公开(公告)号：US20150159089A1

公开(公告)日：2015-06-11

申请号：US14374865

申请日：2013-03-25

申请人： Jouji Kawamura ,  Makoto Negishi ,  Yoshinori Iwashita

发明人： Jouji Kawamura ,  Makoto Negishi ,  Yoshinori Iwashita

IPC分类号： C09K19/44 ,  C09K19/30 ,  C09K19/12

CPC分类号： C09K19/44 ,  C09K19/12 ,  C09K19/20 ,  C09K19/3003 ,  C09K19/3066 ,  C09K19/42 ,  C09K2019/0466 ,  C09K2019/122 ,  C09K2019/123 ,  C09K2019/3004 ,  C09K2019/301 ,  C09K2019/3016 ,  C09K2019/3025 ,  G02F1/133377 ,  Y10T428/10

摘要： It is an object of the present invention to provide a liquid crystal composition having a positive Δ∈, the liquid crystal composition also having a liquid crystal phase in a wide temperature range, a good resistance to resolution at low temperature, an excellent adaptability to an ODF process, a high specific resistance and voltage holding ratio, and stability to heat and light. In order to achieve this object, a liquid crystal composition containing compounds represented by Formulae (i) and (ii) is provided. (where Ri1 represents an alkyl group having 1 to 5 carbon atoms or an alkenyl group having 2 to 5 carbon atoms).

摘要翻译： 本发明的目的是提供一种具有正的＆Dgr;∈的液晶组合物，液晶组合物在宽的温度范围内也具有液晶相，在低温下具有良好的耐分辨能力，适用于 ODF工艺，高电阻率和电压保持率，以及对热和光的稳定性。 为了达到这个目的，提供了含有由式（ⅰ）和（ⅱ）表示的化合物的液晶组合物。 （其中，R 1表示碳原子数1〜5的烷基或碳原子数2〜5的烯基）。

公开(公告)号：US20160068751A1

公开(公告)日：2016-03-10

申请号：US14353184

申请日：2013-03-26

申请人： Yoshinori Iwashita ,  Makoto Negishi

发明人： Yoshinori Iwashita ,  Makoto Negishi

IPC分类号： C09K19/30

摘要： There is provided a liquid crystal composition having a negative dielectric anisotropy and containing at least one compound represented by General Formula (I) and at least one compound represented by General Formula (II). There is also provided a liquid crystal display device involving use of such a liquid crystal composition having a negative dielectric anisotropy and containing at least one compound represented by General Formula (I) and at least one compound represented by General Formula (II).

摘要翻译： 提供具有负介电各向异性并含有至少一种由通式（I）表示的化合物和至少一种由通式（II）表示的化合物的液晶组合物。 还提供了一种液晶显示装置，其包括使用这种具有负介电各向异性并含有至少一种由通式（I）表示的化合物和至少一种由通式（II）表示的化合物的化合物的液晶组合物。

公开(公告)号：US07651630B2

公开(公告)日：2010-01-26

申请号：US11817203

申请日：2006-02-27

申请人： Shotaro Kawakami ,  Takashi Matsumoto ,  Tetsuo Kusumoto ,  Yoshitaka Saito ,  Yutaka Nagashima ,  Makoto Negishi ,  Masayuki Iwakubo

发明人： Shotaro Kawakami ,  Takashi Matsumoto ,  Tetsuo Kusumoto ,  Yoshitaka Saito ,  Yutaka Nagashima ,  Makoto Negishi ,  Masayuki Iwakubo

IPC分类号： C09K19/00 ,  C09K19/06 ,  C09K19/52

CPC分类号： C09K19/3066 ,  C09K2019/0407 ,  Y10T428/10

摘要： A nematic liquid crystal composition of the present invention includes 10 to 80% by mass of either one or at least two compounds represented by general formula (I) as a first component; and 20 to 70% by mass of either one or at least two compounds represented by general formula (II) as a second component, wherein a dielectric constant anisotropy is negative. The use of this nematic liquid crystal composition can provide a highly reliable liquid crystal display element capable of maintaining a high voltage-holding ratio even in a high temperature region, and achieving quick responsiveness without reducing the cell gap.

摘要翻译： 本发明的向列型液晶组合物含有10〜80质量％的作为第1成分的通式（I）所示的1种或2种以上的化合物。 和20〜70质量％的作为第二成分的通式（II）表示的一种或至少两种化合物，其中介电常数各向异性为负。 使用这种向列型液晶组合物可以提供即使在高温区域也能保持高电压保持率的高度可靠的液晶显示元件，并且在不减小电池间隙的情况下实现快速响应。

公开(公告)号：US20090050843A1

公开(公告)日：2009-02-26

申请号：US11817203

申请日：2006-02-27

申请人： Shotaro Kawakami ,  Takashi Matsumoto ,  Tetsuo Kusumoto ,  Yoshitaka Saito ,  Yutaka Nagashima ,  Makoto Negishi ,  Masayuki Iwakubo

发明人： Shotaro Kawakami ,  Takashi Matsumoto ,  Tetsuo Kusumoto ,  Yoshitaka Saito ,  Yutaka Nagashima ,  Makoto Negishi ,  Masayuki Iwakubo

IPC分类号： C09K19/08 ,  C07C43/225

CPC分类号： C09K19/3066 ,  C09K2019/0407 ,  Y10T428/10

摘要： A nematic liquid crystal composition of the present invention includes 10 to 80% by mass of either one or at least two compounds represented by general formula (I) as a first component; and 20 to 70% by mass of either one or at least two compounds represented by general formula (II) as a second component, wherein a dielectric constant anisotropy is negative. The use of this nematic liquid crystal composition can provide a highly reliable liquid crystal display element capable of maintaining a high voltage-holding ratio even in a high temperature region, and achieving quick responsiveness without reducing the cell gap.

摘要翻译： 本发明的向列型液晶组合物含有10〜80质量％的作为第1成分的通式（I）所示的1种或2种以上的化合物。 和20〜70质量％的作为第二成分的通式（II）表示的一种或至少两种化合物，其中介电常数各向异性为负。 使用这种向列型液晶组合物可以提供即使在高温区域也能保持高电压保持率的高度可靠的液晶显示元件，并且在不减小电池间隙的情况下实现快速响应。

公开(公告)号：US5295302A

公开(公告)日：1994-03-22

申请号：US49656

申请日：1993-04-21

申请人： Toru Takai ,  Toshio Koshizuka ,  Tutomu Sunaga ,  Makoto Negishi

发明人： Toru Takai ,  Toshio Koshizuka ,  Tutomu Sunaga ,  Makoto Negishi

IPC分类号： B21C37/14 ,  B23K1/00 ,  B23P15/26 ,  F28D1/03 ,  F28F3/02 ,  F28F9/18

CPC分类号： B21C37/14 ,  B23K1/0012 ,  B23P15/26 ,  F28D1/0316 ,  F28F3/027 ,  F28F9/18 ,  Y10T29/49366 ,  Y10T29/49373 ,  Y10T29/49393

摘要： An aluminum heat exchanger is made from flat aluminum tubes formed with side edge projections having engaging surfaces and coated with brazing material on the outside surface but not on the inside surface of the tube or the projections. The opposite ends of the tubes are inserted into flat tube insertion holes in opposed header tanks which have a brazing material coated on the peripheral surface of the tank, so that, during brazing of the assembled heat exchanger components, brazing material flows from the header tanks to the engaging surfaces of the flat tubes.

摘要翻译： 铝制热交换器由平面铝管制成，该铝管形成有具有接合表面的侧边突起并且在外表面上而不是在管的内表面或突起上涂覆有钎焊材料。 管的相对端插入到相对的集管箱中的扁平管插入孔中，其具有涂覆在罐的周边表面上的钎焊材料，使得在组装的热交换器部件的钎焊期间，钎焊材料从集管箱 到扁平管的接合表面。

公开(公告)号：US20080111107A1

公开(公告)日：2008-05-15

申请号：US11793132

申请日：2005-12-14

申请人： Shotaro Kawakami ,  Takashi Matsumoto ,  Tetsuo Kusumoto ,  Yoshitaka Saito ,  Yutaka Nagashima ,  Makoto Negishi ,  Masayuki Iwakubo

发明人： Shotaro Kawakami ,  Takashi Matsumoto ,  Tetsuo Kusumoto ,  Yoshitaka Saito ,  Yutaka Nagashima ,  Makoto Negishi ,  Masayuki Iwakubo

IPC分类号： C09K19/30 ,  C07C43/225

CPC分类号： C09K19/42 ,  C09K19/3066 ,  C09K2019/0407 ,  Y10T428/10

摘要： The present invention provides a liquid crystal composition having a negative dielectric anisotropy whose absolute value is large, and a low viscosity, and also provides a VA type liquid crystal element using the same.Disclosed is a liquid crystal composition containing a compound represented by the general formula (I) and an alkenyl compound represented by the general formula (II): By combining the liquid compounds according to the present invention, a liquid crystal composition having a low viscosity and a negative dielectric anisotropy could be obtained while nearly maintaining physical properties such as refractive anisotropy. By using the composition, a liquid crystal element having excellent reliability, capable of maintaining a high voltage retention until a high temperature region, is provided, and the display is very applicable as a VA type, ECB type, or IPS type liquid crystal display, and is particularly effective for speeding up response without thinning cell gaps.

摘要翻译： 本发明提供一种具有绝对值大且低粘度的负介电各向异性的液晶组合物，并且还提供使用该液晶组合物的VA型液晶元件。 公开了含有通式（I）表示的化合物和通式（II）表示的烯基化合物的液晶组合物：通过将本发明的液体化合物与低粘度的液晶组合物和 在几乎保持诸如折射各向异性的物理性质的同时，可以获得负的介电各向异性。 通过使用该组合物，提供了具有优异的可靠性，能够保持高电压保持直到高温区域的液晶元件，并且显示器非常适用于VA型，ECB型或IPS型液晶显示器， 并且对于加快响应特别有效，而不会使单元间隙变薄。

公开(公告)号：US06468607B1

公开(公告)日：2002-10-22

申请号：US09296550

申请日：1999-04-22

申请人： Sadao Takehara ,  Masashi Osawa ,  Haruyoshi Takatsu ,  Makoto Negishi

发明人： Sadao Takehara ,  Masashi Osawa ,  Haruyoshi Takatsu ,  Makoto Negishi

IPC分类号： C09K1932

CPC分类号： C07C17/2637 ,  C07C17/263 ,  C07C17/2632 ,  C07C17/2635 ,  C07C17/269 ,  C07C17/354 ,  C07C25/18 ,  C07C25/22 ,  C07C25/24 ,  C07C255/50 ,  C07C2601/14 ,  C07C2602/28 ,  C09K19/322 ,  Y10T428/10

摘要： Disclosed is a novel liquid-crystalline compound which is a naphthalene derivative useful as an electro-optical liquid crystal display material, a liquid crystal composition containing such naphthalene derivatives and a liquid crystal display device comprising the same. The naphthalene derivative provided by the present invention exhibits an excellent liquid-crystallinity and miscibility with currently widely used liquid crystal compositions or compositions. The addition of the naphthalene derivative makes it possible to drastically lower the threshold voltage of the liquid crystal composition while maintaining its high response. The naphthalene derivative of the present invention is characterized by a large birefringence index. Further, most of the naphthalene derivative of the present invention has no strongly polar group in its molecule and thus can also be used for active matrix driving. Moreover, as shown in the foregoing examples, the naphthalene derivative of the present invention can be easily produced and is colorless and chemically stable. Accordingly, the liquid crystal composition comprising the naphthalene derivative of the present invention is extremely useful as a practical liquid crystal composition, particularly a liquid crystal composition which can operate within a wide temperature range and requires a high speed response and a low voltage driving.

摘要翻译： 公开了一种新颖的液晶化合物，它是一种可用作电光液晶显示材料的萘衍生物，含有该衍生物的液晶组合物和包含该衍生物的液晶显示装置。 由本发明提供的萘衍生物与当前广泛使用的液晶组合物或组合物显示出优异的液晶性和混溶性。 通过加入萘衍生物可以使液晶组合物的阈值电压大大降低，同时保持其高响应性。 本发明的萘衍生物的特征在于双折射率大。 此外，本发明的大多数萘衍生物在其分子中没有强极性基团，因此也可用于有源矩阵驱动。 此外，如前述实施例所示，本发明的萘衍生物可以容易地制备，并且是无色和化学稳定的。 因此，含有本发明的萘衍生物的液晶组合物作为实用的液晶组合物，特别是能够在宽温度范围内工作并需要高速响应和低电压驱动的液晶组合物是非常有用的。

公开(公告)号：US07670504B2

公开(公告)日：2010-03-02

申请号：US11793132

申请日：2005-12-14

申请人： Shotaro Kawakami ,  Takashi Matsumoto ,  Tetsuo Kusumoto ,  Yoshitaka Saito ,  Yutaka Nagashima ,  Makoto Negishi ,  Masayuki Iwakubo

发明人： Shotaro Kawakami ,  Takashi Matsumoto ,  Tetsuo Kusumoto ,  Yoshitaka Saito ,  Yutaka Nagashima ,  Makoto Negishi ,  Masayuki Iwakubo

IPC分类号： C09K19/00 ,  C09K19/06 ,  C09K19/52

CPC分类号： C09K19/42 ,  C09K19/3066 ,  C09K2019/0407 ,  Y10T428/10

摘要： The present invention provides a liquid crystal composition having a negative dielectric anisotropy whose absolute value is large, and a low viscosity, and also provides a VA type liquid crystal element using the same.Disclosed is a liquid crystal composition containing a compound represented by the general formula (I) and an alkenyl compound represented by the general formula (II): By combining the liquid compounds according to the present invention, a liquid crystal composition having a low viscosity and a negative dielectric anisotropy could be obtained while nearly maintaining physical properties such as refractive anisotropy. By using the composition, a liquid crystal element having excellent reliability, capable of maintaining a high voltage retention until a high temperature region, is provided, and the display is very applicable as a VA type, ECB type, or IPS type liquid crystal display, and is particularly effective for speeding up response without thinning cell gaps.

摘要翻译： 本发明提供一种具有绝对值大且低粘度的负介电各向异性的液晶组合物，并且还提供使用该液晶组合物的VA型液晶元件。 公开了含有通式（I）表示的化合物和通式（II）表示的烯基化合物的液晶组合物：通过将本发明的液体化合物与低粘度的液晶组合物和 在几乎保持诸如折射各向异性的物理性质的同时，可以获得负的介电各向异性。 通过使用该组合物，提供了具有优异的可靠性，能够保持高电压保持直到高温区域的液晶元件，并且显示器非常适用于VA型，ECB型或IPS型液晶显示器， 并且对于加快响应特别有效，而不会使单元间隙变薄。

公开(公告)号：US07145047B2

公开(公告)日：2006-12-05

申请号：US10224424

申请日：2002-08-21

申请人： Sadao Takehara ,  Masashi Osawa ,  Haruyoshi Takatsu ,  Makoto Negishi

发明人： Sadao Takehara ,  Masashi Osawa ,  Haruyoshi Takatsu ,  Makoto Negishi

IPC分类号： C07C23/18 ,  C07C23/36 ,  C09K19/32

CPC分类号： C07C17/2637 ,  C07C17/263 ,  C07C17/2632 ,  C07C17/2635 ,  C07C17/269 ,  C07C17/354 ,  C07C25/18 ,  C07C25/22 ,  C07C25/24 ,  C07C255/50 ,  C07C2601/14 ,  C07C2602/28 ,  C09K19/322 ,  Y10T428/10

摘要： Disclosed in a novel liquid-crystalline compound which is a naphthalene derivative useful as an electro-optical liquid crystal display material, a liquid crystal composition containing such naphthalene derivatives and a liquid crystal display device comprising the same. The naphthalene derivative provided by the present invention exhibits an excellent liquid-crystallinity and miscibility with currently widely used liquid crystal compositions or compositions. The addition of the naphthalene derivative makes it possible to drastically lower the threshold voltage of the liquid crystal composition while maintaining its high response. The naphthalene derivative of the present invention is characterized by a large birefringence index. Further, most of the naphthalene derivative of the present invention has no strongly polar group in its molecule and thus can also be used for active matrix driving. Moreover, as shown in the foregoing examples, the naphthalene derivative of the present invention can be easily produced and is colorless and chemically stable. Accordingly, the liquid crystal composition comprising the naphthalene derivative of the present invention is extremely useful as a practical liquid crystal composition, particularly a liquid crystal composition which can operate within a wide temperature range and requires a high speed response and a low voltage driving.

公开(公告)号：US06913797B1

公开(公告)日：2005-07-05

申请号：US09763531

申请日：1999-08-23

申请人： Shinji Ogawa ,  Hiroyuki Ohnishi ,  Yutaka Nagashima ,  Sadao Takehara ,  Makoto Negishi ,  Haruyoshi Takatsu ,  Gerwald Grahe ,  Rainer Bruno Frings ,  Christine Fugger ,  Cornelia Pithart

发明人： Shinji Ogawa ,  Hiroyuki Ohnishi ,  Yutaka Nagashima ,  Sadao Takehara ,  Makoto Negishi ,  Haruyoshi Takatsu ,  Gerwald Grahe ,  Rainer Bruno Frings ,  Christine Fugger ,  Cornelia Pithart

IPC分类号： C07C13/50 ,  C07C17/00 ,  C07C17/12 ,  C07C17/26 ,  C07C17/354 ,  C07C22/08 ,  C07C25/22 ,  C07C25/24 ,  C07C45/00 ,  C07C45/62 ,  C07C45/69 ,  C07C47/277 ,  C07C47/47 ,  C07C255/49 ,  C07C255/50 ,  C07C255/55 ,  C09K19/32 ,  C09K19/34 ,  C07C43/225 ,  C07D317/72

CPC分类号： C09K19/322 ,  C07C13/50 ,  C07C17/00 ,  C07C17/12 ,  C07C17/263 ,  C07C17/2632 ,  C07C17/2635 ,  C07C17/354 ,  C07C22/08 ,  C07C25/22 ,  C07C25/24 ,  C07C45/00 ,  C07C45/62 ,  C07C45/69 ,  C07C47/277 ,  C07C47/47 ,  C07C255/49 ,  C07C255/50 ,  C07C255/55 ,  C07C2601/14 ,  C07C2602/28 ,  C09K2019/3004 ,  C09K2019/301 ,  C09K2019/3075 ,  C09K2019/326 ,  C09K2019/3408 ,  C09K2019/3425 ,  C09K2019/3433 ,  C09K2019/3438 ,  Y10T428/10 ,  C07C47/457 ,  C07C47/24 ,  C07C49/447 ,  C07C49/637

摘要： The present invention discloses a decahydronaphthalene derivative represented by general formula (I): a liquid crystal composition in which it is contained, and a liquid crystal device in which it is used. The novel decahydronaphthalene derivative of the present invention can be produced industrially extremely easily as shown in the examples, and by adding a small amount to a base liquid crystal, it is possible to have effects that expand the nematic phase temperature range, thereby improving its various characteristics as a nematic liquid crystal. Moreover, the novel decahydronaphthalene derivative of the present invention also has superior co-solubility with base liquid crystals generally used at present. Thus, it is suitable for various types of liquid crystal devices requiring a wide operating temperature range, and is extremely useful as a liquid crystal material.

摘要翻译： 本发明公开了通式（I）表示的十氢萘衍生物：其中含有的液晶组合物及其使用的液晶装置。 如实施例所示，本发明的新型十氢萘衍生物可以在工业上极容易地制造，通过少量添加到基体液晶中，可以具有使向列相温度范围扩大的效果， 作为向列液晶的特性。 此外，本发明的新型十氢萘衍生物与目前通常使用的基础液晶也具有优异的共溶性。 因此，适用于需要宽工作温度范围的各种液晶装置，作为液晶材料是非常有用的。