Formation of color photographic image with azo dye containing alkoxy or
thioalkoxy metal chelating group
    1.
    发明授权
    Formation of color photographic image with azo dye containing alkoxy or thioalkoxy metal chelating group 失效
    用含有烷氧基或硫代烷氧基金属螯合基团的偶氮染料形成彩色摄影图像

    公开(公告)号:US4425422A

    公开(公告)日:1984-01-10

    申请号:US375547

    申请日:1982-05-06

    摘要: A method for the formation of a color photographic image comprising exposure and development of a photographic element, said photographic element comprising at least one silver halide emulsion layer, a compound capable of releasing a diffusible azo dye compound during development, and at least one mordant layer arranged on a support. The color image formation is effected by the reaction of multivalent metallic ions with an azo dye compound having the formula: ##STR1## wherein G.sup.1 is an alkoxy or a thioalkoxy metallic chelating group; G.sup.2 is a metallic chelating group in which an oxygen atom is involved in the chelate formation; and Z.sup.1 and Z.sup.2 each is a group of atoms necessary to form an aromatic carbocyclic ring or a heterocyclic ring. The azo dye compound and the metallic ions form a metal complex by coordination of the azo group and the G.sup.1 and G.sup.2 groups of the azo dye compound with the multivalent metallic ions.

    摘要翻译: 一种用于形成彩色摄影图像的方法,包括曝光和显影照相元件,所述照相元件包括至少一种卤化银乳剂层,在显影期间能够释放可扩散偶氮染料化合物的化合物,以及至少一种媒染剂层 安排在支持上。 彩色图像形成通过多价金属离子与具有下式的偶氮染料化合物的反应来实现:其中G1是烷氧基或硫代烷氧基金属螯合基团; G2是金属螯合基团,其中氧原子参与螯合物形成; 并且Z 1和Z 2各自是形成芳族碳环或杂环所必需的一组原子。 偶氮染料化合物和金属离子通过偶氮基团和偶氮染料化合物的G1和G2基团与多价金属离子的配位形成金属络合物。

    Photographic light sensitive element
    3.
    发明授权
    Photographic light sensitive element 失效
    摄影光敏元件

    公开(公告)号:US4368260A

    公开(公告)日:1983-01-11

    申请号:US333900

    申请日:1981-12-23

    CPC分类号: G03C8/10 C09B29/3621

    摘要: A photographic light-sensitive element which comprises on a support a light-sensitive silver halide emulsion layer and having associated therewith a non-diffusible compound capable of, under alkaline condition, releasing a diffusible azo dye, said compound having the formula (1), ##STR1## wherein X represents a group of atoms necessary to complete a naphthalene ring or a benzene ring, G.sup.1 represents a hydroxy group, a salt thereof or a hydrolyzable precursor thereof, G.sup.2 represents a carboxy group, a salt thereof or a hydrolyzable precursor thereof, a hydroxy group, a salt thereof or a hydrolyzable precursor thereof, R.sup.1 is a hydrogen atom, an alkyl group or an aryl group, R.sup.2 is a hydrogen atom, an alkyl group or an aryl group, R.sup.2 represents a hydrogen atom, a halogen atom, an alkyl group, a carboxy group, a carbamoyl group or an amino group, each of which group may be substituted, R.sup.3 represents a hydrogen atom, a carboxy group, a carbamoyl group, a cyano group or a trifluoromethyl group, J represents a divalent linking group, Y represents a ballasted carrier moiety capable of releasing said diffusible dye under alkaline condition as a function of development of silver halide, m represents an integer of 1 to 3 and n represents zero or an positive integer not larger than m.

    摘要翻译: 一种照相感光元件,其在支撑体上包含感光卤化银乳剂层,并且与其相关联地具有能够在碱性条件下释放扩散性偶氮染料的不扩散化合物,所述具有式(1)的化合物, (1)其中X表示完成萘环或苯环所需的原子团,G1表示羟基,其盐或其可水解的前体,G2表示羧基,其盐或 可水解的前体,羟基,其盐或其可水解的前体,R1是氢原子,烷基或芳基,R2是氢原子,烷基或芳基,R2表示氢原子 ,卤素原子,烷基,羧基,氨基甲酰基或氨基,其各自可以被取代,R 3表示氢原子,羧基,氨基甲酰基,氰基或三氟甲基, J表示二价连接基团,Y表示能够在碱性条件下作为卤化银显影的函数释放所述可扩散染料的压载载体部分,m表示1〜3的整数,n表示0或1〜 大于m。

    Light-sensitive photographic element comprising a magenta image
dye-providing compound

    公开(公告)号:US4256831A

    公开(公告)日:1981-03-17

    申请号:US68508

    申请日:1979-08-22

    摘要: A light-sensitive photographic element comprising a support and at least one light-sensitive silver halide emulsion layer coated thereon having associated therewith a magenta image dye-providing compound which releases a magenta dye or a precursor thereof corresponding to the imagewise exposure of said emulsion layer, said magenta dye-providing compound being a compound represented by formula [I]: ##STR1## wherein Car represents a carrier moiety which can be oxidized under alkaline conditions to release a diffusible dye or a precursor thereof from said compound;R.sup.1 and R.sup.2, which may be the same or different, independently represent a hydrogen atom or an alkyl group having 1 to 3 carbon atoms (provided that the total sum of carbon atoms in R.sup.1 and R.sup.2 does not exceed 5), or R.sup.1 and R.sup.2 may form, together with the nitrogen atom, ##STR2## X represents a hydroxyl group, a salt thereof or a group, which can be converted into a hydroxyl group by hydrolysis, having the following formula: ##STR3## in which R.sup.3 represents an alkyl or haloalkyl group having 1 to 18 carbon atoms or a phenyl group which may be substituted; Y represents a ##STR4## group in which R.sup.4 and R.sup.5, which may be the same or different, independently represent a hydrogen atom, an alkyl group having 1 to 6 carbon atoms or a cycloalkyl group (provided that the total sum of carbon atoms in R.sup.4 and R.sup.5 does not exceed 6);Z represents a hydrogen atom, a chlorine atom, a methyl group or a methoxy group;l is 1 or 2 provided that when l is 2 each Z may be the same or different;m is 0 or 1;andJ represents a bivalent linking group having the formula --R.sup.6 --(O).sub.n --R.sub.p.sup.7 -- in which R.sup.6 and R.sup.7, which may be the same or different, independently represent an alkylene group having 1 to 8 carbon atoms, a phenylene group which may be substituted; n represents 0 or 1; p represents 0 or 1 provided that p is 1 when n is 1 and 1 or 0 when n is 0 (provided that, when p is 1, the total sum of carbon atoms in R.sup.6 and R.sup.7 does not exceed 13).

    Method and apparatus for controlling warning-information
    8.
    发明授权
    Method and apparatus for controlling warning-information 失效
    用于控制警告信息的方法和装置

    公开(公告)号:US06718490B1

    公开(公告)日:2004-04-06

    申请号:US09640940

    申请日:2000-08-17

    IPC分类号: G06F1100

    摘要: A control methods and an apparatus for outputting warning-information corresponding to the degree of the user's proficiency in inputting operations are described. The apparatus performs consecutive operations based on set-up data of an operating procedure, and includes a receiving section to receive the set-up data of the operating procedure, an error detecting section to detect an error, a history data memorizing section to memorize the set-up data and history data of the errors as an error history data, an error risk calculating section to calculate a degree of error occurrence risk corresponding to the set-up data, and a warning-information generating section to generate warning-information, corresponding to the degree of error occurrence risk.

    摘要翻译: 描述用于输出与用户输入操作的程度相对应的警告信息的控制方法和装置。 该装置基于操作程序的设置数据执行连续的操作,并且包括:接收部分,用于接收操作过程的建立数据;检错部分,用于检测错误;历史数据存储部分, 作为错误历史数据的错误的设置数据和历史数据,用于计算与设置数据相对应的错误发生风险程度的错误风险计算部分,以及用于生成警告信息的警告信息生成部分, 对应于错误发生风险的程度。

    Dye image forming process
    10.
    发明授权
    Dye image forming process 失效
    染料成像工艺

    公开(公告)号:US4209328A

    公开(公告)日:1980-06-24

    申请号:US808867

    申请日:1977-06-22

    CPC分类号: C09B29/06 G03C8/18

    摘要: In a dye image forming process in color photography comprising imagewise exposing a photographic element comprising a support and a light sensitive silver halide emulsion layer, and processing the exposed photographic element with an alkaline processing solution in the presence of a dye developer whereby a dye image corresponding to the imagewise exposure is formed by oxidation of said developer as a function of development of silver halide, the improvement which comprises the dye developer being a mono azo dye developer represented by the following formula:X--N.dbd.N--Y--NH--Zwherein X represents a monovalent group selected from an aromatic group, a non-aromatic-heterocyclic active-methylene-containing group, a non-aromatic-heterocyclic active-methyne-containing group, an aliphatic active-methylene-containing group, and an aliphatic active-methyne-containing group; and Y and Z respectively represent divalent and monovalent groups of an aromatic group, at least one of the X, Y and Z has therein at least one of the developer groups which are either capable of developing silver halide or changeable to a group capable of developing silver halide, the azo radical (--N=N--) and the secondary amino radical (--NH--) are respectively attached to the adjacent carbon atoms in Y, the azo radical being attached to an aromatic ring of the aromatic group of X or to the active methylene or methyne of X and is attached to an aromatic ring of the aromatic group of Y, and the amino radical is attached to aromatic rings of Y and Z.

    摘要翻译: 在彩色摄影中的染料成像过程中,包括将包含载体和感光卤化银乳剂层的照相元件成像曝光,并在染料显影剂存在下用碱性处理溶液处理曝光的照相元件,由此染料图像对应 通过作为卤化银显影的函数的所述显影剂的氧化形成图像曝光,其改进包括染料显影剂是由下式表示的单偶氮染料显影剂:XN = NY-NH-Z其中X表示 选自芳族基团,非芳香族 - 杂环类活性亚甲基基团,非芳香族 - 含杂环式含活性甲基的基团,含脂肪族活性亚甲基基团和脂肪族活性甲基 - 含有组; Y和Z分别表示芳族基团的二价和一价基团,X,Y和Z中的至少一个在其中具有能够显影卤化银或能够显影的基团中的至少一种显影剂组 卤化银,偶氮基(-N = N-)和仲氨基(-NH-)分别连接到Y中的相邻碳原子上,偶氮基连接到X的芳族基团的芳环上或 与X的活性亚甲基或次炔连接并连接到Y的芳族基团的芳环上,并且氨基连接到Y和Z的芳环上。