公开(公告)号：US4179359A

公开(公告)日：1979-12-18

申请号：US924112

申请日：1978-07-12

申请人： John C. Hayes ,  Ernest L. Pollitzer

发明人： John C. Hayes ,  Ernest L. Pollitzer

IPC分类号： B01J23/89 ,  B01J27/08 ,  C10G35/09 ,  C10G49/06 ,  C10G35/08

CPC分类号： B01J23/8966 ,  B01J23/8913 ,  B01J27/08 ,  C10G35/09 ,  C10G49/06

摘要： Hydrocarbons are converted by contacting them at hydrocarbon conversion conditions with an acidic multimetallic catalytic composite comprising a combination of catalytically effective amounts of a platinum or palladium component, an iridium component, a cobalt component, a Group IVA metallic component and a halogen component with a porous carrier material. The platinum or palladium iridium, cobalt, Group IVA metallic and halogen components are present in the multimetallic catalyst in amounts, respectively, calculated on an elemental basis, corresponding to about 0.01 to about 2 wt. % platinum or palladium, about 0.01 to about 2 wt. % iridium, about 0.05 to about 5 wt. % cobalt, about 0.01 to about 5 wt. % Group IVA metal and about 0.1 to about 3.5 wt. % halogen. These metallic components are, moreover, uniformly dispersed throughout the porous carrier material in carefully controlled oxidation states such that substantially all of the platinum or palladium and iridium are present therein in the elemental metallic state, substantially all of the Group IVA metal is in a positive oxidation state and substantially all of the catalytically available cobalt component is present in the elemental metallic state or in a state which is reducible to the elemental metallic state under hydrocarbon conversion conditions or in a mixture of these states. A specific example of the type of hydrocarbon conversion process disclosed is a process for the catalytic reforming of a low-octane gasoline fraction wherein the gasoline fraction and a hydrogen stream are contacted with the acidic multimetallic catalyst disclosed herein at reforming conditions.

摘要翻译： 碳氢化合物通过在烃转化条件下与酸性多金属催化复合物接触而转化，所述酸性多金属催化复合材料包含催化有效量的铂或钯组分，铱组分，钴组分，IVA族金属组分和卤素组分的组合， 载体材料。 铂或钯铱，钴，IVA族金属和卤素组分分别以基于元素计算的量存在于多金属催化剂中，相当于约0.01至约2重量％ ％铂或钯，约0.01至约2重量％ ％铱，约0.05至约5wt。 ％钴，约0.01至约5wt。 ％IVA族金属和约0.1至约3.5重量％ ％卤素。 此外，这些金属组分在仔细控制的氧化态下均匀地分散在整个多孔载体材料中，使得基本上所有的铂或钯和铱以元素金属状态存在，基本上所有的IVA族金属都是正的 氧化态和基本上所有的催化可用的钴组分以元素金属状态存在，或以在烃转化条件下或在这些状态的混合物中可还原成元素金属状态的状态存在。 所公开的烃转化方法的具体实例是一种低辛烷值汽油馏分的催化重整方法，其中汽油馏分和氢气流在重整条件下与本文公开的酸性多金属催化剂接触。

公开(公告)号：US4018668A

公开(公告)日：1977-04-19

申请号：US541674

申请日：1975-01-16

申请人： Ernest L. Pollitzer ,  John C. Hayes

发明人： Ernest L. Pollitzer ,  John C. Hayes

IPC分类号： B01J23/89 ,  C10G35/09 ,  C10G35/08 ,  B01J23/74 ,  C07C5/28 ,  C10G13/02

CPC分类号： B01J23/8966 ,  C10G35/09

摘要： Hydrocarbons are converted by contacting them at hydrocarbon conversion conditions with an acidic multimetallic sulfur-free catalytic composite comprising a combination of catalytically effective and specially selected amounts of a platinum group component, a lead component, a cobalt component, and a halogen component with a porous carrier material. The platinum group component, lead component, cobalt component, and halogen component are present in the multimetallic catalyst in amounts respectively, calculated on an elemental basis, corresponding to about 0.01 to about 2 wt. % platinum group metal, about 0.1 to about 3.5 wt. % halogen, an atomic ratio of lead to platinum group metal of about 0.5:1 to about 1.5:1 and an atomic ratio of cobalt to platinum group metal of at least about 5:1 to about 25:1. Moreover, these metallic components are uniformly dispersed throughout the porous carrier material in carefully controlled oxidation states and in the absence of sulfur such that substantially all of the platinum group metal is present therein in the elemental metallic state, substantially all of the cobalt component is present in the elemental metallic state or in a state which is reducible to the elemental metallic state under hydrocarbon conversion conditions, while substantially all of the lead is present therein in an oxidation state above that of the elemental metal. A specifc example of the type of hydrocarbon conversion process disclosed is a process for the catalytic reforming of a low-octane gasoline fraction wherein the gasoline fraction and a hydrogen stream are contacted with the acidic multimetallic sulfur-free catalyst disclosed herein at reforming conditions.

摘要翻译： 碳氢化合物通过在烃转化条件下与酸性多金属无硫催化复合物接触而转化，所述催化复合材料包含催化有效和特别选择量的铂族组分，铅组分，钴组分和卤素组分的组合， 载体材料。 铂族组分，铅组分，钴组分和卤素组分分别以基于元素计算的量存在于多金属催化剂中，相当于约0.01至约2重量％ ％铂族金属，约0.1至约3.5wt。 ％卤素，铅与铂族金属的原子比为约0.5:1至约1.5:1，钴与铂族金属的原子比为至少约5:1至约25:1。 此外，这些金属组分在仔细控制的氧化状态下并且在不存在硫的情况下均匀分散在整个多孔载体材料中，使得基本上所有的铂族金属存在于元素金属状态中，基本上所有的钴组分都存在 在元素金属状态或在烃转化条件下可还原成元素金属状态的状态下，而基本上所有的铅都存在于比元素金属高的氧化态下。 公开的烃转化方法类型的具体实例是一种低辛烷值汽油馏分的催化重整方法，其中汽油馏分和氢气流在重整条件下与本文公开的酸性多金属无硫催化剂接触。

公开(公告)号：US4009123A

公开(公告)日：1977-02-22

申请号：US632041

申请日：1975-11-14

申请人： Ernest L. Pollitzer ,  John C. Hayes

发明人： Ernest L. Pollitzer ,  John C. Hayes

IPC分类号： B01J23/89 ,  B01J27/08 ,  C10G35/09 ,  C10G47/14 ,  C10G49/06 ,  B01J27/06

CPC分类号： C10G49/06 ,  B01J23/8966 ,  B01J27/08 ,  C10G35/09 ,  C10G47/14 ,  C07C2521/04 ,  C07C2523/02 ,  C07C2523/04 ,  C07C2523/14 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/46 ,  C07C2523/75 ,  C07C2523/89

摘要： Hydrocarbons are converted by contacting them at hydrocarbon conversion conditions with an acidic multimetallic catalytic composite comprising a combination of catalytically effective amounts of a platinum group component, a tin component, a cobalt component and a halogen component with a porous carrier material. The platinum group component, tin component, cobalt component, and halogen component are present in the multimetallic catalyst in amounts respectively, calculated on an elemental basis, corresponding to about 0.01 to about 2 wt. % platinum group metal, about 0.01 to about 5 wt. % tin, about 0.5 to about 5 wt. % cobalt, and about 0.1 to about 3.5 wt. % halogen. Moreover, these metallic components are uniformly dispersed throughout the porous carrier material in carefully controlled oxidation states such that substantially all of the platinum group metal is present therein in the elemental metallic state, substantially all of the cobalt component is present in the elemental metallic state or in a state which is reducible to the elemental metallic state under hydrocarbon conversion conditions, while substantially all of the tin is present therein in an oxidation state above that of the elemental metal. A specific example of the type of hydrocarbon conversion process disclosed is a process for the catalytic reforming of a low-octane gasoline fraction wherein the gasoline fraction and a hydrogen stream are contacted with the acidic multimetallic catalyst disclosed herein at reforming conditions.

摘要翻译： 通过在烃转化条件下与含有催化有效量的铂族组分，锡组分，钴组分和卤素组分与多孔载体材料的组合的酸性多金属催化复合物接触来转化烃。 铂族组分，锡组分，钴组分和卤素组分分别以基于元素计算的量存在于多金属催化剂中，相当于约0.01至约2重量％ ％铂族金属，约0.01至约5wt。 ％锡，约0.5至约5wt。 ％钴，和约0.1至约3.5wt。 ％卤素。 此外，这些金属组分在仔细控制的氧化状态下均匀地分散在整个多孔载体材料中，使得基本上所有的铂族金属都以元素金属状态存在，基本上所有的钴组分都以元素金属状态存在，或者 在碳氢化合物转化条件下可还原成元素金属状态的状态，而基本上全部锡以比元素金属高的氧化态存在。 所公开的烃转化方法的具体实例是一种低辛烷值汽油馏分的催化重整方法，其中汽油馏分和氢气流在重整条件下与本文公开的酸性多金属催化剂接触。

公开(公告)号：US4075259A

公开(公告)日：1978-02-21

申请号：US737352

申请日：1976-11-01

申请人： Ernest L. Pollitzer ,  John C. Hayes

发明人： Ernest L. Pollitzer ,  John C. Hayes

IPC分类号： B01J23/89 ,  B01J27/08 ,  C07C5/27 ,  C10G35/09 ,  C10G45/62 ,  C07C5/28

CPC分类号： C10G45/62 ,  B01J23/8913 ,  B01J23/8966 ,  B01J27/08 ,  C07C5/2724 ,  C10G35/09 ,  C10G2400/02 ,  Y02P20/582

摘要： Saturated hydrocarbons are isomerized using a catalyst comprising a combination of a platinum group component, a cobalt component, a tin component and a halogen component with a porous carrier material. The cobalt and platinum group components are reduced to the metallic state while the tin is present in a positive oxidation state.

摘要翻译： 使用包含铂族组分，钴组分，锡组分和卤素组分的组合的催化剂与多孔载体材料异构化饱和烃。 钴和铂族组分被还原为金属状态，而锡以正氧化态存在。

公开(公告)号：US4069269A

公开(公告)日：1978-01-17

申请号：US737353

申请日：1976-11-01

申请人： Ernest L. Pollitzer ,  John C. Hayes

发明人： Ernest L. Pollitzer ,  John C. Hayes

IPC分类号： B01J23/89 ,  B01J27/08 ,  C07C5/27 ,  C10G35/09 ,  C10G45/62 ,  C07C13/08

CPC分类号： C10G45/62 ,  B01J23/8913 ,  B01J23/8966 ,  B01J27/08 ,  C07C5/2724 ,  C10G35/09 ,  C10G2400/02 ,  Y02P20/582

摘要： Isomerizable hydrocarbons are isomerized using a catalyst comprising a combination of a platinum group component, a cobalt component, a tin component and a halogen component with a porous carrier material. The cobalt and platinum group components are reduced to the metallic state while the tin is present in a positive oxidation state.

摘要翻译： 使用包含铂族组分，钴组分，锡组分和卤素组分的组合的催化剂与多孔载体材料异构化异构化烃。 钴和铂族组分被还原为金属状态，而锡以正氧化态存在。

公开(公告)号：US4018669A

公开(公告)日：1977-04-19

申请号：US687135

申请日：1976-05-17

申请人： John C. Hayes ,  Ernest L. Pollitzer

发明人： John C. Hayes ,  Ernest L. Pollitzer

IPC分类号： B01J23/89 ,  B01J27/08 ,  C10G35/09 ,  C10G47/14 ,  C10G35/08

CPC分类号： C10G47/14 ,  B01J23/8913 ,  B01J23/8966 ,  B01J27/08 ,  C10G35/09 ,  C07C2521/04 ,  C07C2523/02 ,  C07C2523/04 ,  C07C2523/14 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/46 ,  C07C2523/75 ,  C07C2523/89

摘要： Hydrocarbons are converted by contacting them at hydrocarbon conversion conditions with an acidic multimetallic catalytic composite comprising a combination of catalytically effective amounts of a platinum or palladium component, a rhodium component, a cobalt component, and a halogen component with a porous carrier material. A preferred modifying component for the disclosed catalytic composite is a Group IVA metallic component. The platinum or palladium, rhodium, cobalt and halogen components are present in the multimetallic catalyst in amounts respectively, calculated on an elemental basis, corresponding to about 0.01 to about 2 wt. % platinum or palladium, about 0.01 to about 2 wt. % rhodium, about 0.05 to about 5 wt. % cobalt, and about 0.1 to about 3.5 wt. % halogen. Moreover, these metallic components are uniformly dispersed throughout the porous carrier material in carefully controlled oxidation states such that substantially all of the platinum or palladium and rhodium components are present therein in the elemental metallic state and substantially all of the catalytically available cobalt component is present in the elemental metallic state or in a state which is reducible to the elemental metallic state under hydrocarbon conversion conditions or in a mixture of these states. A specific example of the type of hydrocarbon conversion process disclosed is a process for the catalytic reforming of a low-octane gasoline fraction wherein the gasoline fraction and a hydrogen stream are contacted with the acidic multimetallic catalyst disclosed herein at reforming conditions.

摘要翻译： 通过在碳氢化合物转化条件下与含有催化有效量的铂或钯组分，铑组分，钴组分和卤素组分与多孔载体材料的组合的酸性多金属催化复合物接触来转化碳氢化合物。 所公开的催化复合材料的优选改性组分是IVA族金属组分。 铂或钯，铑，钴和卤素组分分别以基于元素计算的量存在于多金属催化剂中，相当于约0.01至约2重量％ ％铂或钯，约0.01至约2重量％ ％铑，约0.05至约5wt。 ％钴，和约0.1至约3.5wt。 ％卤素。 此外，这些金属组分在仔细控制的氧化状态下均匀地分散在整个多孔载体材料中，使得基本上所有的铂或钯和铑组分都存在于元素金属状态中，并且基本上所有的催化可用的钴组分存在于 元素金属状态或在碳氢化合物转化条件下或在这些状态的混合物中可还原成元素金属状态的状态。 所公开的烃转化方法的具体实例是一种低辛烷值汽油馏分的催化重整方法，其中汽油馏分和氢气流在重整条件下与本文公开的酸性多金属催化剂接触。

公开(公告)号：US4013548A

公开(公告)日：1977-03-22

申请号：US715813

申请日：1976-08-19

申请人： Ernest L. Pollitzer ,  John C. Hayes

发明人： Ernest L. Pollitzer ,  John C. Hayes

IPC分类号： B01J23/89 ,  B01J27/08 ,  C10G35/09 ,  C10G45/40 ,  C10G47/14 ,  C10G23/04 ,  B01J23/58

CPC分类号： B01J27/08 ,  B01J23/8966 ,  C10G35/09 ,  C10G45/40 ,  C10G47/14 ,  Y10S585/94

摘要： A process for hydrotreating (hydroprocessing) hydrocarbons and mixtures of hydrocarbons utilizing a catalytic composite comprising a porous carrier material containing, on an elemental basis, about 0.01 to about 2 wt. % platinum group metal, about 0.5 to about 5 wt. % cobalt, about 0.01 to about 5 wt. % germanium and about 0.1 to about 3.5 wt. % halogen, wherein the platinum group metal, cobalt and germanium are uniformly dispersed throughout the porous carrier material, wherein substantially all of the platinum group metal is present in the elemental metallic state, wherein substantially all of the germanium is present in an oxidation state above that of the elemental metal, and wherein substantially all of the cobalt is present in the elemental metallic state or in a state which is reducible to the elemental metallic state under hydrocarbon conversion conditions or in a mixture of these states, in which process there is effected a chemical consumption of hydrogen. A specific example of one such catalyst is a composite of a crystalline aluminosilicate, a platinum group metal component, a cobalt component, a germanium component, and a halogen component, for utilization in a hydrocracking process. Other hydrocarbon hydroprocesses are directed toward hydrogenation of aromatic nuclei, the ring-opening of cyclic hydrocarbons, hydrogenation, etc.

摘要翻译： 使用包含多孔载体材料的催化复合物加氢处理（加氢处理）烃和烃的混合物的方法，该多孔载体材料在元素基础上含有约0.01至约2wt。 ％铂族金属，约0.5至约5wt。 ％钴，约0.01至约5wt。 ％锗和约0.1至约3.5重量％ ％卤素，其中铂族金属，钴和锗均匀地分散在整个多孔载体材料中，其中基本上所有的铂族金属以元素金属状态存在，其中基本上所有的锗以上述氧化态存在 并且其中基本上所有的钴以元素金属状态存在，或者在碳氢化合物转化条件下或以这些状态的混合物中可还原成元素金属状态的状态下，其中所述方法受到影响 氢的化学消耗。 一种这样的催化剂的具体实例是结晶硅铝酸盐，铂族金属组分，钴组分，锗组分和卤素组分的复合物，用于加氢裂化过程。 其他烃类加氢工艺涉及芳烃氢化，环状烃开环，氢化等。

公开(公告)号：US4009220A

公开(公告)日：1977-02-22

申请号：US670015

申请日：1976-03-24

申请人： Ernest L. Pollitzer ,  John C. Hayes

发明人： Ernest L. Pollitzer ,  John C. Hayes

IPC分类号： B01J23/89 ,  B01J27/08 ,  C07C5/41 ,  C10G35/09 ,  C10G47/14 ,  C07C3/04

CPC分类号： C07C5/417 ,  B01J23/8966 ,  B01J27/08 ,  C10G35/09 ,  C10G47/14 ,  C07C2521/12 ,  C07C2523/14 ,  C07C2523/40 ,  C07C2523/75 ,  C07C2523/89 ,  C07C2527/06

摘要： Dehydrocyclizable hydrocarbons are converted to aromatics by contacting them at dehydrocyclization conditions with an acidic multimetallic catalytic composite comprising a combination of catalytically effective amounts of a platinum group component, a germanium component, a cobalt component, and a halogen component with a porous carrier material. The platinum group, germanium, cobalt and halogen components are present in the acidic multimetallic catalyst in amounts respectively, calculated on an elemental basis, corresponding to about 0.01 to about 2 wt. % platinum group metal, about 0.1 to about 5 wt. % cobalt, about 0.01 to about 5 wt. % germanium, and about 0.1 to about 3.5 wt. % halogen. Moreover, the catalytically active sites induced by these metallic components are uniformly dispersed throughout the porous carrier material and these metallic components are present in the catalyst in carefully controlled oxidation states such that substantially all of the platinum group component is in the elemental metallic state, substantially all of the germanium component is in an oxidation state above that of the elemental metal, and substantially all of the catalytically available cobalt is in the elemental metallic state or in a state which is reducible to the elemental metallic state under dehydrocyclization conditions, or in a mixture of these states. A specific example of dehydrocyclization method disclosed herein is a method for converting a feed mixture of n-hexane and n-heptane to a product mixture of benzene and toluene which involves contacting the feed mixture and a hydrogen stream with the acidic multimetallic catalyst disclosed herein at dehydrocyclization conditions.

公开(公告)号：US3960711A

公开(公告)日：1976-06-01

申请号：US564386

申请日：1975-04-02

申请人： George J. Antos ,  John C. Hayes ,  Ernest L. Pollitzer

发明人： George J. Antos ,  John C. Hayes ,  Ernest L. Pollitzer

IPC分类号： B01J23/89 ,  C10G35/09 ,  C10G35/08 ,  C07C5/30 ,  C10G13/10

CPC分类号： B01J23/8986 ,  C10G35/09

摘要： Hydrocarbons are converted by contacting them at hydrocarbon conversion conditions with an acidic multimetallic catalytic composite, comprising a combination of catalytically effective amounts of a platinum group component, a rhenium component, a tin component, a cobalt component, and a halogen component with a porous carrier material. The platinum group component, rhenium component, tin component, cobalt component, and halogen component are present in the multimetallic catalyst in amounts respectively, calculated on an elemental basis, corresponding to about 0.01 to about 2 wt. % platinum group metal, about 0.01 to about 2 wt. % rhenium, about 0.01 to about 5 wt. % tin, about 0.05 to about 5 wt. % cobalt, and about 0.1 to about 3.5 wt. % halogen. Moreover, these metallic components are uniformly dispersed throughout the porous carrier material in carefully controlled oxidation states such that substantially all of the platinum group metal is present therein in the elemental metallic state, substantially all of the cobalt and rhenium components are present in the corresponding elemental metallic state or in a state which is reducible to the corresponding elemental metallic state under hydrocarbon conversion conditions or in a mixture of these states, while substantially all of the tin is present therein in an oxidation state above that of the elemental metal. A specific example of the type of hydrocarbon conversion process disclosed is a process for the catalytic reforming of a low-octane gasoline fraction wherein the gasoline fraction and a hydrogen stream are contacted with the acidic multimetallic catalyst disclosed herein at reforming conditions.

摘要翻译： 碳氢化合物通过在烃转化条件下与酸性多金属催化复合物接触而转化，其包含催化有效量的铂族组分，铼组分，锡组分，钴组分和卤素组分与多孔载体的组合 材料。 铂族组分，铼组分，锡组分，钴组分和卤素组分分别以基于元素计算的量存在于多金属催化剂中，相当于约0.01至约2重量％ ％铂族金属，约0.01至约2重量％ ％铼，约0.01至约5wt。 ％锡，约0.05至约5wt。 ％钴，和约0.1至约3.5wt。 ％卤素。 此外，这些金属组分在仔细控制的氧化状态下均匀分散在整个多孔载体材料中，使得基本上所有的铂族金属存在于元素金属状态中，基本上所有的钴和铼组分存在于相应的元素 金属状态或在烃转化条件下或以这些状态的混合物中还原成相应的元素金属状态的状态，而基本上全部锡以比元素金属高的氧化态存在。 所公开的烃转化方法的具体实例是一种低辛烷值汽油馏分的催化重整方法，其中汽油馏分和氢气流在重整条件下与本文公开的酸性多金属催化剂接触。

公开(公告)号：US4167496A

公开(公告)日：1979-09-11

申请号：US936994

申请日：1978-08-25

申请人： George J. Antos ,  John C. Hayes ,  Ernest L. Pollitzer

发明人： George J. Antos ,  John C. Hayes ,  Ernest L. Pollitzer

IPC分类号： B01J23/89 ,  C07C5/333 ,  C07C5/367 ,  B01J21/04 ,  B01J23/58 ,  B01J23/64 ,  B01J23/78

CPC分类号： C07C5/3337 ,  B01J23/8986 ,  C07C5/367 ,  C07C2521/04 ,  C07C2523/02 ,  C07C2523/04 ,  C07C2523/14 ,  C07C2523/36 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/46 ,  C07C2523/75 ,  C07C2523/89 ,  Y02P20/52

摘要： A nonacidic catalytic composite useful for dehydrogenating hydrocarbons comprises a combination of catalytically effective amounts of a platinum group component, a rhenium component, a cobalt component, a tin component and an alkali or alkaline earth component with a porous carrier material. A specific example of the nonacidic catalytic composite disclosed herein is a combination of a platinum group metal, rhenium, cobalt, tin and an alkali or alkaline earth metal with a porous carrier material in amounts sufficient to result in a composite containing, on an elemental basis, about 0.01 to about 2 wt. % platinum group metal, about 0.01 to about 2 wt. % rhenium, about 0.05 to about 5 wt. % cobalt, about 0.01 to about 5 wt. % tin and about 0.1 to about 5 wt. % alkali metal or alkaline earth metal.

摘要翻译： 可用于脱氢烃的非酸催化复合物包括催化有效量的铂族组分，铼组分，钴组分，锡组分和碱金属或碱土金属组分与多孔载体材料的组合。 本文公开的非酸性催化复合物的具体实例是铂族金属，铼，钴，锡和碱金属或碱土金属与多孔载体材料的组合，其量足以导致在元素基础上含有复合材料 ，约0.01至约2wt。 ％铂族金属，约0.01至约2重量％ ％铼，约0.05至约5wt。 ％钴，约0.01至约5wt。 ％锡和约0.1至约5wt。 ％碱金属或碱土金属。