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公开(公告)号：US08568848B2
公开(公告)日：2013-10-29
申请号：US13139378
申请日：2009-12-14
CPC分类号： C09J7/0228 , C08L27/12 , C08L27/16 , C08L83/08 , C09J7/401 , Y10T428/1457 , Y10T428/2839 , Y10T428/31663 , C08L83/00 , C08L2666/14 , C08L2666/04
摘要： Blended release materials including a blend of a fluoro-functional silicone release polymer and a fluoropolymer are described. Exemplary fluoropolymers include fluoroolefin-based polymers and linear fluoropolymers including linear fluoroacryaltes. Articles including such release materials such as release liners, and adhesive articles, including silicone adhesive articles, are also described.
摘要翻译： 描述了包括氟官能硅氧烷释放聚合物和含氟聚合物的共混物的混合释放材料。 示例性的含氟聚合物包括基于氟烯烃的聚合物和包括直链氟代丙烯酸酯的直链含氟聚合物。 还描述了包括诸如防粘衬垫的释放材料和粘合剂制品的制品，包括硅酮粘合剂制品。
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公开(公告)号：US20110244226A1
公开(公告)日：2011-10-06
申请号：US13139378
申请日：2009-12-14
IPC分类号： B32B7/12 , C08L83/08 , C09D183/08
CPC分类号： C09J7/0228 , C08L27/12 , C08L27/16 , C08L83/08 , C09J7/401 , Y10T428/1457 , Y10T428/2839 , Y10T428/31663 , C08L83/00 , C08L2666/14 , C08L2666/04
摘要： Blended release materials including a blend of a fluoro-functional silicone release polymer and a fluoropolymer are described. Exemplary fluoropolymers include fluoroolefin-based polymers and linear fluoropolymers including linear fluoroacryaltes. Articles including such release materials such as release liners, and adhesive articles, including silicone adhesive articles, are also described.
摘要翻译： 描述了包括氟官能硅氧烷释放聚合物和含氟聚合物的共混物的混合释放材料。 示例性的含氟聚合物包括基于氟烯烃的聚合物和包括直链氟代丙烯酸酯的直链含氟聚合物。 还描述了包括诸如防粘衬垫的释放材料和粘合剂制品的制品，包括硅酮粘合剂制品。
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公开(公告)号：US20080132132A1
公开(公告)日：2008-06-05
申请号：US12028589
申请日：2008-02-08
CPC分类号： C08F220/38 , Y10T428/3154 , Y10T442/2311 , Y10T442/232 , Y10T442/2754
摘要： A composition comprises a copolymer comprising repeating units derived from at least one co-reactant comprising two or more acrylate groups and repeating units derived from a fluoroacrylate comprising the reaction product of: (a) at least one fluorochemical alcohol represented by the formula: C4F9—X—OH wherein: R=hydrogen or an alkyl group of 1 to 4 carbon atoms, m=2 to 8, Rf=CnF2+1, n=1 to 5, y=0 to 6, and q=1 to 8; (b) at least one unbranched symmetric diisocyanate; and (c) at least one hydroxy-terminated alkyl (meth)acrylate or 2-fluoroacrylate monomer having 2 to about 30 carbon atoms in its alkylene portion; wherein the composition is coatable.
摘要翻译： 组合物包含共聚物，其包含衍生自至少一种包含两个或更多个丙烯酸酯基团的共反应物的重复单元和衍生自氟代丙烯酸酯的重复单元，所述重复单元包含以下反应产物：（a）至少一种由下式表示的含氟醇： in-line-formula description =“In-line Formulas”end =“lead”？> C 3 -X-OH <？in-line-formula description 其中：R =氢或1至4个碳原子的烷基，m = 2至8，R f = C 1， n = 2〜1，n = 1〜5，y = 0〜6，q = 1〜8; （b）至少一种非支化对称二异氰酸酯; 和（c）至少一种羟基封端的（甲基）丙烯酸烷基酯或其亚烷基部分具有2-30个碳原子的2-氟丙烯酸酯单体; 其中所述组合物是可涂覆的。
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公开(公告)号：US07666964B2
公开(公告)日：2010-02-23
申请号：US11859295
申请日：2007-09-21
申请人： Zai-Ming Qiu , John C. Clark , Ramesh C. Kumar
发明人： Zai-Ming Qiu , John C. Clark , Ramesh C. Kumar
IPC分类号： C08F12/30 , C08G18/00 , C08L27/12 , C08C261/00
CPC分类号： C08F220/38
摘要： A copolymer comprises repeating units derived from at least one co-reactant comprising two or more mercapto functional groups, and repeating units derived from a fluoroacrylate comprising the reaction product of: (a) at least one fluorochemical alcohol represented by the formula: C4F9—X—OH wherein: R=hydrogen or an alkyl group of 1 to 4 carbon atoms, m=2 to 8, Rf=CnF2n+1, n=1 to 5, y=0 to 6, and q=1 to 8; (b) at least one unbranched symmetric diisocyanate; and (c) at least one hydroxy-terminated alkyl (meth)acrylate or 2-fluoroacrylate monomer having 2 to about 30 carbon atoms in its alkylene portion.
摘要翻译： 共聚物包含衍生自至少一种包含两个或多个巯基官能团的共反应物的重复单元和衍生自氟代丙烯酸酯的重复单元，其包含以下反应产物：（a）至少一种由式C4F9-X表示的含氟醇 -OH其中：R =氢或1至4个碳原子的烷基，m = 2至8，R f = C n F 2n + 1，n = 1至5，y = 0至6，q = 1至8; （b）至少一种非支化对称二异氰酸酯; 和（c）至少一种羟基封端的（甲基）丙烯酸烷基酯或其亚烷基部分具有2至约30个碳原子的2-氟丙烯酸酯单体。
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公开(公告)号：US07659351B2
公开(公告)日：2010-02-09
申请号：US11688074
申请日：2007-03-19
申请人： Gregg A. Caldwell , John C. Clark , David J. Kinning , Alan R. Kirk , Thomas P. Klun , Ramesh C. Kumar , Roger A. Mader , George G I. Moore , Zai-Ming Qiu , Richard B. Ross
发明人： Gregg A. Caldwell , John C. Clark , David J. Kinning , Alan R. Kirk , Thomas P. Klun , Ramesh C. Kumar , Roger A. Mader , George G I. Moore , Zai-Ming Qiu , Richard B. Ross
IPC分类号： C08F12/20
CPC分类号： C08F220/38 , C07C271/20 , C07C271/28 , C07C311/09 , Y10T442/2287
摘要： Fluoroacrylates comprise the reaction product of: (a) at least one fluorochemical alcohol represented by the formula: CnF2n+1—X—OH wherein: n=1 to 4, R=hydrogen or an alkyl group of 1 to 4 carbon atoms, m=2 to 8, Rf=CnF2n+1, y=0 to 6, and q=1 to 8; (b) at least one unbranched symmetric diusocyanate; and (c) at least one hydroxy-terminated alkyl (meth)acrylate or 2-fluoro acrylate monomer having 2 to about 30 carbon atoms in its alkylene portion.
摘要翻译： 氟代丙烯酸酯包括以下反应产物：（a）至少一种由式CnF2n + 1-X-OH表示的含氟醇，其中：n = 1-4，R =氢或1-4个碳原子的烷基，m = 2〜8，Rf = CnF2n + 1，y = 0〜6，q = 1〜8; （b）至少一种非支化对称二异氰酸酯; 和（c）至少一个羟基封端的（甲基）丙烯酸烷基酯或其亚烷基部分具有2至约30个碳原子的2-氟丙烯酸酯单体。
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公开(公告)号：US07268197B2
公开(公告)日：2007-09-11
申请号：US11275114
申请日：2005-12-12
申请人： George G. I. Moore , Ramesh C. Kumar , Zai-Ming Qiu , John C. Clark , Chetan P. Jariwala , Thomas P. Klun
发明人： George G. I. Moore , Ramesh C. Kumar , Zai-Ming Qiu , John C. Clark , Chetan P. Jariwala , Thomas P. Klun
IPC分类号： C08F12/20
CPC分类号： C08G18/2885 , C08G18/2845 , C08G18/3228 , C08G18/61 , C08G18/6212 , C08G18/6705 , C08G18/71 , C09D175/04 , Y10T428/31551
摘要： A fluorochemical compound comprises the reaction product of: (a) the reaction product of: (i) at least one fluorochemical alcohol represented by the formula: CnF2n+1—X—OH wherein: n=1 to 6, R=hydrogen or an alkyl group of 1 to 4 carbon atoms, m=2 to 8, Rf=CnF2n+1, y=0 to 6, q=1 to 8; and (ii) at least one unbranched symmetric diisocyanate, and (b) at least one co-reactant comprising two or more functional groups that are capable of reacting with an isocyanate group.
摘要翻译： 含氟化合物包括以下反应产物：（a）反应产物：（i）至少一种由下式表示的含氟醇：<？in-line-formula description =“In-Line Formulas”end =“lead” 其中：在线式公式描述=“在线公式”end =“tail”→>其中： n = 1至6，R =氢或1至4个碳原子的烷基，m = 2至8，R f = C n N +1，y = 0〜6，q = 1〜8; 和（ii）至少一种非支化的对称二异氰酸酯，和（b）至少一种包含两个或更多个能够与异氰酸酯基团反应的官能团的共反应物。
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公开(公告)号：US07345123B2
公开(公告)日：2008-03-18
申请号：US11027612
申请日：2004-12-28
CPC分类号： C08F220/38 , Y10T428/3154 , Y10T442/2311 , Y10T442/232 , Y10T442/2754
摘要： A composition comprises a copolymer comprising repeating units derived from at least one co-reactant comprising two or more acrylate groups and repeating units derived from a fluoroacrylate comprising the reaction product of: (a) at least one fluorochemical alcohol represented by the formula: C4F9—X—OH wherein: R=hydrogen or an alkyl group of 1 to 4 carbon atoms, m=2 to 8, Rf=CnF2n+1, n=1 to 5, y 32 0 to 6, and q=1 to 8; (b) at least one unbranched symmetric diisocyanate; and (c) at least one hydroxy-terminated alkyl (meth)acrylate or 2-fluoroacrylate monomer having 2 to about 30 carbon atoms in its alkylene portion; wherein the composition is coatable.
摘要翻译： 组合物包含共聚物，其包含衍生自至少一种包含两个或更多个丙烯酸酯基团的共反应物的重复单元和衍生自氟代丙烯酸酯的重复单元，所述重复单元包含以下反应产物：（a）至少一种由下式表示的含氟醇： in-line-formula description =“In-line Formulas”end =“lead”？> C 3 -X-OH <？in-line-formula description 其中：R =氢或1至4个碳原子的烷基，m = 2至8，R f = C 1， n = 2n + 1，n = 1〜5，y = 0〜6，q = 1〜8; （b）至少一种非支化对称二异氰酸酯; 和（c）至少一种羟基封端的（甲基）丙烯酸烷基酯或其亚烷基部分具有2-30个碳原子的2-氟丙烯酸酯单体; 其中所述组合物是可涂覆的。
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公开(公告)号：US07851387B2
公开(公告)日：2010-12-14
申请号：US12028589
申请日：2008-02-08
IPC分类号： B32B27/04
CPC分类号： C08F220/38 , Y10T428/3154 , Y10T442/2311 , Y10T442/232 , Y10T442/2754
摘要： A composition comprises a copolymer comprising repeating units derived from at least one co-reactant comprising two or more acrylate groups and repeating units derived from a fluoroacrylate comprising the reaction product of: (a) at least one fluorochemical alcohol represented by the formula: C4F9—X—OH wherein: R=hydrogen or an alkyl group of 1 to 4 carbon atoms, m=2 to 8, Rf═CnF2n+1, n=1 to 5, y=0 to 6, and q=1 to 8; (b) at least one unbranched symmetric diisocyanate; and (c) at least one hydroxy-terminated alkyl (meth)acrylate or 2-fluoroacrylate monomer having 2 to about 30 carbon atoms in its alkylene portion; wherein the composition is coatable.
摘要翻译： 组合物包含共聚物，其包含衍生自至少一种包含两个或更多个丙烯酸酯基团的共反应物的重复单元和衍生自氟代丙烯酸酯的重复单元，所述重复单元包含以下反应产物：（a）至少一种由式C4F9- X-OH其中：R =氢或1至4个碳原子的烷基，m = 2至8，Rf = C n F 2n + 1，n = 1至5，y = 0至6，q = 1至8; （b）至少一种非支化对称二异氰酸酯; 和（c）至少一种羟基封端的（甲基）丙烯酸烷基酯或其亚烷基部分具有2-30个碳原子的2-氟丙烯酸酯单体; 其中所述组合物是可涂覆的。
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公开(公告)号：US07291688B2
公开(公告)日：2007-11-06
申请号：US11027605
申请日：2004-12-28
申请人： Zai-Ming Qiu , John C. Clark , Ramesh C. Kumar
发明人： Zai-Ming Qiu , John C. Clark , Ramesh C. Kumar
CPC分类号： C08F220/38
摘要： A copolymer comprises repeating units derived from at least one co-reactant comprising two or more mercapto functional groups, and repeating units derived from a fluoroacrylate comprising the reaction product of: (a) at least one fluorochemical alcohol represented by the formula: C4F9—X—OH wherein: R=hydrogen or an alkyl group of 1 to 4 carbon atoms, m=2 to 8, Rf=CnF2n+1, n=1 to 5, y=0 to 6, and q=1 to 8; (b) at least one unbranched symmetric diisocyanate; and (c) at least one hydroxy-terminated alkyl (meth)acrylate or 2-fluoroacrylate monomer having 2 to about 30 carbon atoms in its alkylene portion.
摘要翻译： 共聚物包含衍生自至少一种包含两个或多个巯基官能团的共反应物的重复单元和衍生自氟代丙烯酸酯的重复单元，该重复单元包含以下反应产物：（a）至少一种由下式表示的含氟醇： -line-formula description =“In-line Formulas”end =“lead”？> C 3 -X-OH <？in-line-formula description = “直链式”末端=“尾”→其中：R =氢或1至4个碳原子的烷基，m = 2至8，R f = C n n = 1〜5，y = 0〜6，q = 1〜8; （b）至少一种非支化的对称二异氰酸酯; 和（c）至少一种羟基封端的（甲基）丙烯酸烷基酯或其亚烷基部分具有2至约30个碳原子的2-氟丙烯酸酯单体。
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公开(公告)号：US07199197B2
公开(公告)日：2007-04-03
申请号：US11027604
申请日：2004-12-28
申请人： Gregg A. Caldwell , John C. Clark , David J. Kinning , Alan R. Kirk , Thomas P. Klun , Ramesh C. Kumar , Roger A. Mader , George G. I. Moore , Zai-Ming Qiu , Richard B. Ross
发明人： Gregg A. Caldwell , John C. Clark , David J. Kinning , Alan R. Kirk , Thomas P. Klun , Ramesh C. Kumar , Roger A. Mader , George G. I. Moore , Zai-Ming Qiu , Richard B. Ross
IPC分类号： C08F12/20
CPC分类号： C08F220/38 , C07C271/20 , C07C271/28 , C07C311/09 , Y10T442/2287
摘要： Fluoroacrylates comprise the reaction product of: (a) at least one fluorochemical alcohol represented by the formula: CnF2n+1—X—OH wherein: R=hydrogen or an alkyl group of 1 to 4 carbon atoms, m=2 to 8, Rf=CnF2n+1, y=0 to 6, and q=1 to 8; (b) at least one unbranched symmetric diisocyanate; and (c) at least one hydroxy-terminated alkyl (meth)acrylate or 2-fluoro acrylate monomer having 2 to about 30 carbon atoms in its alkylene portion.
摘要翻译： 氟丙烯酸酯包含反应产物
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