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1.发明授权公开(公告)号：US07531682B2
公开(公告)日：2009-05-12
申请号：US10521324
申请日：2003-07-11
IPC分类号： C07C253/10 , C07F9/02
CPC分类号： C07F9/65746 , B01J31/1608 , B01J31/185 , B01J2231/322 , B01J2231/52 , B01J2531/0266 , B01J2531/16 , B01J2531/17 , B01J2531/18 , B01J2531/26 , B01J2531/27 , B01J2531/28 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/825 , B01J2531/827 , B01J2531/842 , B01J2531/845 , B01J2531/847 , B01J2540/10 , B01J2540/30 , B01J2540/34 , B01J2540/527 , C07C253/10 , C07C253/30 , C07F9/1412 , C07F9/145 , C07F9/5325 , C07F9/58 , C07F9/65515 , C07F9/65517 , C07F9/65522 , C07C255/04 , C07C255/07
摘要： The present invention concerns a process for hydrocyanating ethylenically unsaturated organic compounds to compounds containing at least one nitrile function. It relates more particularly to the hydrocyanation of diolefins such as butadiene or of substituted olefins such as alkenenitriles, for instance pentenenitriles. According to the process of the invention the reaction is implemented in the presence of a metal complex catalyst comprising a transition metal such as nickel and an organic ligand.
摘要翻译： 本发明涉及一种将烯属不饱和有机化合物氢化成含有至少一个腈官能团的化合物的方法。 更具体地涉及二烯烃如丁二烯或取代的烯烃如烯腈（例如戊烯腈）的氢氰化。 根据本发明的方法，反应在含有过渡金属如镍和有机配体的金属络合物催化剂的存在下进行。
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公开(公告)号：US07442825B2
公开(公告)日：2008-10-28
申请号：US10521187
申请日：2003-07-11
IPC分类号： C07C253/10
CPC分类号： C07F9/2479 , C07C253/10 , C07C253/30 , C07F9/1415 , C07F9/145 , C07F9/2466 , C07F9/2475 , C07F9/58 , C07F9/65517 , C07F9/657154 , C07F9/65746 , C07C255/04 , C07C255/07
摘要： The present invention concerns a process for hydrocyanating ethylenically unsaturated organic compounds to compounds containing at least one nitrile function. It relates more particularly to the hydrocyanation of diolefins such as butadiene or of substituted olefins such as alkenenitriles, for instance pentenenitriles. According to the process of the invention the reaction is implemented in the presence of a metal complex catalyst comprising a transition metal such as nickel and an organic ligand.
摘要翻译： 本发明涉及一种将烯属不饱和有机化合物氢化成含有至少一个腈官能团的化合物的方法。 更具体地涉及二烯烃如丁二烯或取代的烯烃如烯腈（例如戊烯腈）的氢氰化。 根据本发明的方法，反应在含有过渡金属如镍和有机配体的金属络合物催化剂的存在下进行。
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3.发明授权Method of producing nitrile compounds from ethylenically-unsaturated compounds 有权由烯属不饱和化合物制备腈化合物的方法公开(公告)号：US07485741B2
公开(公告)日：2009-02-03
申请号：US10537260
申请日：2003-11-25
IPC分类号： C07C253/00
CPC分类号： C07C253/10 , C07C255/04
摘要： The present invention relates to a process for hydrocyanating a hydrocarbon-based compound containing at least one ethylenic unsaturation by reaction in liquid medium with hydrogen cyanide in the presence of a catalyst comprising a metal element chosen from transition metals and an organophosphorus ligand, characterized in that the organophosphorus ligand is a monodentate organophosphorus compound. The present invention is in particular useful for the synthesis of adiponitrile from butadiene.
摘要翻译： 本发明涉及一种在含有选自过渡金属和有机磷配体的金属元素的催化剂存在下，在液体介质中与氰化氢反应，使含有至少一个烯属不饱和基团的烃类化合物氢氰化的方法，其特征在于： 有机磷配体是单齿有机磷化合物。 本发明特别适用于从丁二烯合成己二腈。
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4.发明授权Process for preparing nitrile compounds from ethylenically unsaturated compounds 有权由烯属不饱和化合物制备腈化合物的方法公开(公告)号：US07253298B2
公开(公告)日：2007-08-07
申请号：US11166595
申请日：2005-06-24
IPC分类号： C07C253/10 , C07F9/02
CPC分类号： C07C253/10 , B01J31/185 , B01J31/38 , B01J2231/322 , B01J2531/847 , C07C255/04
摘要： The present invention concerns a process for hydrocyanating ethylenically unsaturated organic compounds to compounds containing at least one nitrile function. It relates more particularly to the hydrocyanation of diolefins such as butadiene or of substituted olefins such as alkenenitriles, for instance pentenenitriles. According to the process of the invention the reaction is implemented in the presence of a metal complex catalyst comprising a transition metal such as nickel and an organic ligand.
摘要翻译： 本发明涉及一种将烯属不饱和有机化合物氢化成含有至少一个腈官能团的化合物的方法。 更具体地涉及二烯烃如丁二烯或取代的烯烃如烯腈（例如戊烯腈）的氢氰化。 根据本发明的方法，反应在含有过渡金属如镍和有机配体的金属络合物催化剂的存在下进行。
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公开(公告)号：US20060128980A1
公开(公告)日：2006-06-15
申请号：US10521324
申请日：2003-07-11
IPC分类号： C07C253/10
CPC分类号： C07F9/65746 , B01J31/1608 , B01J31/185 , B01J2231/322 , B01J2231/52 , B01J2531/0266 , B01J2531/16 , B01J2531/17 , B01J2531/18 , B01J2531/26 , B01J2531/27 , B01J2531/28 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/825 , B01J2531/827 , B01J2531/842 , B01J2531/845 , B01J2531/847 , B01J2540/10 , B01J2540/30 , B01J2540/34 , B01J2540/527 , C07C253/10 , C07C253/30 , C07F9/1412 , C07F9/145 , C07F9/5325 , C07F9/58 , C07F9/65515 , C07F9/65517 , C07F9/65522 , C07C255/04 , C07C255/07
摘要： The present invention concerns a process for hydrocyanating ethylenically unsaturated organic compounds to compounds containing at least one nitrile function. It relates more particularly to the hydrocyanation of diolefins such as butadiene or of substituted olefins such as alkenenitriles, for instance pentenenitriles. According to the process of the invention the reaction is implemented in the presence of a metal complex catalyst comprising a transition metal such as nickel and an organic ligand.
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6.发明申请Process for preparing nitrile compounds from ethylenically unsaturated compounds 有权由烯属不饱和化合物制备腈化合物的方法公开(公告)号：US20060100455A1
公开(公告)日：2006-05-11
申请号：US11166595
申请日：2005-06-24
IPC分类号： C07C253/10 , C07F9/02
CPC分类号： C07C253/10 , B01J31/185 , B01J31/38 , B01J2231/322 , B01J2531/847 , C07C255/04
摘要： The present invention concerns a process for hydrocyanating ethylenically unsaturated organic compounds to compounds containing at least one nitrile function. It relates more particularly to the hydrocyanation of diolefins such as butadiene or of substituted olefins such as alkenenitriles, for instance pentenenitriles. According to the process of the invention the reaction is implemented in the presence of a metal complex catalyst comprising a transition metal such as nickel and an organic ligand.
摘要翻译： 本发明涉及一种将烯属不饱和有机化合物氢化成含有至少一个腈官能团的化合物的方法。 更具体地涉及二烯烃如丁二烯或取代的烯烃如烯腈（例如戊烯腈）的氢氰化。 根据本发明的方法，反应在含有过渡金属如镍和有机配体的金属络合物催化剂的存在下进行。
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公开(公告)号：US20060052624A1
公开(公告)日：2006-03-09
申请号：US10521187
申请日：2003-07-11
IPC分类号： C07C253/10
CPC分类号： C07F9/2479 , C07C253/10 , C07C253/30 , C07F9/1415 , C07F9/145 , C07F9/2466 , C07F9/2475 , C07F9/58 , C07F9/65517 , C07F9/657154 , C07F9/65746 , C07C255/04 , C07C255/07
摘要： The present invention concerns a process for hydrocyanating ethylenically unsaturated organic compounds to compounds containing at least one nitrile function. It relates more particularly to the hydrocyanation of diolefins such as butadiene or of substituted olefins such as alkenenitriles, for instance pentenenitriles. According to the process of the invention the reaction is implemented in the presence of a metal complex catalyst comprising a transition metal such as nickel and an organic ligand.
摘要翻译： 本发明涉及一种将烯属不饱和有机化合物氢化成含有至少一个腈官能团的化合物的方法。 更具体地涉及二烯烃如丁二烯或取代的烯烃如烯腈（例如戊烯腈）的氢氰化。 根据本发明的方法，反应在含有过渡金属如镍和有机配体的金属络合物催化剂的存在下进行。
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公开(公告)号：US06939976B2
公开(公告)日：2005-09-06
申请号：US10822237
申请日：2004-04-09
IPC分类号： C07D307/60
CPC分类号： C07D307/60
摘要： A process for the production of allyl succinic anhydride comprising reacting a mixture of propene with maleic anhydride in the presence of a catalyst comprised of an alkyl tin chloride as provided. The process can be run efficiently at temperatures below about 200° C. without and the formation of polymer or decomposition by-products.
摘要翻译： 一种生产烯丙基琥珀酸酐的方法，包括在由所提供的烷基氯化锡组成的催化剂存在下使丙烯与马来酸酐的混合物反应。 该方法可以在低于约200℃的温度下有效地运行，而不会形成聚合物或分解副产物。
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9.发明授权公开(公告)号：US07105696B2
公开(公告)日：2006-09-12
申请号：US10250477
申请日：2001-12-21
IPC分类号： C07C253/00
CPC分类号： C07C253/10 , C07C255/04
摘要： The invention concerns a method for hydrocyanation of ethylenically unsaturated organic compounds comprising at least a nitrile function. The invention provides a method for hydrocyanation of an ethylenically unsaturated hydrocarbon compound by reacting in liquid medium the hydrogen cyanide in the presence of a catalyst comprising a metal element selected among transition metals and an organophosphorous ligand, characterised in that the organophosphorous ligand is a furylphosphine. The invention is in particular useful for synthesizing adiponitrile from butadiene.
摘要翻译： 本发明涉及一种含有至少一个腈官能团的烯属不饱和有机化合物的氢氰化方法。 本发明提供了一种通过在液体介质中在含有选自过渡金属和有机磷配体的金属元素的催化剂存在下，使氰化氢反应的方法，其特征在于有机磷配体是呋喃基膦。 本发明特别适用于从丁二烯合成己二腈。
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公开(公告)号：US08039660B2
公开(公告)日：2011-10-18
申请号：US12244233
申请日：2008-10-02
申请人： Jean-Marie Basset , Yves Chauvin , Jean-Christophe Galland , Gerald Niccolai , Christine Valerio , Christophe Vallee
发明人： Jean-Marie Basset , Yves Chauvin , Jean-Christophe Galland , Gerald Niccolai , Christine Valerio , Christophe Vallee
IPC分类号： C07C253/10 , C07C255/03
CPC分类号： C07C253/10 , C07C255/04
摘要： The present invention relates to the manufacture of nitrile compounds from unsaturated organic compounds by reaction with hydrogen cyanide. It relates more particularly to the manufacture of nitrile compounds of use in the synthesis of adiponitrile, an important chemical intermediate in the manufacture of major chemical compounds, such as hexamethylenediamine and ε-caprolactam. The invention provides a process for the manufacture of organic compounds comprising at least one nitrile functional group by carrying out a hydrocyanation reaction between hydrogen cyanide and an organic compound comprising at least one ethylenic unsaturation. This reaction is carried out in the presence of a catalytic system comprising a metal element chosen from the group consisting of nickel, platinum and palladium and an organophosphorus ligand, the reaction medium additionally comprising an ionic liquid in the liquid state at least at the temperature at which the hydrocyanation reaction is carried out.
摘要翻译： 本发明涉及通过与氰化氢反应从不饱和有机化合物制备腈化合物。 更具体地涉及用于合成己二腈的腈化合物的制备，其是主要化学化合物如六亚甲基二胺和ε-己内酰胺的制造中的重要化学中间体。 本发明提供一种制备包含至少一个腈官能团的有机化合物的方法，该方法是通过在氰化氢与包含至少一个烯属不饱和键的有机化合物之间进行氢氰化反应。 该反应在包含选自镍，铂和钯的金属元素和有机磷配体的催化体系的存在下进行，所述反应介质另外包含处于液态的离子液体，至少在 进行氢化反应。
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