公开(公告)号：US09777030B2

公开(公告)日：2017-10-03

申请号：US15317725

申请日：2015-03-20

申请人： JOHNSON MATTHEY PUBLIC LIMITED COMPANY

发明人： Thomas Colacot ,  Andrew Jon Deangelis

IPC分类号： C07F15/00 ,  B01J31/24 ,  C07C213/02 ,  C07C67/343 ,  C07C231/08 ,  C07D317/66 ,  C07D213/74 ,  C07D401/12 ,  C07D471/04 ,  C07D409/12 ,  C07B43/04 ,  C07B37/02 ,  C07B47/00 ,  C07D231/44 ,  C07D215/38 ,  C07D417/12 ,  C07D405/12 ,  C07D207/27 ,  C07D263/22 ,  C07D263/24 ,  C07D277/42 ,  C07D241/20 ,  C07D217/02 ,  C07D213/76 ,  C07D209/08 ,  C07D401/04

CPC分类号： C07F15/006 ,  B01J31/2291 ,  B01J31/24 ,  B01J31/2404 ,  B01J31/2419 ,  B01J2231/4205 ,  B01J2231/4283 ,  B01J2231/44 ,  B01J2531/824 ,  C07B37/02 ,  C07B43/04 ,  C07B47/00 ,  C07C67/343 ,  C07C213/02 ,  C07C231/08 ,  C07D207/27 ,  C07D209/08 ,  C07D213/74 ,  C07D213/76 ,  C07D215/38 ,  C07D217/02 ,  C07D231/44 ,  C07D241/20 ,  C07D263/22 ,  C07D263/24 ,  C07D277/42 ,  C07D317/66 ,  C07D401/04 ,  C07D401/12 ,  C07D405/12 ,  C07D409/12 ,  C07D417/12 ,  C07D471/04

摘要： A palladium(II) complex of formula (1) or a palladium(II) complex of formula (3). Also, processes for the preparation of the complexes, and their use in carbon-carbon and carbon-heteroatom coupling reactions.

公开(公告)号：US20210163516A1

公开(公告)日：2021-06-03

申请号：US17173500

申请日：2021-02-11

申请人： Johnson Matthey Public Limited Company

发明人： Thomas Colacot ,  Ruishan Chow ,  Andrew Jon DeAngelis

IPC分类号： C07F15/00 ,  C07D215/38 ,  C07B37/04 ,  C07B43/04 ,  C07D401/06 ,  C07D403/04 ,  C07D405/04 ,  C07D409/04 ,  C07D471/04 ,  C07D295/096 ,  C07D213/127 ,  C07D213/24 ,  C07D213/50 ,  C07D213/56 ,  C07D307/46 ,  C07C45/68 ,  C07C17/32

摘要： The present invention provides a palladium(II) complex of formula (1). R12, m, and X are described in the specification. The invention also provides a process for the preparation of the complex, and its use in carbon-carbon and carbon-heteroatom coupling reactions.

公开(公告)号：US20190241589A1

公开(公告)日：2019-08-08

申请号：US16284841

申请日：2019-02-25

申请人： JOHNSON MATTHEY PUBLIC LIMITED COMPANY

发明人： Thomas Colacot ,  Ruishan Chow ,  Andrew Jon DeAngelis

IPC分类号： C07F15/00 ,  C07C17/32 ,  C07D215/38 ,  C07D307/46 ,  C07D213/56 ,  C07D213/50 ,  C07D213/24 ,  C07D213/127 ,  C07D295/096 ,  C07D471/04 ,  C07D409/04 ,  C07D405/04 ,  C07D403/04 ,  C07D401/06 ,  C07B43/04 ,  C07B37/04 ,  C07C45/68

CPC分类号： C07F15/006 ,  C07B37/04 ,  C07B43/04 ,  C07C17/32 ,  C07C45/68 ,  C07D213/127 ,  C07D213/24 ,  C07D213/50 ,  C07D213/56 ,  C07D215/38 ,  C07D295/096 ,  C07D307/46 ,  C07D401/06 ,  C07D403/04 ,  C07D405/04 ,  C07D409/04 ,  C07D471/04 ,  C07C49/84 ,  C07C22/08

摘要： The present invention provides a palladium(II) complex of formula (1) or a palladium(II) complex of formula (2). R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12, R18, R19, R20, R21, R22, R23 and R24, m, E and X are described in the specification.The invention also provides a process for the preparation of the complexes, and their use in carbon-carbon and carbon-heteroatom coupling reactions.

公开(公告)号：US10968244B2

公开(公告)日：2021-04-06

申请号：US16686960

申请日：2019-11-18

申请人： Johnson Matthey Public Limited Company

发明人： Thomas Colacot ,  Ruishan Chow ,  Andrew Jon DeAngelis

IPC分类号： C07F15/00 ,  C07D215/38 ,  C07B37/04 ,  C07B43/04 ,  C07D401/06 ,  C07D403/04 ,  C07D405/04 ,  C07D409/04 ,  C07D471/04 ,  C07D295/096 ,  C07D213/127 ,  C07D213/24 ,  C07D213/50 ,  C07D213/56 ,  C07D307/46 ,  C07C45/68 ,  C07C17/32

摘要： The present invention provides a palladium(II) complex of formula (1) or a palladium(II) complex of formula (2). R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12, R18, R19, R20, R21, R22, R23 and R24, m, E and X are described in the specification.
The invention also provides a process for the preparation of the complexes, and their use in carbon-carbon and carbon-heteroatom coupling reactions.

公开(公告)号：US20200087332A1

公开(公告)日：2020-03-19

申请号：US16686960

申请日：2019-11-18

申请人： Johnson Matthey Public Limited Company

发明人： Thomas Colacot ,  Ruishan Chow ,  Andrew Jon Deangelis

IPC分类号： C07F15/00 ,  C07C17/32 ,  C07C45/68 ,  C07D307/46 ,  C07D213/56 ,  C07D213/50 ,  C07D213/24 ,  C07D213/127 ,  C07D295/096 ,  C07D471/04 ,  C07D409/04 ,  C07D405/04 ,  C07D403/04 ,  C07D401/06 ,  C07B43/04 ,  C07B37/04 ,  C07D215/38

摘要： The present invention provides a palladium(II) complex of formula (1) or a palladium(II) complex of formula (2). R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12, R18, R19, R20, R21, R22, R23 and R24, m, E and X are described in the specification. The invention also provides a process for the preparation of the complexes, and their use in carbon-carbon and carbon-heteroatom coupling reactions.

公开(公告)号：US11649258B2

公开(公告)日：2023-05-16

申请号：US17173500

申请日：2021-02-11

申请人： Johnson Matthey Public Limited Company

发明人： Thomas Colacot ,  Ruishan Chow ,  Andrew Jon DeAngelis

IPC分类号： C07F15/00 ,  C07D215/38 ,  C07B37/04 ,  C07B43/04 ,  C07D401/06 ,  C07D403/04 ,  C07D405/04 ,  C07D409/04 ,  C07D471/04 ,  C07D295/096 ,  C07D213/127 ,  C07D213/24 ,  C07D213/50 ,  C07D213/56 ,  C07D307/46 ,  C07C45/68 ,  C07C17/32

CPC分类号： C07F15/006 ,  C07B37/04 ,  C07B43/04 ,  C07C17/32 ,  C07C45/68 ,  C07D213/127 ,  C07D213/24 ,  C07D213/50 ,  C07D213/56 ,  C07D215/38 ,  C07D295/096 ,  C07D307/46 ,  C07D401/06 ,  C07D403/04 ,  C07D405/04 ,  C07D409/04 ,  C07D471/04 ,  C07C45/68 ,  C07C49/84 ,  C07C17/32 ,  C07C22/08

摘要： The present invention provides a palladium(II) complex of formula (1).




R12, m, and X are described in the specification.
The invention also provides a process for the preparation of the complex, and its use in carbon-carbon and carbon-heteroatom coupling reactions.

公开(公告)号：US10858382B2

公开(公告)日：2020-12-08

申请号：US16284841

申请日：2019-02-25

申请人： JOHNSON MATTHEY PUBLIC LIMITED COMPANY

发明人： Thomas Colacot ,  Ruishan Chow ,  Andrew Jon DeAngelis

IPC分类号： C07F15/00 ,  C07D215/38 ,  C07B37/04 ,  C07B43/04 ,  C07D401/06 ,  C07D403/04 ,  C07D405/04 ,  C07D409/04 ,  C07D471/04 ,  C07D295/096 ,  C07D213/127 ,  C07D213/24 ,  C07D213/50 ,  C07D213/56 ,  C07D307/46 ,  C07C45/68 ,  C07C17/32

摘要： The present invention provides a palladium(II) complex of formula (1) or a palladium(II) complex of formula (2). R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12, R18, R19, R20, R21, R22, R23 and R24, m, E and X are described in the specification. The invention also provides a process for the preparation of the complexes, and their use in carbon-carbon and carbon-heteroatom coupling reactions.

公开(公告)号：US10808000B2

公开(公告)日：2020-10-20

申请号：US16342309

申请日：2017-09-21

申请人： JOHNSON MATTHEY PUBLIC LIMITED COMPANY

发明人： William Carole ,  Thomas Colacot ,  Carin Seechurn ,  Thomas Scrase

IPC分类号： C07F15/00 ,  C07F9/52

摘要： The present invention provides a process for the preparation of a complex of formula (I): comprising the step of reacting Pd(diolefin)X2 or PdX2 and PR1R2R3 in a solvent to form the complex of formula (I), wherein the process is carried out in the absence of a base, the molar ratio of Pd(diolefin)X2:PR1R2R3 or PdX2:PR1R2R3 is greater than 1:1.1, up to about 1:2.5; each X is independently a halide; and R1, R2 and R3 are independently selected from the group consisting of tert-butyl and isopropyl.

公开(公告)号：US10253056B2

公开(公告)日：2019-04-09

申请号：US15318106

申请日：2015-03-20

申请人： JOHNSON MATTHEY PUBLIC LIMITED COMPANY

发明人： Thomas Colacot ,  Ruishan Chow ,  Andrew Jon Deangelis

IPC分类号： C07F15/00 ,  C07D215/38 ,  C07B37/04 ,  C07B43/04 ,  C07D401/06 ,  C07D403/04 ,  C07D405/04 ,  C07D409/04 ,  C07D471/04 ,  C07D295/096 ,  C07D213/127 ,  C07D213/24 ,  C07D213/50 ,  C07D213/56 ,  C07D307/46 ,  C07C45/68 ,  C07C17/32

摘要： A palladium(II) complex of formula (1) or a palladium(II) complex of formula (2). Also, a process for the preparation of the complexes, and their use in carbon-carbon and carbon-heteroatom coupling reactions.