公开(公告)号：US08093339B2

公开(公告)日：2012-01-10

申请号：US12304554

申请日：2007-06-27

申请人： John White ,  Michel Feder ,  Alain Pouchelon ,  Yassine Maadadi ,  Lucile Gambut-Garel

发明人： John White ,  Michel Feder ,  Alain Pouchelon ,  Yassine Maadadi ,  Lucile Gambut-Garel

IPC分类号： C08L83/04

CPC分类号： C08L83/04 ,  C08G77/12 ,  C08G77/14 ,  C08G77/18 ,  C08G77/20 ,  C08G77/70 ,  C08G77/80 ,  C09D183/04 ,  Y10T428/31511 ,  C08L83/00

摘要： Silicone composites subject to reticulation or reticulated, particularly for creating a coating or water-repellent and anti-adhesive film for flexible substrates such as paper or similar in the form of natural or synthetic polymer films. These compounds contain reticulating polyorganosiloxanes that have SiH units and unsaturated polyorganosiloxanes, preferably vinylated, suitable for reacting with the reticulating agent in an addition reaction and in the presence of platinum to form the reticulated anti-adhesive coating on the flexible substrate, plus at least one additive (D) to promote adhesion to it. A new liquid silicone compound can be applied without using a solvent, which is beneficial, that can be reticulated instantly to produce an anti-adhesive and/or water-repellent coating for the flexible substrate, giving very high quality reticulated silicone coatings, particularly in terms of sticking/adhering to the substrate, being harder to rub off and the anti-adhesion profile (sufficiently increase detaching force at high speed.

摘要翻译： 经过网状或网状的硅氧烷复合材料，特别是为天然或合成聚合物膜形式的柔性基材如纸或类似物形成涂层或防水防粘膜。 这些化合物含有网状聚有机硅氧烷，其具有SiH单元和不饱和聚有机硅氧烷，优选为乙烯基化，适于在加成反应中和在铂存在下与网状化合物反应，以在柔性基材上形成网状抗粘剂涂层，加上至少一种 添加剂（D）以促进其粘附。 可以在不使用溶剂的情况下施加新的液体硅氧烷化合物，这是有利的，其可以立即网状地制备用于柔性基材的抗粘合剂和/或防水涂料，提供非常高质量的网状硅氧烷涂料，特别是在 粘附/粘附在基材上的问题，难以擦去和防粘附特性（足以高速地提高分离力）。

公开(公告)号：US20100028685A1

公开(公告)日：2010-02-04

申请号：US12304554

申请日：2007-06-27

申请人： John White ,  Michel Feder ,  Alain Pouchelon ,  Yassine Maadadi ,  Lucile Gambut-Garel

发明人： John White ,  Michel Feder ,  Alain Pouchelon ,  Yassine Maadadi ,  Lucile Gambut-Garel

IPC分类号： B32B27/08 ,  C09D183/06 ,  C07F7/00 ,  B05D3/02

CPC分类号： C08L83/04 ,  C08G77/12 ,  C08G77/14 ,  C08G77/18 ,  C08G77/20 ,  C08G77/70 ,  C08G77/80 ,  C09D183/04 ,  Y10T428/31511 ,  C08L83/00

摘要： Silicone composites subject to reticulation or reticulated, particularly for creating a coating or water-repellent and anti-adhesive film for flexible substrates such as paper or similar in the form of natural or synthetic polymer films. These compounds contain reticulating polyorganosiloxanes that have SiH units and unsaturated polyorganosiloxanes, preferably vinylated, suitable for reacting with the reticulating agent in an addition reaction and in the presence of platinum to form the reticulated anti-adhesive coating on the flexible substrate, plus at least one additive (D) to promote adhesion to it. A new liquid silicone compound can be applied without using a solvent, which is beneficial, that can be reticulated instantly to produce an anti-adhesive and/or water-repellent coating for the flexible substrate, giving very high quality reticulated silicone coatings, particularly in terms of sticking/adhering to the substrate, being harder to rub off and the anti-adhesion profile (sufficiently increase detaching force at high speed.

摘要翻译： 经过网状或网状的硅氧烷复合材料，特别是为天然或合成聚合物膜形式的柔性基材如纸或类似物形成涂层或防水防粘膜。 这些化合物含有网状聚有机硅氧烷，其具有SiH单元和不饱和聚有机硅氧烷，优选为乙烯基化，适于在加成反应中和在铂存在下与网状化合物反应，以在柔性基材上形成网状抗粘剂涂层，加上至少一种 添加剂（D）以促进其粘附。 可以在不使用溶剂的情况下施加新的液体硅氧烷化合物，这是有利的，其可以立即网状地制备用于柔性基材的抗粘合剂和/或防水涂料，提供非常高质量的网状硅氧烷涂料，特别是在 粘附/粘附在基材上的问题，难以擦去和防粘附特性（足以高速地提高分离力）。

公开(公告)号：US08859635B2

公开(公告)日：2014-10-14

申请号：US13169215

申请日：2011-06-27

申请人： John White ,  Michel Feder ,  Alain Pouchelon ,  Yassine Maadadi ,  Lucile Gambut-Garel

发明人： John White ,  Michel Feder ,  Alain Pouchelon ,  Yassine Maadadi ,  Lucile Gambut-Garel

IPC分类号： C08L83/04 ,  C09D183/04 ,  C08G77/20 ,  C08G77/00 ,  C08G77/18 ,  C08G77/14

CPC分类号： C08L83/04 ,  C08G77/12 ,  C08G77/14 ,  C08G77/18 ,  C08G77/20 ,  C08G77/70 ,  C08G77/80 ,  C09D183/04 ,  Y10T428/31511 ,  C08L83/00

摘要： Silicone composites subject to reticulation or reticulated, particularly for creating a coating or water-repellent and anti-adhesive film for flexible substrates such as paper or similar in the form of natural or synthetic polymer films. These compounds contain reticulating polyorganosiloxanes that have SiH units and unsaturated polyorganosiloxanes, preferably vinylated, suitable for reacting with the reticulating agent in an addition reaction and in the presence of platinum to form the reticulated anti-adhesive coating on the flexible substrate, plus at least one additive (D) to promote adhesion to it. A new liquid silicone compound can be applied without using a solvent, which is beneficial, that can be reticulated instantly to produce an anti-adhesive and/or water-repellent coating for the flexible substrate, giving very high quality reticulated silicone coatings, particularly in terms of sticking/adhering to the substrate, being harder to rub off and the anti-adhesion profile (sufficiently increase detaching force at high speed.

摘要翻译： 经过网状或网状的硅氧烷复合材料，特别是为天然或合成聚合物膜形式的柔性基材如纸或类似物形成涂层或防水防粘膜。 这些化合物含有网状聚有机硅氧烷，其具有SiH单元和不饱和聚有机硅氧烷，优选为乙烯基化，适于在加成反应中和在铂存在下与网状化合物反应，以在柔性基材上形成网状抗粘剂涂层，加上至少一种 添加剂（D）以促进其粘附。 可以在不使用溶剂的情况下施加新的液体硅氧烷化合物，这是有利的，其可以立即网状地制备用于柔性基材的抗粘合剂和/或防水涂料，提供非常高质量的网状硅氧烷涂料，特别是在 粘附/粘附在基材上的问题，难以擦去和防粘附特性（足以高速地提高分离力）。

公开(公告)号：US20110257288A1

公开(公告)日：2011-10-20

申请号：US13169215

申请日：2011-06-27

申请人： John White ,  Michel Feder ,  Alain Pouchelon ,  Yassine Maadadi ,  Lucile Gambut-Garel

发明人： John White ,  Michel Feder ,  Alain Pouchelon ,  Yassine Maadadi ,  Lucile Gambut-Garel

IPC分类号： C09D183/04 ,  B05D3/10 ,  C07F7/08

CPC分类号： C08L83/04 ,  C08G77/12 ,  C08G77/14 ,  C08G77/18 ,  C08G77/20 ,  C08G77/70 ,  C08G77/80 ,  C09D183/04 ,  Y10T428/31511 ,  C08L83/00

摘要： Silicone composites subject to reticulation or reticulated, particularly for creating a coating or water-repellent and anti-adhesive film for flexible substrates such as paper or similar in the form of natural or synthetic polymer films. These compounds contain reticulating polyorganosiloxanes that have SiH units and unsaturated polyorganosiloxanes, preferably vinylated, suitable for reacting with the reticulating agent in an addition reaction and in the presence of platinum to form the reticulated anti-adhesive coating on the flexible substrate, plus at least one additive (D) to promote adhesion to it. A new liquid silicone compound can be applied without using a solvent, which is beneficial, that can be reticulated instantly to produce an anti-adhesive and/or water-repellent coating for the flexible substrate, giving very high quality reticulated silicone coatings, particularly in terms of sticking/adhering to the substrate, being harder to rub off and the anti-adhesion profile (sufficiently increase detaching force at high speed.

摘要翻译： 经过网状或网状的硅氧烷复合材料，特别是为天然或合成聚合物膜形式的柔性基材如纸或类似物形成涂层或防水防粘膜。 这些化合物含有网状聚有机硅氧烷，其具有SiH单元和不饱和聚有机硅氧烷，优选为乙烯基化，适于在加成反应中和在铂存在下与网状化合物反应，以在柔性基材上形成网状抗粘剂涂层，加上至少一种 添加剂（D）以促进其粘附。 可以在不使用溶剂的情况下施加新的液体硅氧烷化合物，这是有利的，其可以立即网状地制备用于柔性基材的抗粘合剂和/或防水涂料，提供非常高质量的网状硅氧烷涂料，特别是在 粘附/粘附在基材上的问题，难以擦去和防粘附特性（足以高速地提高分离力）。

公开(公告)号：US20100266856A1

公开(公告)日：2010-10-21

申请号：US12302039

申请日：2007-05-31

申请人： John White ,  Sean Duffy ,  Michel Feder ,  Alain Pouchelon

发明人： John White ,  Sean Duffy ,  Michel Feder ,  Alain Pouchelon

IPC分类号： C09D183/04 ,  B05D3/02 ,  B32B27/08

CPC分类号： C08J7/047 ,  C08G77/12 ,  C08G77/20 ,  C08G77/70 ,  C08G77/80 ,  C08J2483/00 ,  C08L83/04 ,  C09D183/04 ,  Y10T428/31663 ,  C08L83/00

摘要： Silicon compositions with the silicon compound ingredient A alkenylated PolyOrganoSiloxane (POS) containing an F1 fraction and an F2 fraction that are different from each other; F2, an adherence enhancer comprising a linear monoalkenylated silicon oil (A2.1) at one of its ends and/or a long linear α,ω,-alkenylated silicon oil (A2.2) and/or a “weakly alkenylated linear oil. Applications: non-stick silicon coatings obtained from crosslinking/polyaddition for PET.

摘要翻译： 具有硅化合物成分A的含硅组合物，含有彼此不同的F1级分和F2级分的烯基化聚硅氧烷（POS）; F2，其一端具有直链单烯基化硅油（A2.1）和/或长线型α，ω-烯基化硅油（A2.2）和/或“弱烯基化线型油”的粘附增强剂。 应用范围：从PET的交联/加聚获得的不粘硅涂层。

公开(公告)号：US20090301750A1

公开(公告)日：2009-12-10

申请号：US12296576

申请日：2007-04-12

申请人： Catherine George ,  Alain Pouchelon ,  Rémi Thiria

发明人： Catherine George ,  Alain Pouchelon ,  Rémi Thiria

IPC分类号： H01B3/10 ,  C08K3/34 ,  C08K3/22

CPC分类号： H01B3/46 ,  C08G77/12 ,  C08G77/20 ,  C08L83/04 ,  H01B7/295 ,  C08L83/00

摘要： A polyorganosiloxane composition that can be vulcanized at high temperature to a silicone elastomer, useful in the field of the manufacture of electrical wires or cables having an improved fire performance is provided. The composition includes a semi-reinforcing filler chosen from the group composed of:—calcined kaolin powders, preferably that have undergone a chemical surface treatment;- talc;- calcium carbonate that may or may not have been surface-treated, for example with vinylsilanes, aminosilanes or (reactive or unreactive) silicone oils; and mixtures thereof.

摘要翻译： 提供了可以在高温下硫化成有机硅弹性体的聚有机硅氧烷组合物，其可用于具有改进的防火性能的电线或电缆的制造领域。 组合物包括选自以下的半增强填料：煅烧高岭土粉末，优选已进行化学表面处理; - 滑石; - 可以或可以不经表面处理的碳酸钙，例如用乙烯基硅烷 ，氨基硅烷或（反应性或非反应性）硅油; 及其混合物。

公开(公告)号：US20090264563A1

公开(公告)日：2009-10-22

申请号：US11817645

申请日：2006-02-22

申请人： Delphine Blanc-Magnard ,  Alain Pouchelon ,  Sebastien Sterin ,  Remi Thiria

发明人： Delphine Blanc-Magnard ,  Alain Pouchelon ,  Sebastien Sterin ,  Remi Thiria

IPC分类号： C08K5/3445 ,  C07F15/00 ,  C08L83/04 ,  C08K5/04 ,  C09K3/00

CPC分类号： C08K5/56 ,  C08G77/08 ,  C08G77/12 ,  C08G77/20 ,  C08G77/24 ,  C08G77/44 ,  C08G77/70 ,  C08L83/04 ,  C08L83/00 ,  C08L2666/52

摘要： This invention is directed to stabilizing additives that contain at least one platinum complex, with the complex including a carbene group. The stabilizing additives make it possible to improve the resistance to decomposition of silicone elastomers under high temperatures. The additive can be used in a polyorganosiloxane composition intended for the production of a silicone elastomer with either crosslinks at high temperature under the action of organic peroxides or crosslinks at ambient temperature or with heat by polyaddition reactions in the presence of a metal catalyst.

摘要翻译： 本发明涉及包含至少一种铂络合物的稳定添加剂，其中络合物包括卡宾基团。 稳定添加剂可以提高硅橡胶在高温下的分解性。 该添加剂可用于生产有机硅弹性体的聚有机硅氧烷组合物中，所述聚硅氧烷组合物在有机过氧化物的作用下在高温下交联或在环境温度下交联，或在金属催化剂存在下通过加聚反应进行加热。

公开(公告)号：US07494694B2

公开(公告)日：2009-02-24

申请号：US10537782

申请日：2003-11-25

申请人： Catherine George ,  Alain Pouchelon ,  Fabio Zanandrea ,  Sébastien Sterin

发明人： Catherine George ,  Alain Pouchelon ,  Fabio Zanandrea ,  Sébastien Sterin

IPC分类号： B05D3/02 ,  C08L83/04

CPC分类号： C09K3/1018 ,  C08G77/12 ,  C08G77/14 ,  C08G77/20 ,  C08G77/24 ,  C08G77/26 ,  C08G77/70 ,  C08G77/80 ,  C08K5/526 ,  C08K5/5393 ,  C08L83/00 ,  C08L83/04 ,  C08L2666/28 ,  C09J183/04 ,  C08L2666/52

摘要： The invention relates to adhesive silicone elastomer compositions which can be crosslinked by polyaddition. The composition, crosslinkable by polyaddition (hydrosilylation), comprises: α/ at least one polyorganosiloxane (POS) bearing ethylenic and/or acetylenic unsaturations [POS with ≡Si-(unsaturated) units]; β/ at least one polyorganosiloxane (POS) with ≡Si—H units; γ/ a catalytic combination comprising γ.1 at least one metallic catalyst (preferably platinum based), γ.2 and at least one crosslinking inhibitor; δ/ a filler; ε/ at least one adhesion promoter; ρ/ at least one POS resin; λ/ at least one thermal resistance agent; and φ/ optionally at least one other functional additive. Methods of making and using the subject composition are also described.

摘要翻译： 本发明涉及可通过加聚交联的粘合性硅氧烷弹性体组合物。 通过加聚（氢化硅烷化）可交联的组合物包含：α/至少一种带有烯属和/或炔属不饱和基团的聚有机硅氧烷（POS）[具有≡Si-（不饱和单元）的POS]; β/至少一种具有≡Si-H单元的聚有机硅氧烷（POS）; γ/催化剂组合，其包含γ.1至少一种金属催化剂（优选基于铂的），γ2和至少一种交联抑制剂; 三角填料 ε/至少一种粘合促进剂; rho /至少一个POS树脂; λ/至少一种耐热剂; 和phi /任选的至少一种其它功能添加剂。 还描述了制备和使用该主题组合物的方法。

公开(公告)号：US07423234B2

公开(公告)日：2008-09-09

申请号：US10518344

申请日：2003-06-17

申请人： Laurent Dumont ,  Alain Pouchelon

发明人： Laurent Dumont ,  Alain Pouchelon

IPC分类号： B23K10/00

CPC分类号： C08J5/124 ,  B29C59/005 ,  B29C59/14 ,  B29C2059/145 ,  B29K2083/00 ,  C08J7/123 ,  C08J2383/04 ,  C09J5/02

摘要： A process for increasing the surface tension (“wettability”) of a silicone element crosslinked by polyaddition from a liquid composition containing one or more α,ω-dimethylvinylpolydimethylsiloxanes (PDMS), one or more poly(dimethyl)(methylhydrogenosiloxy)-α,ω-dimethylhydrogenosiloxanes, and a platinum crosslinking catalyst. The silicone surface is treated with a homogeneous atmospheric plasma using a plasma spraying apparatus having a rotating head with one or more plasma nozzles that are offset relative to the axis of rotation, each one being capable of generating a plasma jet whose axis is parallel to said axis of rotation. The articles to which the invention relate include composites of flexible substrate (e.g. textile)/silicone coating. Application: adhesive bonding of silicone surfaces crosslinked by ≡Si—H/≡Si-vinyl polyaddition.

摘要翻译： 通过加聚从含有一种或多种α，ω-二甲基乙烯基聚二甲基硅氧烷（PDMS），一种或多种聚（二甲基）（甲基氢甲硅烷氧基）-α，ω，ω-二甲基乙烯基聚二甲基硅氧烷的液体组合物的组合物交联的硅氧烷元素的表面张力（“润湿性” 二甲基氢硅氧烷和铂交联催化剂。 使用具有旋转头部的等离子体喷涂装置处理硅树脂表面，所述等离子体喷涂装置具有相对于旋转轴线偏移的一个或多个等离子体喷嘴，每个等离子体喷嘴能够产生其轴线平行于所述 旋转轴。 本发明涉及的制品包括柔性基底（例如织物）/硅氧烷涂层的复合材料。 应用：通过≡Si-H /≡Si-乙烯基加聚交联的硅氧烷表面的粘合剂。

公开(公告)号：US07151149B1

公开(公告)日：2006-12-19

申请号：US09958181

申请日：2000-04-07

申请人： Georges Barrandon ,  Fabienne Howe ,  Olivier Loubet ,  Bernard Moulin ,  Alain Pouchelon

发明人： Georges Barrandon ,  Fabienne Howe ,  Olivier Loubet ,  Bernard Moulin ,  Alain Pouchelon

IPC分类号： C08G77/08 ,  C08L83/05 ,  C08L83/07

CPC分类号： F02F7/006 ,  C08G77/12 ,  C08G77/20 ,  C08G77/24 ,  C08G77/26 ,  C08G77/70 ,  C08L83/04 ,  C09K3/1018 ,  C08L2666/04

摘要： A non-drip, preferably self-adhesive, silicone elastomer composition crosslinkable by polyaddition, such as those polyorganosilanes (POS) bearing C2═C6≡Si-alkenyl units and ≡Si—H units but excluding fluorinated POS. The composition includes at least a thixotropic additive containing at least a fluorinated resin, preferably based on polyfluoroethylene (PTFE). The composition may be prepared from a Si—Vi polydimethylsiloxane (PDMS) and a Si—H PDMS crosslinked by platinum catalysis. Polytetrafluorethylene, a filler, particularly one containing silicone, optionally a ternary adherence promoter such as vinyltrimethosilane/glycidoxypropyltrimethoxysilane/butyl orthotitanate, and other typical additives may be added to the composition. The composition (not excluding the fluorinated POS as a possible constituent in the composition) may be used to produce joints in situ and/or as an adhesive, particularly in upholstery.

摘要翻译： 通过加聚可交联的非滴落的，优选自粘性的有机硅弹性体组合物，例如那些带有C 2 -C 6 -C 6烯基单元的聚有机硅烷（POS）和 ≡Si-H单元，但不包括氟化POS。 该组合物至少包含至少含有氟化树脂的触变添加剂，优选基于聚氟乙烯（PTFE）。 组合物可以由Si-Vi聚二甲基硅氧烷（PDMS）和通过铂催化交联的Si-H PDMS制备。 聚四氟乙烯，特别是含有硅氧烷的填料，任选的三元粘附促进剂如乙烯基三甲硅烷/缩水甘油氧基丙基三甲氧基硅烷/原钛酸丁酯，以及其它典型的添加剂可以加入到组合物中。 组合物（不排除作为组合物中的可能成分的氟化POS）可以用于原位和/或粘合剂，特别是在室内装饰中的接合。