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    Oil-free elastomeric poly(aryloxyphosphazene) copolymers
    1.
    发明授权
    Oil-free elastomeric poly(aryloxyphosphazene) copolymers 失效
    无油弹性聚（芳氧基磷腈）共聚物

    公开(公告)号：US4179555A

    公开(公告)日：1979-12-18

    申请号：US919888

    申请日：1978-06-28

    申请人： Tai C. Cheng ,  John W. Fieldhouse ,  Arthur E. Oberster ,  Daniel F. Graves

    发明人： Tai C. Cheng ,  John W. Fieldhouse ,  Arthur E. Oberster ,  Daniel F. Graves

    IPC分类号： C08G79/00 ,  C08G79/02 ,  C08G79/04 ,  C08J9/10 ,  C08L85/00 ,  C08L85/02 ,  C09D185/00 ,  H01B3/30

    CPC分类号： C08J9/10 ,  C08G79/025 ,  C08L85/02 ,  H01B3/30 ,  C08J2385/02 ,  Y10T428/294

    摘要： Poly(aryloxyphosphazene) copolymers are prepared having randomly repeating units represented by the formula: ##STR1## wherein R and R.sup.1 may be the same or different and are selected from the group consisting of monovalent aryl radicals and substituted aryl radicals having the structure: ##STR2## wherein X is a substituent selected from the group consisting of alkyl, alkoxy, aryl, aryloxy, amino and halogen substituted on any sterically permissible position on the phenyl group; and wherein the amount of Cl present in the form of P--C1 bonds is from about 0.4 percent to about 10 percent by weight based upon the total weight of copolymer.The copolymers may contain minor proportions of randomly distributed units in addition to the repeating units described above, these additional units containing reactive sites enabling the properties of the copolymers to be modified by crosslinking and/or curing.The copolymers are elastomeric even in the absence of low molecular weight polyphosphazene oils. The copolymers are curable by a variety of curing agents such as sulfur and peroxides, and can also be cured by radiation and ultraviolet light. The copolymers may be utilized in various applications such as foams and coatings, and are particularly suited for use in wire coating formulations.

    摘要翻译： 制备具有由下式表示的无规重复单元的聚（芳氧基磷腈）共聚物：其中R和R 1可以相同或不同，并且选自具有以下结构的一价芳基和取代的芳基：其中X是选自烷基，烷氧基，芳基，芳氧基，氨基和在苯基上的任何空间上允许的位置上取代的卤素的取代基; 并且其中以P-C1键形式存在的Cl的量为基于共聚物总重量的约0.4重量％至约10重量％。 除了上述重复单元之外，共聚物可以含有少量的随机分布的单元，这些含有能够通过交联和/或固化来改性共聚物性质的反应性位点的这些附加单元。 即使在不存在低分子量聚磷腈油的情况下，共聚物也是弹性体。 共聚物可通过各种固化剂如硫和过氧化物固化，并且还可以通过辐射和紫外光固化。 共聚物可以用于各种应用中，例如泡沫和涂料，并且特别适用于丝线涂布配方。

    Process for the polymerization of cyclic polyhalophosphazenes using a catalyst composition of boron trihalide and oxygenated phosphorus compounds
    3.
    发明授权
    Process for the polymerization of cyclic polyhalophosphazenes using a catalyst composition of boron trihalide and oxygenated phosphorus compounds 失效
    使用三卤化硼和氧化磷化合物的催化剂组合物聚合环状多卤代膦腈的方法

    公开(公告)号：US4226840A

    公开(公告)日：1980-10-07

    申请号：US77245

    申请日：1979-09-19

    申请人： John W. Fieldhouse ,  Daniel F. Graves

    发明人： John W. Fieldhouse ,  Daniel F. Graves

    IPC分类号： B01J27/00 ,  B01J31/00 ,  C01B21/098 ,  C01B25/10

    CPC分类号： C01B21/098 ,  C01B21/0986

    摘要： Linear polydihalophosphazene polymers which are substantially free of gel are prepared by thermally polymerizing a cyclic polyhalophosphazene represented by the formula (NPX.sub.2).sub.3, wherein X is fluorine, chlorine or bromine in the presence of a catalyst which comprises the reaction product of a boron trihalide compound with an oxygenated phosphorus compound.In addition to producing substantially gel free polymers, the catalyst composition of the process of the invention permits improved control of molecular weight, lower polymerization temperature, high rates of conversion of (NPCl.sub.2).sub.3 to (NPCl.sub.2).sub.n and provides for more readily processible and derivatizable polymers.

    摘要翻译： 基本上不含凝胶的线性聚二卤代磷腈聚合物通过在催化剂存在下热聚合由式（NPX2）3表示的环状多卤代膦（NPX2）3，其中X是氟，氯或溴，其包含三卤化硼化合物 与氧化磷化合物。 除了生产基本上不含凝胶的聚合物之外，本发明方法的催化剂组合物允许改进分子量的控制，较低的聚合温度，（NPCl 2）3转化为（NPCl 2）n的高转化率，并提供更容易加工和 可衍生聚合物。

    Oil-free elastomeric poly(aryloxyphosphazene) copolymer foam
    4.
    发明授权
    Oil-free elastomeric poly(aryloxyphosphazene) copolymer foam 失效
    无油弹性聚（芳氧基磷腈）共聚物泡沫

    公开(公告)号：US4207403A

    公开(公告)日：1980-06-10

    申请号：US30598

    申请日：1979-04-16

    申请人： Tai C. Cheng ,  John W. Fieldhouse ,  Arthur E. Oberster ,  Daniel F. Graves

    发明人： Tai C. Cheng ,  John W. Fieldhouse ,  Arthur E. Oberster ,  Daniel F. Graves

    IPC分类号： C08G79/02 ,  C08J9/10 ,  C08L85/02 ,  H01B3/30

    CPC分类号： C08J9/10 ,  C08G79/025 ,  C08L85/02 ,  H01B3/30 ,  C08J2385/02 ,  Y10T428/294

    摘要： Poly(aryloxyphosphazene) copolymers are prepared having randomly repeating units represented by the formula: ##STR1## wherein R and R.sup.1 may be the same or different and are selected from the group consisting of monovalent aryl radicals and substituted aryl radicals having the structure: ##STR2## wherein X is a substituent selected from the group consisting of alkyl, alkoxy, aryl, aryloxy, amino and halogen substituted on any sterically permissible position on the phenyl group; and wherein the amount of Cl present in the form of P-Cl bonds is from about 0.4 percent to about 10 percent by weight based upon the total weight of copolymer.The copolymers may contain minor proportions of randomly distributed units in addition to the repeating units described above, these additional units containing reactive sites enabling the properties of the copolymers to be modified by crosslinking and/or curing.The copolymers are elastomeric even in the absence of low molecular weight polyphosphazene oils. The copolymers are curable by a variety of curing agents such as sulfur and peroxides, and can also be cured by radiation and ultraviolet light. The copolymers may be utilized in various applications such as foams and coatings, and are particularly suited for use in wire coating formulations.

    摘要翻译： 制备具有由下式表示的无规重复单元的聚（芳氧基磷腈）共聚物：其中R和R 1可以相同或不同，并且选自具有以下结构的一价芳基和取代的芳基：其中X是选自烷基，烷氧基，芳基，芳氧基，氨基和在苯基上的任何空间上允许的位置上取代的卤素的取代基; 并且其中以P-Cl键形式存在的Cl的量为基于共聚物总重量的约0.4重量％至约10重量％。 除了上述重复单元之外，共聚物可以含有少量的随机分布的单元，这些含有能够通过交联和/或固化来改性共聚物性质的反应性位点的这些附加单元。 即使在不存在低分子量聚磷腈油的情况下，共聚物也是弹性体。 共聚物可通过各种固化剂如硫和过氧化物固化，并且还可以通过辐射和紫外光固化。 共聚物可以用于各种应用中，例如泡沫和涂料，并且特别适用于丝线涂布配方。

    Process for the production of phosphazene polymers
    5.
    发明授权
    Process for the production of phosphazene polymers 失效
    磷腈聚合物的制备方法

    公开(公告)号：US4128710A

    公开(公告)日：1978-12-05

    申请号：US845009

    申请日：1977-10-25

    申请人： John W. Fieldhouse ,  Daniel F. Graves ,  William M. Cole ,  Mark L. Stayer ,  Steven L. Fenske

    发明人： John W. Fieldhouse ,  Daniel F. Graves ,  William M. Cole ,  Mark L. Stayer ,  Steven L. Fenske

    IPC分类号： C08G79/00 ,  C08G79/02 ,  C08G73/00 ,  C08J3/00

    CPC分类号： C08G79/025

    摘要： The production of phosphazene polymers represented by the general formula ##STR1## WHEREIN R and R' are organic radicals hereinafter defined, and wherein n is an integer from 20 to upwards of 50,000 wherein one or more kinds of OR or OR' groups is attached to the phosphorus atoms in a substantially linear chain of alternating P and N atoms, the groups when more than one group is present being randomly distributed along the PN backbone, as described in copending United States Patent Application Ser. No. 824,004 filed Aug. 12, 1977, is enhanced by an improved procedure for the separation of the sodium chloride by-product from the derivatized phosphazene polymer. By treating the reaction mixture with carbon dioxide, in the presence of water and preferably with an additional alkali metal salt, agglomeration of the sodium chloride is accomplished, and a clean separation of the NaCl from the polyphosphazene ester is more readily achieved.

    摘要翻译： {PG，1}由通式{r1 {tc，1 {rb {ab，44 {m，1 {sb，21 {m，2 {ob，5 {mr，1P {M， 3 {AB，2 OR {MR，3 {AB，6 OR {40 {MR，3 {AD，444 N {M，4 {AB，44 {MR，4 {S，15 {MY，2 {CB，5 {BL，88 {S，6 {HD n {re {PS {PS WHEREIN R和R {40 {0是下文定义的有机基团，其中{1为20至高达50,000的整数，其中一个或多个 OR或OR的种类（40个O基团连接在交替的P和N原子的基本线性链中的磷原子，当存在多于一个基团时的基团沿着PN骨架随机分布，如共同未决United 国家专利申请 1977年8月12日提交的No.824,004通过用于从衍生的磷腈聚合物分离氯化钠副产物的改进方法得到增强。 通过用二氧化碳处理反应混合物，在水的存在下，优选用另外的碱金属盐，完成氯化钠的附聚，更容易实现NaCl与聚磷腈酯的清洁分离。

    Process for the production of phosphazene polymers
    6.
    发明授权
    Process for the production of phosphazene polymers 失效
    磷腈聚合物的制备方法

    公开(公告)号：US4129529A

    公开(公告)日：1978-12-12

    申请号：US824004

    申请日：1977-08-12

    申请人： John W. Fieldhouse ,  Daniel F. Graves ,  William M. Cole ,  Mark L. Stayer ,  Steven L. Fenske

    发明人： John W. Fieldhouse ,  Daniel F. Graves ,  William M. Cole ,  Mark L. Stayer ,  Steven L. Fenske

    IPC分类号： C08G79/02 ,  C08G73/00

    CPC分类号： C08G79/025

    摘要： The production of phosphazene polymers represented by the general formula ##STR1## WHEREIN N IS AN INTEGER FROM 7 TO UPWARDS OF 50,000 WHEREIN ONE OR MORE KINDS OF OR or OR' groups is attached to the phosphorus atoms in a substantially linear chain of alternating P and N atoms, the groups when more than one group is present being randomly distributed along the PN backbone, is enhanced by employing a single solvent for both each of the reactants (polydihalophosphazene and either aryloxide and/or alkoxide) and for the product (phosphazene polymer). By this expedient, the formation of the desired product is achieved in a homogeneous system rather than in a heterogeneous system as in the prior art where different solvents were employed for each of the reactants and for the reaction products.

    摘要翻译： {PG，1}由通式{r1 {tc，1 {rb {ab，44 {m，1 {sb，21 {us，5 {ob，4 {mr，1P {M， 1 {AB，2 OR {MR，1 {AB，6 OR {40 {MR，1 {AD，44 N {AB，44 {SB，21 {US，5 {CB，4 {S，6 { {HD {{{{{{{{{{N {N} N = 1，从7到UPWARDS为50,000，其中一种或多种OR或OR {40 {0组连接在交替的P和N的基本线性链中的磷原子 原子，当存在多于一个基团时的基团通过使用单一溶剂用于每种反应物（聚二卤代膦和芳氧化物和/或醇盐）和对于产物（磷腈聚合物）而增强， 。 通过这种方法，所需产物的形成在均匀系统中而不是在异构体系中实现，如在现有技术中，其中对于每种反应物和反应产物使用不同的溶剂。