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    Process for producing elastomeric compound having reduced hysteresis
    1.
    发明授权
    Process for producing elastomeric compound having reduced hysteresis 失效
    具有降低滞后性的弹性体化合物的制造方法

    公开(公告)号：US5698646A

    公开(公告)日：1997-12-16

    申请号：US467370

    申请日：1995-06-06

    申请人： Takashi Kitamura ,  Mark L. Stayer, Jr. ,  Akira Matsuda

    发明人： Takashi Kitamura ,  Mark L. Stayer, Jr. ,  Akira Matsuda

    IPC分类号： C08F4/42 ,  C08F4/48 ,  C08F4/56 ,  C08F36/04 ,  C08F236/10

    CPC分类号： C08F36/04

    摘要： The present invention is directed toward anionic polymerization employing lithio aldimines mixed with an organic alkali metal compound and optionally, a chelating reagent. The lithio aldimines have the general formula (A)Li, where A is derived from a substituted aldimine. The invention is also directed toward polymers and other products made using the initiator, and methods therefor. Further, the invention contemplates a polymer, a polymer composition and products therefrom, which include a functional group from the reaction product of a substituted aldimine and an organolithium compound. The resulting polymers may be modified with a terminating, coupling or linking agent, which may provide the polymer with a multifunctionality.

    摘要翻译： 本发明涉及使用与有机碱金属化合物和任选的螯合剂混合的锂二醛的阴离子聚合。 锂二亚胺具有通式（A）Li，其中A衍生自取代的醛亚胺。 本发明还涉及使用引发剂制备的聚合物和其它产品及其方法。 此外，本发明考虑了聚合物，聚合物组合物及其产物，其包括来自取代的醛亚胺与有机锂化合物的反应产物的官能团。 所得聚合物可以用终止的，偶联或连接剂进行改性，其可以提供聚合物的多功能性。

    Solubilized anionic polymerization initiators
    2.
    发明授权
    Solubilized anionic polymerization initiators 失效
    溶解的阴离子聚合引发剂

    公开(公告)号：US5616704A

    公开(公告)日：1997-04-01

    申请号：US639980

    申请日：1996-04-29

    申请人： David F. Lawson ,  Mark L. Stayer, Jr. ,  David Saffles ,  H. James Harwood

    发明人： David F. Lawson ,  Mark L. Stayer, Jr. ,  David Saffles ,  H. James Harwood

    IPC分类号： B60C1/00 ,  C08C19/44 ,  C08F4/08 ,  C08F4/48 ,  C08F36/04 ,  C07D295/02

    CPC分类号： C08F4/086 ,  B60C1/00 ,  B60C1/0016 ,  B60C1/0025 ,  C08C19/44 ,  C08F36/04 ,  Y10S152/905

    摘要： The present invention is directed toward anionic polymerization initiators which are soluble in acyclic alkane solvents. The initiators include a solubilized lithio amine having the general formula (A)Li(SOL).sub.y. SOL is a solubilizing component and A is an alkyl, dialkyl or cycloalkyl amine radical or a cyclic amine and y is from about 1 to 4. The cyclic amine has an alkylene, oxy- or amino-alkylene group having from about 3 to about 16 methylene groups. The invention is also directed toward polymers and other products made using the initiator, and methods therefor. Further, the invention contemplates a polymer, a polymer composition and products therefrom, which include a functional group from the reaction product of an amine and an organolithium compound. The resulting polymers may be terminated with a terminating, coupling or linking agent, which may provide the polymer with a multifunctionality.

    摘要翻译： 本发明涉及可溶于无环烷烃溶剂的阴离子聚合引发剂。 引发剂包括具有通式（A）Li（SOL）y的溶解的锂胺。 SOL是增溶组分，A是烷基，二烷基或环烷基胺基或环状胺，y约为1-4。环状胺具有约3至约16的亚烷基，氧基或氨基亚烷基 亚甲基。 本发明还涉及使用引发剂制备的聚合物和其它产品及其方法。 此外，本发明涉及聚合物，聚合物组合物及其产物，其包括来自胺和有机锂化合物的反应产物的官能团。 所得聚合物可以用终止的，偶联或连接剂终止，其可以为聚合物提供多功能性。

    Elastomers and products having reduced hysteresis
    5.
    发明授权
    Elastomers and products having reduced hysteresis 失效
    弹性体和滞后性降低的产品

    公开(公告)号：US5268413A

    公开(公告)日：1993-12-07

    申请号：US791910

    申请日：1991-11-13

    申请人： Thomas A. Antkowiak ,  David F. Lawson ,  Russell W. Koch ,  Mark L. Stayer, Jr.

    发明人： Thomas A. Antkowiak ,  David F. Lawson ,  Russell W. Koch ,  Mark L. Stayer, Jr.

    IPC分类号： C08C19/44 ,  C08F4/48 ,  C08F36/04 ,  C08K3/04

    CPC分类号： C08F4/48 ,  C08C19/44 ,  C08F36/04

    摘要： An anionic polymerization initiator comprising the reaction product of a functionalizing agent selected from the group consisting of substituted aldimines, ketimines and secondary amines and, an organolithium compound. Elastomeric polymers prepared with these initiators have functional sites incorporated at the initiator end of the polymer chain and provide vulcanizable rubber compounds exhibiting reduced hysteresis. Articles such as tires, produced with low hysteresis elastomeric polymers have lower rolling resistance. Methods are also provided for preparing the initiators, functionalized polymers and vulcanizable elastomeric compounds having reduced hysteresis.

    摘要翻译： 一种阴离子聚合引发剂，其包含选自取代的醛亚胺，酮亚胺和仲胺的官能化试剂的反应产物和有机锂化合物。 用这些引发剂制备的弹性体聚合物具有并入聚合物链的引发剂末端的功能性位点，并提供具有降低的滞后性的可硫化橡胶化合物。 用低滞后弹性体聚合物制成的轮胎等制品具有较低的滚动阻力。 还提供了用于制备具有降低的滞后的引发剂，官能化聚合物和可硫化弹性体化合物的方法。

    Diene polymers having reduced hysteresis and improved raw viscosity incorporating primary partial coupling and fused-ring polynuclear aromatic terminators
    6.
    发明授权
    Diene polymers having reduced hysteresis and improved raw viscosity incorporating primary partial coupling and fused-ring polynuclear aromatic terminators 失效
    二烯聚合物具有降低的滞后和改进的原始粘度，其中包含初级部分偶联和稠环多核芳族终止子

    公开(公告)号：US5210144A

    公开(公告)日：1993-05-11

    申请号：US812172

    申请日：1991-12-20

    申请人： David F. Lawson ,  Mark L. Stayer, Jr. ,  Thomas A. Antkowiak

    发明人： David F. Lawson ,  Mark L. Stayer, Jr. ,  Thomas A. Antkowiak

    IPC分类号： C08C19/44

    CPC分类号： C08C19/44

    摘要： Diene polymers or copolymers having improved raw polymer viscosity and reduced hysteresis in the cured and carbon black reinforced state are provided. These diene polymers or copolymers comprise a mixture of diene polymer or copolymer chains containing carbon-tin bonds in the main polymer or copolymer chains and diene polymer or copolymer chains containing terminals derived from fused-ring polynuclear aromatic compounds.The diene polymer or copolymers are prepared by first coupling a portion of the living diene polymer or copolymer chains obtained by anionic polymerization using a tin polyhalide coupling agent and then terminating the remaining living diene polymer or copolymer chains using fused-ring polynuclear aromatic compounds. The resultant diene polymers or copolymers have improved raw polymer viscosity and when compounded with carbon black and cured have reduced hysteresis properties. The polymers can be utilized to form elastomer compositions for tire treads having reduced rolling resistance.

    摘要翻译： 提供了在固化和炭黑增强状态下具有改进的原料聚合物粘度和降低的滞后的二烯聚合物或共聚物。 这些二烯聚合物或共聚物包含在主聚合物或共聚物链中含有碳 - 锡键的二烯聚合物或共聚物链的混合物，以及含有衍生自稠环多核芳族化合物的末端的二烯聚合物或共聚物链。 二烯聚合物或共聚物是通过首先将一部分活性二烯聚合物或通过阴离子聚合得到的共聚物链与多卤化锡偶联剂偶联，然后使用稠环多核芳族化合物终止剩余的活性二烯聚合物或共聚物链来制备的。 所得二烯聚合物或共聚物具有改善的原始聚合物粘度，并且当与炭黑复合并固化时具有降低的滞后性能。 聚合物可用于形成具有降低的滚动阻力的轮胎胎面的弹性体组合物。

    Diene polymers and copolymers terminated by reaction with N-alkyl and N-aryl imines
    8.
    发明授权
    Diene polymers and copolymers terminated by reaction with N-alkyl and N-aryl imines 失效
    通过与N-烷基和N-芳基亚胺反应终止二烯聚合物和共聚物

    公开(公告)号：US5109907A

    公开(公告)日：1992-05-05

    申请号：US732851

    申请日：1991-07-19

    申请人： Mark L. Stayer, Jr. ,  Thomas A. Antkowiak ,  David F. Lawson ,  Russell W. Koch

    发明人： Mark L. Stayer, Jr. ,  Thomas A. Antkowiak ,  David F. Lawson ,  Russell W. Koch

    IPC分类号： B60C1/00 ,  C08C19/44

    CPC分类号： C08C19/44 ,  B60C1/0016

    摘要： A process is provided for preparing a terminally functionalized polymer from a living polymer obtained by anionic polymerization of a diene monomer or mixture of a diene monomer and a vinyl aromatic hydrocarbon monomer which comprises reacting the living polymer with a compound having the formula: ##STR1## wherein R.sub.1 and R.sub.2 are selected from the group consisting of H, alkyl, cycloalkyl, aryl, dialkylaminoaryl, aralkyl, and aprotic O, N and S- containing alkyl, cycloalkyl, aryl and aralkyl groups; wherein R.sub.3 is selected from the group consisting of alkyl, cycloalkyl, aryl, dialkylaminoaryl, aralkyl, and aprotic O, N and S- containing alkyl, cycloalkyl, aryl and aralkyl groups; with the proviso that at least one of the R.sub.1, R.sub.2 and R.sub.3 groups must be a dialkylaminoaryl group and that not all of the R.sub.1, R.sub.2 and R.sub.3 groups can be aryl groups.The resultant terminally functionalized polymer has reduced hysteresis properties and may be utilized to prepare elastomer compositions and tire treads having reduced rolling resistance.

    摘要翻译： 提供了一种通过二烯单体或二烯单体和乙烯基芳族烃单体的混合物的阴离子聚合获得的活性聚合物制备末端官能化聚合物的方法，其包括使活性聚合物与具有下式的化合物反应： 其中R 1和R 2选自H，烷基，环烷基，芳基，二烷基氨基芳基，芳烷基和非质子O，N和S-含烷基，环烷基，芳基和芳烷基; 其中R 3选自烷基，环烷基，芳基，二烷基氨基芳基，芳烷基和非质子O，N和S-含烷基，环烷基，芳基和芳烷基; 条件是R1，R2和R3基团中的至少一个必须是二烷基氨基芳基，并且不是所有的R 1，R 2和R 3基团都可以是芳基。 所得的末端官能化聚合物具有降低的滞后性能，并且可用于制备具有降低的滚动阻力的弹性体组合物和轮胎胎面。

    Sulfenyl halide polymerization terminators
    9.
    发明授权
    Sulfenyl halide polymerization terminators 有权
    磺酰卤聚合终止子

    公开(公告)号：US06274680B1

    公开(公告)日：2001-08-14

    申请号：US09224328

    申请日：1998-12-31

    申请人： David F. Lawson ,  Mark L. Stayer ,  Thomas A. Antkowiak

    发明人： David F. Lawson ,  Mark L. Stayer ,  Thomas A. Antkowiak

    IPC分类号： C08F834

    CPC分类号： C08C19/44

    摘要： A method of preparing a functionalized polymer comprising the steps of initiating the formation and propagation of an anionically-polymerized living polymer, and terminating the propagation of the living polymer by reacting the polymer with a terminating agent selected from the group of agents defined by the formulas (III), (IV), and (V) where C is a carbon atom, S is a sulfur atom, X is a halogen atom, R2 and R4 are independently selected from hydrogen and carbon-based moieties, and where the phenyl groups are selected from unsubstituted and substituted phenyl groups.

    摘要翻译： 一种制备官能化聚合物的方法，包括以下步骤：引发阴离子聚合的活性聚合物的形成和扩散，并通过使聚合物与选自由式 （III），（IV）和（V）其中C是碳原子，S是硫原子，X是卤素原子，R2和R4独立地选自氢和碳基部分，并且其中苯基 选自未取代的和取代的苯基。