-
公开(公告)号：US4224429A
公开(公告)日：1980-09-23
申请号：US823590
申请日：1977-08-11
申请人： Jean-Marie Lehn , Francois Schue , Sylvie Boileau , Alain A. Cau , Bernd Kaempf , Jean R. Moinard , Serge F. Raynal
发明人： Jean-Marie Lehn , Francois Schue , Sylvie Boileau , Alain A. Cau , Bernd Kaempf , Jean R. Moinard , Serge F. Raynal
IPC分类号： C08F2/00 , C08F2/04 , C08F4/00 , C08F4/42 , C08F36/00 , C08F36/04 , C08G61/10 , C08G63/00 , C08G63/78 , C08G63/82 , C08G65/26 , C08G77/08 , C08G85/00 , C08F4/46 , C08F4/50 , C08G63/10 , C08G63/62 , C08G65/12
CPC分类号： C08G77/08 , C08F36/04 , C08F4/00 , C08G61/10 , C08G65/2603 , C08G65/2651
摘要： A process for the anionic polymerization or copolymerization of olefinic monomers, dienic monomers, vinyl monomers and heterocyclic monomers is described which comprises reacting at least one monomer which is an olefinic monomer, a vinyl monomer or an heterocyclic monomer with a catalyst capable of inducing anionic polymerization and an aprotic macroheterocyclic cryptant, said at least one monomer being the only medium for the reaction.The macroheterocyclic complexing agent has general formula ##STR1## in which: R.sub.1 is hydrogen, a hydrocarbon radical or alkoxycarbonyl, or the two R.sub.1 together can form a group of the general formula: ##STR2## in which A is a hydrocarbon radical,D is oxygen, sulfur, or a hydrocarbon radical, with the proviso that at leat two of the D groups are oxygen or sulfur and that if R.sub.1 is hydrogen, a hydrocarbon radical or alkoxycarbonyl, one of these two D groups is oxygen or sulfur and the other is oxygen, andn and p are integers from 1 to 3 and m is 2 or 3.
摘要翻译： 描述了烯属单体，二烯单体，乙烯基单体和杂环单体的阴离子聚合或共聚方法，其包括使至少一种单体，即烯属单体，乙烯基单体或杂环单体与能够引发阴离子聚合的催化剂 所述至少一种单体是所述反应的唯一介质。 大环杂合络合剂具有通式“IMAGE”，其中：R 1为氢，烃基或烷氧基羰基，或两个R 1可以形成下列通式的基团：其中A为烃基 ，D是氧，硫或烃基，条件是在两个D基团中的两个是氧或硫，如果R 1是氢，则烃基或烷氧基羰基，这两个D基团之一是氧或硫 另一个为氧，n和p为1〜3的整数，m为2或3。
-
2.发明授权Anionic polymerization of heterocyclic monomers with alkali metal amide hydroxylated compound initiator 失效杂环单体与碱金属酰胺羟化化合物引发剂的阴离子聚合
公开(公告)号：US4316001A
公开(公告)日：1982-02-16
申请号：US061288
申请日：1979-07-27
IPC分类号： C08F4/46 , C08F36/04 , C08G63/82 , C08G85/00 , C08G77/08 , C08G59/68 , C08G63/10 , C08G69/20
CPC分类号： C08G85/00 , C08F36/04 , C08F4/46 , C08G63/823
摘要： An initiator for the anionic polymerization of heterocyclic monomers comprises the product from the association of an alkali metal amide and the salt from at least one hydroxylated compound with the same alkali metal in an aprotic solvent. The hydroxylated compound is a primary alcohol, a secondary or tertiary alcohol, an ether alcohol, an amino alcohol, a polyether alcohol, a polyamino alcohol, a polyaminoetheralcohol, or an enol from a ketone.
摘要翻译： 用于杂环单体的阴离子聚合的引发剂包括在非质子传递溶剂中由碱金属氨化物与至少一种羟化化合物与相同碱金属的盐缔合的产物。 羟基化化合物是伯醇，仲醇或叔醇，醚醇，氨基醇，聚醚醇，聚氨基醇，聚氨基醚醇或来自酮的烯醇。
-
3.发明授权Polymer with ethylenic unsaturations incorporating silylmetallocene groups, process for the manufacture of this polymer, and propellant composition having this polymer as a binder 失效具有结合甲硅烷基茂金属基团的烯属不饱和基团的聚合物，该聚合物的制造方法和具有该聚合物作为粘合剂的推进剂组合物
公开(公告)号：US4647628A
公开(公告)日：1987-03-03
申请号：US750076
申请日：1985-06-28
CPC分类号： C06B45/10 , C08C19/26 , Y10S526/943
摘要： The invention relates to a polymer with ethylenic unsaturations incorporating silylmetallocene groups, a process for the manufacture of these polymers and a propellant composition having the polymer of the invention as a binder.The polymer of the invention incorporates ethylenic unsaturations, to at least some of which there are added silylmetallocene groups of formula ##STR1## in which M denotes a transistion metal such as, for example, iron, the radicals R.sub.1, R.sub.2 and R.sub.3 being hydrocarbon 2 radicals. The polymer may be a hydroxytelechelic or carboxytelechelic polybutadiene. This modified polymer is employed as a binder in composite propellant compositions, thus making it possible to solve the problem related to the migration of the combustion catalyst.The invention has application particularly in the field of solid propulsion.
摘要翻译： 本发明涉及具有烯键式烯属基团的烯属不饱和基团的聚合物，制备这些聚合物的方法和具有本发明聚合物作为粘合剂的推进剂组合物。 本发明的聚合物结合了烯属不饱和基团，至少其中一些添加了式“IMAGE”的甲硅烷基茂金属基团，其中M表示转移金属，例如铁，基团R 1，R 2和R 3为烃2 激进分子 聚合物可以是羟基可转移或羧甲基螯合的聚丁二烯。 这种改性聚合物用作复合推进剂组合物中的粘合剂，从而可以解决与燃烧催化剂迁移有关的问题。 本发明特别适用于固体推进领域。
-
公开(公告)号：US4254247A
公开(公告)日：1981-03-03
申请号：US800036
申请日：1977-05-24
IPC分类号： C08F2/00 , C08F4/00 , C08F4/06 , C08F4/08 , C08F4/46 , C08F36/04 , C08G63/82 , C08G85/00 , C08G63/10
CPC分类号： C08G85/00 , C08F36/04 , C08F4/46 , C08G63/823
摘要： An initiator for the anionic polymerization of vinyl monomers and dienic monomers comprises the product from the association of an alkali metal amide and the salt from at least one hydroxylated compound with the same alkali metal in an aprotic solvent. The hydroxylated compound is a primary, secondary, or tertiary alcohol. The hydroxylated compound may be a member selected from the group consisting of an alcohol substituted by an heterocyclic group, alcohols containing ethylenic unsaturation, alcohols substituted by an aromatic group, alicyclic alcohols, aromatic alcohols, polyhydroxy compounds, ether-alcohols, polyether-alcohols, and enols from ketones and amino acids.
摘要翻译： 乙烯基单体和二烯单体的阴离子聚合引发剂包括在非质子溶剂中由碱金属氨化物与至少一种羟化化合物与相同碱金属的盐缔合的产物。 羟基化合物是伯，仲或叔醇。 羟基化化合物可以是选自被杂环基取代的醇，含有烯属不饱和醇的醇，被芳香族取代的醇，脂环醇，芳香醇，多羟基化合物，醚醇，聚醚醇， 并从酮和氨基酸中得到。
-
5.发明授权Polymer with ethylenic unsaturations incorporating silylmetallocene groups, process for the manufacture of this polymer, and propellant composition having this polymer as a binder 失效具有结合甲硅烷基茂金属基团的烯属不饱和基团的聚合物，该聚合物的制造方法和具有该聚合物作为粘合剂的推进剂组合物
公开(公告)号：US4668313A
公开(公告)日：1987-05-26
申请号：US879404
申请日：1986-06-27
CPC分类号： C06B45/10 , C08C19/26 , Y10S526/943
摘要： The invention relates to a polymer with ethylenic unsaturations incorporating silylmetallocene groups, a process for the manufacture of these polymers and a propellant composition having the polymer of the invention as a binder.The polymer of the invention incorporates ethylenic unsaturations, to at least some of which there are added silylmetallocene groups of formula ##STR1## in which M denotes a transition metal such as, for example, iron, the radicals R.sub.1, R.sub.2 and R.sub.3 being hydrocarbon radicals. The polymer may be a hydroxytelechelic or carboxytelechelic polybutadiene. This modified polymer is employed as a binder in composite propellant compositions, thus making it possible to solve the problem related to the migration of the combustion catalyst.The invention has application particularly in the field of solid propulsion.
摘要翻译： 本发明涉及具有烯键式烯属基团的烯属不饱和基团的聚合物，制备这些聚合物的方法和具有本发明聚合物作为粘合剂的推进剂组合物。 本发明的聚合物结合了烯属不饱和基团，至少其中一些添加了式“IMAGE”的甲硅烷基茂金属基团，其中M表示过渡金属，例如铁，基团R 1，R 2和R 3为烃基 。 聚合物可以是羟基可转移或羧甲基螯合的聚丁二烯。 这种改性聚合物用作复合推进剂组合物中的粘合剂，从而可以解决与燃烧催化剂迁移有关的问题。 本发明特别适用于固体推进领域。
-
6.发明授权Anionic polymerization initiators based on alkali metal amides in combination with alkali metal salts and anionic polymerization process using these initiators 失效基于碱金属酰胺与碱金属盐组合的阴离子聚合引发剂和使用这些引发剂的阴离子聚合方法
公开(公告)号：US4292421A
公开(公告)日：1981-09-29
申请号：US046192
申请日：1979-06-06
申请人： Sylvie L. Boileau , Paul J. Caubere , Serge F. Raynal , Serge L. Lecolier , Gilberte N. N'Debeka
发明人： Sylvie L. Boileau , Paul J. Caubere , Serge F. Raynal , Serge L. Lecolier , Gilberte N. N'Debeka
IPC分类号： C08F4/00 , C08F4/06 , C08F4/46 , C08F36/04 , C08G63/82 , C08G65/26 , C08G69/20 , C08F4/08 , C08F112/08 , C08F112/34 , C08F120/14
CPC分类号： C08G69/20 , C08F36/04 , C08F4/46 , C08G63/823 , C08G65/2648
摘要： The invention relates to an anionic polymerization process using an initiator based on an alkali metal amide in combination with an alkali metal salt, as well as to the polymers obtained by this process.The polymerization process according to the invention is characterized in that an initiator is used which results from the combination of an alkali metal amide selected from the group comprising sodium amide, potassium amide or lithium amide and an alkali metal salt of which the cation is selected from the group comprising potassium, lithium or sodium, the anion being selected from the group comprising the thiocyanate, nitrite, cyanide and cyanate anions.These initiators make it possible to carry out the anionic polymerization or vinyl, heterocyclic and diene monomers in order to obtain special polymers or widely used polymers, with great adaptability and under advantageous economic conditions.
摘要翻译： 本发明涉及使用基于碱金属酰胺与碱金属盐组合的引发剂以及通过该方法得到的聚合物的阴离子聚合方法。 根据本发明的聚合方法的特征在于使用引发剂，其由选自包括氨基钠，氨基化钾或氨基化锂的碱金属胺与碱金属盐组合而成，其中阳离子选自 包含钾，锂或钠的阴离子选自硫氰酸盐，亚硝酸盐，氰化物和氰酸根阴离子。 这些引发剂使得可以进行阴离子聚合或乙烯基，杂环和二烯单体，以获得特殊的聚合物或广泛使用的聚合物，具有很好的适应性和有利的经济条件。
-
公开(公告)号：US4661608A
公开(公告)日：1987-04-28
申请号：US749803
申请日：1985-06-28
摘要： The present invention relates to a process for the manufacture of silylmetallocene compounds and the compounds obtained by this process.The process of the invention consists in reacting, in the presence of a hydrosilylation catalyst, a metallocene of general formula (I): ##STR1## M denoting a transition metal such as iron with a halosilane of general formula (II): ##STR2## in which X denotes a halogen and then reducing the resultant product to form a silylmetallocene compound containing at least one Si-H bond.The invention has application in the field of chemical industry.
摘要翻译： 本发明涉及一种制备甲硅烷基茂金属化合物的方法和通过该方法获得的化合物。 本发明的方法在于在氢化硅烷化催化剂存在下使通式（I）的金属茂反应：表示具有通式（II）的卤代硅烷的过渡金属例如铁：＆lt; IMAGE＆gt; 其中X表示卤素，然后还原所得产物以形成含有至少一个Si-H键的甲硅烷基茂金属化合物。 本发明应用于化工领域。
-
8.发明授权Bulk anionic polymerization process using an alkali metal amide and the salt of the same alkali metal with a hydroxylic compound 失效使用碱金属酰胺和相同碱金属的盐与羟基化合物的本体阴离子聚合方法
公开(公告)号：US4243787A
公开(公告)日：1981-01-06
申请号：US957889
申请日：1978-11-06
IPC分类号： C08F4/00 , C08F2/02 , C08F4/42 , C08F4/46 , C08F36/04 , C08G63/82 , C08G65/26 , C08G69/20 , C08F4/48
CPC分类号： C08G69/20 , C08F36/04 , C08F4/46 , C08G63/823 , C08G65/2648
摘要： The invention relates to a process for the anionic polymerization and copolymerization of vinyl, dienic and heterocyclic monomers.According to the invention, the process consists in carrying out the reaction in the presence of an initiator consisting of a molecular combination of an alkali metal amide and the salt of the same alkali metal with at least one hydroxylic compound and in the absence of solvent. The initiator can be prepared by intimately mixing its constituents or in the presence of a solvent of low polarity which is subsequently evaporated off, or in situ in the monomer.Application to the synthesis of special or widely used polymers and copolymers.
摘要翻译： 本发明涉及乙烯基，二烯和杂环单体的阴离子聚合和共聚方法。 根据本发明，该方法包括在由碱金属酰胺和相同碱金属的盐与至少一种羟基化合物的分子组合和不存在溶剂的分子组合的引发剂存在下进行反应。 引发剂可以通过紧密混合其组分或在低极性溶剂的存在下制备，随后将其蒸发掉或在单体中原位。 适用于特殊或广泛应用的聚合物和共聚物的合成。
-
-
-
-
-
-
-
搜索结果
8 条记录 (耗时 0.028 秒)
