Amine-terminated graft copolymer dispersions and polyurethanes prepared
therefrom
    1.
    发明授权
    Amine-terminated graft copolymer dispersions and polyurethanes prepared therefrom 失效
    胺封端的接枝共聚物分散体和由其制备的聚氨酯

    公开(公告)号:US4286074A

    公开(公告)日:1981-08-25

    申请号:US137194

    申请日:1980-04-04

    CPC分类号: C08G18/632 C08F283/06

    摘要: Stable graft polymer dispersions are prepared employing in situ free radical polymerization of ethylenically unsaturated monomer or monomers in an amine-terminated polyoxyalkylene polyether polymer. These dispersions are useful in the preparation of polyurethane foams which have improved tensile strength, elongation, load deflection and tear strength properties.

    摘要翻译: 使用胺封端的聚氧化烯聚醚聚合物中烯属不饱和单体或单体的原位自由基聚合制备稳定的接枝聚合物分散体。 这些分散体可用于制备具有改进的拉伸强度,伸长率,载荷挠度和撕裂强度性能的聚氨酯泡沫塑料。

    Curable fixtures of polyepoxides and amine-terminated graft polymer
dispersions
    2.
    发明授权
    Curable fixtures of polyepoxides and amine-terminated graft polymer dispersions 失效
    聚环氧化物和胺封端的接枝聚合物分散体的固化夹具

    公开(公告)号:US4321342A

    公开(公告)日:1982-03-23

    申请号:US238756

    申请日:1981-02-27

    CPC分类号: C08F283/06 C08L51/08

    摘要: Curable mixtures of polyepoxides and amine-terminated polymers are employed. The amine-terminated polymers are prepared by the in situ free radical polymerization of ethylenically unsaturated monomer or monomers in amine-terminated polyoxyalkylene polyether polymers.

    摘要翻译: 使用聚环氧化物和胺封端聚合物的可固化混合物。 通过在胺封端的聚氧化烯聚醚聚合物中的烯属不饱和单体或单体的原位自由基聚合制备胺封端的聚合物。

    Novel oxyalkylated polyol prepolymers, flame retardant interpolymers
prepared therefrom, and processes for the preparation thereof
    4.
    发明授权
    Novel oxyalkylated polyol prepolymers, flame retardant interpolymers prepared therefrom, and processes for the preparation thereof 失效
    新型烷氧基化多元醇预聚物,由其制备的阻燃互聚物及其制备方法

    公开(公告)号:US4108808A

    公开(公告)日:1978-08-22

    申请号:US745049

    申请日:1976-11-26

    摘要: Liquid oxyalkylated polyol prepolymers are prepared by oxyalkylating a prepolymer prepared from a hydroxy aromatic compound, an aldehyde and furfuryl alcohol with an alkylene oxide containing about 2-4 carbon atoms. The oxyalkylated polyol prepolymers have a viscosity of 1000-500,000 centipoises at 25.degree. C. and contain about 1.1-6 moles of interpolymerized aldehyde, about 3.1-15 moles of interpolymerized furfuryl alcohol, and about 1-10 moles of interpolymerized alkylene oxide for each mole of interpolymerized hydroxy aromatic compound. The resultant prepolymers are highly reactive and may be further polymerized with or without monomers such as polyisocyanate to produce flame retardant solid or cellular interpolymers. Flame retardant solid or cellular polyurethanes are prepared in one variant by interpolymerizing organic polyisocyanates with the oxyalkylated polyol prepolymers. In another variant, flame retardant closed cell cellular interpolymers are provided. Processes are provided for preparing the aforementioned novel oxyalkylated polyol prepolymers and solid or cellular interpolymers.

    摘要翻译: 液体烷氧基化多元醇预聚物通过使由羟基芳族化合物,醛和糠醇制备的预聚物与含约2-4个碳原子的烯化氧进行烷氧基化来制备。 烷氧基化多元醇预聚物在25℃下的粘度为1000-500,000厘泊,并且含有约1.1-6摩尔的共聚醛,约3.1-15摩尔的共聚糠醇,以及每个约1-10摩尔的互聚环氧烷 的共聚羟基芳族化合物。 得到的预聚物是高度反应性的并且可以与单体如多异氰酸酯进一步聚合,以产生阻燃固体或细胞互聚物。 通过使有机多异氰酸酯与烷氧基化多元醇预聚物共聚制备阻燃固体或细胞聚氨酯。 在另一个变体中,提供阻燃闭孔细胞互聚物。 提供了制备上述新型烷氧基化多元醇预聚物和固体或细胞互聚物的方法。

    Carbodiimide-isocyanurate foams containing urethane linkages
    5.
    发明授权
    Carbodiimide-isocyanurate foams containing urethane linkages 失效
    含氨基甲酸酯键的碳二亚胺 - 异氰脲酸酯泡沫

    公开(公告)号:US4029610A

    公开(公告)日:1977-06-14

    申请号:US566249

    申请日:1975-04-09

    摘要: Cellular foam compositions are prepared by catalytically condensing an organic polyisocyanate in the presence of a blowing agent, from 0.01 to 0.5 equivalent per equivalent of isocyanate of a primary hydroxy-terminated polyoxyalkylene or polyester polyol and a catalyst system comprising (a) methanol, (b) a tertiary amine trimerization catalyst, and (c) a urethane catalyst. The resulting foam compositions are characterized by carbodiimide, isocyanurate and urethane linkages and exhibit unexpectedly low friability, improved strength properties, and good flame retardancy.

    摘要翻译: 蜂窝状泡沫组合物通过在发泡剂存在下催化缩合有机多异氰酸酯制备,每当量的主要羟基封端的聚氧化烯或聚酯多元醇的异氰酸酯为0.01至0.5当量,以及包含(a)甲醇,(b )叔胺三聚催化剂,和(c)氨基甲酸酯催化剂。 所得的泡沫组合物的特征在于碳二亚胺,异氰脲酸酯和氨基甲酸酯键,并且具有出人意料的低脆性,改进的强度性能和良好的阻燃性。

    Novel prepolymers, flame retardant interpolymers prepared therefrom, and
processes for the preparation thereof
    9.
    发明授权
    Novel prepolymers, flame retardant interpolymers prepared therefrom, and processes for the preparation thereof 失效
    新型预聚物,由其制备的阻燃互聚物及其制备方法

    公开(公告)号:US4108809A

    公开(公告)日:1978-08-22

    申请号:US745628

    申请日:1976-11-29

    IPC分类号: C08G16/02 C08G18/54 C08J9/00

    CPC分类号: C08G16/0262 C08G18/542

    摘要: Liquid prepolymers are prepared by interpolymerizing monomers including a hydroxy aromatic compound, an aldehyde and furfuryl alcohol. The resultant liquid prepolymers have a viscosity of about 100-500,000 centipoises at 25.degree. C. and contain about 1.1-6 moles of interpolymerized aldehyde and about 3.1-15 moles of interpolymerized furfuryl alcohol for each mole of interpolymerized hydroxy aromatic compound. The prepolymers are highly reactive and may be polymerized with or without other monomers to produce flame retardant solid or cellular interpolymers. In one variant, flame retardant solid or cellular polymers are produced by interpolymerizing organic polyisocyanates with the prepolymers. In another variant, solid or cellular interpolymers are produced by polymerizing the prepolymers without monomers such as polyisocyanate in the presence of unreacted furfuryl alcohol. Processes are provided for preparing the aforementioned novel liquid prepolymers and solid or cellular interpolymers.

    摘要翻译: 液体预聚物通过使包含羟基芳族化合物,醛和糠醇的单体共聚来制备。 所得液态预聚物在25℃下的粘度约为100-500,000厘泊,每摩尔共聚羟基芳族化合物含有约1.1-6摩尔的共聚醛和约3.1-15摩尔的共聚糠醇。 预聚物是高反应性的并且可以与或不与其它单体聚合以产生阻燃固体或细胞互聚物。 在一个变体中,通过将有机多异氰酸酯与预聚物共聚来制备阻燃固体或多孔聚合物。 在另一个变体中,固体或细胞互聚物是通过在未反应的糠醇的存在下聚合预聚物而不使用单体如多异氰酸酯来制备的。 提供了制备上述新型液体预聚物和固体或细胞互聚物的方法。

    Carbodiimide-isocyanurate foams modified with ethoxylated polyols
    10.
    发明授权
    Carbodiimide-isocyanurate foams modified with ethoxylated polyols 失效
    用乙氧基化多元醇改性的碳二亚胺 - 异氰脲酸酯泡沫

    公开(公告)号:US4051082A

    公开(公告)日:1977-09-27

    申请号:US654445

    申请日:1976-02-02

    IPC分类号: C08G18/09 C08G18/48 C08G18/50

    摘要: Rigid cellular foams are prepared by catalytically condensing an organic polyisocyanate in the presence of (a) a carbodiimide-promoting catalyst, (b) a trimerization catalyst, (c) a urethane catalyst, and (d) from 10 parts to 40 parts per 100 parts of polyisocyanate of a polyol mixture comprising (1) from 5 parts to 30 parts of a polyoxyethylated polyhydric alcohol and (2) from 5 parts to 25 parts of a polyoxyethylated phosphate polyol.

    摘要翻译: 在(a)碳二亚胺促进催化剂,(b)三聚催化剂,(c)氨基甲酸酯催化剂和(d)10份至40份/ 100份的存在下,通过催化缩合有机多异氰酸酯制备刚性泡孔泡沫体 多元醇混合物的多异氰酸酯的部分,其包含(1)5〜30份聚氧乙烯化多元醇和(2)5〜25份聚氧乙基化磷酸酯多元醇。