公开(公告)号：US08212078B2

公开(公告)日：2012-07-03

申请号：US11909824

申请日：2005-12-30

申请人： John Y. Lee ,  Paul L. Wiggins ,  Judit Orgad ,  Mahmood Sabahi ,  Vernon O. Brandt ,  David W. Owens

发明人： John Y. Lee ,  Paul L. Wiggins ,  Judit Orgad ,  Mahmood Sabahi ,  Vernon O. Brandt ,  David W. Owens

IPC分类号： C07C211/00

CPC分类号： C07C211/12 ,  C07C211/51 ,  C08G18/10 ,  C08G18/3234 ,  C08G18/324 ,  C08G18/325 ,  C08G18/5024 ,  C08G18/6685 ,  C08G18/7671 ,  Y02P20/582

摘要： This invention provides aromatic diimines where the diimines have imino groups with at least two carbon atoms, and either are in the form of one benzene ring having two imino groups on the ring, which imino groups are meta or para relative to each other, and in which each position ortho to an imino group bears a hydrocarbyl group, or are in the form of two benzene rings connected by an alkylene bridge and having one imino group on each ring, and in which each position ortho to an imino group bears a hydrocarbyl group. This invention also provides aromatic secondary diamines where the diamines have amino hydrocarbyl groups with at least two carbon atoms, and either are in the form of one benzene ring having two amino groups on the ring, which amino groups are meta or para relative to each other, and in which each position ortho to an amino group bears a hydrocarbyl group, or are in the form of two benzene rings connected by an alkylene bridge and having one amino group on each ring, and in which each position ortho to an amino group bears a hydrocarbyl group. Also provided are processes for forming diimines and secondary diamines from primary diamines, including the aromatic diimines and aromatic secondary diamines of the invention.

摘要翻译： 本发明提供芳族二亚胺，其中二亚胺具有至少两个碳原子的亚氨基，并且是环上具有两个亚氨基的一个苯环的形式，该亚氨基相对于彼此是间位或对位的，并且在 其中每个位于亚氨基的邻位具有烃基，或者是由亚烷基桥连接并在每个环上具有一个亚氨基的两个苯环的形式，并且其中亚氨基的邻位各有一个烃基 。 本发明还提供芳族仲二胺，其中二胺具有至少两个碳原子的氨基烃基，并且是环上具有两个氨基的一个苯环的形式，该氨基相对于彼此是间位或对位的 并且其中氨基的每个位置具有烃基，或者为两个苯环的形式，其通过亚烷基桥连接并且在每个环上具有一个氨基，并且其中氨基的邻位各自承载 烃基。 还提供了由伯二胺形成二亚胺和仲二胺的方法，包括本发明的芳族二亚胺和芳族仲二胺。

公开(公告)号：US07288677B2

公开(公告)日：2007-10-30

申请号：US11390777

申请日：2006-03-27

申请人： John Y. Lee ,  Paul L. Wiggins ,  Judit Orgad ,  Mahmood Sabahi ,  Vernon O. Brandt

发明人： John Y. Lee ,  Paul L. Wiggins ,  Judit Orgad ,  Mahmood Sabahi ,  Vernon O. Brandt

IPC分类号： C07C249/00 ,  C07C251/00 ,  C07C257/00 ,  C07C263/00 ,  C07C265/00 ,  C07C267/00 ,  C07C291/00

CPC分类号： C07C211/12 ,  C07C211/51 ,  C08G18/10 ,  C08G18/3234 ,  C08G18/324 ,  C08G18/325 ,  C08G18/5024 ,  C08G18/6685 ,  C08G18/7671 ,  Y02P20/582

摘要： This invention provides aromatic diimines which have imino hydrocarbylidene groups with at least two carbon atoms, and aromatic secondary diamines which have amino hydrocarbyl groups with at least two carbon atoms. Both the aromatic diimines and the aromatic secondary diamines either are in the form of one phenyl ring, or are in the form of two phenyl rings connected by an alkylene bridge; each position ortho to an imino group or an amino group bears a hydrocarbyl group. When in the form of one phenyl ring, there are two imino groups on the ring or two amino groups on the ring; the imino groups or amino groups are meta or para relative to each other. When in the form of two phenyl rings connected by an alkylene bridge, there is either one imino group or one amino group on each phenyl ring. Also provided are processes for forming diimines and secondary diamines.

摘要翻译： 本发明提供具有至少两个碳原子的亚氨基亚烃基的芳族二亚胺和具有至少两个碳原子的氨基烃基的芳族仲二胺。 芳族二亚胺和芳族仲胺都是一个苯环的形式，或者是由亚烷基桥连接的两个苯环的形式; 亚氨基或氨基的邻位各为一个烃基。 当以一个苯环的形式，环上有两个亚氨基或环上两个氨基; 亚氨基或氨基相对于彼此是间位或对位的。 当以亚烷基桥连接的两个苯环的形式，每个苯环上有一个亚氨基或一个氨基。 还提供了形成二亚胺和仲二胺的方法。

公开(公告)号：US07964695B2

公开(公告)日：2011-06-21

申请号：US11534968

申请日：2006-09-25

申请人： John Y. Lee ,  Paul L. Wiggins ,  Judit Orgad ,  Mahmood Sabahi ,  Vernon O. Brandt

发明人： John Y. Lee ,  Paul L. Wiggins ,  Judit Orgad ,  Mahmood Sabahi ,  Vernon O. Brandt

IPC分类号： C08G18/10 ,  C08G18/32 ,  C07C249/00 ,  C07C251/00 ,  C07C257/00 ,  C07C263/00 ,  C07C265/00 ,  C07C267/00 ,  C07C291/00

CPC分类号： C08G18/7671 ,  C07C211/09 ,  C07C211/12 ,  C07C211/49 ,  C07C211/51 ,  C07C251/08 ,  C08G18/12 ,  C08G18/3228 ,  C08G18/3234 ,  C08G18/324 ,  C08G18/325 ,  C08G18/5024 ,  C08G18/6685

摘要： This invention provides chain extender compositions. These compositions comprise (i) an aromatic primary diamine, and (ii) a component selected from the group consisting of: (a) an aliphatic secondary diamine; (b) an aliphatic primary diamine; (c) an aliphatic secondary diamine and an aliphatic primary diamine; (d) a diimine; and (e) a combination of any two or more of (a) through (d). When (ii) is (a), (a) has amino hydrocarbyl groups which are secondary or tertiary hydrocarbyl groups; when (ii) is (d), and (d) is an aromatic diimine, each imino hydrocarbylidene group has at least two carbon atoms. Processes for producing polyurethanes, polyureas, and polyurea-urethanes are also provided.

公开(公告)号：US20080194788A1

公开(公告)日：2008-08-14

申请号：US11909824

申请日：2005-12-30

申请人： John Y. Lee ,  Paul L. Wiggins ,  Judit Orgad ,  Mahmood Sabahi ,  Vernon O. Brandt ,  David W. Owens

发明人： John Y. Lee ,  Paul L. Wiggins ,  Judit Orgad ,  Mahmood Sabahi ,  Vernon O. Brandt ,  David W. Owens

IPC分类号： C08G18/00 ,  C07C211/49 ,  C07C249/02

CPC分类号： C07C211/12 ,  C07C211/51 ,  C08G18/10 ,  C08G18/3234 ,  C08G18/324 ,  C08G18/325 ,  C08G18/5024 ,  C08G18/6685 ,  C08G18/7671 ,  Y02P20/582

摘要： This invention provides aromatic diimines where the diimines have imino groups with at least two carbon atoms, and either are in the form of one benzene ring having two imino groups on the ring, which imino groups are meta or para relative to each other, and in which each position ortho to an imino group bears a hydrocarbyl group, or are in the form of two benzene rings connected by an alkylene bridge and having one imino group on each ring, and in which each position ortho to an imino group bears a hydrocarbyl group. This invention also provides aromatic secondary diamines where the diamines have amino hydrocarbyl groups with at least two carbon atoms, and either are in the form of one benzene ring having two amino groups on the ring, which amino groups are meta or para relative to each other, and in which each position ortho to an amino group bears a hydrocarbyl group, or are in the form of two benzene rings connected by an alkylene bridge and having one amino group on each ring, and in which each position ortho to an amino group bears a hydrocarbyl group. Also provided are processes for forming diimines and secondary diamines from primary diamines, including the aromatic diimines and aromatic secondary diamines of the invention.

摘要翻译： 本发明提供芳族二亚胺，其中二亚胺具有至少两个碳原子的亚氨基，并且是环上具有两个亚氨基的一个苯环的形式，该亚氨基相对于彼此是间位或对位的，并且在 其中每个位于亚氨基的邻位具有烃基，或者是由亚烷基桥连接并在每个环上具有一个亚氨基的两个苯环的形式，并且其中亚氨基的邻位各有一个烃基 。 本发明还提供芳族仲二胺，其中二胺具有至少两个碳原子的氨基烃基，并且是环上具有两个氨基的一个苯环的形式，该氨基相对于彼此是间位或对位的 并且其中氨基的每个位置具有烃基，或者为两个苯环的形式，其通过亚烷基桥连接并且在每个环上具有一个氨基，并且其中氨基的邻位各自承载 烃基。 还提供了由伯二胺形成二亚胺和仲二胺的方法，包括本发明的芳族二亚胺和芳族仲二胺。

公开(公告)号：US07767858B2

公开(公告)日：2010-08-03

申请号：US11855839

申请日：2007-09-14

申请人： Paul L. Wiggins ,  Judit Orgad ,  John Y. Lee ,  Mahmood Sabahi

发明人： Paul L. Wiggins ,  Judit Orgad ,  John Y. Lee ,  Mahmood Sabahi

IPC分类号： C07C209/26

CPC分类号： C07C211/12 ,  C07C211/51 ,  C08G18/10 ,  C08G18/3234 ,  C08G18/324 ,  C08G18/325 ,  C08G18/5024 ,  C08G18/6685 ,  C08G18/7671 ,  Y02P20/582

摘要： This invention provides aromatic diimines which have imino hydrocarbylidene groups with at least two carbon atoms, and aromatic secondary diamines which have amino hydrocarbyl groups with at least two carbon atoms. Both the aromatic diimines and the aromatic secondary diamines either are in the form of one phenyl ring, or are in the form of two phenyl rings connected by an alkylene bridge; each position ortho to an imino group or an amino group bears a hydrocarbyl group. When in the form of one phenyl ring, there are two imino groups on the ring or two amino groups on the ring; the imino groups or amino groups are meta or para relative to each other. When in the form of two phenyl rings connected by an alkylene bridge, there is either one imino group or one amino group on each phenyl ring. Also provided are processes for forming diimines and secondary diamines.

摘要翻译： 本发明提供具有至少两个碳原子的亚氨基亚烃基的芳族二亚胺和具有至少两个碳原子的氨基烃基的芳族仲二胺。 芳族二亚胺和芳族仲胺都是一个苯环的形式，或者是由亚烷基桥连接的两个苯环的形式; 亚氨基或氨基的邻位各为一个烃基。 当以一个苯环的形式，环上有两个亚氨基或环上两个氨基; 亚氨基或氨基相对于彼此是间位或对位的。 当以亚烷基桥连接的两个苯环的形式，每个苯环上有一个亚氨基或一个氨基。 还提供了形成二亚胺和仲二胺的方法。

公开(公告)号：US20110137005A1

公开(公告)日：2011-06-09

申请号：US13028579

申请日：2011-02-16

申请人： John Y. Lee ,  Paul L. Wiggins ,  Judit Orgad

发明人： John Y. Lee ,  Paul L. Wiggins ,  Judit Orgad

IPC分类号： C08G18/32

CPC分类号： C08G18/7671 ,  C07C211/09 ,  C07C211/12 ,  C07C211/49 ,  C07C211/51 ,  C07C251/08 ,  C08G18/12 ,  C08G18/3228 ,  C08G18/3234 ,  C08G18/324 ,  C08G18/325 ,  C08G18/5024 ,  C08G18/6685

摘要： This invention provides chain extender compositions. These compositions comprise(i) an aromatic primary diamine, and (ii) a component selected from the group consisting of: (a) an aliphatic secondary diamine; (b) an aliphatic primary diamine; (c) an aliphatic secondary diamine and an aliphatic primary diamine; (d) a diimine; and (e) a combination of any two or more of (a) through (d). When (ii) is (a), (a) has amino hydrocarbyl groups which are secondary or tertiary hydrocarbyl groups; when (ii) is (d), and (d) is an aromatic diimine, each imino hydrocarbylidene group has at least two carbon atoms. Processes for producing polyurethanes, polyureas, and polyurea-urethanes are also provided.

摘要翻译： 本发明提供扩链剂组合物。 这些组合物包含（i）芳族伯二胺，和（ii）选自以下的组分：（a）脂族仲胺; （b）脂族伯胺; （c）脂族二胺和脂族伯二胺; （d）二亚胺; 和（e）（a）至（d）中任意两个或多个的组合。 当（ii）是（a）时，（a）具有二级或三级烃基的氨基烃基; 当（ii）是（d）和（d）是芳族二亚胺时，每个亚氨基亚烃基具有至少两个碳原子。 还提供了生产聚氨酯，聚脲和聚脲 - 聚氨酯的方法。

公开(公告)号：US08080626B2

公开(公告)日：2011-12-20

申请号：US13028579

申请日：2011-02-16

申请人： Paul L. Wiggins ,  John Y. Lee ,  Judit Orgad

发明人： Paul L. Wiggins ,  John Y. Lee ,  Judit Orgad

IPC分类号： C08G18/10 ,  C08G18/32

CPC分类号： C08G18/7671 ,  C07C211/09 ,  C07C211/12 ,  C07C211/49 ,  C07C211/51 ,  C07C251/08 ,  C08G18/12 ,  C08G18/3228 ,  C08G18/3234 ,  C08G18/324 ,  C08G18/325 ,  C08G18/5024 ,  C08G18/6685

摘要： This invention provides chain extender compositions. These compositions comprise (i) an aromatic primary diamine, and (ii) a component selected from the group consisting of: (a) an aliphatic secondary diamine; (b) an aliphatic primary diamine; (c) an aliphatic secondary diamine and an aliphatic primary diamine; (d) a diimine; and (e) a combination of any two or more of (a) through (d). When (ii) is (a), (a) has amino hydrocarbyl groups which are secondary or tertiary hydrocarbyl groups; when (ii) is (d), and (d) is an aromatic diimine, each imino hydrocarbylidene group has at least two carbon atoms. Processes for producing polyurethanes, polyureas, and polyurea-urethanes are also provided.

摘要翻译： 本发明提供扩链剂组合物。 这些组合物包含（i）芳族伯二胺，和（ii）选自以下的组分：（a）脂族仲胺; （b）脂族伯胺; （c）脂族二胺和脂族伯二胺; （d）二亚胺; 和（e）（a）至（d）中任意两个或多个的组合。 当（ii）是（a）时，（a）具有二级或三级烃基的氨基烃基; 当（ii）是（d）和（d）是芳族二亚胺时，每个亚氨基亚烃基具有至少两个碳原子。 还提供了生产聚氨酯，聚脲和聚脲 - 聚氨酯的方法。

公开(公告)号：US08076518B2

公开(公告)日：2011-12-13

申请号：US11534980

申请日：2006-09-25

申请人： Paul L. Wiggins ,  John Y. Lee ,  Judit Orgad ,  David W. Owens

发明人： Paul L. Wiggins ,  John Y. Lee ,  Judit Orgad ,  David W. Owens

IPC分类号： C07C211/00 ,  C08G18/10

CPC分类号： C07C209/26 ,  C07C211/50 ,  C07C211/53 ,  C07C249/02 ,  C07C251/08 ,  C08G18/10 ,  C08G18/3228 ,  C08G18/3234 ,  C08G18/5024 ,  C08G18/755 ,  C09D175/02 ,  C08G18/6685

摘要： This invention provides chain extender compositions. These compositions comprise (i) an aliphatic secondary diamine, and (ii) a component selected from the group consisting of: (a) a cycloaliphatic primary diamine; (b) an aliphatic secondary diamine; (c) an aliphatic secondary diamine and an aliphatic primary diamine; (d) an aliphatic diimine; and (e) a combination of any two or more of (a) through (d), with the proviso that when (ii) is (a), (i) is a noncyclic aliphatic secondary diamine. Processes for producing polyurethanes, polyureas, and polyurea-urethanes are also provided.

摘要翻译： 本发明提供扩链剂组合物。 这些组合物包含（i）脂族仲胺，和（ii）选自以下的组分：（a）脂环族伯胺; （b）脂肪族二胺; （c）脂族二胺和脂族伯二胺; （d）脂族二亚胺; 和（e）（a）至（d）中任意两个或更多个的组合，条件是当（ii）是（a）时，（i）是非环状脂族二胺。 还提供了生产聚氨酯，聚脲和聚脲 - 聚氨酯的方法。

公开(公告)号：US20070270566A1

公开(公告)日：2007-11-22

申请号：US11534968

申请日：2006-09-25

申请人： John Lee ,  Paul Wiggins ,  Judit Orgad ,  Mahmood Sabahi ,  Vernon Brandt

发明人： John Lee ,  Paul Wiggins ,  Judit Orgad ,  Mahmood Sabahi ,  Vernon Brandt

IPC分类号： C08G18/00 ,  C07D249/02

CPC分类号： C08G18/7671 ,  C07C211/09 ,  C07C211/12 ,  C07C211/49 ,  C07C211/51 ,  C07C251/08 ,  C08G18/12 ,  C08G18/3228 ,  C08G18/3234 ,  C08G18/324 ,  C08G18/325 ,  C08G18/5024 ,  C08G18/6685

摘要： This invention provides chain extender compositions. These compositions comprise (i) an aromatic primary diamine, and (ii) a component selected from the group consisting of: (a) an aliphatic secondary diamine; (b) an aliphatic primary diamine; (c) an aliphatic secondary diamine and an aliphatic primary diamine; (d) a diimine; and (e) a combination of any two or more of (a) through (d). When (ii) is (a), (a) has amino hydrocarbyl groups which are secondary or tertiary hydrocarbyl groups; when (ii) is (d), and (d) is an aromatic diimine, each imino hydrocarbylidene group has at least two carbon atoms. Processes for producing polyurethanes, polyureas, and polyurea-urethanes are also provided.

摘要翻译： 本发明提供扩链剂组合物。 这些组合物包含（i）芳族伯二胺，和（ii）选自以下的组分：（a）脂族仲胺; （b）脂族伯胺; （c）脂族二胺和脂族伯二胺; （d）二亚胺; 和（e）（a）至（d）中任意两个或多个的组合。 当（ii）是（a）时，（a）具有二级或三级烃基的氨基烃基; 当（ii）是（d）和（d）是芳族二亚胺时，每个亚氨基亚烃基具有至少两个碳原子。 还提供了生产聚氨酯，聚脲和聚脲 - 聚氨酯的方法。