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公开(公告)号：US07799956B2
公开(公告)日：2010-09-21
申请号：US11660065
申请日：2005-08-05
申请人： Jane Chi-ya Cheng , John S. Buchanan , Doron Levin , Michael A. Steckel , Jihad M. Dakka , James P. Stokes , John L. Robbins , Jon E. Stanat , Charles M. Smith , José G. Santiesteban
发明人： Jane Chi-ya Cheng , John S. Buchanan , Doron Levin , Michael A. Steckel , Jihad M. Dakka , James P. Stokes , John L. Robbins , Jon E. Stanat , Charles M. Smith , José G. Santiesteban
CPC分类号： C07C37/08 , C07C45/53 , C07C409/08 , C07C2529/70 , Y02P20/127 , Y02P20/52 , C07C49/10 , C07C39/04
摘要： A process for producing phenol and methyl ethyl ketone comprises contacting benzene with a C4 alkylating agent under alkylation conditions with catalyst comprising zeolite beta or a molecular sieve having an X-ray diffraction pattern including d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07 Angstrom to produce an alkylation effluent comprising sec-butylbenzene. The sec-butylbenzene is then oxidized to produce a hydroperoxide and the hydroperoxide is decomposed to produce phenol and methyl ethyl ketone.
摘要翻译： 一种生产苯酚和甲基乙基酮的方法包括在烷基化条件下使苯与C4烷基化剂与包含β沸石的催化剂或具有包含d-间距最大值的X射线衍射图的分子筛在12.4±0.25,6.9±0.15， 3.57±0.07和3.42±0.07埃，以产生包含仲丁基苯的烷基化流出物。 然后将仲丁基苯氧化生成氢过氧化物，氢过氧化物分解生成苯酚和甲基乙基酮。
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公开(公告)号：US07910778B2
公开(公告)日：2011-03-22
申请号：US12665154
申请日：2008-07-11
IPC分类号： C07C45/27 , C07C27/08 , C07C2/68 , C07C15/067
CPC分类号： C07C6/126 , C07C2/74 , C07C37/07 , C07C37/08 , C07C45/53 , C07C407/00 , C07C409/14 , C07C2521/04 , C07C2521/06 , C07C2523/06 , C07C2523/14 , C07C2523/44 , C07C2523/46 , C07C2523/75 , C07C2523/755 , C07C2601/14 , Y02P20/52 , C07C13/28 , C07C49/403 , C07C39/04
摘要： In a process for producing cyclohexylbenzene, benzene and hydrogen are contacted with a catalyst under hydroalkylation conditions to produce an effluent containing cyclohexylbenzene. The catalyst comprises a composite of a molecular sieve, an inorganic oxide different from said molecular sieve and at least one hydrogenation metal, wherein at least 50 wt % of said hydrogenation metal is supported on the inorganic oxide.
摘要翻译： 在生产环己基苯的方法中，苯和氢在加氢烷基化条件下与催化剂接触以产生含有环己基苯的流出物。 催化剂包括分子筛，不同于所述分子筛的无机氧化物和至少一种氢化金属的复合物，其中至少50wt％的所述氢化金属负载在无机氧化物上。
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3.发明申请USE OF LOW BOILING POINT AROMATIC SOLVENT IN HYDROPROCESSING HEAVY HYDROCARBONS 有权低沸点芳香族溶剂在氢化重油中的应用公开(公告)号：US20130081978A1
公开(公告)日：2013-04-04
申请号：US13597582
申请日：2012-08-29
IPC分类号： C10G47/00
CPC分类号： C10G45/00 , C10G45/02 , C10G45/32 , C10G45/44 , C10G45/58 , C10G47/00 , C10G2300/1037 , C10G2300/107 , C10G2300/1077 , C10G2300/202 , C10G2300/205 , C10G2300/206 , C10G2300/44
摘要： This invention is directed to a process for producing a hydroprocessed product. The invention is particularly advantageous in that substantially less hydrogen is absorbed during the process relative to conventional hydroprocessing methods. This benefit is achieved by using a particular solvent as a co-feed component. In particular, the solvent component contains at least one single ring aromatic compound and has a relatively low boiling point range compared to the heavy hydrocarbon oil component used as another co-feed component.
摘要翻译： 本发明涉及一种加氢处理产物的生产方法。 本发明特别有利的是，相对于常规的加氢处理方法，在该方法中吸收相对较少的氢。 通过使用特定溶剂作为共进料组分来实现该益处。 特别地，溶剂组分含有至少一种单环芳族化合物，并且与用作另一种共进料组分的重质烃油组分相比具有相对较低的沸点范围。
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4.发明申请公开(公告)号：US20130081977A1
公开(公告)日：2013-04-04
申请号：US13597523
申请日：2012-08-29
CPC分类号： C10G45/00 , B01J23/74 , B01J23/883 , B01J23/8885 , B01J35/023 , B01J35/1038 , B01J35/1042 , B01J35/1061 , B01J37/0201 , B01J37/0207 , B01J37/20 , C10G45/02 , C10G45/04 , C10G45/32 , C10G45/44 , C10G45/58 , C10G47/00 , C10G47/02 , C10G49/02 , C10G49/22 , C10G67/0454 , C10G67/049 , C10G2300/1037 , C10G2300/107 , C10G2300/1077 , C10G2300/202 , C10G2300/205 , C10G2300/206 , C10G2300/301 , C10G2300/4006 , C10G2300/4012 , C10G2300/4018 , C10G2300/4081 , C10G2300/44 , C10L1/04
摘要： Heavy oil feeds are hydroprocessed in the presence of a solvent and in the presence of a catalyst with a median pore size of about 85 Å to about 120 Å under conditions that provide a variety of benefits. The solvent can be an added solvent or a portion of the liquid effluent from hydroprocessing. The processes allow for lower pressure processing of heavy oil feeds for extended processing times or extended catalyst lifetimes be reducing or mitigating the amount of coke formation on the hydroprocessing catalyst.
摘要翻译： 重油进料在溶剂存在下和在提供各种有益效果的条件下在中等孔径约为85至大约120的催化剂存在下进行加氢处理。 溶剂可以是加氢处理的添加溶剂或一部分液体流出物。 该方法允许重油进料的较低压力处理用于延长的处理时间或延长的催化剂寿命来减少或减轻加氢处理催化剂上焦炭形成的量。
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公开(公告)号：US09725327B2
公开(公告)日：2017-08-08
申请号：US14440946
申请日：2013-11-14
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , Machteld Maria Wilfried Mertens , Marc H. Anthonis , Antonie Jan Bons , Brita Engels , Wilfried Jozef Mortier , Jane Chi-ya Cheng
发明人： Machteld Maria Wilfried Mertens , Marc H. Anthonis , Antonie Jan Bons , Brita Engels , Wilfried Jozef Mortier , Jane Chi-ya Cheng
CPC分类号： C01B39/40 , B01J20/18 , B01J29/40 , C07C5/52 , C07C2529/44 , C07C2529/46 , C07C2529/48
摘要： A method of making a crystalline molecular sieve of MFI framework type, preferably ZSM-5, from a synthesis mixture comprising at least one source of tetravalent element (Y), at least one source of trivalent element (X), at least one source of alkali metal hydroxide (MOH), at least one structure directing; (R) and water, said synthesis mixture having the following molar composition: YO2, (p)X2O3: (q) MOH: (r) R: (s) H2O, wherein (p) is from 0.005 to 0.025, (q) is from 0.05 to 0.5, (r) is from 0.05 to 0.15 and (s) is from 35 to 45, wherein the ratio of the largest dimension (L) to the smallest dimension (S) of each crystal of the molecular sieve product is at least 5, and the smallest dimension (S) is from 20 nm to 200 nm.
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公开(公告)号：US09206363B2
公开(公告)日：2015-12-08
申请号：US13597598
申请日：2012-08-29
申请人： Hyung Suk Woo , Jane Chi-ya Cheng , Teh C. Ho , Stephen Harold Brown , Richard Charles Dougherty , David Thomas Ferrughelli , Federico Barrai
发明人： Hyung Suk Woo , Jane Chi-ya Cheng , Teh C. Ho , Stephen Harold Brown , Richard Charles Dougherty , David Thomas Ferrughelli , Federico Barrai
IPC分类号： C10G47/00 , C10G53/02 , C10G53/04 , C10G65/12 , C10G47/02 , C10G45/04 , C10G49/02 , C10G49/22 , C10G67/04 , B01J37/20 , B01J23/74 , B01J35/02 , B01J37/02 , B01J23/883 , B01J23/888 , B01J35/10
CPC分类号： C10G45/00 , B01J23/74 , B01J23/883 , B01J23/8885 , B01J35/023 , B01J35/1038 , B01J35/1042 , B01J35/1061 , B01J37/0201 , B01J37/0207 , B01J37/20 , C10G45/02 , C10G45/04 , C10G45/32 , C10G45/44 , C10G45/58 , C10G47/00 , C10G47/02 , C10G49/02 , C10G49/22 , C10G67/0454 , C10G67/049 , C10G2300/1037 , C10G2300/107 , C10G2300/1077 , C10G2300/202 , C10G2300/205 , C10G2300/206 , C10G2300/301 , C10G2300/4006 , C10G2300/4012 , C10G2300/4018 , C10G2300/4081 , C10G2300/44 , C10L1/04
摘要： Heavy oil feeds are hydroprocessed in the presence of a solvent under conditions that provide a variety of benefits. The solvent can be an added solvent or a portion of the liquid effluent from hydroprocessing. The processes allow for lower pressure processing of heavy oil feeds for extended processing times or extended catalyst lifetimes be reducing or mitigating the amount of coke formation on the hydroprocessing catalyst.
摘要翻译： 在提供各种益处的条件下，在溶剂存在下将重油进料加氢处理。 溶剂可以是加氢处理的添加溶剂或一部分液体流出物。 该方法允许重油进料的较低压力处理用于延长的处理时间或延长的催化剂寿命来减少或减轻加氢处理催化剂上焦炭形成的量。
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公开(公告)号：US20130161237A1
公开(公告)日：2013-06-27
申请号：US13597598
申请日：2012-08-29
申请人： Hyung Suk Woo , Jane Chi-ya Cheng , Teh C. Ho , Stephen Harold Brown , Richard Charles Dougherty , David Thomas Ferrughelli , Federico Barrai
发明人： Hyung Suk Woo , Jane Chi-ya Cheng , Teh C. Ho , Stephen Harold Brown , Richard Charles Dougherty , David Thomas Ferrughelli , Federico Barrai
IPC分类号： C10G67/04
CPC分类号： C10G45/00 , B01J23/74 , B01J23/883 , B01J23/8885 , B01J35/023 , B01J35/1038 , B01J35/1042 , B01J35/1061 , B01J37/0201 , B01J37/0207 , B01J37/20 , C10G45/02 , C10G45/04 , C10G45/32 , C10G45/44 , C10G45/58 , C10G47/00 , C10G47/02 , C10G49/02 , C10G49/22 , C10G67/0454 , C10G67/049 , C10G2300/1037 , C10G2300/107 , C10G2300/1077 , C10G2300/202 , C10G2300/205 , C10G2300/206 , C10G2300/301 , C10G2300/4006 , C10G2300/4012 , C10G2300/4018 , C10G2300/4081 , C10G2300/44 , C10L1/04
摘要： Heavy oil feeds are hydroprocessed in the presence of a solvent under conditions that provide a variety of benefits. The solvent can be an added solvent or a portion of the liquid effluent from hydroprocessing. The processes allow for lower pressure processing of heavy oil feeds for extended processing times or extended catalyst lifetimes be reducing or mitigating the amount of coke formation on the hydroprocessing catalyst.
摘要翻译： 在提供各种益处的条件下，在溶剂存在下将重油进料加氢处理。 溶剂可以是加氢处理的添加溶剂或一部分液体流出物。 该方法允许重油进料的较低压力处理用于延长的处理时间或延长的催化剂寿命来减少或减轻加氢处理催化剂上焦炭形成的量。
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公开(公告)号：US20130081979A1
公开(公告)日：2013-04-04
申请号：US13597616
申请日：2012-08-29
IPC分类号： C10G47/34
CPC分类号： C10G47/34 , C10G45/02 , C10G47/00 , C10G2300/205 , C10G2300/206 , C10G2300/301 , C10G2300/308 , C10G2300/44
摘要： This invention is directed to a process for producing a hydroprocessed product. The invention is particularly advantageous in that substantially longer run length can be attained relative to conventional hydroprocessing methods. This benefit is achieved by using a particular solvent as a co-feed component. In particular, the solvent component is comprised of at least one or more supercritical solvent compounds.
摘要翻译： 本发明涉及一种加氢处理产物的生产方法。 本发明特别有利的是，相对于常规的加氢处理方法可以实现更长的运行长度。 通过使用特定溶剂作为共进料组分来实现该益处。 特别地，溶剂组分由至少一种或多种超临界溶剂化合物组成。
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公开(公告)号：US20100191017A1
公开(公告)日：2010-07-29
申请号：US12665154
申请日：2008-07-11
CPC分类号： C07C6/126 , C07C2/74 , C07C37/07 , C07C37/08 , C07C45/53 , C07C407/00 , C07C409/14 , C07C2521/04 , C07C2521/06 , C07C2523/06 , C07C2523/14 , C07C2523/44 , C07C2523/46 , C07C2523/75 , C07C2523/755 , C07C2601/14 , Y02P20/52 , C07C13/28 , C07C49/403 , C07C39/04
摘要： In a process for producing cyclohexylbenzene, benzene and hydrogen are contacted with a catalyst under hydroalkylation conditions to produce an effluent containing cyclohexylbenzene. The catalyst comprises a composite of a molecular sieve, an inorganic oxide different from said molecular sieve and at least one hydrogenation metal, wherein at least 50 wt % of said hydrogenation metal is supported on the inorganic oxide.
摘要翻译： 在生产环己基苯的方法中，苯和氢在加氢烷基化条件下与催化剂接触以产生含有环己基苯的流出物。 催化剂包括分子筛，不同于所述分子筛的无机氧化物和至少一种氢化金属的复合物，其中至少50wt％的所述氢化金属负载在无机氧化物上。
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