公开(公告)号：US5071913A

公开(公告)日：1991-12-10

申请号：US131938

申请日：1987-12-11

申请人： Kenneth W. Powers ,  Hsien-Chang Wang ,  Debra C. Handy ,  James V. Fusco

发明人： Kenneth W. Powers ,  Hsien-Chang Wang ,  Debra C. Handy ,  James V. Fusco

IPC分类号： C08L23/20 ,  B60C1/00 ,  C08F10/10 ,  C08F210/12 ,  C08L23/18 ,  C08L23/22 ,  C08L23/28

CPC分类号： B60C1/0008 ,  C08F10/10 ,  C08F210/12 ,  C08L23/22 ,  C08L23/283 ,  Y10S525/918

摘要： A substantially gel free C.sub.4 to C.sub.7 isoolefin homopolymer rubber, butyl copolymer rubber, halogenated butyl rubber (e.g., chlorinated or brominated), or mixtures thereof, comprising a molecular weight distribution such that the ratio of the moments of said molecular weight distribution, Mz/Mw, is equal to or exceeds 2.0, and that portion of said molecular weight distribution which is equal to and greater than 4 times the peak molecular weight, Mp, comprises greater than 8 percent of the total polymer species, and Mp is greater than about 250,000 and wherein said polymer species of molecular weight less than Mp are substantially branch free. Various means are disclosed for effecting the molecular weight distribution including blending of homopolymers and/or copolymers of appropriate molecular weight and molecular weight distribution and direct polymerization using a functional reagent to introduce branching. The rubber compositions are particularly useful in applications in which butyl or halogenated butyl rubber is used and where it is desired to obtain high green strength in combination with an increased rate of stress relaxation. Such polymers are particularly well suited for use in tire innerliner compositions.

公开(公告)号：US5286804A

公开(公告)日：1994-02-15

申请号：US761211

申请日：1991-09-17

申请人： Kenneth W. Powers ,  Hsien C. Wang ,  Robert N. Webb ,  James V. Fusco ,  Hans F. Vanbrackle ,  Michael F. McDonald, Jr.

发明人： Kenneth W. Powers ,  Hsien C. Wang ,  Robert N. Webb ,  James V. Fusco ,  Hans F. Vanbrackle ,  Michael F. McDonald, Jr.

IPC分类号： C08C19/12 ,  C08F8/20 ,  C08F210/12 ,  C08F8/18

CPC分类号： C08F8/20

摘要： A process for halogenating star-branched butyl rubber is provided wherein water and a wetting agent or wetting agent precursor are added to a solution comprising the star-branched butyl rubber, solid particles of branching agent and an organic solvent prior to the neutralization step to increase the rate of neutralization of the hydrogen halide by-product of the halogenation reaction.

摘要翻译： 提供了一种卤化星形支链丁基橡胶的方法，其中在中和步骤之前，将水和润湿剂或润湿剂前体加入到包含星形支链丁基橡胶，支化剂固体颗粒和有机溶剂的溶液中以增加 卤化反应的卤化氢副产物的中和速率。

公开(公告)号：US5426167A

公开(公告)日：1995-06-20

申请号：US182911

申请日：1994-01-14

申请人： Kenneth W. Powers ,  Hsien-Chang Wang

发明人： Kenneth W. Powers ,  Hsien-Chang Wang

IPC分类号： C08F8/00 ,  C08F8/20 ,  C08F210/08 ,  C08F210/10 ,  C08F210/14 ,  C08F212/12 ,  C08G81/02 ,  C08L23/02 ,  C08L23/22 ,  C08L23/28 ,  C08L71/12

CPC分类号： C08F8/00 ,  C08F210/08 ,  C08F210/10 ,  C08F210/14 ,  C08F212/12 ,  C08F8/20 ,  C08G81/021 ,  C08L23/02 ,  C08L23/22 ,  C08L23/283 ,  C08L71/123 ,  Y02P20/582 ,  Y10S526/912

摘要： A copolymer having a substantially homogeneous composition distribution, said copolymer comprising the direct reaction product of an isoolefin and para-alkylstyrene.

摘要翻译： 具有基本均匀的组成分布的共聚物，所述共聚物包含异烯烃和对烷基苯乙烯的直接反应产物。

公开(公告)号：US5162445A

公开(公告)日：1992-11-10

申请号：US442028

申请日：1989-11-27

申请人： Kenneth W. Powers ,  Hsien-Chang Wang ,  T-C Chung ,  Anthony J. Dias ,  Joseph A. Olkusz

发明人： Kenneth W. Powers ,  Hsien-Chang Wang ,  T-C Chung ,  Anthony J. Dias ,  Joseph A. Olkusz

IPC分类号： C08F8/00 ,  C08F8/20 ,  C08F210/08 ,  C08F210/10 ,  C08F210/14 ,  C08F212/12 ,  C08G81/02 ,  C08L23/02 ,  C08L23/22 ,  C08L23/28 ,  C08L71/12

CPC分类号： C08L23/283 ,  C08F210/08 ,  C08F210/10 ,  C08F210/14 ,  C08F212/12 ,  C08F8/00 ,  C08F8/20 ,  C08G81/021 ,  C08L23/02 ,  C08L23/22 ,  C08L71/123 ,  Y02P20/582 ,  Y10S526/912

摘要： A copolymer of a C.sub.4 to C.sub.7 isoolefin and a para-alkylstyrene is provided as well as the corresponding halogenated, functionalized and grafted derivatives thereof. Processes for producing these copolymers are also provided.

摘要翻译： 提供C4至C7异烯烃与对烷基苯乙烯的共聚物及其相应的卤化官能化和接枝衍生物。 还提供了制备这些共聚物的方法。

公开(公告)号：US5430118A

公开(公告)日：1995-07-04

申请号：US181713

申请日：1994-01-14

申请人： Kenneth W. Powers ,  Hsien-Chang Wang

发明人： Kenneth W. Powers ,  Hsien-Chang Wang

IPC分类号： C08F8/00 ,  C08F8/20 ,  C08F210/08 ,  C08F210/10 ,  C08F210/14 ,  C08F212/12 ,  C08G81/02 ,  C08L23/02 ,  C08L23/22 ,  C08L23/28 ,  C08L71/12

CPC分类号： C08F8/00 ,  C08F210/08 ,  C08F210/10 ,  C08F210/14 ,  C08F212/12 ,  C08F8/20 ,  C08G81/021 ,  C08L23/02 ,  C08L23/22 ,  C08L23/283 ,  C08L71/123 ,  Y02P20/582 ,  Y10S526/912

摘要： A copolymer having a substantially homogeneous composition distribution, said copolymer comprising the direct reaction product of an isoolefin and para-alkylstrene.

摘要翻译： 具有基本均匀的组成分布的共聚物，所述共聚物包含异烯烃和对位烷基酯的直接反应产物。

公开(公告)号：US5548029A

公开(公告)日：1996-08-20

申请号：US404803

申请日：1995-03-15

申请人： Kenneth W. Powers ,  Hsien-Chang Wang ,  T-C. Chung ,  Anthony J. Dias ,  Joseph A. Olkusz

发明人： Kenneth W. Powers ,  Hsien-Chang Wang ,  T-C. Chung ,  Anthony J. Dias ,  Joseph A. Olkusz

IPC分类号： C08F8/00 ,  C08F8/20 ,  C08G81/02 ,  C08L23/02 ,  C08L23/22

CPC分类号： C08L23/22 ,  C08F8/00 ,  C08F8/20 ,  C08G81/021 ,  C08L23/02 ,  Y02P20/582

摘要： Graft copolymers which are isoolefin/para-alkylstyrene copolymer represented by the formula ##STR1## in which R and R' can be hydrogen, alkyl, and the primary and secondary alkyl halides, "a" ranges from about 14 to about 70,000, "b" ranges from 0 to about 70,000, "c" ranges from 0 to about 70,000, "d" ranges from about 1 to about 70,000, X is a halogen, and Nu is a nucleophilic residue provided by a polymeric nucleophile.

摘要翻译： 作为其中R和R'可以是氢，烷基和伯和仲烷基卤化物的式“IMAGE”表示的异烯烃/对烷基苯乙烯共聚物的接枝共聚物，“a”为约14至约70,000，“b “为0至约70,000，”c“为0至约70,000，”d“为约1至约70,000，X为卤素，Nu为由聚合物亲核试剂提供的亲核残基。

公开(公告)号：US5548023A

公开(公告)日：1996-08-20

申请号：US402792

申请日：1995-03-13

申请人： Kenneth W. Powers ,  Hsien-Chang Wang ,  T-C. Chung ,  Anthony J. Dias ,  Joseph A. Olkusz

发明人： Kenneth W. Powers ,  Hsien-Chang Wang ,  T-C. Chung ,  Anthony J. Dias ,  Joseph A. Olkusz

IPC分类号： C08F8/00 ,  C08F8/20 ,  C08G81/02 ,  C08L23/02 ,  C08L23/22 ,  C08L25/16

CPC分类号： C08L23/22 ,  C08F8/00 ,  C08F8/20 ,  C08G81/021 ,  C08L23/02 ,  Y02P20/582

摘要： A method of compatibilizing a blend of at least a hydrocarbon polymer with at least one other polymer which is incompatible with the hydrocarbon polymer, said method comprising adding to the polymer blend a compatibilizer which is an isoolefin/para-alkylstyrene copolymer represented by the formula ##STR1## in which R and R' can be hydrogen, alkyl, and the primary and secondary alkyl halides, "a" ranges from about 14 to about 70,000, "b" ranges from 0 to about 70,000, "c" ranges from 0 to about 70,000, "d" ranges from about 1 to about 70,000, X is a halogen, and Nu is a nucleophilic residue provided by a polymeric nucleophile.

摘要翻译： 一种使至少一种烃聚合物与至少一种与烃聚合物不相容的其它聚合物的共混物相容的方法，所述方法包括向聚合物共混物中加入作为由式I表示的异烯烃/对烷基苯乙烯共聚物的增容剂 ，并且伯和仲烷基卤化物“a”的范围为约14至约70,000，“b”为0至约70,000，“c”为0至约70,000，“d”为约1至约70,000 ，X是卤素，Nu是由聚合物亲核试剂提供的亲核残基。

公开(公告)号：US5244961A

公开(公告)日：1993-09-14

申请号：US762284

申请日：1991-09-19

申请人： Thomas C. Yu ,  Hsien C. Wang ,  Kenneth W. Powers

发明人： Thomas C. Yu ,  Hsien C. Wang ,  Kenneth W. Powers

IPC分类号： C08K3/10 ,  C08K3/22 ,  C08L23/00 ,  C08L23/18 ,  C08L23/20 ,  C08L23/28 ,  C08L25/00 ,  C08L25/16 ,  C08L25/18 ,  C08L77/00

CPC分类号： C08L23/283 ,  C08K3/22 ,  C08L77/00

摘要： A non-vulcanized thermoplastic composition comprising a polyamide and an elastomeric halogen-containing copolymer of a C.sub.4 to C.sub.7 isomonoolefin and a para-alkylstyrene is prepared by blending the polyamide and elastomeric copolymer in the presence of specified metal compounds in an amount insufficient for vulcanizing the composition. Optionally, the resulting composition may be subjected to vulcanization.

摘要翻译： 包含聚酰胺和C4-C7异单烯烃和对烷基苯乙烯的弹性体含卤素共聚物的非硫化热塑性组合物通过在特定金属化合物的存在下共混聚酰胺和弹性体共聚物而制备，其量不足以硫化 组成。 任选地，所得组合物可以进行硫化。