公开(公告)号：US20140216555A1

公开(公告)日：2014-08-07

申请号：US13980404

申请日：2012-01-20

申请人： Eray S. Aydil ,  David J. Norris ,  Ankur Khare ,  Andrew Wilke Wills ,  Banu Selin Tosun

发明人： Eray S. Aydil ,  David J. Norris ,  Ankur Khare ,  Andrew Wilke Wills ,  Banu Selin Tosun

IPC分类号： H01L31/032 ,  H01L31/18

CPC分类号： H01L31/0326 ,  C23C18/1204 ,  C23C18/1225 ,  C23C18/1266 ,  H01L21/02557 ,  H01L21/0256 ,  H01L21/02568 ,  H01L21/02601 ,  H01L21/02628 ,  H01L31/035218 ,  H01L31/068 ,  H01L31/072 ,  H01L31/1864 ,  Y02E10/547

摘要： Metal chalcogenides, and methods of making and using metal chalcogenides, are disclosed herein. Metal chalcogenides can be prepared by heating suitable copper, zinc, and/or tin compounds selected from the group consisting of chalcogenocarbamates, dichalcogenocarbamates, mercaptides, thiiocarbonates, trithiocarbonates, and combinations thereof (e.g., copper, zinc, and/or tin dichalcogenocarbamates) under conditions effective to form metal can be used, for example, to prepare solar cells.

摘要翻译： 金属硫族化物，以及制造和使用金属硫族化物的方法。 金属硫族化物可以通过加热合适的选自硫属碳酸氢盐，二硫代碳酸铵，硫醇盐，硫代碳酸盐，三硫代碳酸盐及其组合（例如铜，锌和/或锡二硫代碳酸氢铵）的铜，锌和/或锡化合物来制备， 可以使用有效形成金属的条件，例如制备太阳能电池。

公开(公告)号：US08183108B2

公开(公告)日：2012-05-22

申请号：US12301791

申请日：2006-06-15

申请人： William J. Borland ,  Seigi Suh ,  Jon-Paul Maria ,  Jon Fredrick Ihlefeld ,  Ian Burn

发明人： William J. Borland ,  Seigi Suh ,  Jon-Paul Maria ,  Jon Fredrick Ihlefeld ,  Ian Burn

IPC分类号： H01L21/20 ,  H01B3/20 ,  H01B3/00

CPC分类号： H01L21/31691 ,  C23C18/1212 ,  C23C18/1241 ,  C23C18/1266 ,  C23C18/1283 ,  C23C18/1295 ,  H01G4/129 ,  H05K1/162 ,  H05K2201/017 ,  H05K2201/0355

摘要： A method of making dense dielectrics layers via chemical solution deposition by adding inorganic glass fluxed material to high dielectric constant compositions, depositing the resultant mixture onto a substrate and annealing the substrate at temperatures between the softening point of the inorganic glass flux and the melting point of the substrate. A method of making a capacitor comprising a dense dielectric layer.

摘要翻译： 一种通过在高介电常数组合物中添加无机玻璃助熔材料，通过化学溶液沉积制造致密电介质层的方法，将所得混合物沉积在基材上，并在无机玻璃熔剂的软化点和熔点之间的温度 底物。 一种制造包括致密介电层的电容器的方法。

公开(公告)号：US08038909B2

公开(公告)日：2011-10-18

申请号：US11933338

申请日：2007-10-31

申请人： Dong Yu ,  Jacqueline Fidanza ,  Brian M. Sager

发明人： Dong Yu ,  Jacqueline Fidanza ,  Brian M. Sager

IPC分类号： H01B1/10 ,  H01B1/12 ,  H01B1/14 ,  H01B1/20 ,  H01L31/20

CPC分类号： H01L31/06 ,  B82Y5/00 ,  B82Y10/00 ,  B82Y30/00 ,  C23C18/1204 ,  C23C18/1266 ,  C23C18/1295 ,  H01L31/0322 ,  H01L31/0749 ,  H01L31/18 ,  Y02E10/541 ,  Y02P70/521

摘要： An ink for forming CIGS photovoltaic cell active layers is disclosed along with methods for making the ink, methods for making the active layers and a solar cell made with the active layer. The ink contains a mixture of nanoparticles of elements of groups IB, IIIA and (optionally) VIA. The particles are in a desired particle size range of between about 1 nm and about 500 nm in diameter, where a majority of the mass of the particles comprises particles ranging in size from no more than about 40% above or below an average particle size or, if the average particle size is less than about 5 nanometers, from no more than about 2 nanometers above or below the average particle size. The use of such ink avoids the need to expose the material to an H2Se gas during the construction of a photovoltaic cell and allows more uniform melting during film annealing, more uniform intermixing of nanoparticles, and allows higher quality absorber films to be formed.

摘要翻译： 公开了一种用于形成CIGS光伏电池有源层的墨水以及用于制造墨水的方法，制备活性层的方法和由活性层制成的太阳能电池。 油墨含有IB，IIIA和（任选地）VIA组分的纳米颗粒的混合物。 颗粒的直径在约1nm至约500nm之间的所需粒度范围，其中大部分颗粒的质量包括尺寸不超过平均粒度的约40％或以下的颗粒，或 如果平均粒度小于约5纳米，高于或低于平均粒度的不超过约2纳米。 使用这种墨水避免了在构建光伏电池期间将材料暴露于H 2 Se气体的需要，并且允许在膜退火期间更均匀的熔融，更均匀的纳米颗粒的混合，并且允许形成更高质量的吸收膜。

公开(公告)号：US20090009563A1

公开(公告)日：2009-01-08

申请号：US12165591

申请日：2008-06-30

申请人： Hiroyuki KAMEI

发明人： Hiroyuki KAMEI

IPC分类号： B41J2/045

CPC分类号： C23C18/1216 ,  B41J2/14233 ,  B41J2002/14241 ,  B41J2002/14419 ,  B41J2202/03 ,  C23C18/12 ,  C23C18/1254 ,  C23C18/1266 ,  H01L41/1876 ,  H01L41/318

摘要： A composition for ferroelectric thin film formation, comprising at least a colloidal solution containing metals serving as materials constituting a ferroelectric thin film, the colloidal solution having an average colloidal particle diameter of 1 to 100 nm, and obtaining a particle size distribution having two or more peaks; a ferroelectric thin film formed from the composition for ferroelectric thin film formation, and a liquid-jet head equipped with a piezoelectric element having the ferroelectric thin film.

摘要翻译： 一种铁电薄膜形成用组合物，至少包含含有构成铁电薄膜的材料的胶体溶液，所述胶体溶液的平均胶体粒径为1〜100nm，得到具有2个以上的粒径分布的粒径分布 山峰 由用于铁电薄膜形成的组合物形成的铁电薄膜，以及配备有具有铁电薄膜的压电元件的液体喷射头。

公开(公告)号：US20080142081A1

公开(公告)日：2008-06-19

申请号：US11933136

申请日：2007-10-31

申请人： Dong Yu ,  Jacqueline Fidanza ,  Brian M. Sager

发明人： Dong Yu ,  Jacqueline Fidanza ,  Brian M. Sager

IPC分类号： H01L31/0216 ,  C09D11/00 ,  B05C1/08

CPC分类号： H01L31/06 ,  B82Y5/00 ,  B82Y10/00 ,  B82Y30/00 ,  C23C18/1204 ,  C23C18/1266 ,  C23C18/1295 ,  H01L31/0322 ,  H01L31/0749 ,  H01L31/18 ,  Y02E10/541 ,  Y02P70/521

摘要： An ink for forming CIGS photovoltaic cell active layers is disclosed along with methods for making the ink, methods for making the active layers and a solar cell made with the active layer. The ink contains a mixture of nanoparticles of elements of groups IB, IIIA and (optionally) VIA. The particles are in a desired particle size range of between about 1 nm and about 500 nm in diameter, where a majority of the mass of the particles comprises particles ranging in size from no more than about 40% above or below an average particle size or, if the average particle size is less than about 5 nanometers, from no more than about 2 nanometers above or below the average particle size. The use of such ink avoids the need to expose the material to an H2Se gas during the construction of a photovoltaic cell and allows more uniform melting during film annealing, more uniform intermixing of nanoparticles, and allows higher quality absorber films to be formed.

公开(公告)号：US20080135812A1

公开(公告)日：2008-06-12

申请号：US11933400

申请日：2007-10-31

申请人： Dong Yu ,  Jacqueline Fidanza ,  Brian M. Sager

发明人： Dong Yu ,  Jacqueline Fidanza ,  Brian M. Sager

IPC分类号： H01B1/02 ,  B05D1/00 ,  B05D1/02 ,  B01J19/10 ,  B41F31/00

CPC分类号： H01L31/06 ,  B82Y5/00 ,  B82Y10/00 ,  B82Y30/00 ,  C23C18/1204 ,  C23C18/1266 ,  C23C18/1295 ,  H01L31/0322 ,  H01L31/0749 ,  H01L31/18 ,  Y02E10/541 ,  Y02P70/521

摘要： An ink for forming CIGS photovoltaic cell active layers is disclosed along with methods for making the ink, methods for making the active layers and a solar cell made with the active layer. The ink contains a mixture of nanoparticles of elements of groups IB, IIIA and (optionally) VIA. The particles are in a desired particle size range of between about 1 nm and about 500 nm in diameter, where a majority of the mass of the particles comprises particles ranging in size from no more than about 40% above or below an average particle size or, if the average particle size is less than about 5 nanometers, from no more than about 2 nanometers above or below the average particle size. The use of such ink avoids the need to expose the material to an H2Se gas during the construction of a photovoltaic cell and allows more uniform melting during film annealing, more uniform intermixing of nanoparticles, and allows higher quality absorber films to be formed.

公开(公告)号：US20080135811A1

公开(公告)日：2008-06-12

申请号：US11933375

申请日：2007-10-31

申请人： Dong Yu ,  Jacqueline Fidanza ,  Brian M. Sager

发明人： Dong Yu ,  Jacqueline Fidanza ,  Brian M. Sager

IPC分类号： H01B1/02

CPC分类号： H01L31/06 ,  B82Y5/00 ,  B82Y10/00 ,  B82Y30/00 ,  C23C18/1204 ,  C23C18/1266 ,  C23C18/1295 ,  H01L31/0322 ,  H01L31/0749 ,  H01L31/18 ,  Y02E10/541 ,  Y02P70/521

摘要： An ink for forming CIGS photovoltaic cell active layers is disclosed along with methods for making the ink, methods for making the active layers and a solar cell made with the active layer. The ink contains a mixture of nanoparticles of elements of groups IB, IIIA and (optionally) VIA. The particles are in a desired particle size range of between about 1 nm and about 500 nm in diameter, where a majority of the mass of the particles comprises particles ranging in size from no more than about 40% above or below an average particle size or, if the average particle size is less than about 5 nanometers, from no more than about 2 nanometers above or below the average particle size. The use of such ink avoids the need to expose the material to an H2Se gas during the construction of a photovoltaic cell and allows more uniform melting during film annealing, more uniform intermixing of nanoparticles, and allows higher quality absorber films to be formed.

公开(公告)号：US08617710B2

公开(公告)日：2013-12-31

申请号：US13577661

申请日：2011-02-07

申请人： Ari Auvinen ,  Jorma Jokiniemi ,  Pipsa Mattila ,  Unto Tapper

发明人： Ari Auvinen ,  Jorma Jokiniemi ,  Pipsa Mattila ,  Unto Tapper

IPC分类号： B32B5/16

CPC分类号： B22F9/22 ,  B22F1/0018 ,  B22F1/02 ,  B22F1/025 ,  B22F9/24 ,  B22F2999/00 ,  C01P2004/64 ,  C01P2006/42 ,  C09C1/62 ,  C22C19/07 ,  C23C18/08 ,  C23C18/1216 ,  C23C18/1266 ,  C23C18/1279 ,  B22F2201/013 ,  B22F2201/02 ,  B22F2201/11

摘要： The present invention relates to a process for forming cobalt nanoparticles and coating them with copper or copper oxide, in which process a copper salt is mixed to a cobalt salt so that the formed salt mixture obtains a cobalt:copper ratio of >1:1, and a reduction is carried out with a reducing gas, whereby nanoparticles are formed while a coating is formed onto their surface.

摘要翻译： 本发明涉及一种用于形成钴纳米颗粒并用铜或氧化铜涂覆的方法，其中将铜盐与钴盐混合，使得形成的盐混合物获得的钴：铜比> 1:1， 并用还原气体进行还原，由此在其表面上形成涂层时形成纳米颗粒。

公开(公告)号：US08133579B2

公开(公告)日：2012-03-13

申请号：US12666540

申请日：2008-06-26

申请人： Martin Mennig ,  Helmut Schmidt

发明人： Martin Mennig ,  Helmut Schmidt

IPC分类号： B32B7/02 ,  B05D3/02

CPC分类号： C23C18/1279 ,  C23C18/1212 ,  C23C18/1225 ,  C23C18/1241 ,  C23C18/1254 ,  C23C18/1266 ,  C23C18/1275 ,  Y10T428/24388 ,  Y10T428/249921 ,  Y10T428/25 ,  Y10T428/252 ,  Y10T428/256 ,  Y10T428/257 ,  Y10T428/258 ,  Y10T428/259 ,  Y10T428/265

摘要： The invention relates to a metal substrate comprising an ultra-hard composite layer consisting of an inorganic, vitreous matrix containing one or more abrasive fillers. According to the invention, the diameter of the filler particles or, if the filler particles have a platelet-type form, the thickness of the filler particles is less than the layer thickness of the composite layer.

摘要翻译： 本发明涉及包含由含有一种或多种磨料填料的无机玻璃质基质组成的超硬复合层的金属基材。 根据本发明，填料颗粒的直径，或者如果填料颗粒具有血小板形式，填料颗粒的厚度小于复合层的层厚度。

公开(公告)号：US08088309B2

公开(公告)日：2012-01-03

申请号：US11933400

申请日：2007-10-31

申请人： Dong Yu ,  Jacqueline Fidanza ,  Brian M. Sager

发明人： Dong Yu ,  Jacqueline Fidanza ,  Brian M. Sager

IPC分类号： H01B1/22 ,  B05D5/12

CPC分类号： H01L31/06 ,  B82Y5/00 ,  B82Y10/00 ,  B82Y30/00 ,  C23C18/1204 ,  C23C18/1266 ,  C23C18/1295 ,  H01L31/0322 ,  H01L31/0749 ,  H01L31/18 ,  Y02E10/541 ,  Y02P70/521

摘要： An ink for forming CIGS photovoltaic cell active layers is disclosed along with methods for making the ink, methods for making the active layers and a solar cell made with the active layer. The ink contains a mixture of nanoparticles of elements of groups IB, IIIA and (optionally) VIA. The particles are in a desired particle size range of between about 1 nm and about 500 nm in diameter, where a majority of the mass of the particles comprises particles ranging in size from no more than about 40% above or below an average particle size or, if the average particle size is less than about 5 nanometers, from no more than about 2 nanometers above or below the average particle size. The use of such ink avoids the need to expose the material to an H2Se gas during the construction of a photovoltaic cell and allows more uniform melting during film annealing, more uniform intermixing of nanoparticles, and allows higher quality absorber films to be formed.

摘要翻译： 公开了一种用于形成CIGS光伏电池有源层的墨水以及用于制备墨水的方法，制备活性层的方法和由活性层制成的太阳能电池。 油墨含有IB，IIIA和（任选地）VIA组分的纳米颗粒的混合物。 颗粒的直径在约1nm至约500nm之间的所需粒度范围，其中大部分颗粒的质量包括尺寸不超过平均粒度的约40％或以下的颗粒，或 如果平均粒度小于约5纳米，高于或低于平均粒度的不超过约2纳米。 使用这种墨水避免了在构建光伏电池期间将材料暴露于H 2 Se气体的需要，并且允许在膜退火期间更均匀的熔融，更均匀的纳米颗粒的混合，并且允许形成更高质量的吸收膜。