公开(公告)号：US20100103524A1

公开(公告)日：2010-04-29

申请号：US12532953

申请日：2008-03-22

申请人： Joachim Spatz ,  Robert Brunner ,  Theobald Lohmueller

发明人： Joachim Spatz ,  Robert Brunner ,  Theobald Lohmueller

IPC分类号： G02B1/11

CPC分类号： G02B1/11 ,  B81B2203/0361 ,  B81C1/00396 ,  C03C15/00 ,  C03C17/008 ,  C03C17/009 ,  C03C17/10 ,  C03C17/25 ,  C03C17/256 ,  C03C23/0005 ,  C03C23/006 ,  C03C2217/21 ,  C03C2217/212 ,  C03C2217/217 ,  C03C2217/25 ,  C03C2217/254 ,  C03C2217/255 ,  C03C2217/256 ,  C03C2217/27 ,  C03C2217/29 ,  C03C2217/73 ,  C03C2218/111 ,  C03C2218/32 ,  C03C2218/34 ,  G02B1/111

摘要： The invention relates to a method for producing an anti-reflection surface on an optical element, said method comprising the following steps: a) the optical element is prepared; b) uncharged, spherical, micellar polymer units comprising an inner core region and an outer shell region are prepared; and c) at least one region of the surface of the optical element is coated with polymer units in such a way that the polymer units are essentially regularly dispersed in a film-type layer over the surface of the optical element. The invention also relates to an optical element having an anti-reflection surface (28a, 28b, 28c) comprising spherical micellar polymer units (16a, 16b, 16c) having an inner core region (18) and an outer shell region (20) and being essentially regularly dispersed in a film-type layer (26a, 26b, 26c) over the surface of the optical element (22). The invention further relates to an optical element having an anti-reflection surface (34, 34a) comprising metal clusters (32, 32a) and/or metal oxide clusters (38, 38) which are essentially regularly distributed over the surface of the optical element (22).

摘要翻译： 本发明涉及一种在光学元件上制造抗反射表面的方法，所述方法包括以下步骤：a）制备光学元件; b）制备包含内芯区域和外壳区域的不带电荷的球形聚合物单元; 和c）光学元件的表面的至少一个区域以聚合物单元涂覆，使得聚合物单元基本上规则地分散在光学元件的表面上的膜型层中。 本发明还涉及具有防反射表面（28a，28b，28c）的光学元件，该抗反射表面包括具有内核区域（18）和外壳区域（20）的球形胶束聚合物单元（16a，16b，16c）和 基本上规则地分散在光学元件（22）的表面上的膜型层（26a，26b，26c）中。 本发明还涉及一种光学元件，其具有包括金属簇（32,32a）和/或金属氧化物簇（38,38）的抗反射表面（34,34a），其基本上规则地分布在光学元件的表面上 （22）。

公开(公告)号：US20090181315A1

公开(公告)日：2009-07-16

申请号：US12302733

申请日：2007-05-29

申请人： Joachim Spatz ,  Theobald Lohmueller

发明人： Joachim Spatz ,  Theobald Lohmueller

IPC分类号： G03F1/00

CPC分类号： B01D67/0034 ,  B01D67/0072 ,  B01D67/0088 ,  B01D67/009 ,  B01D69/02 ,  B01D71/022 ,  B01D2323/28 ,  B01D2323/36 ,  B01D2325/16 ,  B01D2325/18 ,  G03F1/20

摘要： The invention relates to a method for the production of micro- and/or nanopore mass arrangements on a substrate including functionalization of the substrate surface in selected areas; deposition of colloidal particles that have the capacity to selectively bond to the functionalized areas of the substrate surface from an aqueous dispersion on the substrate surface, during which an ordered monolayer of the particles forms on the substrate surface; separation of non-bound colloidal particles; freezing of the substrate; and sublimation of the residual water on the substrate in the vacuum, during which the short-range order of the particle monolayer is preserved.

摘要翻译： 本发明涉及一种用于在衬底上生产微孔和/或纳米孔质量排列的方法，包括在选定区域中的衬底表面的官能化; 能够从衬底表面上的水性分散体选择性地结合到衬底表面的功能化区域的能力的胶体颗粒的沉积，在此期间粒子的有序单层在衬底表面上形成; 非结合胶体颗粒的分离; 底物冻结; 并在真空中升华底物上的残留水，在此期间粒子单层的短距离顺序得以保留。

公开(公告)号：US08257798B2

公开(公告)日：2012-09-04

申请号：US12595507

申请日：2008-03-12

申请人： Joachim P. Spatz ,  Theobald Lohmueller ,  Marco Arnold

发明人： Joachim P. Spatz ,  Theobald Lohmueller ,  Marco Arnold

IPC分类号： H05H1/00 ,  G01N1/00

CPC分类号： C23C18/14 ,  B82Y5/00 ,  B82Y30/00 ,  C23C18/08 ,  C23C18/1216 ,  C23C18/1237 ,  C23C18/1266 ,  C23C18/1295

摘要： A method for creating extensive variations in size or distance in nanostructure patterns on surfaces preferably includes: a) contacting a substrate with a liquid phase containing organic two-block or multi-block copolymer micelles, which are charged with an inorganic metal compound, by immersion into this liquid phase, during which chemically different polymer domains including inorganic metal compounds enclosed in micelles are deposited on the substrate; b) withdrawing the substrate from the liquid phase at a predetermined withdrawing speed, which is varied continuously or gradually, so that a gradient of the lateral separation length of the polymer domains is produced on the substrate surface; c) converting the deposited inorganic metal compounds by an oxidation- or reduction treatment into inorganic nanoparticles and optionally complete or partial removal of the organic polymer by a plasma treatment, wherein positions and lateral separation length of the nanoparticles obtained are determined by those of deposited polymer domains.

摘要翻译： 用于在表面上形成纳米结构图案的尺寸或距离的广泛变化的方法优选包括：a）通过浸渍使基底与含有无机金属化合物的有机二嵌段或多嵌段共聚物胶束的液相接触 在该液相中，其中包含胶束中的无机金属化合物的化学不同的聚合物域沉积在基底上; b）以预定的抽出速度从液相中取出基材，其以连续或逐渐变化的方式变化，从而在基材表面上产生聚合物区域的横向分离长度的梯度; c）通过氧化或还原处理将沉积的无机金属化合物转化为无机纳米颗粒，并通过等离子体处理任选地完全或部分除去有机聚合物，其中获得的纳米颗粒的位置和横向分离长度由沉积聚合物 域名

公开(公告)号：US20100112234A1

公开(公告)日：2010-05-06

申请号：US12595507

申请日：2008-03-12

申请人： Joachim P. Spatz ,  Theobald Lohmueller ,  Marco Arnold

发明人： Joachim P. Spatz ,  Theobald Lohmueller ,  Marco Arnold

IPC分类号： B05D3/06

CPC分类号： C23C18/14 ,  B82Y5/00 ,  B82Y30/00 ,  C23C18/08 ,  C23C18/1216 ,  C23C18/1237 ,  C23C18/1266 ,  C23C18/1295

摘要： A method for creating extensive variations in size or distance in nanostructure patterns on surfaces preferably includes: a) contacting a substrate with a liquid phase containing organic two-block or multi-block copolymer micelles, which are charged with an inorganic metal compound, by immersion into this liquid phase, during which chemically different polymer domains including inorganic metal compounds enclosed in micelles are deposited on the substrate; b) withdrawing the substrate from the liquid phase at a predetermined withdrawing speed, which is varied continuously or gradually, so that a gradient of the lateral separation length of the polymer domains is produced on the substrate surface; c) converting the deposited inorganic metal compounds by an oxidation- or reduction treatment into inorganic nanoparticles and optionally complete or partial removal of the organic polymer by a plasma treatment, wherein positions and lateral separation length of the nanoparticles obtained are determined by those of deposited polymer domains.

摘要翻译： 用于在表面上形成纳米结构图案的尺寸或距离的广泛变化的方法优选包括：a）通过浸渍使基底与含有无机金属化合物的有机二嵌段或多嵌段共聚物胶束的液相接触 在该液相中，其中包含胶束中的无机金属化合物的化学不同的聚合物域沉积在基底上; b）以预定的抽出速度从液相中取出基材，其以连续或逐渐变化的方式变化，从而在基材表面上产生聚合物区域的横向分离长度的梯度; c）通过氧化或还原处理将沉积的无机金属化合物转化为无机纳米颗粒，并通过等离子体处理任选地完全或部分除去有机聚合物，其中获得的纳米颗粒的位置和横向分离长度由沉积聚合物 域名