Process for preparing tetrahydrocarbylphosphonium bicarbonate salts
    2.
    发明授权
    Process for preparing tetrahydrocarbylphosphonium bicarbonate salts 失效
    四烃基碳酸氢盐的制备方法

    公开(公告)号:US4266079A

    公开(公告)日:1981-05-05

    申请号:US91280

    申请日:1979-11-05

    IPC分类号: C07F9/54

    CPC分类号: C07F9/5442 C07F9/5407

    摘要: Certain tetrahydrocarbylphosphonium bicarbonate salts are produced by reacting a trihydrocarbyl(hydrocarbylcarboxymethyl)phosphonium hydroxide inner salt with water. For example, methyl tri-n-butylphosphonium bicarbonate salt was prepared in quantitative yields by heating tri-n-butylcarboxymethylphosphonium hydroxide inner salt in an aqueous methanol solution at 100.degree. C. for 3 hours.

    摘要翻译: 通过使氢氧化三烃基(烃基羧甲基)磷酸氢盐与水反应制备某些烃基碳酸氢盐。 例如,通过在100℃的甲醇水溶液中加热三正丁基羧甲基鏻氢氧化物内盐3小时,以定量的产率制备甲基三正丁基鏻碳酸氢盐。

    Catalyst for making polyurethanes
    3.
    发明授权
    Catalyst for making polyurethanes 失效
    制备聚氨酯的催化剂

    公开(公告)号:US4189543A

    公开(公告)日:1980-02-19

    申请号:US935233

    申请日:1978-08-21

    IPC分类号: C08G18/16 C08G18/20

    CPC分类号: C08G18/2027 C08G18/168

    摘要: Compounds of formulas I and II are heat-activated catalysts used in making polyurethanes. ##STR1## wherein R, R.sub.1, and R.sub.2 are each independently H, hydrocarbyl or an inertly-substituted hydrocarbyl; R.sub.3 and R.sub.4 are each independently hydrocarbyl or an inertly-substituted hydrocarbyl; and X is an anion. Upon heating, Compounds I and II catalyze the reaction and may release gaseous by-products which cause the resulting polyurethane compound to foam. For example, the catalyst, t-butyl imidazole-N-carboxylate, when heated to 120.degree. C., catalyzes the reaction between a polyol and a polyisocyanate to give a foamed polyurethane which cured in 16 minutes.

    摘要翻译: 式I和II的化合物是用于制备聚氨酯的热活化催化剂。 其中R,R 1和R 2各自独立地为H,烃基或惰性取代的烃基; R 3和R 4各自独立地为烃基或惰性取代的烃基; X为阴离子。 加热时,化合物I和II催化反应,并可能释放导致所得聚氨酯化合物发泡的气态副产物。 例如,催化剂叔丁基咪唑-N-羧酸酯在加热至120℃时催化多元醇与多异氰酸酯之间的反应,得到在16分钟内固化的发泡聚氨酯。

    Epoxy resin compositions comprising latent amine curing agents and novel
accelerators
    5.
    发明授权
    Epoxy resin compositions comprising latent amine curing agents and novel accelerators 失效
    包含潜在胺固化剂和新型促进剂的环氧树脂组合物

    公开(公告)号:US3956237A

    公开(公告)日:1976-05-11

    申请号:US486721

    申请日:1974-07-08

    摘要: Novel epoxy resin compositions are disclosed which comprise (A) an epoxy resin, (B) a latent amine curing agent for said epoxy resin, and (C) a unique class of latent accelerators corresponding to formula I ##SPC1##wherein:X is an atom of oxygen or sulfur;n is 1 or 2;R.sub.1 is lower alkyl, chloro or bromo;R.sub.2 is hydrogen, lower alkyl, chloro or bromo; romo;R.sub.3 is hydrogen or an inert organic radical; orR.sub.1 and R.sub.2 or R.sub.3 can be joined to form a 5- or 6-membered carbocylic ring; and--NR.sub.4 R.sub.5 is the organic residue derived by the removal of the amino hydrogen atom from a secondary amine;With the proviso that at least one of the urea or thiourea substituents is located .alpha. on the benzene nucleus with respect to R.sub.1 ; andWith the proviso that when n is 2, I is the position isomer having the urea or thiourea substituents located .alpha.,.alpha.' on the benzene nucleus with respect to R.sub.1, or, I is a mixture of position isomers consisting essentially of at least about 35 percent of the aforesaid .alpha.,.alpha.' position isomer and up to about 65 percent of the .alpha.,.gamma. isomer.

    摘要翻译: 公开了新的环氧树脂组合物,其包含(A)环氧树脂,(B)用于所述环氧树脂的潜在胺固化剂,和(C)对应于式I的独特类型的潜在促进剂,其中:

    Ar-cyclic sulfonium arenethiol salts and their zwitterions
    7.
    发明授权
    Ar-cyclic sulfonium arenethiol salts and their zwitterions 失效
    Ar-环锍异戊二烯盐及其两性离子

    公开(公告)号:US4130543A

    公开(公告)日:1978-12-19

    申请号:US673579

    申请日:1976-04-05

    IPC分类号: C07D333/46 C08G65/44

    CPC分类号: C07C321/00 C07D333/46

    摘要: Ar-cyclic sulfonium arenethiol salts exemplified by the formula: ##STR1## may be converted to their corresponding zwitterion, exemplified by the formula: ##STR2## The latter polymerize very readily upon exposure to mild conditions of heat or radiative energy. The resultant polymers are water-insoluble resins useful as adhesives, coatings, films and the like. The zwitterions containing more than one arenesulfide and cyclic sulfonium group per molecule, crosslink upon exposure to heat to form thermoset resins.

    摘要翻译: 以下式示出的Ar-环状锍异戊二烯盐:可将“IMAGE”转化成其相应的两性离子,其例子如下: