公开(公告)号：US07868060B2

公开(公告)日：2011-01-11

申请号：US12024222

申请日：2008-02-01

申请人： Junichi Sakai ,  Kousuke Yamasaki ,  Katsuhiko Suzuki ,  Itaru Tsuji ,  Aki Takano ,  Hideki Takayama ,  Shin-ichi Sato

发明人： Junichi Sakai ,  Kousuke Yamasaki ,  Katsuhiko Suzuki ,  Itaru Tsuji ,  Aki Takano ,  Hideki Takayama ,  Shin-ichi Sato

IPC分类号： B05D1/36 ,  B05D5/00 ,  B05D7/00 ,  B32B9/04 ,  B32B27/00 ,  B41J2/01 ,  B41J2/17 ,  B41J2/175 ,  B60C7/00 ,  C08J3/00 ,  C08K3/00 ,  C08K3/04 ,  C08L31/00 ,  C08L33/00 ,  C09D5/02 ,  C09D11/00 ,  G01D11/00 ,  H01B1/12

CPC分类号： C09D11/322 ,  C09D11/326 ,  Y10T428/24802 ,  Y10T428/31504 ,  Y10T428/31855

摘要： Provided is an aqueous ink with high storage stability and scratch resistance at such a high level that the coloring material of an image is not scraped off even when lightly touched with a sharp product. The aqueous ink includes a water-insoluble coloring material and plural polymers. The plural polymers include a polymer A which relatively contributes to dispersion of the water-insoluble coloring material and a polymer B which does not relatively contribute to the dispersion of the water-insoluble coloring material compared to the polymer A. The polymer A includes a block copolymer having an acid value of 120 mgKOH/g to 180 mgKOH/g and having an ethylene oxide group as a nonionic group. The polymer B has an acid value of 150 mgKOH/g or less and a hydrogen bond parameter (δh) of the polymer obtained by solubility parameters of monomers constituting the polymer of 1.0 cal0.5/cm1.5 or more and 3.2 cal0.5/cm1.5 or less.

摘要翻译： 提供了一种具有高储存稳定性和耐刮擦性的水性油墨，即使在用尖锐的产品轻轻触摸时，图像的着色材料也不会被刮掉。 水性油墨包括水不溶性着色材料和多种聚合物。 多个聚合物包括相对于水不溶性着色材料的分散相对有利的聚合物A和与聚合物A相比不对水不溶性着色材料的分散不相关的聚合物B.聚合物A包括嵌段 共聚物，其酸值为120mgKOH / g至180mgKOH / g，并且具有环氧乙烷基团作为非离子基团。 聚合物B的酸值为150mgKOH / g以下，由构成聚合物的单体的溶解度参数得到的聚合物的氢键参数（δh）为3.2cal / /cm1.5以下。

公开(公告)号：US20080187726A1

公开(公告)日：2008-08-07

申请号：US12024222

申请日：2008-02-01

申请人： Junichi Sakai ,  Kousuke Yamasaki ,  Katsuhiko Suzuki ,  Itaru Tsuji ,  Aki Takano ,  Hideki Takayama ,  Shin-ichi Sato

发明人： Junichi Sakai ,  Kousuke Yamasaki ,  Katsuhiko Suzuki ,  Itaru Tsuji ,  Aki Takano ,  Hideki Takayama ,  Shin-ichi Sato

IPC分类号： B41M1/00 ,  C09D131/00 ,  B05D5/00 ,  G01D11/00 ,  B41J2/175

CPC分类号： C09D11/322 ,  C09D11/326 ,  Y10T428/24802 ,  Y10T428/31504 ,  Y10T428/31855

摘要： Provided is an aqueous ink with high storage stability and scratch resistance at such a high level that the coloring material of an image is not scraped off even when lightly touched with a sharp product. The aqueous ink includes a water-insoluble coloring material and plural polymers. The plural polymers include a polymer A which relatively contributes to dispersion of the water-insoluble coloring material and a polymer B which does not relatively contribute to the dispersion of the water-insoluble coloring material compared to the polymer A. The polymer A includes a block copolymer having an acid value of 120 mgKOH/g to 180 mgKOH/g and having an ethylene oxide group as a nonionic group. The polymer B has an acid value of 150 mgKOH/g or less and a hydrogen bond parameter (δh) of the polymer obtained by solubility parameters of monomers constituting the polymer of 1.0 cal0.5/cm1.5 or more and 3.2 cal0.5/cm1.5 or less.

摘要翻译： 提供了一种具有高储存稳定性和耐刮擦性的水性油墨，即使在用尖锐的产品轻轻触摸时，图像的着色材料也不会被刮掉。 水性油墨包括水不溶性着色材料和多种聚合物。 多个聚合物包括相对于水不溶性着色材料的分散相对有利的聚合物A和与聚合物A相比不对水不溶性着色材料的分散不相关的聚合物B.聚合物A包括嵌段 共聚物，其酸值为120mgKOH / g至180mgKOH / g，并且具有环氧乙烷基团作为非离子基团。 聚合物B的酸值为150mgKOH / g以下，由构成聚合物的单体的溶解度参数得到的聚合物的氢键参数（deltah）（1.0mI / 1.5以上且3.2±0.5±1.5±1.5以下。

公开(公告)号：US07909449B2

公开(公告)日：2011-03-22

申请号：US12121310

申请日：2008-05-15

申请人： Shin-ichi Sato ,  Hideki Takayama ,  Yoshihisa Yamashita ,  Kenji Nishiguchi ,  Aki Takano

发明人： Shin-ichi Sato ,  Hideki Takayama ,  Yoshihisa Yamashita ,  Kenji Nishiguchi ,  Aki Takano

IPC分类号： G01D11/00

CPC分类号： B41J2/16508

摘要： An ink jet recording apparatus is provided with a plurality of inks and includes a unit configured to perform a recovery operation by suction of inks from a plurality of ink ejection portions using a suction cap, wherein the plurality of inks include an ink set including a combination of at least a first ink and a second ink, the first ink containing (i) a self-dispersion pigment having at least one hydrophilic group directly or through another atomic group bonded to the surface of the pigment, and (ii) ammonium ions, the second ink containing a pigment, a polymer having an acid value of 160 mg KOH/g or less, and alkali metal ions, and the suction cap used in the recovery operation is individually provided for each of the first ink and the second ink.

摘要翻译： 一种喷墨记录装置设置有多种墨水，并且包括被配置为通过使用吸嘴从多个墨水喷射部分抽吸墨水进行恢复操作的单元，其中所述多种墨水包括包括组合的墨水组 至少第一油墨和第二油墨，所述第一油墨含有（i）具有至少一个亲水基团的自分散颜料，或通过与所述颜料的表面键合的另一原子团，和（ii）铵离子， 分别为第一墨水和第二墨水分别提供含有颜料的第二墨水，酸值为160mg KOH / g以下的聚合物和碱金属离子，以及用于回收操作的吸嘴。

公开(公告)号：US20080292794A1

公开(公告)日：2008-11-27

申请号：US12121310

申请日：2008-05-15

申请人： Shin-ichi Sato ,  Hideki Takayama ,  Yoshihisa Yamashita ,  Kenji Nishiguchi ,  Aki Takano

发明人： Shin-ichi Sato ,  Hideki Takayama ,  Yoshihisa Yamashita ,  Kenji Nishiguchi ,  Aki Takano

IPC分类号： B05D5/00 ,  G01D11/00 ,  B41J2/165

CPC分类号： B41J2/16508

摘要： An ink jet recording apparatus is provided with a plurality of inks and includes a unit configured to perform a recovery operation by suction of inks from a plurality of ink ejection portions using a suction cap, wherein the plurality of inks include an ink set including a combination of at least a first ink and a second ink, the first ink containing (i) a self-dispersion pigment having at least one hydrophilic group directly or through another atomic group bonded to the surface of the pigment, and (ii) ammonium ions, the second ink containing a pigment, a polymer having an acid value of 160 mg KOH/g or less, and alkali metal ions, and the suction cap used in the recovery operation is individually provided for each of the first ink and the second ink.

摘要翻译： 一种喷墨记录装置设置有多种墨水，并且包括被配置为通过使用吸嘴从多个墨水喷射部分抽吸墨水进行恢复操作的单元，其中所述多种墨水包括包括组合的墨水组 至少第一油墨和第二油墨，所述第一油墨含有（i）具有至少一个亲水基团的自分散颜料，或通过与所述颜料的表面键合的另一原子团，和（ii）铵离子， 分别为第一墨水和第二墨水分别提供含有颜料的第二墨水，酸值为160mg KOH / g以下的聚合物和碱金属离子，以及用于回收操作的吸嘴。

公开(公告)号：US08011777B2

公开(公告)日：2011-09-06

申请号：US12121289

申请日：2008-05-15

申请人： Yoshihisa Yamashita ,  Kenji Nishiguchi ,  Aki Takano

发明人： Yoshihisa Yamashita ,  Kenji Nishiguchi ,  Aki Takano

IPC分类号： G01D11/00

CPC分类号： C09D11/322 ,  C09D11/38 ,  C09D11/40

摘要： An ink set includes a combination of a first ink and a second ink, the first ink containing a self-dispersion pigment having at least one hydrophilic group directly or through another atomic group bonded to the surface of the pigment particle, and ammonium ions, the second ink containing a pigment, a polymer having an acid value of 160 mg KOH/g or less, and alkali metal ions, wherein the first ink further contains a compound (A) selected from nonionic surfactants and/or a compound (B) selected from the group consisting of polyethylene glycol with an average molecular weight of 600 to 2,000, α,ω-alkanediol having six carbon atoms, and an imidazolidinone derivative.

摘要翻译： 油墨组包括第一油墨和第二油墨的组合，第一油墨含有直接或通过与颜料颗粒表面结合的另一原子团的至少一个亲水基团的自分散颜料和铵离子， 含有颜料的第二油墨，酸值为160mg KOH / g以下的聚合物和碱金属离子，其中第一油墨还含有选自非离子表面活性剂和/或选自下列化合物（B）的化合物（A） 来自平均分子量为600〜2,000的聚乙二醇，具有6个碳原子的α，ω-链烷二醇和咪唑烷酮衍生物。

公开(公告)号：US20080292793A1

公开(公告)日：2008-11-27

申请号：US12121289

申请日：2008-05-15

申请人： Yoshihisa Yamashita ,  Kenji Nishiguchi ,  Aki Takano

发明人： Yoshihisa Yamashita ,  Kenji Nishiguchi ,  Aki Takano

IPC分类号： C09D11/02 ,  G01D11/00 ,  B05D5/00

CPC分类号： C09D11/322 ,  C09D11/38 ,  C09D11/40

摘要： An ink set includes a combination of a first ink and a second ink, the first ink containing a self-dispersion pigment having at least one hydrophilic group directly or through another atomic group bonded to the surface of the pigment particle, and ammonium ions, the second ink containing a pigment, a polymer having an acid value of 160 mg KOH/g or less, and alkali metal ions, wherein the first ink further contains a compound (A) selected from nonionic surfactants and/or a compound (B) selected from the group consisting of polyethylene glycol with an average molecular weight of 600 to 2,000, a,w-alkanediol having six carbon atoms, and an imidazolidinone derivative.

摘要翻译： 油墨组包括第一油墨和第二油墨的组合，第一油墨含有直接或通过与颜料颗粒表面结合的另一原子团的至少一个亲水基团的自分散颜料和铵离子， 含有颜料的第二油墨，酸值为160mg KOH / g以下的聚合物和碱金属离子，其中第一油墨还含有选自非离子表面活性剂和/或选自下列化合物（B）的化合物（A） 来自平均分子量为600〜2,000的聚乙二醇，具有6个碳原子的ω-链烷二醇和咪唑烷酮衍生物。