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公开(公告)号：US06660823B1
公开(公告)日：2003-12-09
申请号：US09709783
申请日：2000-11-14
IPC分类号： C08G7738
CPC分类号： C07F7/21 , C07F7/0876 , C08G77/04 , C08G77/045 , C08G77/38
摘要： Method is provided for controlling the stereo chemistry of functionalities or X groups to exo or endo positions on a polyhedral oligomeric silsesquioxane (POSS) compound by adding certain reagents to said X groups to change one or more positions thereof to endo or exo. Also provided are the POSS species formed by the above inventive method. Method is also provided for inserting a ring substituent into a POSS compound. Also provided are the POSS species formed by such inventive method.
摘要翻译： 提供了通过向所述X基团添加某些试剂以将其一个或多个位置改变为内切或外切来控制功能性或X基团在多面体低聚倍半硅氧烷（POSS）化合物上的内部或内部位置的立体化学性质的方法。 还提供了通过上述发明方法形成的POSS种类。 还提供了将环取代基插入POSS化合物的方法。 还提供了通过这种创造性方法形成的POSS物种。
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公开(公告)号：US6100417A
公开(公告)日：2000-08-08
申请号：US387682
申请日：1999-08-31
CPC分类号： C07F7/21
摘要： Method is provided for reacting silsesquioxane resins or polyhedral oligomeric silsesquioxanes (POSS) bearing one or more olefinic groups with strong acids to cleave one or more olefin bonds of the olefinic groups to form POSS species of monomers or polymers having one or more functionalities suitable for reaction with a wide range of polymeric systems, to thus form new POSS derived compounds. Also provided are the new compounds so formed.
摘要翻译： 提供了将含有一个或多个烯属基团的倍半硅氧烷树脂或多面体低聚倍半硅氧烷（POSS）与强酸反应以切割烯烃基团的一个或多个烯烃键以形成具有一个或多个适合于反应的官能团的单体或聚合物的POSS种类的方法 具有广泛的聚合体系，从而形成新的POSS衍生化合物。 还提供了如此形成的新化合物。
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公开(公告)号：US06770724B1
公开(公告)日：2004-08-03
申请号：US09783719
申请日：2001-02-16
IPC分类号： C08G7706
CPC分类号： C07F7/21 , C07F7/0876 , C08G77/04 , C08G77/045 , C08G77/38
摘要： Method is provided for selectively opening rings of polyhedral oligomeric silsesquioxane (POSS) compounds to from functionalized derivatives thereof or new POSS species. Per the inventive method, the POSS compound is reacted with an acid to selectively cleave bonds in the POSS rings to add functionalities thereto for grafting, polymerization or catalysis, to thus form new familes of POSS derived compounds. Also provided are the new compounds so formed. Method is also provided for expanding rings of POSS compounds. Per the inventive method, a POSS compound is reacted with silane reagents to obtain an expanded POSS framework with added Si ring substituends to form new families of POSS compounds. Also provided are the new compounds so formed.
摘要翻译： 提供了从其官能化衍生物或新的POSS物质选择性地打开多面体低聚倍半硅氧烷（POSS）化合物的环的方法。 按照本发明的方法，POSS化合物与酸反应以选择性地切割POSS环中的键，以便为其接枝，聚合或催化添加官能团，从而形成新的POSS衍生化合物。 还提供了如此形成的新化合物。 还提供了扩展POSS化合物环的方法。 根据本发明的方法，POSS化合物与硅烷试剂反应以获得具有添加的Si环取代基的扩展的POSS框架，以形成新的POSS化合物族。 还提供了如此形成的新化合物。
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4.发明授权
公开(公告)号：US5942638A
公开(公告)日：1999-08-24
申请号：US003083
申请日：1998-01-05
CPC分类号： C07F7/21 , C07F7/0878
摘要： A synthetic process for the selective preparation of reactive polyhedral oligomeric silsesquioxanes (POSS) as well as polyhedral oligomeric silicate (POS) (spherosilicate) is provided. The method claimed herein employs metal catalyzed metathesis reactions for the selective reaction of .alpha.-olefin containing polyhedral oligomeric silsesquioxanes or silicates with olefinic reagents bearing functionalities useful for grafting reactions, polymerization chemistry and sol-gel processes. The use of metal catalyzed metathesis chemistry to form both linear or network polyhedral silsesquioxane polymers directly from .alpha.-olefin-containing polyhedral oligomeric silsesquioxanes is also described.
摘要翻译： 提供了选择性制备反应性多面体低聚倍半硅氧烷（POSS）以及多面体低聚硅酸盐（POS）（硅藻土）的合成方法。 本文所要求的方法使用金属催化的复分解反应，用于选择性反应含α-烯烃的多面体低聚倍半硅氧烷或硅酸盐与含有可用于接枝反应，聚合化学和溶胶 - 凝胶方法的官能团的烯属试剂。 还描述了使用金属催化的复分解化学直接从含α-烯烃的多面体低聚倍半硅氧烷形成直链或网络多面体倍半硅氧烷聚合物。
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5.发明授权
公开(公告)号：US5939576A
公开(公告)日：1999-08-17
申请号：US3084
申请日：1998-01-05
CPC分类号： C07F7/21
摘要： A synthetic process for the selective preparation of reactive polyhedral oligomeric silsesquioxanes (POSS) as well as polyhedral oligomeric silicate (POS) (spherosilicate) is provided. The inventive process employs the use of metal catalyzed hydrosilylation reactions for the selective reaction of silane containing polyhedral oligomeric silsesquioxanes or silicates with olefinic reagents bearing functionalities useful for grafting reactions, polymerization chemistry and sol-gel processes. The invention also discloses metal-catalyzed hydrosulfidation reactions and metal-catalyzed hydrophosphidation reacttions for functionalization of polycyclic silicones.
摘要翻译： 提供了选择性制备反应性多面体低聚倍半硅氧烷（POSS）以及多面体低聚硅酸盐（POS）（硅藻土）的合成方法。 本发明方法采用金属催化的氢化硅烷化反应来选择性反应含硅烷的多面体低聚倍半硅氧烷或硅酸盐与含有可用于接枝反应，聚合化学和溶胶 - 凝胶法的官能团的烯属试剂。 本发明还公开了金属催化的加氢硫化反应和用于多环硅氧烷官能化的金属催化的氢磷化反应。
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公开(公告)号：US20100305282A1
公开(公告)日：2010-12-02
申请号：US12787145
申请日：2010-05-25
申请人： Joseph D. Lichtenhan , Xuan Fu , Marion R. Blue , Paul Wheeler , Rahul Misra , Sarah Morgan
发明人： Joseph D. Lichtenhan , Xuan Fu , Marion R. Blue , Paul Wheeler , Rahul Misra , Sarah Morgan
IPC分类号： C08G77/38
CPC分类号： C08F283/00 , B82Y30/00 , C08F283/12 , C08F289/00 , C08F291/00 , C08J3/20 , C08J3/203 , C08J3/226 , C08J5/005 , C08J2201/038 , C08J2483/00 , C08K5/549
摘要： A method of using metallized and nonmetallized nanostructured chemicals as surface and volume modification agents within polymers and on the surfaces of nano and macroscopic particulates and fillers. Because of their 0.5 nm-3.0 nm size, nanostructured chemicals can be utilized to greatly increase surface area, improve compatibility, and promote lubricity between surfaces at a length scale not previously attainable.
摘要翻译： 使用金属化和非金属化的纳米结构化学物质作为表面和体积改性剂在聚合物和纳米和宏观颗粒和填料的表面上的方法。 由于它们为0.5nm-3.0纳米尺寸的，纳米结构化的化学品可被用于大大增加的表面积，提高的相容性，并且在长度尺度先前无法达到促进表面之间的润滑性。
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公开(公告)号：US07612143B2
公开(公告)日：2009-11-03
申请号：US11466053
申请日：2006-08-21
IPC分类号： C08F8/00
CPC分类号： C08K5/549
摘要： Metallized nanostructured chemicals are incorporated at the molecular level as alloying agents for the reinforcement of polymer microstructures, including polymer coils, domains, chains, and segments. Direct blending processes are effective because of the tailorable compatibility of the metallized nanostructured chemicals with polymers.
摘要翻译： 金属化纳米结构化学品在分子水平上作为用于增强聚合物微结构的合金化剂，包括聚合物线圈，结构域，链和链段。 直接共混过程是有效的，因为金属化纳米结构化学品与聚合物的可定制的相容性。
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公开(公告)号：US07572872B2
公开(公告)日：2009-08-11
申请号：US11379993
申请日：2006-04-24
申请人： Jason T. Flodin , Joseph D. Lichtenhan , Joseph J. Schwab , Yi-Zhong An , Xuan Fu , Zachary Kemp
发明人： Jason T. Flodin , Joseph D. Lichtenhan , Joseph J. Schwab , Yi-Zhong An , Xuan Fu , Zachary Kemp
IPC分类号： C08F30/08
CPC分类号： A61L27/18 , A61L2400/12 , C08L83/04
摘要： Nanostructured chemicals such as polyhedral oligomeric silsesquioxanes, polyhedral oligomeric silicates, and polyhedral oligomeric metallasesquioxanes are attached to living and nonliving systems as biomaterials to provide a nanoscopic topology that favors biomimetic function and cellular modulation. The resulting surface is nanoscopically thin, nanoscopically dispersed, provides systematic chemistry, surface area, surface volume, surface topology, and is essentially free of impurities, and has controllable properties through selection of composition, R groups, nanostructure size and topology. Highly shape specific and chemically tailorable nanostructured molecules are sized to biological material dimensions and are compatible with all sterilization methods.
摘要翻译： 纳米结构化学物质如多面体低聚倍半硅氧烷，多面体低聚硅酸盐和多面体低聚金属氧化物倍半硅氧烷作为生物材料连接到生物和非活性体系上，以提供有利于仿生功能和细胞调节的纳米视觉拓扑结构。 所得表面纳米级薄，纳米级分散，提供系统化学，表面积，表面体积，表面拓扑，基本上不含杂质，通过选择组成，R基团，纳米结构尺寸和拓扑结构具有可控性。 高度形状的特定和化学可裁剪的纳米结构分子的大小适合生物材料尺寸，并与所有灭菌方法兼容。
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公开(公告)号：US07217683B1
公开(公告)日：2007-05-15
申请号：US10236461
申请日：2002-09-05
申请人： Rusty L. Blanski , Shawn H. Phillips , Stephen L. Rodgers , Joseph D. Lichtenhan , Joseph J. Schwab
发明人： Rusty L. Blanski , Shawn H. Phillips , Stephen L. Rodgers , Joseph D. Lichtenhan , Joseph J. Schwab
IPC分类号： C10M139/00 , C10M171/06
CPC分类号： C10M171/06 , C10M139/02 , C10M139/04 , C10M2227/02 , C10M2227/04 , C10N2220/082 , C10N2230/02 , C10N2230/06
摘要： Nanoscale chemicals based on polyhedral oligomeric silsesquioxanes (POSS) and polyhedral oligomeric silicates (POS) are taught as lubricants, mold release agents, and as additives to control the viscosity, lubrication, wear, and thermal properties of conventional lubricous materials. The precisely defined nanoscopic dimensions of POSS materials enable viscosity, miscibility, and thermal properties to be (increased) or reduced (decreased) as desired. A key feature to the successful tailoring of properties is the inherent thermal and chemical stability of the POSS/POS nanostructure and the ability to control its topology and chemical potential to match that of surfaces and other materials.
摘要翻译： 基于多面体低聚倍半硅氧烷（POSS）和多面体低聚硅酸盐（POS）的纳米级化学品被教导为润滑剂，脱模剂和作为添加剂，以控制常规润滑材料的粘度，润滑，磨损和热性能。 POSS材料的精确定义的纳米尺寸使得粘度，混溶性和热性能根据需要（增加）或减少（减少）。 成功定制性能的一个关键特征是POSS / POS纳米结构的固有热稳定性和化学稳定性，以及控制其拓扑和化学势能以匹配表面和其他材料的能力。
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公开(公告)号：US08680215B2
公开(公告)日：2014-03-25
申请号：US12787145
申请日：2010-05-25
申请人： Joseph D. Lichtenhan , Xuan Fu , Marion R. Blue , Paul Wheeler , Rahul Misra , Sarah Morgan
发明人： Joseph D. Lichtenhan , Xuan Fu , Marion R. Blue , Paul Wheeler , Rahul Misra , Sarah Morgan
IPC分类号： C08G77/04
CPC分类号： C08F283/00 , B82Y30/00 , C08F283/12 , C08F289/00 , C08F291/00 , C08J3/20 , C08J3/203 , C08J3/226 , C08J5/005 , C08J2201/038 , C08J2483/00 , C08K5/549
摘要： A method of using metallized and nonmetallized nanostructured chemicals as surface and volume modification agents within polymers and on the surfaces of nano and macroscopic particulates and fillers. Because of their 0.5 nm-3.0 nm size, nanostructured chemicals can be utilized to greatly increase surface area, improve compatibility, and promote lubricity between surfaces at a length scale not previously attainable.
摘要翻译： 使用金属化和非金属化的纳米结构化学物质作为表面和体积改性剂在聚合物和纳米和宏观颗粒和填料的表面上的方法。 由于它们的0.5nm-3.0nm的尺寸，可以利用纳米结构化学物质来大大增加表面积，提高相容性，并提高表面之间以前所未有的长度尺度的润滑性。
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