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    Ethylene copolymer and process for producing the same, resin composition containing the copolymer, and uses of these
    1.
    发明授权
    Ethylene copolymer and process for producing the same, resin composition containing the copolymer, and uses of these 有权
    乙烯共聚物及其制造方法，含有共聚物的树脂组合物及其用途

    公开(公告)号：US06462136B1

    公开(公告)日：2002-10-08

    申请号：US09582274

    申请日：2000-06-23

    申请人： Junji Saito ,  Keiji Okada ,  Kenichi Morizono ,  Makoto Mitani ,  Terunori Fujita

    发明人： Junji Saito ,  Keiji Okada ,  Kenichi Morizono ,  Makoto Mitani ,  Terunori Fujita

    IPC分类号： C08L2308

    CPC分类号： C08L23/04 ,  C08F210/16 ,  C08L23/0815 ,  C08L23/10 ,  C08L2314/06 ,  C08F4/64048 ,  C08L2666/04 ,  C08F210/06 ,  C08F2500/17 ,  C08F2500/03 ,  C08F2500/19 ,  C08F2500/20 ,  C08F210/08 ,  C08F4/64189 ,  C08F4/68

    摘要： The present invention is intended to provide an ethylene copolymer having excellent mechanical properties and moldability, a process for preparing the copolymer, a resin composition containing the copolymer and uses thereof. The ethylene copolymer has the following properties: the copolymer comprises 90 to 99% by mol of ethylene constituent units and 1 to 60% by mol of C3-20 &agr;-olefin constituent units; the ratio (Mz/Mw) of a Z average molecular weight (Mz) to a weight-average molecular weight (Mw), each molecular weight being measured by GPC, is in the range of 10 to 30, and said ratio (Mz/Mw) and the ratio (Mw/Mn) of a weight-average molecular weight (Mw) to a number-average molecular weight (Mn), each molecular weight being measured by GPC, satisfy the relation (Mz/Mw)>(Mw/Mn); the intrinsic viscosity is in the range of 0.5 to 9 dl/g; the ratio (n*0.01/n*8) of a melt viscosity (&eegr;*0.01) at a shear rate of 0.01 rad/sec, as measured at 190° C., to a melt viscosity (&eegr;*8) at a shear rate of 8 rad/sec, as measured at 190° C., and the intrinsic viscosity (&eegr;) satisfy the relation (&eegr;*0.01/&eegr;*8)≧0.893×(&eegr;)+1.0; and the absolute value of an activation energy (Ea) of a shift factor of melt viscoelasticity is not more than 4×104 J/mol.K.

    摘要翻译： 本发明旨在提供具有优异的机械性能和成型性的乙烯共聚物，制备共聚物的方法，含有该共聚物的树脂组合物及其用途。 乙烯共聚物具有以下性质：共聚物包含90-99摩尔％的乙烯构成单元和1至60摩尔％的C 3-20α-烯烃构成单元; 通过GPC测定的各分子量的Z平均分子量（Mz）与重均分子量（Mw）的比（Mz / Mw）在10〜30的范围内，所述比例（Mz / Mw）和通过GPC测定的各分子量的重均分子量（Mw）与数均分子量（Mn）的比（Mw / Mn）满足关系式（Mz / Mw）>（Mw / Mn）; 特性粘度在0.5〜9dl / g的范围内; 在190℃下，剪切速率为0.01rad / sec的熔体粘度（η* 0.01）与剪切时的熔体粘度（ηa* 8）的比（n * 0.01 / n * 8） 速度为8rad / sec，在190℃下测定，特性粘度（eta）满足关系式（eta * 0.01 / eta * 8）> = 0.893x（eta）+1.0; 熔体粘弹性变化系数的活化能（Ea）的绝对值不大于4×104J / mol·K。

    Ethylene polymer
    5.
    发明授权
    Ethylene polymer 有权
    乙烯聚合物

    公开(公告)号：US07452946B2

    公开(公告)日：2008-11-18

    申请号：US10553726

    申请日：2004-05-19

    申请人： Sadahiko Matsuura ,  Naoto Matsukawa ,  Makoto Mitani ,  Junji Saito ,  Terunori Fujita ,  Yasushi Tohi ,  Koji Endo ,  Kenji Iwamasa ,  Keiko Takahashi

    发明人： Sadahiko Matsuura ,  Naoto Matsukawa ,  Makoto Mitani ,  Junji Saito ,  Terunori Fujita ,  Yasushi Tohi ,  Koji Endo ,  Kenji Iwamasa ,  Keiko Takahashi

    IPC分类号： C08F4/6592 ,  C08F4/642 ,  C08F4/645 ,  C08F210/16

    CPC分类号： C08F210/16 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65927 ,  C08F10/00 ,  C08F4/65904 ,  C08F4/64048 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/11 ,  C08F2500/20 ,  C08F2500/14 ,  C08F2500/04

    摘要： An ethylene-based polymer which is a copolymer obtained from ethylene and a C3 to C10α-olefin and satisfies the following requirements (i), (ii), (iii) and (iv) simultaneously provides a blow-molded product and an extrusion-molded product excellent in moldability, mechanical strength and outward appearance. (i) melt flow rate [MFR2 (g/10 min)] under a loading of 2.16 kg at 190° C. is in the range of 0.01 to 10, (ii) melt tension [MT (g)] and the above melt flow rate [MFR2 (g/10 min)] satisfy the following relationship: MT≧3.2×MFR2−0.55, (iii) an activation energy [Ea] of fluidization is less than 30 (KJ/mol), and (iv) swell ratio is 1.36 or more. The ethylene-based polymer of the invention is preferably produced by copolymerizing ethylene with a C3 to C10 α-olefin, in the presence of a solid catalyst carrying, on (C) a solid carrier, a mixed transition metal compound consisting of (A1) a group 4 transition metal compound containing a specific salicyl aldimine ligand and (A2) a group 4 transition metal compound containing a specific cyclopentadienyl ligand and (B) at least one compound selected from (b-1) an organometallic compound, (b-2) an organoaluminum oxy compound, and (b-3) a compound reacting with the transition metal compound to form an ion pair.

    摘要翻译： 乙烯基聚合物是由乙烯和C 3〜C 10α-烯烃得到的共聚物，其满足以下要求（i），（ii），（iii）和（iv）同时提供吹塑成型品， 成型性，机械强度和外观优异的成型品。 （i）在190℃下2.16kg负荷下的熔体流动速率[MFR 2]（g / 10min）]在0.01至10的范围内，（ii）熔体张力[MT （g）]和上述熔体流动速率[MFR 2（g / 10min）]满足以下关系：MT> = 3.2×MFR 2 <-0.005 （iii）流化的活化能[Ea]小于30（KJ / mol），（iv）溶胀比为1.36以上。 本发明的乙烯类聚合物优选通过在（C）固体载体，由（A1）组成的混合过渡金属化合物的固体催化剂存在下，使乙烯与C 3至C 10α-烯烃共聚而制备， 含有特定水杨醛亚胺配体的第4族过渡金属化合物和（A2）含有特定环戊二烯基配体的第4族过渡金属化合物和（B）至少一种选自（b-1）有机金属化合物，（b-2） ）有机铝氧化合物，和（b-3）与过渡金属化合物反应形成离子对的化合物。

    Ethylene polymer
    7.
    发明申请
    Ethylene polymer 有权
    乙烯聚合物

    公开(公告)号：US20060199925A1

    公开(公告)日：2006-09-07

    申请号：US10553726

    申请日：2004-05-19

    申请人： Sadahiko Matsuura ,  Naoto Matsukawa ,  Makoto Mitani ,  Junji Saito ,  Terunori Fujita ,  Yasushi Tohi ,  Koji Endo ,  Kenji Iwamasa ,  Keiko Takahashi

    发明人： Sadahiko Matsuura ,  Naoto Matsukawa ,  Makoto Mitani ,  Junji Saito ,  Terunori Fujita ,  Yasushi Tohi ,  Koji Endo ,  Kenji Iwamasa ,  Keiko Takahashi

    IPC分类号： C08F4/44

    CPC分类号： C08F210/16 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65927 ,  C08F10/00 ,  C08F4/65904 ,  C08F4/64048 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/11 ,  C08F2500/20 ,  C08F2500/14 ,  C08F2500/04

    摘要： An ethylene-based polymer which is a copolymer obtained from ethylene and a C3 to C10α-olefin and satisfies the following requirements (i), (ii), (iii) and (iv) simultaneously provides a blow-molded product and an extrusion-molded product excellent in moldability, mechanical strength and outward appearance. (i) melt flow rate [MFR2 (g/10 min)] under a loading of 2.16 kg at 190° C. is in the range of 0.01 to 10, (ii) melt tension [MT (g)] and the above melt flow rate [MFR2 (g/10 min)] satisfy the following relationship: MT≧3.2×MFR2−0.55, (iii) an activation energy [Ea] of fluidization is less than 30 (KJ/mol), and (iv) swell ratio is 1.36 or more. The ethylene-based polymer of the invention is preferably produced by copolymerizing ethylene with a C3 to C10 α-olefin, in the presence of a solid catalyst carrying, on (C) a solid carrier, a mixed transition metal compound consisting of (A1) a group 4 transition metal compound containing a specific salicyl aldimine ligand and (A2) a group 4 transition metal compound containing a specific cyclopentadienyl ligand and (B) at least one compound selected from (b-1) an organometallic compound, (b-2) an organoaluminum oxy compound, and (b-3) a compound reacting with the transition metal compound to form an ion pair.

    摘要翻译： 乙烯基聚合物是由乙烯和C 3〜C 10α-烯烃得到的共聚物，其满足以下要求（i），（ii），（iii）和（iv）同时提供吹塑成型品， 成型性，机械强度和外观优异的成型品。 （i）在190℃下2.16kg负荷下的熔体流动速率[MFR 2]（g / 10min）]在0.01至10的范围内，（ii）熔体张力[MT （g）]和上述熔体流动速率[MFR 2（g / 10min）]满足以下关系：MT> = 3.2×MFR 2 <-0.005 （iii）流化的活化能[Ea]小于30（KJ / mol），（iv）溶胀比为1.36以上。 本发明的乙烯类聚合物优选通过在（C）固体载体，由（A1）组成的混合过渡金属化合物的固体催化剂存在下，使乙烯与C 3至C 10α-烯烃共聚而制备， 含有特定水杨醛亚胺配体的第4族过渡金属化合物和（A2）含有特定环戊二烯基配体的第4族过渡金属化合物和（B）至少一种选自（b-1）有机金属化合物，（b-2） ）有机铝氧化合物，和（b-3）与过渡金属化合物反应形成离子对的化合物。