Amine polymer-modified nanoparticulate carriers
    1.
    发明授权
    Amine polymer-modified nanoparticulate carriers 失效
    胺聚合物改性纳米颗粒载体

    公开(公告)号:US07541017B2

    公开(公告)日:2009-06-02

    申请号:US11036814

    申请日:2005-01-14

    IPC分类号: A61K51/00 B01J13/00 C09D11/00

    摘要: The invention relates to a composition comprising a colloid which is stable under physiological pH and ionic strength, said colloid comprising particles having a silica core and a shell: a) wherein said shell comprises a cross-linked poly(ethylene)imine polymer having amine functionalities; b) wherein the particles have a volume-weighted mean particle size diameter of less than 200 nm, and c) wherein greater than 50% of said polymer in the colloid is bound to the core surfaces, wherein the polymer having amine functionalities has an average molecular weight less than 100,000 g/mol, the composition has a H of between 6 and 8; and d) wherein the colloid contains between 300 and 6000 .μmol amine-monomer/g core particles.

    摘要翻译: 本发明涉及包含在生理pH和离子强度下稳定的胶体的组合物,所述胶体包含具有二氧化硅芯和壳的颗粒:a)其中所述壳包含具有胺官能团的交联聚(亚乙基)亚胺聚合物 ; b)其中所述颗粒具有小于200nm的体积加权平均粒度直径,和c)其中胶体中大于50%的所述聚合物与核表面结合,其中具有胺官能团的聚合物具有平均值 分子量小于100,000g / mol,组合物的H为6至8; 和d)其中所述胶体含有300至6000μmol胺单体/ g核心颗粒。

    Colloidal core-shell assemblies and methods of preparation
    3.
    发明授权
    Colloidal core-shell assemblies and methods of preparation 有权
    胶体核壳组件及其制备方法

    公开(公告)号:US08287952B2

    公开(公告)日:2012-10-16

    申请号:US11036752

    申请日:2005-01-14

    IPC分类号: B05D7/00 B05D3/10 A61K9/14

    摘要: This invention relates to a method of making a composition comprising a colloid comprising particles having a colloidal silica core and a shell, said method comprising the steps of: simultaneously introducing into a vessel a first liquid stream containing silica core particles, a second liquid stream containing a polymer having amine functionalities; and a third liquid stream having a pH adjusting substance such that said vessel is maintained at a pH below 6.0, and followed by readjusting the pH of the colloid to a pH between about 7-10; the addition of a cross-linking reagent, and adjusting the pH of the colloid to approximately physiological conditions, wherein the core-shell colloid contains between 10 and 30 μmol amine-monomer/m2 core surface area.

    摘要翻译: 本发明涉及一种制备包含胶体的组合物的方法,所述胶体包含具有胶体二氧化硅芯和壳的颗粒,所述方法包括以下步骤:同时向容器中引入含有二氧化硅核颗粒的第一液流,含有 具有胺官能团的聚合物; 以及具有pH调节物质的第三液体流,使得所述容器保持在低于6.0的pH,然后将胶体的pH调节至约7-10之间的pH; 加入交联剂,并将胶体的pH值调节至约生理条件,其中核 - 壳胶体含有10至30μmol胺单体/ m2核心表面积。

    Silver halide imaging element containing sequestered silver ions

    公开(公告)号:US06649330B2

    公开(公告)日:2003-11-18

    申请号:US10033517

    申请日:2001-12-28

    IPC分类号: G03C1295

    摘要: In accordance with one embodiment of the invention, a photographic element is described comprising a support bearing one or more hydrophilic colloid layers including at least one photographic silver halide emulsion layer, wherein sequestered silver ions are incorporated into at least one hydrophilic colloid layer in the form of a silver ion containing material which sequesters silver ions prior to photographic processing and releases silver ions upon exposure to photographic processing solutions. Method for preparing and processing such photographic element are also described. In accordance with particular embodiments of the invention, the silver ion containing material comprises a silver ion-exchanged zeolite material or an intercalation composition comprising a layered host material having silver ions inserted as guest ions between the layers of the host material. The invention provides novel photographic materials and a method of incorporating silver ions directly into a photographic imaging element with improved stability and keeping response. The incorporation of silver ion containing materials into a photographic element in accordance with the invention enables increased upper scale density without excessive build-up of fog in the system.

    Photocomposite, light source and thermal detector

    公开(公告)号:US10568726B2

    公开(公告)日:2020-02-25

    申请号:US15228651

    申请日:2016-08-04

    IPC分类号: A61C13/15 A61C1/00

    摘要: The invention provides a dental curing device comprising a light source having a wavelength capable of inducing polymerization of a photopolymer, and a noncontact thermal detector in alignment with said light source and capable of measuring the temperature or temperature change of the photopolymer upon polymerization.

    LIGHT SOURCE, DETECTOR AND LUMINESCENT COMPOSITE
    6.
    发明申请
    LIGHT SOURCE, DETECTOR AND LUMINESCENT COMPOSITE 审中-公开
    光源,检测器和发光复合材料

    公开(公告)号:US20160113746A1

    公开(公告)日:2016-04-28

    申请号:US14923435

    申请日:2015-10-27

    IPC分类号: A61C13/15 A61K6/083 A61K6/00

    摘要: The present invention relates to a system comprising photopolymerizable composites and an associated light polymerization device. The composite comprises a photopolymerizable resin and a luminophore, and optionally inorganic fillers and a photobleaching agent. The polymerization device comprises a light source and a photodetector. The composite and the device are coupled via a feedback loop to indicate the degree of polymerization, or to indicate that polymerization is complete. The invention relates to any photopolymerizable composite or coating including industrial, protective, biomedical and dental composites and coatings.

    摘要翻译: 本发明涉及包含光聚合复合物和相关联的光聚合装置的系统。 复合材料包括光聚合树脂和发光体,以及任选的无机填料和光漂白剂。 聚合装置包括光源和光电检测器。 复合材料和器件通过反馈环耦合以指示聚合度,或指示聚合完成。 本发明涉及任何可光聚合的复合材料或涂层,包括工业,保护,生物医学和牙科复合材料和涂层。

    IMAGE RECORDING ELEMENT COMPRISING ENCAPSULATED MORDANT PARTICLES
    7.
    发明申请
    IMAGE RECORDING ELEMENT COMPRISING ENCAPSULATED MORDANT PARTICLES 有权
    包含加密颗粒的图像记录单元

    公开(公告)号:US20080160228A1

    公开(公告)日:2008-07-03

    申请号:US11617777

    申请日:2006-12-29

    IPC分类号: B41M5/40 B41J29/38

    CPC分类号: B41M5/5245 B41M5/5218

    摘要: The present invention discloses an ink printing method using an image-recording element, which provides an image having excellent image quality and superior dry time, comprising insoluble cationic core-shell polymeric particles each comprising a core comprising cationic core polymer having at least 10 mole percent of a cationic mordant monomeric unit and a shell comprising hydrophilic shell polymer that is substantially less cationic than the cationic core polymer, wherein the shell is at least 10% by weight of the core.

    摘要翻译: 本发明公开了一种使用图像记录元件的油墨印刷方法,该图像记录元件提供具有优异图像质量和优异干燥时间的图像,其包含不溶性阳离子核 - 壳聚合物颗粒,其各自包含包含至少10摩尔% 的阳离子媒染剂单体单元和包含亲水壳聚合物的壳体,其阳离子比阳离子芯聚合物基本上少得多,其中壳体至少为核心重量的10%。

    Silver ion sequester and release agent
    10.
    发明授权
    Silver ion sequester and release agent 失效
    银离子螯合剂和脱模剂

    公开(公告)号:US06689335B1

    公开(公告)日:2004-02-10

    申请号:US10324234

    申请日:2002-12-19

    IPC分类号: C01B1516

    摘要: A silver ion sequester and release agent is described which comprises a silver ion exchangeable material of the formula: M(H1−x−yAgxM′yPO4)2.nH2O; where M is Zr, Ti, Sn, Ge or Hf or any combination thereof; M′ is an Alkali or alkaline earth metal; x is a number from 0.10 to 0.80; y is a number from 0.15 to 0.85; (x+y) is a number from 0.25 to 0.95; and n is a rational number between 0 and 10. Processes for preparing such silver ion sequester and release agent material are also described comprising combining in an aqueous medium a crystalline or amorphous metal hydrogen phosphate ion exchange host material of the formula M(HPO4)2.nH2O with less than 2 molar equivalents of silver ions relative to the amount of ion exchange host material such that silver ions are exchanged for protons in the host material, and adding a base compound to the aqueous medium to achieve a pH of at least 4.4 and sequester at least 95% of the combined silver ions into the host material. Further described are photographic elements comprising a support bearing one or more hydrophilic colloid layers including at least one photographic silver halide emulsion layer, wherein one or more layers contain such a silver ion sequester and release agent which sequesters silver ions prior to photographic processing and releases silver ions upon exposure to photographic processing solutions.

    摘要翻译: 描述了银离子螯合剂和脱模剂,其包含下式的银离子可交换材料:其中M是Zr,Ti,Sn,Ge或Hf或其任何组合; M'是碱金属或碱土金属; x是从0.10到0.80的数字; y为0.15〜0.85的数; (x + y)为0.25〜0.95的数; 还描述了制备这种银离子螯合剂和脱模剂材料的方法,其包括在水性介质中结合式M(HPO 4)2的结晶或无定形金属磷酸氢盐离子交换主体材料 相对于离子交换主体材料的量使用小于2摩尔当量的银离子,使得银离子在主体材料中交换为质子,并将碱性化合物加入到水性介质中以达到至少4.4的pH 并将至少95%的组合银离子螯合到主体材料中。 进一步描述的是包含承载一个或多个亲水胶体层的载体的照相元件,所述亲水胶体层包括至少一个照相卤化银乳剂层,其中一个或多个层含有这样的银离子螯合物和释放剂,其在照相处理之前螯合银离子并释放银 暴露于照相处理溶液中的离子。