摘要:
A non-vulcanized thermoplastic composition comprising a polyamide and an elastomeric halogen-containing copolymer of a C.sub.4 to C.sub.7 isomonoolefin and a para-alkylstyrene is prepared by blending the polyamide and elastomeric copolymer in the presence of specified metal compounds in an amount insufficient for vulcanizing the composition. Optionally, the resulting composition may be subjected to vulcanization.
摘要:
Transparent and colorable elastomeric compositions are provided. The transparent elastomeric compositions can be covulcanized with rubbers such as polybutadiene, polyisoprene, styrene-butadiene rubber, styrene-isoprene-butadiene rubber, isoprene-butadiene rubber, ethylene-propylene diene rubber or natural rubber. The colorable rubber compositions have sufficient properties to function as a reinforcing member in an automobile tire. Preferably, both the transparent and colorable elastomeric compositions include at least one copolymer of a C4 to C7 isoolefin and a para-alkylstyrene, silica and a coupling agent.
摘要:
This invention provides for curable and graft-cured polymer compositions prepared from a mixture comprising:a) an elastomeric copolymer containing from about 0.01 up to about 10 mole % of Y ester groups randomly distributed along and pendant to the elastomeric polymer chain, said Y ester groups having the structure: ##STR1## wherein R.sub.2 and R.sub.3 are independently selected from the group consisting of hydrogen and an alkyl group containing 1 to about 6 carbon atoms and R.sub.4 is selected from the group consisting of hydrogen, an alkyl group containing from 1 to about 28 carbon atoms, an aryl group and an alkenyl group containing from 2 to about 28 carbon atoms; andb) at least one free radically polymerizable monomer. The invention also provides for a process for preparing graft-cured polymer compositions comprising forming the above recited mixture of (a) and (b) and subjecting said mixture to free radical polymerization conditions. The Y ester groups pendant to the elastomeric polymer chain, e.g. benzylic(meth)acrylic acid ester groups present in isobutylene/para-methystyrene interpolymer chains, are capable of participating in free radical initiated reactions with monofunctional or polyfunctional free radically polymerizable monomers to produce graft-crosslinked compositions having an unusual balance of physical properties. These compositions may be formed into shaped articles such as films, coatings, adhesive layers and moldings and subjected to free radical polymerization conditions to produce crosslinked shaped articles.
摘要:
The invention relates to impact modifiers for polyamide compositions which improve the impact strength of the polyamides without adversely affecting the flexural modulus of the composition. The impact modifiers comprise blends of halogenated copolymers of a C.sub.4 to C.sub.7 isomonoolefin and an alkyl/styrene with a polyolefin.
摘要:
A dynamically vulcanized thermoplastic composition is provided which comprises a polymer blend of a thermoplastic olefinic resin, and an elastomeric halogen-containing copolymer of a C.sub.4 to C.sub.7 isomonoolefin and a paraalkylstyrene. A process for preparing the dynamically vulcanized composition is also provided.
摘要:
A non-vulcanized thermoplastic composition comprising a polyamide and an elastomeric halogen-containing copolymer of a C.sub.4 to C.sub.7 isomonoolefin and a para-alkylstyrene is prepared by blending the polyamide and elastomeric copolymer in the presence of specified metal compounds in an amount insufficient for vulcanizing the composition. Optionally, the resulting composition may be subjected to vulcanization.
摘要:
A grafted polymer of an isomonoolefin and an alkylstyrene, such as a maleic anhydride-grafted copolymer of isobutylene and para-methylstyrene, is provided. Processes for preparing the grafted polymer are also provided.
摘要:
A process for halogenating star-branched butyl rubber is provided wherein water and a wetting agent or wetting agent precursor are added to a solution comprising the star-branched butyl rubber, solid particles of branching agent and an organic solvent prior to the neutralization step to increase the rate of neutralization of the hydrogen halide by-product of the halogenation reaction.
摘要:
A thermoplastic composition is provided which comprises a polyamide, a grafted polymer of an isomonoolefin and an alkylstyrene, such as a maleic anhydride-grafted copolymer of isobutylene and para-methylstyrene, and optionally a polyolefin polymer.
摘要:
Polymerization slurries of elastomeric isoolefin homopolymers and copolymers, such as butyl rubber, in diluents such as methyl chloride are effectively stabilized against agglomeration of polymer particles through addition of minor proportions of an hydrogenated preformed copolymer stabilizer having both a lyophobic and a lyophilic portion. The chemical and structural nature of the lyophobic and lyophilic portions which comprise the copolymer stabilizer are significant in determining the extent and method of hydrogenation for production of the most effective stabilizer. Agglomeration of polymer products is effectively prevented, yielding a number of significant processing advantages. The process is especially adaptable to the production of isobutylene-isoprene butyl rubber.